• Title/Summary/Keyword: Dust sample

Search Result 178, Processing Time 0.024 seconds

Effects on Indoor Air Quality of Burning Chemicals (Scented Candles and Incense Sticks) (태우는 생활화학제품(향초와 인센스 스틱)의 사용이 실내 공기질에 미치는 영향)

  • Eun-Ah Park;Seungyeon Eo;Yerin Oh;Na-Youn Park;Myoungho Lee;Younglim Kho
    • Journal of Environmental Health Sciences
    • /
    • v.50 no.1
    • /
    • pp.36-42
    • /
    • 2024
  • Background: The use of scented candles and incense sticks, both of which are household products that are burned for indoor deodorization and calming effects, is increasing. Fine dust has been designated as a group 1 carcinogen by the International Agency for Research on Cancer. Volatile organic compounds (VOCs) affect air pollution and can cause diseases. Objectives: This study aims to determine the effect on indoor air quality by measuring PM2.5 and VOCs generated when burning scented candles and incense sticks. Methods: Scented candles and incense sticks were selected as household products to burn. As for the target sample, top-selling products (five types of scented candles, five types of incense sticks) were purchased online. The PM2.5 concentration according to time was measured immediately next to the sample and three meters away from each other in an enclosed space using a real-time aerosol photometer. VOCs were collected as samples under the same conditions using Tenax tubes and were quantitatively analyzed by TD-GC/MS. Results: In the case of scented candles, the concentration of PM2.5 did not increase during combustion and after being extinguished by placing a cover on the candle. For the incense sticks, the concentration of PM2.5 averaged 1,901.27 ㎍/m3. After burning scented candles and incense sticks, some VOCs concentrations were increased such as ethyl acetate and BTEX (benzene, toluene, ethylbenzene, xylene). Conclusions: Therefore, when using scented candles, extinguishment by placing a cover on the candle can be expected to reduce PM2.5. It is advisable to avoid using incense sticks because PM2.5 concentration increases from the start of combustion.

Effects of Thawing Conditions in Sample Treatment on the Chemical Properties of East Siberian Ice Wedges (동시베리아 얼음쐐기 시료의 해동방법이 시료의 화학적 특성분석에 미치는 영향)

  • Subon Ko;Jinho Ahn;Alexandre Fedorov;Giehyeon Lee
    • Economic and Environmental Geology
    • /
    • v.55 no.6
    • /
    • pp.727-736
    • /
    • 2022
  • Ice wedges are subsurface ice mass structures that formed mainly by freezing precipitation with airborne dust and surrounding soil particles flowed through the active layer into the cracks growing by repeating thermal contractions in the deeper permafrost layer over time. These ice masses characteristically contain high concentrations of solutes and solids. Because of their unique properties and distribution, the possibility of harnessing ice wedges as an alternative archive for reconstructing paleoclimate and paleoenvironment has been recently suggested despite limited studies. It is imperative to preserve the physicochemical properties of the ice wedge (e.g., solute concentration, mineral particles) without any potential alteration to use it as a proxy for reconstructing the paleo-information. Thawing the ice wedge samples is prerequisite for the assessment of their physicochemical properties, during which the paleo-information could be unintentionally altered by any methodological artifact. This study examined the effect of thawing conditions and procedures on the physicochemical properties of solutes and solid particles in ice wedge samples collected from Cyuie, East Siberia. Four different thawing conditions with varying temperatures (4 and 23℃) and oxygen exposures (oxic and anoxic) for the ice wedge sample treatment were examined. Ice wedge samples thawed at 4℃ under anoxic conditions, wherein biological activity and oxidation were kept to a minimum, were set as the standard thawing conditions to which the effects of temperature and oxygen were compared. The results indicate that temperature and oxygen exposure have negligible effects on the physicochemical characteristics of the solid particles. However, the chemical features of the solution (e.g., pH, electric conductivity, alkalinity, and concentration of major cations and trace elements) at 4℃ under oxic conditions were considerably altered, compared to those measured under the standard thawing conditions. This study shows that the thawing condition of ice wedge samples can affect their chemical features and thereby the geochemical information therein for the reconstruction of the paleoclimate and/or paleoenvironment.

