• Title/Summary/Keyword: Dy^{3+}$

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Effect of Additives and Cooling Rates on the Electrical Resistivity of $BaTiO_3$ Ceramics: (II) Multi-Component Systems of $TiO_2$, $SiO_2$ and $Al_2O_3$ Additives ($BaTiO_3$ 세라믹스의 전기저항에 미치는 첨가제와 냉각속도의 영향: (II) $TiO_2$, $SiO_2$$Al_2O_3$ 복합첨가)

  • 염희남;하명수;이재춘;정윤중
    • Journal of the Korean Ceramic Society
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    • v.28 no.10
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    • pp.803-809
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    • 1991
  • Microstructure, room temperature resistivity and temperature coefficient of resistance of BaTiO3 ceramics were characterized and measured in this study. The basic composition of the BaTiO3 cremics was formed by adding 0.25 mol% Dy2O3 and 0.07 mol% MnO2 to the BaTiO3 composition. Samples of the BaTiO3 ceramics were prepared by adding various amounts of the TiO2, SiO2 and Al2O3 to the basic composition. An addition of 1 mol% TiO2, 2 mol% SiO2 and 0.5 mol% Al2O3 to the basic composition resulted both the values of the room temperature resistivity and the temperatured coefficient being maxium. Meanwhile, an addition of 1 mol% TiO2 and 1 mol% Al2O3 to the basic composition resulted the value of the room temperature resistivity maxium and the temperature coefficient minimum. The temperature coefficient showed a maximum value as well as a minimum value when the three kinds of the additives were added together to the basic composition of the BaTiO3 ceramics. Maxed phases of BaTi3O7, BaTiSiO5 and BaAl2Si2O8 were present at the grain boundary.

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Effects of Al2O3-RE2O3 Additive for the Sintering of SiC and the Fabrication of SiCf/SiC Composites (SiC 소결에 미치는 Al2O3-RE2O3 첨가제의 영향과 SiCf/SiC 복합체의 제조)

  • Yu, Hyun-Woo;Raju, Kati;Park, Ji Yeon;Yoon, Dang-Hyok
    • Journal of the Korean Ceramic Society
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    • v.50 no.6
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    • pp.364-371
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    • 2013
  • The sintering behavior of monolithic SiC is examined using the binary sintering additive of $Al_2O_3$-rare earth oxide ($RE_2O_3$, where RE = Sc, Nd, Dy, Ho, or Yb). Through hot pressing at 20 MPa and $1750^{\circ}C$ for 1 h in an Ar atmosphere for 52 nm fine ${\beta}$-SiC powder added with 5 wt% sintering additive, a SiC density of > 97% is achieved, which indicates the effectiveness of $Al_2O_3-RE_2O_3$ system as a sintering of additive for SiC. Based on this result, 7 wt% of $Al_2O_3-Sc_2O_3$ is tested as an additive system for the fabrication of a continuous SiC fiber-reinforced SiC-matrix composite ($SiC_f$/SiC). Electrophoretic deposition combined with the application of ultrasonic pulses is used to efficiently infiltrate the matrix phase into the voids of $Tyranno^{TM}$-SA3 fabric. After hot pressing, a composite density of > 97% is obtained, along with a maximum flexural strength of 443 MPa.

A study on the dielectric characteristics of 0.05PAN-0.85PZT ceramics with additive (첨가제에 의한 0.05PAN-0.95PZT계 세라믹의 유전 특성에 관한 연구)

  • Kim, Hyun-Chul;Shin, Hyea-Koung;Kim, Jean-Shop;Yoon, Hyun-Sang;Bae, Seon-Gi
    • Proceedings of the KIEE Conference
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    • 2000.07c
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    • pp.1661-1663
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    • 2000
  • This study was to measure the dielectric characteristics of 0.05Pb($Al_{0.5}Nb_{0.5}$)-0.95Pb($Zr_{0.52}Ti_{0.48})O_3$[PAN-PZT] system ceramics according to the variation of $Cr_{2}O_3$, $Fe_{2}O_3$ addition amount. 0.0$\sim$1.2[wt%] and according to sintering temperature after creating the specimens with a general sintering way. The results of this study were summarized as follows : the dielectric constant at 20[$^{\circ}C$] reduced dy increasing additive on the whole. The dielectric loss was minimum value of 12.77[%], sintered at 1200[$^{\circ}C$], dopped with $Cr_{2}O_3$ 0.3[wt%] and minimum value of 10.89[%], sintered at 1200[$^{\circ}C$], dopped with $Fe_{2}O_3$ 0.6[wt%]. The variation rate of dielectric constant according to the change of frequency was decreased slowly by increasing frequency. The temperature coefficient of capacitance turned out increasing the stability of the temperature, decreased $Cr_{2}O_3$ 0.3wt% showed its minimum value 0.59[%/$^{\circ}C$], the maximum value 0.9[%/$^{\circ}C$] with $Cr_{2}O_3$ 3wt%.

