• Bulletin of the Korean Chemical Society
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• v.35 no.8
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• pp.2271-2276
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• 2014

Second-order rate constants ($k_N$) have been measured spectrophotometrically for the reaction of 4-chloro-2-nitrophenyl X-substituted-benzoates (6a-6h) with a series of primary amines including hydrazine in 80 mol % $H_2O$/20 mol % DMSO at $25.0^{\circ}C$. The Br${\o}$nsted-type plot for the reaction of 4-chloro-2-nitrophenyl benzoate (6d) is linear with ${\beta}_{nuc}$ = 0.74 when hydrazine is excluded from the correlation. Such a linear Br${\o}$nsted-type plot is typical for reactions reported previously to proceed through a stepwise mechanism in which expulsion of the leaving group occurs in the rate-determining step (RDS). The Hammett plots for the reactions of 6a-6h with hydrazine and glycylglycine are nonlinear. In contrast, the Yukawa-Tsuno plots exhibit excellent linear correlations with ${\rho}_X$ = 1.29-1.45 and r = 0.53-0.56, indicating that the nonlinear Hammett plots are not due to a change in RDS but are caused by resonance stabilization of the substrates possessing an electron-donating group (EDG). Hydrazine is ca. 47-93 times more reactive than similarly basic glycylglycine toward 6a-6h (e.g., the ${\alpha}$-effect). The ${\alpha}$-effect increases as the substituent X in the benzoyl moiety becomes a stronger electron-withdrawing group (EWG), indicating that destabilization of the ground state (GS) of hydrazine through the repulsion between the nonbonding electron pairs on the two N atoms is not solely responsible for the substituent-dependent ${\alpha}$-effect. Stabilization of transition state (TS) through five-membered cyclic TSs, which would increase the electrophilicity of the reaction center or the nucleofugality of the leaving group, contributes to the ${\alpha}$-effect observed in this study.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.60 no.3
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• pp.217-227
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• 2024

To analyse and review the fishing performance and species composition according to the size of the entrance and mesh of the pot in the southern coastal waters (Tongyeong, Gyeongsangnam-do and Yeosu, Jeollanam-do), the experiment in this study caught one class, eight orders, 17 families, 23 species, 662 fishes, and 99,833 g. The largest number of fish species was Conger myriaster (301 fishes caught) accounting for 45.5%, followed by Octopus vulgaris (152) accounting for 23.0%, Charybdis japonica (45) accounting for 6.8%, Sebastiscus marmoratus (43) accounting for 6.5%, and Parapercis sexfasciata (42) accounting for 6.3%. Conger myriaster, Octopus vulgaris, Charybdis japonica, Sebastiscus marmoratus, and Parapercis sexfasciata accounted for 88.1% of the total catch. For other fish species, 68 fishes of 18 species were caught, accounting for 12.5% of the total. As a result of the total catch survey, the catch rate of Conger myriaster was the highest at 50.9% in B. 22 mm/280 mm. In addition, the average total length per fish increased as the entrance size increased. The weight ratios of Conger myriaster, Octopus vulgaris, and other fish species based on the total weight caught in each pots of the six species of test fishing gear are as follows. A pots 66.6%, 26.5%, 6.9%, B pots 57.2%, 24.5 %, 18.3%, C pots 43.2%, 31.5%, 25.3%, D pots 7.4%, 56.7%, 35.9%, E pots 43.6%, 0%, 56.4%, and F pots 5.0%, 79.6%, 15.4%.