Studies on the Hydrolysis of Wood with Dilute Sulphuric Acid Solution and Trichoderma viride Cellulase (묽은황산(黃酸) 및 Cellulase에 의(依)한 목재당화(木材糖化)에 관(關)한 연구(硏究))

  • Chung, In-Pyo;Kim, Hong-Eun;Min, Du-Sik
    • Journal of Korean Society of Forest Science
    • /
    • v.41 no.1
    • /
    • pp.1-6
    • /
    • 1979
  • 1. The study was conducted on the optimum condition of the treated substrate with dilute sulphuric acid solution and cellulase for saccharification. The wood (saw dust) of Alnus hirsuta Rupr. (10~15 years) was treated with 0.3%, 0.6%, 0.9%, 1.2%, 1.5%, $H_2SO_4$ solution at $1.5kg/cm^2$ for 15min., 30min., 45min., and 60min., followed by thermal treatment at $190^{\circ}C$ for 30min., and screening with 60 mesh sieve, after which to 0.5 grams of each sample was added 0.5ml cellulase solution, and 50ml 0.1M acetic acid buffer solution (pH 5.0), after incubating at $40^{\circ}C$ for 96hr. 2. The crude cellulase of Trichoderma viride Perx. ex. Fr. SANK 16374 was produced by the submerged culture process and produced in the culture fluid was salted out quantitatively by the use of ammonium sulfite. 3. Reducing sugar was determined by the 3.5-dinitrosalicylic acid (DNS) method. 4. The reducing sugar was increased with increase of the sulphuric acid concentration and saw dust was treated with 1.5% $H_2SO_4$ solution at $1.5kg/cm^2$ for 45min. showed the best saccharification (16.0%). The reducing sugar formation did not show statistically significant in 5% levels by thermal treatment time 45min. and 60min. 5. The substrate for cellulase which was treated with 0.9% $H_2SO_4$ solution at $1.5kg/cm^2$ for 60min. showed the best reducing sugar formation (23.6%). And did not show significant difference in 5% levels at 0.9%, 1.2%, and 1.5% $H_2SO_4$ solution.

  • PDF

Exposure Assessment to Particulates and Noise among Sculptors at a College of Fine Art (미술대학 조소작업 중 발생하는 분진 및 소음에 대한 노출평가)

  • Cho, Hyun-Woo;Yoon, Chung-Sik;Ham, Seung-Hon;Lee, Lim-Kyu;Park, Ji-Hoon;Park, Dong-Jin;Chung, Jin-Ho;Yeom, Jong-Soo;Seo, Kyu-Jin
    • Journal of Environmental Health Sciences
    • /
    • v.37 no.4
    • /
    • pp.267-278
    • /
    • 2011
  • Objectives: A great number of hazardous agents can be emitted from various types of art-creation in a fine arts college, but little data on exposure assessment has been published. A variety of processes encompassing toxic or non-toxic materials, tools, and components are involved in a sculptor work at a fine art college. The aim of this study was to assess exposure levels to particulates and noise during sculpture classes in a college of fine arts. Methods: Students in sculpture classes participated in this study. Mass, number, and surface area concentrations of particulates, noise level, temperature and relative humidity were monitored by both personal and area sampling during the tasks of metal, wood, and stone sculpting. Results: The number and surface concentration of particulates was the highest in the task of wood sculpting, followed by metal and stone work. The mass concentration of particulates was the highest in stone sculpting (personal GM 3.0 mg/$m^3$, GSD 3.0), followed by wood (personal GM 1.5 mg/$m^3$, GSD 1.8) and metal work (personal GM 0.95 mg/$m^3$, GSD 1.51) in that order. Occupational exposure limits (OEL) for particulates depends on the type of particulate. For wood dust, 86% (six subjects) of the personal samples and all area samples exceeded the Korean OEL for wood dust (1 mg/$m^3$), while 20% (two subjects) among stone sculpting students were exposed above the Korean OEL (10 mg/$m^3$). In contrast, metal sculpting did not exceed the OEL (5 mg/$m^3$). For noise level, metal sculpting students (Leq 95.1 dB(A) in the morning, 85.3 dB(A) in the afternoon) were exposed the most, followed by stone sculpting (88.3 dB(A)), and wood sculpting (84.8 dB(A)) in that order. Compared with the 90 dB(A) of the Korean OEL and 85 dB(A) of the American Conference of Governmental Industrial Hygienists' threshold limit value (ACGIH-TLV) for noise, 100% of the subjects (five subjects) and area samples during metal sculpting in the morning session exceeded both OELs, but only three subjects (60%) exceeded the ACGIH-TLV in the afternoon session. For stone sculpting, 50% (one subject) and 100% (two subjects) exceeded the Korean OEL and ACGIH-TLV, respectively, but the area sample did not exceed either OEL. During wood sculpting, two subjects (40%) exceeded ACGIH TLV. Conclusions: This work evaluated the sculptors' exposure to particulate matter and noise in fine art college, and revealed a poor working environment for the participating students. Effective measures should be supplemented by the administration of colleges.

