• 제목/요약/키워드: Dy^{3+}$

검색결과 338건 처리시간 0.023초

4[N-Furfural)amino]antipyrine Semicarbazone의 질산 란탄(III) 배위화합물의 입체화학에 미치는 Picolines의 영향과 항박테리아 활성 (Studies on the Effect of Picolines on the Stereochemistry of Lanthanide(III) Nitrate Coordination Compounds of 4[N-Furfural)amino]antipyrine Semicarbazone and Antibacterial Activities)

  • Agarwal, Ram K.;Agarwal, Himanshu;Prasad, Surendra;Kumar, Anil
    • 대한화학회지
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    • 제55권4호
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    • pp.594-602
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    • 2011
  • 4[N-(furfural)amino]antipyrine semicarbazone(FFAAPS)와 질산 란탄(III)이 형성하는 배위화합물의 입체화학에 미치는 ${\alpha}$-, ${\beta}$- 및 ${\gamma}$-picolines의 영향을 연구하였다. 이들 배위화합물의 일반적 조성은 [Ln(FFAAPS)$(NO_3)_3$Pic] (Ln=La, Pr, Nd, Sm, Gd, Tb, Dy 또는 Ho 및 Pic=${\alpha}$-, ${\beta}$- or ${\gamma}$-picolines)이다. 모든 배위화합물은 원소분석, 분자량, 몰전기전도도, 자기수자율, 적외선 및 자외선 스펙트럼으로 특성을 조사하였다. 적외선 연구결과 FFAAPS는 N, N, O 주개를 갖는 중성 삼배위 리간드로 행동하는 반면, ${\alpha}$-, ${\beta}$- 또는 ${\gamma}$-picoline는 헤테로 N-원자를 통하여 란탄(III) 이온에 배위된다. 질산 음이온은 이들 화합물에서 이배위로 결합한다. 자외선 스펙트럼 결과로부터 전자구름 퍼짐 효과(${\beta}$), covalence factor($b^{1/2}$), Sinha parameter (${\delta}%$) 및 covalence angular overlap parameter(${\eta}$)를 계산하였다. 이들 착물의 열적성질을 열무게 분석법에 의해 연구하였다. 본 화합물에 있어서 란탄(III)의 배위수는 10으로 조사되었다. 기본 리간드인 FFAAPS와 착물의 항박테리아 선별조사 결과, 이들 착물은 중간 정도의 항박테리아 활성을 보였다.

$(Sm_{0.5}RE_{0.5})Fe_{11}Ti$ 화합물의 구조 및 자기특성 (Structure and Magnetic Properties of $(Sm_{0.5}RE_{0.5})Fe_{11}Ti$ Compounds)

  • 김희태;김윤배;김창석;김택기;권혁무
    • 한국자기학회지
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    • 제3권3호
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    • pp.196-200
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    • 1993
  • $(Sm_{0.5}RE_{0.5})Fe_{11}Ti$ 화합물(RE=Ce, Pr, Nd, Sm, Gd, Tb, Dy)은 정방정(tetragonal) $ThMn_{12}$ 형 구조로 형성되며 c축을 자화용이축으로하는 일축결정자기이방성을 갖 는다. 주조한 $(Sm_{0.5}RE_{0.5})Fe_{11}Ti$ 화합물은 RE=Sm일 때 가장 높은 이방성자장 11200 kA/m(140 kOe)을 가지며, RE=Nd일 때 포화자화가 $122.3\;Am^{2}/kg$(122.3 emu/g)로 가장 크며, RE=Gd일 때 큐리온도가 $326^{\circ}C$로 가장 높다.

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Optimization of the Deflection Yoke Coil for Color Display Tubes

  • Im, Chang-Hwan;Jung, Hyun-Kyo;Jung, Kwang-Sig;Cho, Yoon-Hyoung
    • KIEE International Transaction on Electrical Machinery and Energy Conversion Systems
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    • 제11B권3호
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    • pp.81-85
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    • 2001
  • Processes for optimizing the coil shape of deflection yoke are proposed A very accurate and practical winding modeler is developed and volume integral equation method (VIEM) is used for field calculation. Two steps of optimizations are done by using (1+1) evolution strategy. Those are dimensional optimization and pin-position optimization Various techniques are applied for reducing computational time for the optimization.

우리나라 남동지방(南東地方)의 환경방사선(環境放射線) 선량율(線量率)의 결정(決定)(1980년도(年度)) (Determination of Environmental Radiation Dose Rate in the Southeastern Korea)

  • 노재식;이현덕
    • Journal of Radiation Protection and Research
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    • 제5권1호
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    • pp.1-6
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    • 1980
  • A portable count-ratemeter and a thermoluminescent detector ($CaSO_4:Dy$) have been used to obtain total gamma dose rates at approximately 50 locations during the course of several survey trips in the southeastern Korea. The purposes of these measurement were to provide a future reference data and to establish the approximate range of population exposure to the natural environmental radiation. The natural levels encountered ranged from a low of 14.6 microroentgen per hour to a high of 18.9 microroentgen per hour with a mean of $16.3{\pm}1.0$ microroentgen per hour. Among these results are the relatively high natural dose rate levels in the Masan area and Yangsan-Tongdosa area with the relatively low natural dose rate levels in the Gyeongsan-Cheongdo area and the Samrangjin-Jinyeong-Gimhae area.

