• 한국신재생에너지학회:학술대회논문집
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• 2007.11a
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• pp.105-108
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• 2007

최근 세라믹 막은 우수한 화학적, 열적 안정성으로 기체 분리 공정에 각광을 받아왔다. 특히 혼합기체에서 고 순도의 수소를 분리해 내는 기술은 연료전지 공정에서 화학 에너지를 적기화학 에너지로 전환시키는데 중요한 역할을 차지한다. 본 연구에서는 MTES 템플레이팅 막을 이용하여 이 막 공정의 흡착 및 투과 특성을 규명하고, 이성분 혼합기체에서 고 순도의 수소를 추출해 낼 수 있는 최적 조건을 도출해 내었다. 또한, 기체 분리 거동을 살펴보기 위해 Gproms Simulator를 이용하였으며, 이때 기체상의 물질전달을 모사하기 위해 Dust Gas Model(DGM)을, 표면 확산 거동을 모사하기 위해 Generalized Stefan-Maxwell(GSM)식을 적용하였다. 이를 통해 평형론적 흡착 뿐 아니라 속도론적 흡착을 동시에 적용할 수 있게 하였다. MTES 템플레이팅 막의 흡착 및 분리능을 규명하기 위해 본 연구에서는 혼합기체의 투과, 분리 실험이 선행되었다. 실험 조건은 온도범위 $30{\sim}50$ $^{\circ}C$, 압력범위 $0{\sim}5$ atm에서 수행되었으며, 혼합기체는 2성분으로 수소 메탄, 수소-이산화탄소, 수소-질소로 기체의 구성비는 각각 50:50 이다. 본 연구를 통해 각 혼합 기체들이 정상상태에 도달하는 시간과 분리능을 계산해 내었으며, 이 분리능을 다시 온도와 압력에 따른 결과로 분석하여 어느 조건에서의 수소 분리도가 최고치를 보이는지를 규명했으며, 시뮬레이션과 비교, 대조하여 예측도를 검사하였다.

• Journal of Soil and Groundwater Environment
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• v.16 no.1
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• pp.71-81
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• 2011

Cause of contamination in the study area nearby Jang Hang Refinery is dust scattering in refinery stack, and soil washing treatment is one of the proper technologies for soil remediation in this area. Site conditions frequently limit the selection of a treatment process. A treatment technology may be eliminated based on the soil classification or physicochemical characteristics of soil. This study was assessed the soil washing efficiency by conducting of soil characteristic analysis in the vicinity of Jang Hang Refinery Stack within a 2 km radius. Also, it was decided about remedial range with comparative analysis of As in soil by Korean Standard Test Method before/after revision, whereupon As concentration in soil showed a increasing tendency after revision. As a result, the soil washing using the size separation of soil was determined through identifying of As species in the soil. In this site, only particle size distribution and water content of soil can provide the initial means of screening for the potential use of soil washing.

• 한국지구물리탐사학회:학술대회논문집
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• 2003.11a
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• pp.590-597
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• 2003

Processing and smelting of copper containing sulphide concentrates result in the accumulation of impurities into various process streams. All primary copper smelters and refineries around the world produce significant amounts of slag, dust, sludge, residues and others, which contain copper and precious metals. The recovery of these valuable metals is essential to the overall economics of the smelting process. Physical, chemical and mineralogical characterization of particular slag and Cottrell dusts from primary smelters and $Dor\'{e}$ furnace (TBRC) slag and Pressure Leached Anode slimes from a copper refinery have been carried out to understand the basic behind the recovery processes. Various process options have been evaluated and adapted for the treatment of slag from different smelting furnaces and Cottrell dusts as well as the intermediate products from copper refineries. Besides the hydro- or pyro-metallurgical treatments, the above mentioned physical separation options such as magnetic, gravity separation, flotation and precipitation flotation processes have been successfully identified and adapted as the possible process options to produce a Cu-rich or precious metal-rich concentrates for in-house recycling and other valued by-product for further treatment. The results of laboratory, pilot plant and production operations are presented, and incorporation of several alternative flowsheet is discussed in this paper.

• Proceedings of the Korean Institute of Resources Recycling Conference
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• 2003.10a
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• pp.22-34
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• 2003

Processing and smelting of copper containing sulphide concentrates result in the accumulation of impurities into various process streams. All primary copper smelters and refineries around the world produce significant amounts of slag, dust, sludge, residues and others, which contain copper and precious metals. The recovery of these valuable metals is essential to the overall economics of the smelting process. Physical, chemical and mineralogical characterization of particular slag and Cottrell dusts from primary smelters and Dore furnace (TBRC) slag and Pressure Leached Anode slimes from a copper refinery have been carried out to understand the basic behind the recovery processes. Various process options have been evaluated and adapted for the treatment of slag from different smelting furnaces and Cottrell dusts as well as the intermediate products from copper refineries. Besides the hydro- or pyre-metallurgical treatments, the above mentioned physical separation options such as magnetic, gravity separation, flotation and precipitation flotation processes have been successfully identified and adapted as the possible process options to produce a Cu-rich or precious metal-rich concentrates for in-house recycling and other valued by-product for further treatment. The results of laboratory, pilot plant and production operations are presented, and incorporation of several alternative flowsheet is discussed in this paper.