A Study on the Development of Explosion Proof ESD Detector and Intrinsic Safety Characteristics Analysis (방폭구조 ESD Detector 개발 및 본질안전 특성 분석에 관한 연구)

  • Byeon, Junghwan;Choi, Sang-won
    • Journal of the Korean Society of Safety
    • /
    • v.35 no.1
    • /
    • pp.1-11
    • /
    • 2020
  • Article 325 (Prevention of Fire Explosion due to Electrostatic) of the Rule for Occupational Safety and Health Standard specifies that in order to prevent the risk of disasters caused by static electricity, fire, explosion and static electricity in the production process, However, in order to do this, it is absolutely necessary to use a pre-detection technology and a detector for antistatic discharge prediction, which is a precautionary measure by static electricity in a fire / explosion hazard place, but in Korea, And there is no technical standard for the application of the technology of the explosion proof structure of the related equipment. Research methods include domestic and overseas electrostatic discharge detection technology and literature investigation of related equipment explosion proofing technology, domestic and foreign electrostatic discharge detection device production and use situation investigation, advanced foreign technology data analysis and benchmarking. In particular, we sought to verify the results of empirical experiments using electrostatic discharge detection technology through sample purchase and analysis of related major products, development of optimization technology through prototype production, evaluation, and supplementation, and expert knowledge through expert consultation. The results of this study were developed and fabricated two prototypes of electrostatic discharge detector based on the technology / standard related to electrostatic discharge detection technology in Korea and abroad through development of electrostatic discharge detection technology and development and production of detector. In addition, based on the development of electrostatic discharge detection technology, we developed an intrinsic safety explosion proof ib class explosion proof technology applicable to the process of using and handling flammable gas and flammable liquid vapor and combustible dust. In the case of the over voltage and minimum voltage are supplied to the explosion-proof structure ESD detector, check the state of the circuit and the transient and transient currents generated by the coil and capacitor elements during the input and standby of the signal pulse voltage. Explosion-proof equipment-Part 11: Intrinsically safe explosion proof structure The comparative evaluation with the reference curve in Annex A of "i" confirms that the characteristics of the intrinsically safe explosion protection structure are met.

A Comparative Study on PM10 Source Contributions in a Seoul Metropolitan Subway Station Before/After Installing Platform Screen Doors (서울시 지하철 승강장의 스크린도어 설치 전·후 PM10 오염원의 기여도 비교 연구)

  • Lee, Tae-Jung;Jeon, Jae-Sik;Kim, Shin-Do;Kim, Dong-Sool
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.26 no.5
    • /
    • pp.543-553
    • /
    • 2010
  • Almost five million citizens a day are using subways as a means of traffic communication in the Seoul metropolitan. As the subway system is typically a closed environment, indoor air pollution problems frequently occurs and passengers complain of mal-health impact. Especially $PM_{10}$ is well known as one of the major pollutants in subway indoor environments. The purpose of this study was to compare the indoor air quality in terms of $PM_{10}$ and to quantitatively compare its source contributions in a Seoul subway platform before and after installing platform screen doors (PSD). $PM_{10}$ samples were collected on the J station platform of Subway Line 7 in Seoul metropolitan area from Jun. 12, 2008 to Jan. 12, 2009. The samples collected on membrane filters using $PM_{10}$ mini-volume portable samplers were then analyzed for trace metals and soluble ions. A total of 18 chemical species (Ba, Mn, Cr, Cd, Si, Fe, Ni, Al, Cu, Pb, Ti, $Na^+$, $NH_4^+$, $K^+$, $Mg^{2+}$, $Ca^{2+}$, $Cl^-$, and ${SO_4}^{2-}$) were analyzed by using an ICP-AES and an IC after performing proper pre-treatments of each sample filter. Based on the chemical information, positive matrix factorization (PMF) model was applied to identify the source of particulate matters. $PM_{10}$ for the station was characterized by three sources such as ferrous related source, soil and road dust related source, and fine secondary aerosol source. After installing PSD, the average $PM_{10}$ concentration was decreased by 20.5% during the study periods. Especially the contribution of the ferrous related source emitted during train service in a tunnel route was decreased from 59.1% to 43.8% since both platform and tunnel areas were completely blocked by screen doors. However, the contribution of the fine secondary aerosol source emitted from various outside combustion activities was increased from 14.8% to 29.9% presumably due to ill-managed ventilation system and confined platform space.