• Korean Journal of Food Science and Technology
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• v.49 no.2
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• pp.173-180
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• 2017

This study evaluated the characteristics of rice cookies with varying amounts (0, 250, 500, and 750 mg) of dandelion complex powder. Dandelion powder is considered a functional food with skin-moisturizing and atopic skin improvement effects by KFDA. Quality characteristics of AF343 and rice cookies were measured by determining antimicrobial activities, physical characteristics, sensory evaluation values, and antioxidant activities. An antibiotic susceptibility test of the powder showed positive activities in Escherichia coli (O157:H7), Staphylococcus aureus, Bacillus cereus, and Listeria monocytogenes. Rice cookie containing 250-500 mg powder showed significantly increased antioxidant activities compared to controls (p<0.05). However, sensory intensities between the two sample groups were not significantly different. Thus, rice cookies containing 250-500 mg dandelion complex powder were successfully developed to improve antioxidant and antimicrobial qualities. These products may attract the attention of health-conscious consumers in the highly competitive cookie industry.

• Journal of the Korean Society of Food Science and Nutrition
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• v.44 no.11
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• pp.1700-1707
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• 2015

The effects of drying temperature on drying characteristics of soybeans with different grain sizes [6.0 (S), 7.5 (M), and 9.0 mm (L) (${\pm}0.2$)] with 25.0% (${\pm}0.8$) initial moisture content were studied. Drying temperatures varied at 25, 35, and $45^{\circ}C$, with a constant air velocity (13.2 m/s). Thin-layer drying models were applied to describe the drying process of soybeans. The Midilli-Kucuk model showed the best fit ($R^2$ >0.99). Based on the model parameters, drying time to achieve the target moisture content (10%) was successfully estimated. Drying time was strongly dependent on the size of soybeans and the drying temperature. The effective moisture diffusivity ($D_{eff}$) was estimated by the diffusion model based on Fick's second law. $D_{eff}$ values increased as grain size and drying temperature increased due to the combined effect of high temperatures and high drying rates, which promote compact tissue. Deff values of S, M, and L estimated were in the range of $0.83{\times}10^{-10}$ to $1.51{\times}10^{-10}m^2/s$, $1.17{\times}10^{-10}$ to $2.17{\times}10^{-10}m^2/s$, and $1.53{\times}10^{-10}$ to $2.95{\times}10^{-10}m^2/s$, respectively, whereas activation energy ($E_a$) based on drying temperature showed no significant differences in the size of soybeans.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.10 no.6
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• pp.128-133
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• 2011

In this study, the steel material for shipbuilding(LR-A class) was used, and FCAW was taken advantage of 3G attitude and they are welded by different welding ways. As a result of analyzing wave with welding monitoring system, the stable values are obtained which are the first floor(electronic current 164~182 A, voltage 24 V), the second floor(electronic current 174~190 A, voltage 22~25 V), the third floor(electronic current 158~188 A, voltage 22~25 V), and fourth floor(electronic current 172~184 A, voltage 22~25 V), at this time, the stable wave standard deviation and changing coefficient could be obtained. When the welding testing through nondestructive inspection was analyzed know defect of welding, there was no defect of welding in A, D, E, but some porosities in B, and slag conclusion near the surface in C, because the length of arc was not accurate, and the electronic current and voltage was not stable. After observing the change of heat affect zone through micro testing, each organization of floor formed as Grain Refinement, so welding part was fine, the distance of heat affect zone is getting wider up to change the values of the electronic current and voltage. As a result of degree of hardness testing, the hardness orders were the heat affect zone(HAZ), Welding Zone(WZ), and Base Metal(BM). When the distribution of degree of hardness is observed. B is the highest degree of hardness The reason why heat effect zone is higher than welding zone and base metal, welding zone is boiled over melting point($1539^{\circ}C$) and it starts to melt after the result of analysis through metal microscope, so we can know that delicate tissue is created at the welding zone. Therefore, in order to get the optimal conditions of the welding, the proper current of the welding and voltage is needed. Furthermore the precise work of welding is required.