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Effect of Small Black Soybean Powder on Blood Glucose and Insulin Sensitivity in Streptozotocin-Induced Diabetic Rats (Streptozotocin-유도 당뇨모델을 이용한 쥐눈이콩 분말의 혈당강하 및 인슐린 감수성의 효과)

  • Lee, Dae-Hoon;Kwak, Dong-Hoon;Kim, Sung-Min;Ju, Eun-Jin;Choi, Han-Gil;Kim, Ok-Hee;Hwang, Jin-Bong;Bae, Nahm-Gung;Jung, Kyu-Yong;Han, Jin-Chul;Park, Hum-Dai;Choo, Young-Kug
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.33 no.10
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    • pp.1618-1625
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    • 2004
  • Beans are acknowledged to be food resources, which have more abundant proteins and fats. The constituent parts of beans (i.e. aspartic aid, glycine, arginine) are effective against diabetes, and dietary fiber contained in the beans has an important property to maintain insulin sensitivity. Based on these, using streptozotocin (STZ)-induced diabetic rats, this study examined how the rat-eye soybean, which is principal products of the Imsil province, is effective to attenuate and/or prevent the development of diabetes mellitus. We divided rats into the non-diabetic and diabetic group, and diabetic group was further subdivided into six experimental groups [DC, diabetic control; DI, diabetes with insulin treatment (4∼6 IU/rat); DB, diabetes with black bean; DY, diabetes with yellow soybean; DS, diabetes with rat-eye soybean; DSS, diabetes with vinegar-fermented rat-eye soybean. All bean treatment (1.5 mg/l g body weight).]. Food efficiency ratio (FER), body weight and insulin sensitivity in diabetic rats were significantly reduced compared to those in normal control animals. These reductions were obviously attenuated by administration of a variety of beans used in this study (20∼30%), and the recovery effects were comparable to the results obtained by insulin treatment. Taken together, this study suggests that all beans used may have an essential property to improve and/or attenuate the development of diabetes mellitus in rats.

Effect of Milling Condition on Low-temperature Sinterability and Electrical Properties of BaTiO3 Ceramics (Milling 조건에 따른 BaTiO3의 저온 소결성 및 전기적 특성 변화)

  • Hong, Min-Hee;Sohn, Sung-Bum;Kim, Young-Tae;Hur, Kang-Heon
    • Journal of the Korean Ceramic Society
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    • v.46 no.2
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    • pp.200-210
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    • 2009
  • It is necessary to minimize the mismatch of sintering shrinkage between dielectric ceramic and Ni inner electrode layers for the purpose of developing the ultra high-capacity multi layered ceramic condenser(MLCC). Thus, low temperature sintering of dielectric $BaTiO_3$ ceramic should be precedently investigated. In this work, the influence of the milling condition on sintering behavior and electrical properties of $BaTiO_3$ ceramics was investigated in the $BaTiO_3$(BT)-Mg-Dy-Mn-Ba system with borosilicate glass as a sintering agent. As milling time increased, specific surface area(SSA) of the powder increased linearly, while both sinterability and dielectric property were found to be drastically decreased with an increasing SSA. It was also revealed that the sinterability of the excessively milled $BaTiO_3$ ceramics could be recovered by increasing Ba content, rather than increasing glass addition. These results suggest that the sintering behavior of $BaTiO_3$ ceramics under the high SSA was more strongly dependent on the transient liquid phase caused by Ba addition, than the liquid phase from additional glass.

Analyses of structural dynamic characteristics and end milling in a vertical machining center (금형 가공기의 엔드밀 가공 및 구조 동특성 해석)

  • 이신영;김성걸;이장무
    • Journal of the Korean Society for Precision Engineering
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    • v.14 no.3
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    • pp.66-74
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    • 1997
  • In a high speed and high precision vertical machining center, chatter vibration is easily generated due to unbalanced masses in rotating parts and changtes of cutting forces. In this paper, modal test is performed to obtain modal parameters of the vertical machining center. In order to predit the cutting force of endmilling process for various cutting conditions, a mathematical model is given and this model is based on chip load, cutting geometry, and relationship between cutting forces and the chip load. Specific cutting constants of the model are obtained by averaging forces of cutting tests. The interactions between the dy- namic characteristics and cutting dynamics of the vertical machining center make the primary and the secondary feedback loops, and we make use of the equations of system to predict the chatter vibration. The chatter prediction is formulated as linear differential-differene equations, and simulated for several cases. Trends of vibration as radial and axial depths of cut are changed are shown and compared.

