• Title/Summary/Keyword: Durability capability

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Trends in Research and Technical Development of Sorbents for Hot Gas Desulfurization for H2S Removal (H2S 제거를 위한 고온건식 탈황제의 연구 및 기술개발동향)

  • Seo, Jun-Hyung;Baek, Chul-Seoung;Kwon, Woo Tech;Ahn, Ji-Whan;Cho, Kye-Hong
    • Resources Recycling
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    • v.25 no.5
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    • pp.14-27
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    • 2016
  • Theoretical reviews of integrated gasification combined cycle one of the clean coal technologies and trends in the study and technology development for high temperature desulfurization sorbents were investigated. Reactivity, durability and abrasion resistance is an important key for development of high temperature desulfurization sorbents, the kind of things include calcium, zinc, manganese, iron and copper-based sorbents. Current status of high temperature desulfurization sorbents, manufacturing techniques of zinc-based sorbent in advanced countries has commercialized. In case of Korea, various research studies are underway to commercialize the Zn and non Zn-based high temperature desulfurization sorbents to cheaper and superior capability using various supports.

Crack Self-Healing Performance According to Absorption Test of Fiber Reinforced Concrete (콘크리트의 흡수율에 따른 균열 자기치유 성능)

  • Woo, Hae Sik;Park, Byoung Sun;Yoo, Sung Won;Choi, Young Cheol
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.2
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    • pp.122-129
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    • 2019
  • Cracks in concrete structures are inevitable phenomena caused by shrinkage, hydration heat, and external loads. These cracks facilitate the penetration of external harmful ions into the concrete, which greatly reduces its durability. Recently, self-healing concrete has been actively studied. Also, self-healing fiber-reinforced concrete have been studied to control the crack in concrete and to maximize the shelf-healing capability. In this study, mortar specimens containing PVA fiber, fly ash and crystalline admixture were fabricated. The compressive and flexural strength were evaluated. Also, the self-healing performance was evaluated by the absorption test. From the results, it was confirmed that the amount of water absorbed by healing of the crack decreased as time increased. It was also found that PVA fiber is beneficial for the production of calcium carbonate, an additional healing product.

A Study on Corrosion Resistance of CA2-Mixed Paste (CA2 혼입 페이스트의 부식저항성에 관한 연구)

  • Kim, Jae-Don;Jang, Il-Young
    • Journal of the Korean Society of Industry Convergence
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    • v.25 no.2_2
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    • pp.289-297
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    • 2022
  • Deterioration in durability of structures due to the steel corrosion is difficult to determine whether or not corrosion is initiated and how much propagated, and moreover, repair and maintenance are not easy to deal with. Therefore, preventive treatments can be the best option to avoid the deterioration. Various methods for preventing corrosion of steel, such as electrochemical treatments, anti-corrosion agents and steel surface coatings, are being developed, but economic and environmental aspects make it difficult to apply them to in-situ field. Thus, the purpose of this study was to improve corrosion resistance by using CA-based clinker that are relatively simple and expected to be economically profitable Existing CA-based clinkers had problems such as flash setting and low strength development during the initial hydration process, but in order to solve this problem, CA clinker with low initial reactivity were used as binder in this study. The cement paste used in the experiments was replaced with CA2 clinker for 0%, 10%, 20%, and 30% in OPC. And the mixture used in the chloride binding test for the extraction of water-soluble chloride was intermixed with Cl- 0.5%, 1%, 2%, and 3% by weight of binder content. To evaluate characteristic of hydration heat evolution, calorimetry analysis was performed and simultaneously chloride binding capacity and acid neutralization capacity were carried out. The identification of hydration products with curing ages was verified by X-ray diffraction analysis. The free chloride extraction test showed that the chlorine ion holding ability improved in order OC 10 > OC 30 > OC 20 > OC 0 and the pH drop resistance test showed that the resistance capability in pH 12 was OC 0 > OA 10 > OA 20 > OA 30. The XRD analyses showed that AFm phase, which can affect the ability to hold chlorine ions, tended to increase when CA2 was mixed, and that in pH12 the content of calcium hydroxide (Ca(OH)2), which indicates pH-low resistance, decreased as CA2 was mixed

UV-cured Polymer Solid Electrolyte Reinforced using a Ceramic-Polymer Composite Layer for Stable Solid-State Li Metal Batteries

