• Title/Summary/Keyword: Dye-Sensitized Solar Cells (DSSCs)

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Highly Flexible Dye-sensitized Solar Cell Prepared on Single Metal Mesh

  • Yun, Min Ju;Cha, Seung I.;Seo, Seon Hee;Lee, Dong Y.
    • Current Photovoltaic Research
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    • v.2 no.3
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    • pp.79-83
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    • 2014
  • Dye-sensitized solar cells (DSSCs) are applied in the emerging fields of building integrated photovoltaic and electronics integrated photovoltaic like small portable power sources as demands are increased with characteristic advantages. Highly flexible dye-sensitized solar cells (DSSCs) prepared on single stainless steel mesh were proposed in this paper. Single mesh DSSCs structure utilizing the spraying the chopped glass paper on the surface treated stainless steel mesh for integrating the space element and the electrode components, counter electrode component and photoelectrode component were coated on each side of the single mesh. The fabricated single mesh DSSCs showed the energy-conversion efficiency 0.50% which show highly bendable ability. The new single mesh DSSCs may have potential applications as highly bendable solar cells to overcome the limitations of TCO-based DSSCs.

Organic Sensitizers based on Bis-carbazole for Dye-Sensitized Solar Cells (비스-카바졸 유기염료를 이용한 염료감응태양전지)

  • Kim, Hyo-Jeong;Byun, Yeo-Jin;Nam, Jung-Eun;Kim, Dae-Hwan;Kang, Jin-Kyu
    • 한국태양에너지학회:학술대회논문집
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    • 2012.03a
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    • pp.397-399
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    • 2012
  • Dye-sensitized solar cells (DSSCs) have received considerable attention as the most promising candidates for renewable energy systems in recent years. Among these, organic dyes which have many advantages such as large absorption coefficients, customized molecular design for desired photophysical and photochemical properties, inexpensiveness and environment-friendliness, are suitable as photosensitizers for DSSCs. We have studied on the design and synthesis of two organic dyes (BECZ 1 and BECZ 2) with a 9-ethyl-9H-carbazole core for dye-sensitized solar cells (DSSCs). Two organic dyes comprised of two 9-ethyl-9H-carbazole moiety as electron-donor, two types of cyanoacrylic acid moiety acting as acceptor. In addition, n-ethyl unit introduced for increasing the solubility and the donating power. The obtained organic dyes were comprehensively characterized by NMR, GC-MS, FAB-MS and UV/Vis spectroscopies. DSSCs sensitized by the dyes BECZ1 and BECZ2 produced ${\eta}$ value 3.31% and a ${\eta}$ value 3.21%.

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Facile Fabrication of $TiO_2$ Photoelectrodes Using Intense Pulsed Light for Dye-Sensitized Solar Cells

  • Jin, Hwa-Yeong;Yu, Gi-Cheon;Lee, Jin-A;Im, Jeong-A;Kim, Ji-Hyeon;Go, Min-Jae
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.228-228
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    • 2013
  • Dye-Sensitized Solar Cells (DSSCs) have attracted great interests as they offer high energyconversion efficiencies at low cost. For the conventional fabrication of DSSCs, high temperature sintering is required for the construction of interconnect $TiO_2$. However, more simplified process which can be applicable to large-sized solar cells module, is strongly necessary for the commercialization of DSSCs. In this work, we developed novel sintering method using Intense Pulsed Light (IPL), which can replace the conventional high temperature sintering methods. The photovoltaic properties of DSSCs utilizing IPL methods will be reported.

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Room temperature-processed TiO2 coated photoelectrodes for dye-sensitized solar cells

  • Kim, Dae-gun;Lee, Kyung-min;Lee, Hyung-bok;Lim, Jong-woo;Park, Jae-hyuk
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.30 no.2
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    • pp.61-65
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    • 2020
  • The depletion of fossil fuels and the increase in environmental awareness have led to greater interest in renewable energy. In particular, solar cells have attracted attention because they can convert an infinite amount of solar energy into electricity. Dye-sensitize solar cells (DSSCs) are low cost third generation solar cells that can be manufactured using environmentally friendly materials. However, DSSC photoelectrodes are generally produced by screen printing, which requires high temperature heat treatment, and low temperature processes that can be used to produce flexible DSSCs are limited. To overcome these temperature limitations, this study fabricated photoelectrodes using room-temperature aerosol deposition. The resulting DSSCs had an energy conversion efficiency of 4.07 %. This shows that it is possible to produce DSSCs and flexible devices using room-temperature processes.

Development Trends and Perspectives of Dye-Sensitized Solar Cells (염료감응 태양전지 개발동향 및 전망)

  • Kang , Moon-Sung;Kang , Yong-Soo
    • Journal of Powder Materials
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    • v.12 no.1
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    • pp.7-16
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    • 2005
  • Dye-sensitized solar cells(DSSCs) have been under investigation for the past decade due to their attractive features such as high energy conversion efficiency and low production costs. The basis for energy conversion in the injection of electrons from a photoexcited stateof a dye sensitizer into the conduction band of the nanocrystalline $TiO_2$ semiconductor upon absorption of light. It is believed that the DSSC is one of the most promising technologies to solve the significant energy problems. In this article, the development trends and perspective of DSSCs were reviewed.

