• Journal of the Mineralogical Society of Korea
• /
• v.19 no.3 s.49
• /
• pp.189-195
• /
• 2006

Compression work on a pyrite powder has been carried out using energy dispersive X-ray diffraction (EDXRD) with Mao-Bell type diamond anvil cell (DAC) and synchrotron radiation(SR) at room temperature. It has been reported the bulk moduli of pyrite show the large variations depending on the experimental conditions as well as the apparatus used. Thus, two kinds of sample in different pressure transmitting media of both NaCl and MgO powder emerged in alcoholic fluids were subjected to measure their compressibilities. Bulk moduli thus obtained are 138.9 GPa and 198.2 GPa, respectively, and this result contradicts to the anticipated values according to the hydrostaticity conditions of the sample chamber. This might be due to the alcoholic fluids phase transition mainly with the side effects from the difference of both solid state detector (SSD) used and E*d value applied. All experiments were performed at the Beam Line 1B2 of Pohang Light Source (PLS).

• The Journal of the Petrological Society of Korea
• /
• v.3 no.1
• /
• pp.34-40
• /
• 1994

High pressure X-ray diffraction study was carried out on a graphite to investigate its compressibility as well as any possible phase transition to the hexagonal diamond structure at room temperature. Energy dispersive X-ray diffraction method was introduced using a Mao-Bell type diamond anvil cell with Synchrotron Radiation. Polycrystalline sodium chloride was compressed together with graphite for the high pressure determinations. Because of the poor resolution of the X-ray diffraction pattern of graphite, its compressibility was estimated to be almost same as that of NaCl by graphite (002) X-ray diffraction peak only. An observation of any new peak from a possible hexagonal diamond phase seems very unplausible for its definite identification based on the present data. Alternative approaches such as an Wiggler Radiation source as well as a Large Volume high pressure apparatus will be necessary for the detailed studies on a graphite in future.

• Journal of the Korean Society for Heat Treatment
• /
• v.21 no.5
• /
• pp.235-243
• /
• 2008

Ni-C composite films were prepared using a combination of microwave plasma CVD and ion beam sputtering deposition working in a codeposition way. The structure of these films was characterized by energy-dispersive X-ray diffraction (EDXRD), transmission electron microscopy (TEM) and Raman spectroscopy. It was found that a nickel carbide phase, $Ni_3C$ (hcp), formed as very fine crystallites over a wide temperature range when Ni-C films were deposited at low $CH_4$ flow rates. The thermal stability of this nonequilibrium carbide $Ni_3C$ was also studied. As a result, the $Ni_3C$ carbide was found to decompose into nickel and graphite at around $400^{\circ}C$. With high $CH_4$ flow rates (> 0.2 sccm), the structure of the Ni-C films became amorphous. The formation behavior of the carbide and amorphous Ni-C phases are discussed in relation to the electrical resistivity of the films.

• The Journal of the Petrological Society of Korea
• /
• v.5 no.2
• /
• pp.129-134
• /
• 1996

Possibile phase transitions of graphite have been examined experimentally using piston cylinder and DAC with synchrotron radiation. The graphite-forming processes in high pressure and low temperature conditions and the phase change under super high pressure were studied in the conditions of 0.7 Gpa and 270-$360^{\circ}C$ in piston cylinder and under 39.6 Gpa in DAC. In the piston cylinder experiment using LiCO3as a catalyzer, we could synthesize disordered graphites whose TGD values change progressively form 9 to 53. It was known that the temperature of graphitization in 0.7 Gpa is between 270-$300^{\circ}C$. Numerous unknown XRD peaks were observed in the super high-pressure experiment. However, it is difficult to pick up a new peak of a hexagonal diamond phase. Application of the different high pressure apparatus as well as a peculiar X-ray source and various graphite specimen would be useful for super high-pressure experiment, and more detailed works are needed to characterize the unknown phase(s) observed in this study.