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Lp BOUNDS FOR THE PARABOLIC LITTLEWOOD-PALEY OPERATOR ASSOCIATED TO SURFACES OF REVOLUTION

  • Wang, Feixing;Chen, Yanping;Yu, Wei
    • 대한수학회보
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    • 제49권4호
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    • pp.787-797
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    • 2012
  • In this paper the authors study the $L^p$ boundedness for parabolic Littlewood-Paley operator $${\mu}{\Phi},{\Omega}(f)(x)=\({\int}_{0}^{\infty}{\mid}F_{\Phi,t}(x){\mid}^2\frac{dt}{t^3}\)^{1/2}$$, where $$F_{\Phi,t}(x)={\int}_{p(y){\leq}t}\frac{\Omega(y)}{\rho(y)^{{\alpha}-1}}f(x-{\Phi}(y))dy$$ and ${\Omega}$ satisfies a condition introduced by Grafakos and Stefanov in [6]. The result in the paper extends some known results.

Effect of mixed alkaline earth doping on phosphorence properties of $BaAl_2O_4:Eu^{2+}$, $Dy^{3+}$

  • Singh, B.K.;Ryu, R.J.
    • 한국반도체및디스플레이장비학회:학술대회논문집
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    • 한국반도체및디스플레이장비학회 2006년도 추계학술대회 발표 논문집
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    • pp.22-25
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    • 2006
  • Long lasting phosphor materials are in great demand for their applications in the area of light emitting diodes (LEDs), commercial displays and warning signals. After glow longevity, brightness, photo-resistance and chemical and environment stability are most important qualities that are desired for these materials. Alumina as host lattice with various rare earth elements has been found to be good at the same time inexpensive material for the synthesis of the phosphor materials. This communication explored the effect of mixed rare earth metal on the luminescence properties of these materials for the first time. Various permutations and combinations of $Sr^{2+}$ and $Ba^{2+}$ have been investigated in order to achieve robust and high luminescence characteristics in the tailored phosphor materials.

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Axial Impact Collapse Analysis of Spot Welded Hat and Double-hat Shaped Section Members Using an Explicit Finite Element Code

  • Cha, Cheon-Seok;Kim, Young-Nam;Kim, Sun-Kyu;Im, Kwang-Hee;Yang, In-Young
    • Journal of Mechanical Science and Technology
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    • 제16권1호
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    • pp.32-38
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    • 2002
  • The purpose of this study is to analyze the collapse characteristics of widely used spot welded section members (hat and double hat section, nembers of vehicles) which possess the greatest energy absorbing capacity In an axial impact collapse. This study also suggests how the collapse load and deformation mode are obtained under impact. In the program system presented in this study, an explicit finite element code, LS-DY7A3D, is adopted for simulating complicated collapse behavior of the hat and double hat shaped section members with respect to section dimensions and spot weld pitches. Comparing the results with experiments, the simulation has been verified under a velocity of 7.19 m/sec (impact energy of 1034J)

초자기변형합금 Terfenol-D의 기초특성에 관한 연구 (A study on the fundamental characteristics of Giant Magnetostirictive Alloy, Terfenol-D)

  • 백창욱;김용권
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1994년도 하계학술대회 논문집 A
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    • pp.186-188
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    • 1994
  • Fundamental characteristics of Giant Magnetostrictive Alloy Terfenol-D$(Tb_{0.3}Dy_{0.7}Fe_{1.9\sim1.95})$ were measured by experiments. Magnetostrictions of Terfenol-D samples whose lengths are 15 and 25 mm have been measured under compressive stress from 0 to 14 MPa, when the applied magnetic field was up to 1200 Oe. The relationship between magnetostriction and field is shown graphically in the form of $H-{\lambda}$, curve. For the experiment, solenoid magnet and lever-arm-type stress equipment were designed and fabricated. The magnetostriction is measured by laser displacement measuring system and the stress applied to the sample is measured by load cell.

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형상의 대칭성을 이용한 효율적인 3차원 유한요소 해석 기법에 관한 연구 (A Study on the Efficient Finite Element Technique using Geometrical Symmetry)

  • 임창환;김홍규;이석희;정현교
    • 대한전기학회논문지:전기기기및에너지변환시스템부문B
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    • 제49권7호
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    • pp.462-467
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    • 2000
  • In general, when geometry and current distribution have a periodic or symmetric property, the analysis of a part model is sufficient to represent that of a whole model by using the periodic boundary condition. It is impossible, however, to apply the periodic boundary condition when the current distribution is not symmetric even if the geometry of the model is symmetric. In this paper, a novel technique to resolve this problem is proposed. Even when the geometry is symmetric and the current distribution is not, the proposed method enables that calculation time for a whole model is reduced to that for a part model. The proposed method is applied to a deflection yoke (DY), and validness and efficiency of the method are verified.

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Stability characteristics of DyBCO coated conductor stabilized with stainless steel

  • Dixit, Manglesh;Kim, Tae-Hyung;Oh, Sang-Soo;Song, Kyu-Jeong;Kim, Ho-Min;Park, Kwon-Bae
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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    • pp.288-289
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    • 2005
  • As high temperature superconductor applications became a reality due to increase in coated conductor performance, it is important to understand their stability behavior to design safe electrical power systems. We have experimentally studied the dependence of quench and recovery characteristics of coated conductors on the amplitude of current and duration time. The sample used in the present study is stabilized with stainless steel. Stability tests of 3 cm long sample were performed in a liquid nitrogen bath cooling condition by applying a short period over current pulses for 50 and 100 ms, with amplitude up to ~ 6 times of the critical current. The transport current that follows before and after the current pulse was fixed about ~85% the critical current. We analyzed the quench recovery using the current voltage characteristic.

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