• Journal of the Korean Applied Science and Technology
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• v.32 no.2
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• pp.290-295
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• 2015

The purpose of this study is to separate nitrocellulose from 175 mm ammunition propellant by environmentally responsible recovery method. Recovery of nitrocellulose from obsolete ammunition is much more desirable than destruction since it can be reused in the several purpose. In spite of durable demilitarization of obsolete ammunition, the current holding amount of obsolete ammunition is gradually increasing and accumulated. The existing demilitarization methods, such as incineration and priming are strictly restricted for the noise, dust, oscillation and air and soil pollution. This study is focused on the separation of nitrocellulose by environmentally responsible recovery method by the solubility difference of nitrocellulose in nonpolar solvent. The purity of an extracted nitrocellulose was analysed by IR and TLC method and was clarified as very high.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.3
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• pp.282-288
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• 2023

In this study, we analyzed the amount of roadside fine dust generated from newly constructed specially modified asphalt pavement and general asphalt pavement from existing roads. We collected the 1,000 g (100 g/day) of dust samples from the roadside of the express bus terminal and commercial facility area in Chungcheongnam-do's C site at three-day intervals during the summer of 2022 and 2023. The collected samples were separated from fine dust according to size in the 75-150 ㎛ range and, were separated only from Tire and Road Wear Particles through density separation. No.1-3 are general asphalt pavement section as an existing road. Fine dust and Tire and Road Wear Particles in No.1-3 were 24.27 g, 24.36 g, 0.53 g, and 0.53 g, respectively, and the quantitative results for 2022 and 2023 were similar. On the other hand, No.4-6 are newly constructed specially modified asphalt pavement section. Fine dust decreased by 14.8 % and tire and road wear particles decreased by 29.6 % in 2023 compared to 2022 in No.4-6. In addition, according to the results of thermogravimetric analysis, Tire and road wear particles in No.1-3 are tire and road components at 30 % and 70 %, respectively. And Tire and road wear particles in No.4-6 are tire and road components at 35 % and 65 % in 2023, respectively. From these results, it was confirmed that the newly constructed specially modified asphalt pavement can be effective in reducing roadside fine dust and Tire and Road Wear Particles. However, there may be some shortcomings in conclusive research results due to limited space and sample collection period. In the future, we plan to conduct various case studies.

• Journal of Korean Society for Atmospheric Environment
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• v.29 no.3
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• pp.237-250
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• 2013

At Gosan ABC superstation in Jeju Island, we measured organic carbon (OC) and elemental carbon (EC) in $PM_{2.5}$ from October 2009 to June 2010 using a Sunset Laboratory Model-4 Semi-Continuous OC/EC Field Analyzer. It employs TOT (Thermal-Optical-Transmittance) method with NIOSH 5040 protocol and enables to continuously monitor OC and EC concentrations with 1-hour time resolution. The mean values of OC and EC for the entire period of measurements were $2.1{\pm}1.4{\mu}g/m^3$ and $0.7{\pm}0.6{\mu}g/m^3$, respectively. The OC/EC ratio was 3 and EC accounted $25{\pm}2.1%$ of total carbon (TC, TC=OC+EC). Although OC and EC showed similar trend in seasonal variation, the ratio of OC to EC was the highest in early summer when temperature was the highest and the air was affected by biomass burning in the southern part of China. In winter, the high OC and EC concentrations were likely influenced by increased coal combustion from residential heating. The high OC and EC concentrations were observed during events such as haze, dust, and the combination of the two. During the haze events, OC and EC were enhanced with increase in $PM_{10}$, $PM_{2.5}$, $SO_2$, and $NO_2$ with broad maxima. When dust occurred, both OC and EC started decreasing after reaching their maxima a couple of hours before $PM_{10}$ maximum. The peak separation of carbonaceous species and aerosol masses with time was more noticeable when haze event was followed by dust plume. These results confirm that OC and EC are key components of haze occurring in the study region.

• Resources Recycling
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• v.30 no.1
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• pp.66-76
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• 2021

Electric arc furnace dust (EAFD) contains compounds, such as oxides and chlorides, including large quantities of Zn, Pb and Fe. An efficient and stable method for the extraction of metal elements from EAFD is the Rotary Kiln Process. This method is used to recover Zn in the form of crude ZnO (approximately 60%) via the addition of a reducing agent (coke, anthracite) and limestone (for basicity control) to EAFD. This process is commonly used in industry as well as in research and development. Currently, this method is used in many Korean commercial plants, producing approximately 150,000 tons of Crude ZnO per year. The majority of Zn is found in crude ZnO (approximately 76%). In addition components such as Pb, Cd, Sn, In, Fe, Cl, and F are present as oxides, chlorides, and alkaline compounds. This elements have an adverse effect on the zinc smelting process. Therefore, a refining process that eliminates these impurities is essential. In this study, we developed a process technology that efficiently separates Zn and Pb from byproducts (mainly chlorides). A bag filter was used to collect Zn and Pb generated during the dry purification process of crude ZnO. Pure components were recovered as metals or metal carbonate.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2000.10a
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• pp.665-668
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• 2000

This paper presents development of a different substance monitoring system base reliable detection between the conveyer belt and hopper used lot materials transport line of steel company. Conventional detection method of a piece of iron separation system is losed the confidence, because of the place with bad surroundings of measurement so much that materials Production line are completely exposed to dust, moisture and vibration. For the solution of this problem, we developed a different substance detection system using the acoustic emittion sensor and one chip microprocessor which is available for bad surroundings and inexpensive. The reliability of the system was estimated by experiment.

• Proceedings of the KSME Conference
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• 2002.08a
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• pp.733-736
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• 2002

The inside configuration of intake nozzle of vacuum cleaner greatly affects the dust-collection efficiency and acoustic-noise effect generated from flow separation Interaction between high-speed flow and internal structure. In order to improve the performance of the vacuum cleaner, flow fields inside the intake nozzles were investigated using flow visualization and FIV (Particle Image Vetocimetry) technique. The measurement to aerodynamic power, suction efficiency and noise level were also carried out. Valuable information was obtained from the experiments, revealing how to modify the intake nozzle. In this paper, the results of visualization, velocity distribution of flow fields, aerodynamic power, suction efficiency and noise level are discussed.