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Effect of Cu Content on Microstructural and Magnetic Properties of a Nd-Fe-B Strip Cast (Cu 첨가에 따른 Nd-Fe-B strip cast의 미세조직과 자기적 특성의 상관관계)

  • Park, Song-E;Kim, Tae-Hoon;Lee, Seong-Rae;Kim, Dong-Hwan;NamKung, Seok;Jang, Tae-Suk
    • Journal of Powder Materials
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    • v.18 no.1
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    • pp.24-28
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    • 2011
  • Effect of Cu content on microstructural and magnetic properties of a $(Nd_{26.06},Dy_{6.51})Fe_{bal.}$ $Cu_xB_{0.97}$(wt.%), (x = 0.2, 0.3, 0.4, 0.5) strip-cast was studied. The average inter-lamellar spacing in the free surface and wheel side of the strip cast increased as the Cu content increases. The grain uniformity, the grain alignment, and (00L) texture of the strip cast increased with Cu contents up to 0.4 wt.%. These microstructural changes were attributed to the decrease of the effective cooling rate of the melted alloy caused by the decrease of the melting temperature of resulting from Cu addition. Coercivity and remanence were increased because of the grain alignment and (00L) texture improvement with Cu contents up to 0.4 wt.%.

Effect of Pr6O11/CoO Ratio on Electrical Characteristics of ZPCD-Based varistor Ceramics (ZPCD계 바리스터 세라믹스의 전기적 특성에 Pr6O11/CoO 비의 영향)

  • 남춘구;김향숙
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.10
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    • pp.876-882
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    • 2002
  • The microstructure and electrical characteristics of ZPCD (ZnO-$Pr_{6}O_{11}$-CoO-$Dy_2O_3$) -based varistor ceramics were investigated with various $Pr_{6}O_{11}$/CoO ratios and sintering temperatures. The density of varistor ceramics with $Pr_{6}O_{11}$=1.0 was almost constant with sintering temperature, whereas it was increased noticeably in $Pr_{6}O_{11}$=0.5. Increasing $Pr_{6}O_{11}$ content enhanced the densification for any CoO content and the density was greatly affected not by CoO content but by $Pr_{6}O_{11}$ content. The varistor ceramics with $Pr_{6}O_{11}$/CoO=0.5/l.0 exhibited a higher nonlinearity than any other composition ratios. In particular, the varistor ceramics sintered at $1350^{\circ}C$ exhibited the best electrical properties, with nonlinear exponent of 37.8, leakage current of 7.6 ${\mu}$A, and tan $\delta$ of 0.059.

Hookah Smoking: Characteristics, Behavior and Perceptions of Youth Smokers in Pune, India

  • Kakodkar, Pradnya V.;Bansal, Shruti S.
    • Asian Pacific Journal of Cancer Prevention
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    • v.14 no.7
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    • pp.4319-4323
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    • 2013
  • Background: Hookah smoking has been referred to as a global tobacco epidemic by public health officials. This study aimed to investigate the characteristics, behaviour and perceptions related to hookah smoking among the youth smokers in Pune. Methods: Two hundred and eighty established hookah smokers participated in this study. Data was collected using a 29-item questionnaire, constructed using three main domains: Characteristics (socio-demographic and personal), behaviour and perceptions (about harmful effects in comparison to cigarette smoking). Results: The results indicated that the mean age of starting hookah smoking was 17.3 years; 75% of participants did not have parental acceptance; light-headedness, dizziness and headache were most common reported nicotine effects, post hookah smoking. Hookah smoking on a daily basis was reported by 24.6% participants. The mean time of hookah session was 1 hour and 19 minutes. 68.2% participants were reported to smoke hookah in hookah-cafes and 35.7% participants were found to share the hookah. Some 66.7% participants had no intention to quit. Most of them (71-80%) had misperception about the safety of hookah smoking over cigarette smoking and 54-82% participants were unaware of health effects. Conclusions: Educational intervention is urgently needed to create awareness among the youth about the harmful effects of hookah smoking.

Inhibitory effect of Panax notoginseng and emodin on LPS-induced iNOS, COX-2 and prostaglandin E2

  • Shin, Jin-Cheul;Moon, Jin-Young;Park, Won-Hwan
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.20 no.3
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    • pp.724-729
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    • 2006
  • Many traditional herbal remedies exhibit several beneficial effects including anti-inflammation. The exact mechanism of the a-inflammato action of Panax notoginseng Buck F.H. Chen. however, has not been determined. In the present study, we have isolted the acting compound, emodin, from P. notoginseng and examined the effects of p. notoginseng and emodin on lipopolysaccharide (LPS)-induced nitric oxide (NO) production, and inducible nitric oxide synthase (iNOS) and cyclooxygenase-2 (COX-2) gene expression in RAW264.7 macrophages. The results indicated that p. notoginseng concentration-dependently inhibited LPS-induced NO production. Furthermore, P. notoginseng inhibited the expression of LPS-induced iNOS and COX-2 proteins without an appreciable cytotoxic effect on RAW264.7 cells. Emodin also inhibited LPS-induced iNOS protein as potently as P. notoginseng. This was consistent with the findings that P. notoginseng but not emodin inhibited prostaglandin E2 synthesis induced Dy LPS.