Cobalt Redox Electrolytes in Dye-Sensitized Solar Cells : Overview and Perspectives (염료감응 태양전지용 코발트 전해질의 최신 연구동향 및 전망)

  • Kwon, Young Jin;Kim, Hwan Kyu
    • Current Photovoltaic Research
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    • v.2 no.1
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    • pp.18-27
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    • 2014
  • Dye-sensitized solar cells (DSSCs), developed two decades ago, are considered to be an attractive technology among various photovoltaic devices because of their low cost, accessible dye chemistry, ease of fabrication, high power conversion efficiency, and environmentally friendly nature. A typical DSSCs consists of a dye-coated $TiO_2$ photoanode, a redox electrolyte, and a platinum (Pt)-coated fluorine-doped tin oxide (FTO) counter electrode. Among them, redox electrolytes have proven to be extremely important in improving the performance of DSSCs. Due to many drawbacks of iodide electrolytes, many research groups have paid more attention to seeking other alternative electrolyte systems. With regard to this, one-electron outer sphere redox shuttles based on cobalt complexes have shown promising results: In 2014, porphyrin dye (SM315) with the cobalt (II/III) redox couple exhibited a power conversion efficiency of 13% in DSSCs. In this review, we will provide an overview and perspectives of cobalt redox electrolytes in DSSCs.

A review of zinc oxide photoanode films for dye-sensitized solar cells based on zinc oxide nanostructures

  • Tyona, M.D.;Osuji, R.U.;Ezema, F.I.
    • Advances in nano research
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    • v.1 no.1
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    • pp.43-58
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    • 2013
  • Zinc oxide (ZnO) is a unique semiconductor material that exhibits numerous useful properties for dye-sensitized solar cells (DSSCs) and other applications. Various thin-film growth techniques have been used to produce nanowires, nanorods, nanotubes, nanotips, nanosheets, nanobelts and terapods of ZnO. These unique nanostructures unambiguously demonstrate that ZnO probably has the richest family of nanostructures among all materials, both in structures and in properties. The nanostructures could have novel applications in solar cells, optoelectronics, sensors, transducers and biomedical sciences. This article reviews the various nanostructures of ZnO grown by various techniques and their application in DSSCs. The application of ZnO nanowires, nanorods in DSSCs became outstanding, providing a direct pathway to the anode for photo-generated electrons thereby suppressing carrier recombination. This is a novel characteristic which increases the efficiency of ZnO based dye-sensitized solar cells.

Dye-sensitized solar cells using size dependent SBM binder

  • Park, Gyeong-Hui;Kim, Eun-Mi;Jo, Hong-Gwan;Wang, Gyo;Hong, Chang-Guk;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.116-116
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    • 2009
  • $TiO_2$ pastes was synthesized to obtained of high efficiency dye-sensitized solar cells using size dependent co-polymer. SBM co-polymer binder is consist of styrene, n-butyl acrylate, and methacrylic acid (SBM) monodisperse co-polymer binder materials and this $TiO_2$ pastes were applied of dye-sensitized solar cells (DSSCs). The photoanodes were characterized by ATR-Fourier Transform spectrometer, X-ray diffraction (XRD) and morphology was investigated by field emission scanning electron microscopy (FE-SEM). The photoelectrochemical properties of the thin films and the performance of DSSCs were measured by photovoltaic-current density, AC impedance and monochromatic incident photon-to-current conversion efficiency (IPCE). DSSC based on the 100nm size co-polymer binder was obtained conversion efficiency of 8.1% under irradiation of AM 1.5(100 $mWcm^2$).

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A Formation of Hole Pattern on Ti Electrode by Lift-off and Its Application to TCO-less Dye-sensitized Solar Cells (Ti 전극의 Lift-off 공정을 이용한 홀 패턴 형성과 TCO-less 염료감응형 태양전지의 응용)

  • Jung, Haeng-Yun;Ki, Hyun-Chul;Gu, Hal-Bon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.3
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    • pp.175-179
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    • 2015
  • In this study, we propose Ti hole pattern structure on the transparent conductive oxide (TCO) less dye-sensitized solar cells (DSSCs) using the lift-off process to improve the low light transmittance and low efficiency caused by opaque Ti electrode. The formation of Ti hole patterns make it possible to move the dye adsorption and electrolyte. The DSSCs with Ti hole patterns showed a higher photoelectric conversion efficiency (PCE) than those with general structure by 11.1%. As a result, The Ti hole pattern structure can be improved to increase the light absorption of the dyes and PCE of the TCO-less DSSCs is also increased.

Synthesis and Applications of Dicationic Iodide Materials for Dye-Sensitized Solar Cells

  • Nam, Heejin;Ko, Yohan;Kunnan, Sakeerali C.;Choi, Nam-Soon;Jun, Yongseok
    • Journal of Electrochemical Science and Technology
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    • v.10 no.2
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    • pp.214-222
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    • 2019
  • Dye-sensitized solar cells (DSSCs) have been receiving growing attentions as a potential alternative to order photovoltaic devices due to their high efficiency and low manufacturing cost. DSSCs are composed of a photosensitizing dye adsorbed on a mesoporous film of nanocrystalline $TiO_2$ as a photoelectrode, an electrolyte containing triiodide/iodide redox couple, and a platinized counter electrode. To improve photovoltaic properties of DSSCs, new dicationic salts based on ionic liquids were synthesized. Quite comparable efficiencies were obtained from electrolytes with new dicationic iodide salts. The best cell performance of 7.96% was obtained with dicationic salt of PBDMIDI.