  • Hye Min Choi;Su Jin Jun;Jinhong Lee;Myung-Hyun Ryu;Hyeyoung Shin;Kyu-Nam Jung
    • Journal of Electrochemical Science and Technology
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    • v.14 no.1
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    • pp.85-95
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    • 2023
  • In recent years, solid-state Li metal batteries (SSLBs) have attracted significant attention as the next-generation batteries with high energy and power densities. However, uncontrolled dendrite growth and the resulting pulverization of Li during repeated plating/stripping processes must be addressed for practical applications. Herein, we report a plastic-crystal-based polymer/ceramic composite solid electrolyte (PCCE) to resolve these issues. To fabricate the one-side ceramic-incorporated PCCE (CI-PCCE) film, a mixed precursor solution comprising plastic-crystal-based polymer (succinonitrile, SN) with garnet-structured ceramic (Li7La3Zr2O12, LLZO) particles was infused into a thin cellulose membrane, which was used as a mechanical framework, and subsequently solidified by using UV-irradiation. The CI-PCCE exhibited good flexibility and a high room-temperature ionic conductivity of over 10-3 S cm-1. The Li symmetric cell assembled with CI-PCCE provided enhanced durability against Li dendrite penetration through the solid electrolyte (SE) layer than those with LLZO-free PCCEs and exhibited long-term cycling stability (over 200 h) for Li plating/stripping. The enhanced Li+ transference number and lower interfacial resistance of CI-PCCE indicate that the ceramic-polymer composite layer in contact with the Li anode enabled the uniform distribution of Li+ flux at the interface between the Li metal and CI-PCCE, thereby promoting uniform Li plating/stripping. Consequently, the Li//LiFePO4 (LFP) full cell constructed with CI-PCCE demonstrated superior rate capability (~120 mAh g-1 at 2 C) and stable cycle performance (80% after 100 cycles) than those with ceramic-free PCCE.

Corroded and loosened bolt detection of steel bolted joints based on improved you only look once network and line segment detector

  • Youhao Ni;Jianxiao Mao;Hao Wang;Yuguang Fu;Zhuo Xi
    • Smart Structures and Systems
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    • v.32 no.1
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    • pp.23-35
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    • 2023
  • Steel bolted joint is an important part of steel structure, and its damage directly affects the bearing capacity and durability of steel structure. Currently, the existing research mainly focuses on the identification of corroded bolts and corroded bolts respectively, and there are few studies on multiple states. A detection framework of corroded and loosened bolts is proposed in this study, and the innovations can be summarized as follows: (i) Vision Transformer (ViT) is introduced to replace the third and fourth C3 module of you-only-look-once version 5s (YOLOv5s) algorithm, which increases the attention weights of feature channels and the feature extraction capability. (ii) Three states of the steel bolts are considered, including corroded bolt, bolt missing and clean bolt. (iii) Line segment detector (LSD) is introduced for bolt rotation angle calculation, which realizes bolt looseness detection. The improved YOLOv5s model was validated on the dataset, and the mean average precision (mAP) was increased from 0.902 to 0.952. In terms of a lab-scale joint, the performance of the LSD algorithm and the Hough transform was compared from different perspective angles. The error value of bolt loosening angle of the LSD algorithm is controlled within 1.09%, less than 8.91% of the Hough transform. Furthermore, the proposed framework was applied to fullscale joints of a steel bridge in China. Synthetic images of loosened bolts were successfully identified and the multiple states were well detected. Therefore, the proposed framework can be alternative of monitoring steel bolted joints for management department.

A Study on the Resistance Against Environmental Loading of the Fine-Size Exposed Aggregate Portland Cement Concrete Pavements (소입경 골재노출콘크리트포장의 환경하중 저항성에 대한 연구)

  • Chon, Beom-Jun;Lee, Seung-Woo;Chae, Sung-Wook;Bae, Jae-Min
    • International Journal of Highway Engineering
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    • v.11 no.2
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    • pp.99-109
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    • 2009
  • Fine-size exposed aggregate portland cement concrete pavements (FEACP) have surface texture of exposed aggregate by removing upper 2$\sim$3mm mortar of surface of which curing is delayed by using delay-setting agent. FEACPs have advantages of maintaining low-noise and adequate skid-resistance level during the performance period than general portland cement concrete pavements. It is necessary to ensure the durability environmental loading to prevent unexpected distress during the service life of FEACP. In the process of curing, volume change accompanied change in by moisture and temperature could be an important cause of crack in concrete to construct for successful FEACP, The use of chloride containing deicer may accelerate defects of concrete pavement, such as crack and scaling. This study aim to evaluate environmental loading resistance of FEACP, based on the estimation of shrinkage-crack-control-capability by moisture evaporation and scaling by deicer in freeze-thaw reaction.

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High Voltage Performance of the Electrical Double Layer Capacitor with Various Electrolytes (다양한 전해액을 적용한 전기이중층 커패시터의 고전압 특성 연구)

  • Kim, Jung Wook;Choi, Seung-Hyun;Kim, Jeom-Soo
    • Journal of the Korean Electrochemical Society
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    • v.20 no.2
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    • pp.34-40
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    • 2017
  • Electric double layer capacitors (EDLC: electric double layer capacitors) have drew attention as an energy storage device for the next generation because of their outstanding power capability and durability. But their usage is somewhat limited due to low energy density over secondary batteries. One of methods to improve the energy of EDLC is expanding the voltage window of cell operation by increasing the charge cut-off voltage. In this study, $SBP-BF_4$ (spirobipyrrolidinium tetrafluoroborate), $TEA-BF_4$ (tetraethylammonium tetraflouroborate) and $EMI-BF_4$ (1-ethyl-3-methylimidazolium tetrafluoroborate) in AN (acetonitrile) were selected to evaluate the possibility of application at high voltage environment. The LSV (linear sweep voltammetry) measurements showed that the 1.5M SBP-BF4/AN electrolyte was stable over a wide potential window and showed the best electrochemical performance compared to other combinations of electrolytes at high voltage environments (over 3.0 V). Furthermore, TMSP (tris(trimethylsilyl) phosphite) was applied to 1.5M SBP-BF4/AN in order to maintain stable performance at high voltage for the long period of time. The electrolyte with TMSP additive showed the capacity retention of 93% after 10,000 cycles at 3.3 V.

