• Title/Summary/Keyword: Dye sensitized

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Analysis Thermal Performance of PV/Thermal Collector with Dye-sensitized Solar Cell Module (염료감응형태양전지 모듈 적용 PVT 집열기의 열적 성능 분석)

  • Jang, Han-Bin;Mun, Jong-Hyeok;Gang, Jun-Gu;Kim, Jin-Hui;Kim, Jun-Tae
    • Proceedings of the Korean Society for Emotion and Sensibility Conference
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    • 2009.11a
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    • pp.273-276
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    • 2009
  • Photovoltaic-thermal(PVT) collectors are a combination of photovoltaic modules with solar thermal collectors, forming one device that receives solar radiation and produces electricity and heat simultaneously. Of various PV modules, dye-sensitized solar cell(DSC) is a relatively new type of solar cell technology that can transmit light while they can generate electricity. With this aspect, DSC can be applied into solar thermal collectors. The object of this study is to evaluate the thermal performance of PVT collector with DSC. The thermal performance of the DSC PVT combind collector was measured in outdoor conditions with the solar radiation of over $700W/m^2$. In this study, the PVT collector with the 30% light transmittance of DSC achieved its thermal efficiency of about 36%.

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Dye-sensitized solar cells using size dependent SBM binder

  • Park, Gyeong-Hui;Kim, Eun-Mi;Jo, Hong-Gwan;Wang, Gyo;Hong, Chang-Guk;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.116-116
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    • 2009
  • $TiO_2$ pastes was synthesized to obtained of high efficiency dye-sensitized solar cells using size dependent co-polymer. SBM co-polymer binder is consist of styrene, n-butyl acrylate, and methacrylic acid (SBM) monodisperse co-polymer binder materials and this $TiO_2$ pastes were applied of dye-sensitized solar cells (DSSCs). The photoanodes were characterized by ATR-Fourier Transform spectrometer, X-ray diffraction (XRD) and morphology was investigated by field emission scanning electron microscopy (FE-SEM). The photoelectrochemical properties of the thin films and the performance of DSSCs were measured by photovoltaic-current density, AC impedance and monochromatic incident photon-to-current conversion efficiency (IPCE). DSSC based on the 100nm size co-polymer binder was obtained conversion efficiency of 8.1% under irradiation of AM 1.5(100 $mWcm^2$).

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Enhanced Light Harvesting from F$\ddot{o}$rst-type resonance Energy Transfer in the Quasi-Solid State Dye-Sensitized Solar Cells (F$\ddot{o}$rst energy transfer 를 적용한 준고체 DSSC 의 효율향상)

  • Cheon, Jong Hun;Lee, Jeong Gwan;Yang, Hyeon Seok;Kim, Jae Hong
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.117.1-117.1
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    • 2011
  • We have demonstrated Forst-type resonance energy transfer (FRET) in the quasi-solid type dye-sensitized solar cells between organic fluorescence materials as an energy donor doped in polymeric gel electrolyte and ruthenium complex as an energy acceptor on surface of $TiO_2$. The strong spectral overlap of emission/absorption of energy donor and acceptor is required to get high FRET efficiency. The judicious choice of energy donor allows the enhancement of light harvesting characters of energy acceptor in quasi-solid dye sensitized solar cells which increase the power conversion efficiency. The enhanced light harvesting effect by the judicious choice/design of the fluorescence materials and sensitizing dyes permits the enhancement of photovoltaic performance of DSSC.

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Synthesis of Dye-sensitized Solar Cells with Titanium Mesh Electrode (티타늄 메쉬 전극구조를 이용한 염료 태양전지 제작)

  • Paeng, Sung-Hwan;Kim, Doo-Hwan;Park, Min-Woo;Sung, Youl-Moon
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.58 no.12
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    • pp.2436-2440
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    • 2009
  • In this work, TCO-less dye-sensitized solar cells (DSCs) using Ti-mesh layer is fabricated for high-efficient low-cost solar cell application. The Ti-mesh metal can replace TCO in the photo-electrode part of DSCs, thus the cell structure is composed of a glass/dye sensitized TiO2 particle/ Ti-mesh layer/electrolyte/Pt sputtered counter electrode/ glass. The Ti-mesh electrode with high conductivity can collect electrons from the $TiO_2$ layer and allows the ionic diffusion of $I^-/I_3^-$ through the mesh hole. Thin Ti-mesh ($\sim40{\mu}m$ in thickness) electrode material is processed using rapid prototype method. The efficiency of prepared TCO-less DSCs sample is about 1.45 % ((ff: 0.5, Voc: 0.52V, Jsc: 5.55 $mA/cm^2$).

A New Unsymmetrical Zinc Phthalocyanine as Photosensitizers for Dye-sensitized Solar Cells

  • Zhang, Dan;Zhang, Xue-Jun;Zhang, Lei;Mao, Li-Jun
    • Bulletin of the Korean Chemical Society
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    • v.33 no.4
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    • pp.1225-1230
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    • 2012
  • A new unsymmetrical zinc phthalocyanine has been designed and synthesized based on the 'push-pull' and extended ${\pi}$-conjugation concept for the dye-sensitized solar cells. Three tert-butoxy groups, which act as electron releasing ('push'), enhance the solubility of phthalocyanine in common organic solvents and reduce the aggregation. Hydroxy substituted 9,10-anthraquinones act as electron acceptors ('pull') for the study of photoinduced electron transfer processes as well as grafting onto nanocrystalline $TiO_2$. The new unsymmetrical zinc phthalocyanine was fully characterized by FTIR, UV-vis, $^1H$ NMR, cyclic voltammetry and differential pulse voltammetry. The new sensitizer was tested in dye-sensitized solar cells, and gave a better performance.

Fabrication of $TiO_2$ Blocking Layers for CuSCN Based Dye-Sensitized Solar Cells by Atomic Layer Deposition Method

  • Baek, Jang-Mi;Seong, Myeong-Mo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.310.2-310.2
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    • 2013
  • For enhancement of dye-sensitized solar cell performance, TiO2 blocking layer has been used to prevent recombination between electron and hole at the conducting oxide and electrolyte interface. In solid state dye-sensitized solar cells, it is necessary to fabricate pin-hole free TiO2 blocking layer. In this work, we deposited the TiO2 blocking layer on conducting oxide by atomic layer deposition and compared the efficiency. To compare the efficiency, we fabricate solid state dye-sensitized solar cell with using CuSCN as hole transport material. We see the efficiency improve with 40nm TiO2 blocking layer and the TiO2 blocking layer morphology was characterized by SEM. Also, we used this blocking layer in TiO2/Sb2S3/ CuSCN solar cell.

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Physical-based Dye-sensitized Solar Cell Equivalent Circuit Modeling and Performance Analysis (물리 기반의 염료 감응형 태양전지 등가회로 모델링 및 성능 분석)

  • Wonbok Lee;Junhyeok Song;Hwijun Choi;Bonyong Gu;Jonghwan Lee
    • Journal of the Semiconductor & Display Technology
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    • v.22 no.3
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    • pp.67-72
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    • 2023
  • In this paper, a dye-sensitized solar cell (DSSC), one of the representative third-generation solar cells with eco-friendly materials and processes compared to other solar cells, was modeled using MATLAB/Simulink. The simulation was conducted by designating values of series resistance, parallel resistance, light absorption coefficient, and thin film electrode thickness, which are directly related to the efficiency of dye-sensitized solar cells, as arbitrary experimental values. In order to analyze the performance of dye-sensitized solar cells, the optimal value among each parameter experimental value related to efficiency was found using formulas for fill factor (FF) and conversion efficiency.

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