• Journal of the Korean Society for Nondestructive Testing
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• v.35 no.2
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• pp.112-119
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• 2015

Photoacoustic microscopy is capable of providing high-resolution molecular images, and its spatial resolution is typically determined by ultrasonic transducers used to receive the photoacoustic signals. Therefore, ultrasonic transducers for photoacoustic microscopy (PAM) should have a high operating frequency, broad bandwidth, and high signal-reception efficiency. Polyvinylidene fluoride (PVDF) is a suitable material. To take full advantage of this material, the selection of the backing material is crucial, as it influences the center frequency and bandwidth of the transducer. Therefore, we experimentally determined the most suitable backing material among EPO-TEK 301, E-Solder 3022, and RTV. For this, three PVDF high-frequency single-element transducers were fabricated with each backing material. The center frequency and -6 dB bandwidth of each transducer were ascertained by a pulse-echo test. The spatial resolution of each transducer was examined using wire-target images. The experimental results indicated that EPO-TEK 301 is the most suitable backing material for a PAM transducer. This material provides the highest signal magnitude and a reasonable bandwidth because a large portion of the energy propagates toward the front medium, and the PVDF resonates in the half-wave mode.

• Korean Journal of Environment and Ecology
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• v.25 no.5
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• pp.767-786
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• 2011

This study analyzed and compared characteristic of vegetation structure in Bonghwa mountain, the base Mt. outside urban area, and Hakseoung neighborhood park, Ilsan neighborhood park and Musil neighborhood park, disconnected residual Mt. inside urban area of Wonju. Regarding vegetation of urban forest in Wonju, Quercus mongolica forest and Robinia pseudo-acacia forest were widely distributed in the base Mt. outside urban area. Quercus acutissima forest and Robinia pseudo-acacia forest were widely distributed in the disconnected residual Mt. inside urban area. Forests in both areas were managed as part of forest management campaign. Analysis on importance value of a community classified by DCA and DBH class categorized communities into three groups according to the expected ecological succession. Community B was the one to be maintained as Pinus densiflora community. Community A, D and d were expected to be maintained as Quercus spp. Community. Community C, E, F, e, f and g were classified as exotic plant community. Ecological succession was suspended in both base Mt. outside urban area and disconnected residual Mt. inside urban area. However, importance value of Quercus spp. which appeared in the understory layer and shrub layer and their DBH class showed that the potential for ecological succession of exotic plant community was higher in base Mt. outside urban area than disconnected residual Mt. inside urban area. According to the analysis on number of species and individuals and species diversity, understory and shrub layer were reduced due to Forest Management campaign and plant species which appear at an earlier stage of succession varied as time went by since the campaign began. Species diversity comparison between natural and artificial forest showed no clear difference in both base Mt. outside urban area and disconnected residual Mt. inside urban area due to man-made disruption such as thinning and brush cutting. Six communities in base Mt. outside urban area had 17.76~52.22% of similarity index. Four communities in disconnected residual Mt. inside urban area showed 13.34~37.01% of similarity index, which was lower than base Mt. outside urban area. Among naturalized plants, Tupatorium rugosum and Phytolacca americana appeared more in disconnected residual Mt. inside urban area.

• International Journal of Industrial Entomology and Biomaterials
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• v.26 no.2
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• pp.74-80
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• 2013

Three new Multi ${\times}$ Bi combinations M.Con.4 ${\times}$ (SK6 ${\times}$ SK7), M.Con.4 ${\times}$ NB4D2 and Nistari ${\times}$ (SK6 ${\times}$ SK7) were studied in five seasons i.e. during the period of $18^{th}$ June - $12^{th}$ July, $30^{th}$ August - $23^{rd}$ September, $3^{rd}$ November - $2^{nd}$ December, $29^{th}$ January- $2^{nd}$ March and $30^{th}$ March-$25^{th}$ April with one control Nistari ${\times}$ NB4D2 considering nine reeling characteristics along with shell percent and cocoon yield per 100 disease free layings (DFLs) to establish the seasonal effect on all the parameters. Results reveal that all the characters performed well in November-December. Highest yield per 100 DFLs was recorded during November-December in all combinations showing >60 kg yield. Higher correlation of yield/100 DFLs with filament length, non-breakable filament length, denier, raw silk percent, reelability percent and recovery percent was recorded in all combinations of Multi ${\times}$ Bi considered in this study. Variability observed among four combinations indicates the effect of different temperature and humidity of different seasons on expression of different traits. The results indicate that there is significant relationship of raw silk percent with reelability percent, recovery percent and evenness. Reelability percent showed higher correlation with recovery percent. It was observed that neatness was positively correlated with evenness. The overall performance of the newly evolved combinations with regard to productivity and reeling characteristics is discussed emphasizing their utilization at commercial level.