Metal Concentrations Analysed in the Inorganic Bulk Pigment Samples by ICP-AES and the Provision Rate of MSDS and Agreement Rate with MSDS (우리 나라에서 제조/사용하는 일부 무기 안료중 ICP-AES를 이용한 주요 중금속 농도와 MSDS 비치율 및 일치율 비교)

  • Kim, Hyoung-Ah;Lee, Kyoung-Joo;Kim, Yong-Woo;Kim, Hyun Wook
    • Journal of Korean Society of Occupational and Environmental Hygiene
    • /
    • v.8 no.2
    • /
    • pp.196-208
    • /
    • 1998
  • To improve the quality of environmental measurements and evaluation of the workplace air in the pigment manufacturing industries, we analyzed metal(chromium, cadmium, lead, iron, cobalt, manganese, antimony, titanium, arsenic, and selenium) concentrations by ICP-AES in sixty seven samples of inorganic bulk pigments which are produced and/or used in Korea. We also collected MSDS which has to be supplied by manufacturer and/or supplier and posted in the workplace according to the Hazard Communication Standards, and compared the number of metals listed in each MSDS with the number of metals determined by ICP-AES. Results were as followed; 1. Among seventeen yellowish-colored samples, chromium(2~19%) and lead(0.1~61%) were the two major metals. In thirteen reddish-colored samples, iron was the major component with 37~81%. Cobalt and manganese were detected in blue-colored samples with less than 1%, while antimony and titanium were the major two metals in white-colored pigments with 178~300 ppm and with 36~65%, respectively. 2. In area samples collected in workplace air(one pigments producing factory and five retailer stores), iron and manganese were detected but the concentrations not exceeded the TLVs(1 and $5mg/m^3$, respectively). In three of fifteen samples, the concentrations of lead exceeded the TLV ($0.05mg/m^3$). 3. Two out of seven companies provided MSDS, and the average provision rate was 22.4%. And the coincidence rate of the number of metals referenced in MSDS and determined by ICP-AES mostly accorded, but in one sample, different metal was detected from MSDS. In summary, metals have to be concerned in evaluation of the workplace air dealing with compounds of inorganic pigments dust are cobalt, chromium, iron, manganese, lead and antimony, and these are simultaneously determined by ICP-AES. Taking this opportunity, it is needed to reinforce that the personnel is to be concerned about prevention of workers' ill health regarding to provision of MSDS.

  • PDF

NIRS ANALYSIS OF MOLASSES AND EATS USED AT THE ANIMAL FEEDS INDUSTRY

  • Garrido-Varo, Ana;Perez-Marin, Maria Dolores;Gomez-Cabrera, Augusto;Guerrero-Ginel, Jose Emilio;Paz, Felix De;Delgado, Natividad
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
    • /
    • 2001.06a
    • /
    • pp.1613-1613
    • /
    • 2001
  • Fats and molasses are used, at the present time, in a considerable proportion as ingredients for the animal feed industry. They are mainly used as energy sources, but also they provide other characteristics of technological and nutritional interest (dust reduction, increase in palatability, etc). Both semi-liquid ingredients have numerous aspects in common from the point of view of their use in livestock feeds, as well as of their analytical control. Feed manufacturers use several criteria to evaluate the quality of fat and molasses. Furthermore, the traditional methods currently used, for their evaluation (eg. fatty acids, sugars, etc) are expensive and more sophisticated that the traditionally used for solid ingredients. The objective of the present work is to carry out a viability study to evaluate the ability of NIRS technology for the quality control of fat and molasses. Samples of liquid molasses (n = 42) and liquid fat ( n = 61), provided by a feed manufacturer, were scanned in a FOSS-NIR Systems 6500 monochromator equipped with a spinning module. The samples were analysed by folded transmission, using a sample cup of 0.1mm pathlength and gold surface reflector. For molasses, calibration equations were developed for the prediction of moisture (SECV=1.69%; $r^2$=0, 42), gross protein (SECV=0, 14%; $r^2$=0, 99), ashy (SECV=0, 60%; $r^2$=0, 84), NaCl (SECV=0, 05%; $r^2$=0, 99) and sugars (SECV=1, 04%; $r^2$=0, 86). For animal fats calibrations were obtained for the prediction of moisture (SECV=0, 14%, $r^2$=0, 88), acidity index (SECV=0, 83%, $r^2$=0, 82), MIU (SECV=0, 38%, $r^2$=0, 94) and unsaponifiables (SECV=0, 45%, $r^2$=0, 87). High accuracy calibration equations were also obtained for the prediction of the fatty acid profile. The equations have $r^2$values around 0.9 or highest. The results showed that NIRS technology could provide rapid and accurate results and reduce analytical costs associated to the quality control of two Important feed ingredients of a well known chemical variability.

