Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
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Effect of Milling Condition on Low-temperature Sinterability and Electrical Properties of BaTiO3 Ceramics

Milling 조건에 따른 BaTiO3의 저온 소결성 및 전기적 특성 변화

  • Hong, Min-Hee (Material Development Group, LCR Division, Samsung Electro-Mechanics) ;
  • Sohn, Sung-Bum (Material Development Group, LCR Division, Samsung Electro-Mechanics) ;
  • Kim, Young-Tae (Material Development Group, LCR Division, Samsung Electro-Mechanics) ;
  • Hur, Kang-Heon (LCR Development Team, LCR Division, Samsung Electro-Mechanics)
  • 홍민희 (삼성전기 LCR 사업부 재료개발그룹) ;
  • 손성범 (삼성전기 LCR 사업부 재료개발그룹) ;
  • 김영태 (삼성전기 LCR 사업부 재료개발그룹) ;
  • 허강헌 (삼성전기 LCR 사업부 LCR개발팀)
  • Published : 2009.03.31
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Abstract

It is necessary to minimize the mismatch of sintering shrinkage between dielectric ceramic and Ni inner electrode layers for the purpose of developing the ultra high-capacity multi layered ceramic condenser(MLCC). Thus, low temperature sintering of dielectric $BaTiO_3$ ceramic should be precedently investigated. In this work, the influence of the milling condition on sintering behavior and electrical properties of $BaTiO_3$ ceramics was investigated in the $BaTiO_3$(BT)-Mg-Dy-Mn-Ba system with borosilicate glass as a sintering agent. As milling time increased, specific surface area(SSA) of the powder increased linearly, while both sinterability and dielectric property were found to be drastically decreased with an increasing SSA. It was also revealed that the sinterability of the excessively milled $BaTiO_3$ ceramics could be recovered by increasing Ba content, rather than increasing glass addition. These results suggest that the sintering behavior of $BaTiO_3$ ceramics under the high SSA was more strongly dependent on the transient liquid phase caused by Ba addition, than the liquid phase from additional glass.

Keywords

References

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