• Archives of Pharmacal Research
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• v.29 no.11
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• pp.969-976
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• 2006

Novel chalcones were found as potent inhibitors of interleukin-5 (II-5). 1-(6-Benzyloxy-2-hydroxyphenyl)-3-(4-hydroxyphenyl)propenone (2a, 78.8% inhibition at $50\;{\mu}M,\;IC_{50}=25.3\;{\mu}M$) was initially identified as a potent inhibitor of IL-5. This activity is comparable to that of budesonide or sophoricoside (1a). The benzyloxy group appears to be critical for the enhancement of the IL-5 inhibitory activity. To identify the role of this hydrophobic moiety, cyclohexyloxy (2d), cyclohexylmethoxy (2c), cyclohexylethoxy (2e), cyclohexylpropoxy (2f), 2-methylpropoxy (2g), 3-methylbutoxy (2h), 4-methylpentoxy (2i), and 2-ethylbutoxy (2j) analogs were prepared and tested for their effects on IL-5 bioactivity. Compounds 2c ($IC_{50}=12.6\;{\mu}M$), 2d ($IC_{50}=12.2\;{\mu}M$), and 2i ($IC_{50}=12.3\;{\mu}M$) exhibited the most potent activity. Considering the cLog P values of 2, the alkoxy group contributes to the cell permeability of 2 for the enhancement of activity, rather than playing a role in ligand motif binding to the receptor. The optimum alkoxy group in ring A of 2 should be one that provides the cLog P of 2 in the range of 4.22 to 4.67.

• Journal of Nutrition and Health
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• v.6 no.2
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• pp.25-33
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• 1973

With the object of the study id every possible correlation between daily food intake and growth rate of primary school students, aged eleven years old, the author distributed prepared questionnaires through 200 children of 5th grade in both sexes in K private primary school, Seoul. Specific object of this study were included following three points: such as daily food intake records for six days. daily food intake records for six days. school records of sample children at the end of 4th grade. physical growth index calculated by means of weight and height of sample children at the first part of the 5th grade. CR. t. F. test as well as percentage calculations were included for statistical analysis. The result of this study were as follows: 1. For the living circumstances a) Average numbers of brother and sister in sampled family were two to three. b) Approximately 50%of the children were brought up by mother's milk at their infants and about 35% of children were weaned at the age of 7 to 12 months. c) Thirty to forty percent of the respondents revealed irregulity in their meal time due to early school time in the morning. d) Monthly average expenditure for daily food reached 20 to 29% out of total income. e) The most favorit foods reflect as follows: The most favorit main dish is boiled rice mixed with other careals and side dish beaf. Fruits and juice are more popular snack among whole children. 2. Nutrition survey a) The calcium and thiamine were the most limited factors out of daily nutrients consumption. b) The total calory intake were composed of carbohydrate 63%, protein 16% and fat 21% respectively. c) The total food intake were composed of 20 to 24% of animal source of foods and 76 to 80% of plant source of foods (vegetables, grains, fruits) d) The total protein intake were composed of 46% of animal protein and 54% of others. e) The grain stuffs consumed in the largest quantity at the level of 50% out whole food groups. f) Twenty four percent of total food intake came from snack between meal time. 3. The result of statistical analysis were as follows: a) The correlation between the calory intake and plysical growth index revealed statistical significancy at the level of p<0.001. b) The correlation between the protein intake and physical growth index revealed statistical significancy at the level of p<0.001. c) The correlation between the meal time and physical growth index revealed statistical significancy at the level of 0.02