  • PDF

Identification of PM10 Chemical Characteristics and Sources and Estimation of their Contributions in a Seoul Metropolitan Subway Station (서울시 지하역사에서 PM10의 화학적 특성과 오염원의 확인 및 기여도 추정)

  • Park, Seul-Ba-Sen-Na;Lee, Tae-Jung;Ko, Hyun-Ki;Bae, Sung-Joon;Kim, Shin-Do;Park, Duckshin;Sohn, Jong-Ryeul;Kim, Dong-Sool
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.29 no.1
    • /
    • pp.74-85
    • /
    • 2013
  • Since the underground transportation system is a closed environment, indoor air quality problems may seriously affect many passengers' health. The purpose of this study was to understand $PM_{10}$ characteristics in the underground air environment and further to quantitatively estimate $PM_{10}$ source contributions in a Seoul Metropolitan subway station. The $PM_{10}$ was intensively collected on various filters with $PM_{10}$ aerosol samplers to obtain sufficient samples for its chemical analysis. Sampling was carried out in the M station on the Line-4 from April 21 to 28, July 13 to 21, and October 11 to 19 in the year of 2010 and January 11 to 17 in the year of 2011. The aerosol filter samples were then analyzed for metals, water soluble ions, and carbon components. The 29 chemical species (OC1, OC2, OC3, OC4, CC, PC, EC, Ag, Al, Ba, Cd, Cr, Cu, Fe, Mn, Ni, Pb, Si, Ti, V, Zn, $Cl^-$, $NO_3{^-}$, $SO_4{^{2-}}$, $Na^+$, $NH_4{^+}$, $K^+$, $Mg^{2+}$, $Ca^{2+}$) were analyzed by using ICP-AES, IC, and TOR after proper pretreatments of each sample filter. Based on the chemical information, positive matrix factorization (PMF) model was applied to identify the $PM_{10}$ sources and then six sources such as biomass burning, outdoor, vehicle, soil and road dust, secondary aerosol, ferrous, and brakewear related source were classified. The contributions rate of their sources in tunnel are 4.0%, 5.8%, 1.6%, 17.9%, 13.8% and 56.9% in order.

A Study on the Heat Treatment Technology for Reduction of Oxidation Scales (산화피막 저감을 위한 열처리 기술에 관한 연구)

  • Koo, Hee Jun;Chung, Chan Kyo
    • Clean Technology
    • /
    • v.4 no.2
    • /
    • pp.41-53
    • /
    • 1998
  • Most of flame furnace with uncontrolled atmosphere forms oxidation scales in the surface during heat treatment. In this case, shot blasting and pickling are commonly used for reduction of oxidation scales. These processes have many disadvantages, such as long process time, high operating cost and environmental problems due to polishing dust, etc. Hence, this study aimed to develop the advanced heat treating equipment which could make a controlled atmosphere using a heatresisting structure into the flame furnace. The analysis result with SEM, EPMA, and EDX revealed that the amount of scales formed is much less than that with the conventional flame furnace. A brightness of the sample treated with the advanced process is similar compared to the treatment with vacuum furnace. In the present work, it was recommended that the inside structure of the furnace and gas line system could made up of SBB410 and STS310, respectively. The operating cost with the advanced heat treatment system could be reduced annually by forty million won. As a result of this study, it may be possible to reduce the oxidation scales. The fundamental information obtained in this study will be useful not only for improving the heat treatment process(reduction of shot blast and cleaning process), but for promoting the manufacture of bright products.

  • PDF