Behavioral characteristic of Japanese flying squid, Todarodes pacificus to LED light (발광다이오드 빛에 대한 살오징어의 행동 특성)

  • Bae, Bong-Seong;Jeong, Eui-Cheol;Park, Hae-Hoon;Chang, Dae-Soo;Yang, Yong-Su
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.44 no.4
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    • pp.294-303
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    • 2008
  • Squid jigging fishery is very important in that there are about 1,000 jigging vessels more than 10 tonnage and about 5,000 ones less than 10 tonnage in Korea. But the cost of oil which is used to light fishing lamps, goes significantly up to almost one hundred million won for 50 tonnage vessels and forty million won in case of vessels less than 10 tonnage. This cost has almost taken 40% of total fishing costs. That is, the fishing business condition of squid jigging fishery is recently in the very difficult situation. As oil price increases, the business condition of the fishery gets worse and worse. Therefore it is very urgent to develop an economical fishing lamp, to solve this problem of fishery's business difficulty. This research aims at developing a fishing lamp for squid jigging fishery using the light emitting diode which has very excellent efficiency and durability. We made a water tank with 20 meters width which is a shape of raceway to research behavioral characteristics of Japanese flying squid to LED light, and made an experiment to investigate optimum wave of LED light to lure squid. The method is to establish LED lamps on both ends of water tank and to observe squid's behavior. Colors and wave lengths of LED lamps, used in experiment, are red(634nm), yellow(596nm), green(523nm), blue(454nm) and white(454nm+560nm). In experiment for attractive capability of LED lamp to squids, Japanese flying squid are highly attracted to blue lamp and white lamp. However, they are dispersed to red and yellow lamps. In addition, Japanese flying squid have moved and stayed in both dark ends of water tank. When compared intermittent lamp with continuous lamp, Japanese flying squid are highly attracted to intermittent lamp when intermittent interval is 0.25 second.

Evaluation of Spraying Characteristics for Masonry Buildings Seismic Retrofit Fiber-Reinforced Mortar (조적조 내진보강용 섬유보강 모르타르의 분사특성 평가)

  • Hwang, Byoung-Il;Park, Jong-Pil;Yoo, Byung-Hyun;Lee, Dong-gyu
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.11
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    • pp.37-43
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    • 2020
  • The seismic reinforcement ratio of SOC facilities, such as domestic roads and railroads, is 96%. Out of approximately 7 million buildings as of 2016, only 0.51 million buildings with seismic performance were secured. Although the proportion of masonry structures is 38.8% of the total buildings, there is almost no seismic resistance, only 2.0%. To solve the problem in Korea, government-level seismic measures are being promoted, but the situation is insufficient. Overseas, the UBC research team in Vancouver, Canada, has developed and used EDCC to reinforce the seismic performance of masonry buildings. EDCC is a construction material that can secure concrete ductility capability by mixing fibers and secure deformation resistance of concrete through bridging action. It is necessary to examine various materials because EDCC is not used as a spray type of secure seismic reinforcement. In this study, as part of the research and development of spraying materials to improve the durability of masonry buildings, this study examined the spraying characteristics of fiber-reinforced mortar according to fiber use and the viscosity change according to the use of thickener. As a result, the working performance of the fiber-reinforced mortar for seismic reinforcement was improved when using 1% fiber and 1% thickener.

Fabrication and Characterization of Aluminum Honeycomb Panel (경량 알루미늄 허니콤 판재의 제작 및 특성 평가)

  • Kim, Kee Joo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.1
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    • pp.666-671
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    • 2018
  • A honeycomb panel is a plate made by attaching two surface plateson eitherside of a honeycomb core. The honeycomb plate hasexcellent specific strength and energy absorption and is suitable for use in regions where good impact resistance is required. Recently, with the increasing the need for a lightweight design to facilitate transportation, numerous studies have been conducted using aluminum honeycomb plates as body materials for vehicles such as automobiles and high-speed trains. In addition, honeycomb plates have excellent sound deadening properties, as well as excellent heat insulation and durability. Savings in weight using lightweight materials such as aluminum alloy for honeycomb panel's skin can lead to increase fuel economy and reduction in air pollution. In this study, in order to improve the design technology of the honeycomb plate material, the manufacturing technology of the aluminum honeycomb core and honeycomb plate material and various mechanical properties of the honeycomb plate were evaluated. From the results, it was found that the design of the manufacturing process of the aluminum honeycomb plate, as well as itsproduction and characteristics, were improved. The resulting excellent energy absorption capability of the honeycomb plate was due to the repetitive core buckling, indicating that the higher the compressive strength, the higher the strength per bonded area.