• Title/Summary/Keyword: Durability Evaluation

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Effects of Changes in Accelerated Degradation Conditions for Catalyst Supports in Polymer Electrolyte Fuel Cell (고분자전해질 연료전지(PEMFC)에서 촉매 지지체 가속 열화 조건 변화의 영향)

  • Sohyeong Oh;Yuhan Han;Donggeun Yoo;Myoung Hwan Kim;Ji Young Park;Youngjin Choi;Kwonpil Park
    • Korean Chemical Engineering Research
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    • v.62 no.1
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    • pp.7-12
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    • 2024
  • The durability of the catalyst support has a significant effect on the durability of proton exchange membrane fuel cells (PEMFC). The accelerated durability evaluation of the catalyst support is performed at a high voltage (1.0 to 1.5 V), and the catalyst and ionomer binder in the catalyst layer are also deteriorated, hindering the evaluation of the durability of the support. The existing protocol (DOE protocol) was improved to find conditions in which the support, which is a durability evaluation target, deteriorates further. A protocol (MDOE) was developed in which the relative humidity was lowered by 35% and the number of voltage changes was reduced. After repeating the 1.0 ↔ 1.5 V voltage change cycle, the catalyst mass activitiy (MA), electrochemical active area (ECSA), electrical double layer capacity (DLC), Pt dissolution and particle growth were analyzed. Reaching 40% reduction in mass activity, the MDOE protocol took only 500 cycles, reducing the number of voltage changes compared to the DOE method and increasing the degradation of the carbon support by 50% compared to the DOE protocol.

Durability Evaluation of Inorganic-Impregnated Concrete Exposed to Long-Term Chloride Exposure Test (무기계 침투제를 적용한 콘크리트의 장기폭로실험을 통한 염해 내구성 평가)

  • Kwon, Seung-Jun;Park, Sang-Soon;Lho, Byeong-Cheol
    • Journal of the Korea Concrete Institute
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    • v.20 no.3
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    • pp.283-290
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    • 2008
  • The repair technique using surface impregnation of reactive compound is so effective for deteriorated concrete structures that many researches are recently focused on these works. Particularly, inorganic impregnant is regarded as ecofriendly material because there is no air-pollution during manufacturing process as well as field coating works. Furthermore, The delamination between old concrete and impregnated surface does not occur, resulting from different material characteristics. In order to evaluate the durability performance of surface-impregnated concrete, durability evaluation through the long-term exposure tests is significant, however, experiments are usually limited to the temporary and qualitative laboratorial scope. In this study, durability characteristics for inorganic and organic/inorganic impregnated concrete specimens are evaluated through longterm chloride exposure test. The specimens with 21MPa and 34MPa strength have been prepared and exposed to chloride attack in the atmospheric, tidal, and submerged conditions. Evaluation for compressive strength, chloride penetration, and electrical potential (half cell potential) for steel corrosion are performed for the specimens exposed for 2 years. From the results, no distinct strength gaining is observed but the resistance to chloride penetration and steel corrosion is evaluated to be improved through surface impregnation. The more improved resistance to chloride attack is measured in the inorganic impregnated concrete and the results from atmospheric condition show more improved resistance to chloride attack than those from submerged and tidal condition.

A Study of Cosmetic Sustainability Evaluation of Powder Base Make-up Products (파우더 베이스 메이크업 제품의 지속성 평가 방법 연구)

  • Lee, Sang Gil;Kim, Ki Jung;Kim, Young Ho;Pyo, Hyeong Bae;Lee, Dong Kyu
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.41 no.3
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    • pp.209-218
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    • 2015
  • Once powder base makeup products are applied to the skin, the products are formed a film and attached on the skin for 8 to 12 hours. The makeup film is deformed by secretions such as sweat and sebum secreted from the skin. Thus, durability of the film is an important quality factor in the makeup and its evaluation is also important. In this study, characteristics of the semi-finished powder products such as water absorption, oil absorption, water repellent and oil repellent were evaluated in a number of ways. Also, simple methods, which are not affected by evaluation conditions such as a difference between sweat and sebum secretion, temperature and humidity, were examined to predict the durability of the products. We measured water absorption, oil absorption, water repellent and oil-repellent properties of semifinished product by tablet, capillary and dipping method and then compared with the data of color difference meter and ROBO skin analyzer. Results showed that the durability of powder base makeup products was associated with more oil absorption and water-repellent characteristics than water absorption and oil-repellent. Oil absorption characteristics by tablet and capillary method and water-repellent characteristics by dipping method provides a simple and quick method to precdict the durability of the makeup products.

Degradation Evaluation of PEM Water Electrolysis by Method of Degradation Analysis Used in PEMFC (고분자전해질 연료전지 열화 분석방법에 의한 PEM 수전해 열화 평가)

  • Oh, Sohyeong;Yang, Jinwon;Chu, Cheun-Ho;Na, Il-Chai;Park, Kwonpil
    • Korean Chemical Engineering Research
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    • v.59 no.1
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    • pp.1-5
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    • 2021
  • The PEM(Proton Exchange Membrane)water electrolysis uses the same PEM electrolyte membrane as the PEM fuel cell and proceeds by the same reaction but the opposite direction. The PEM fuel cell has many methods of degradation analysis since many studies have been conducted on the degradation and durability of the membrane and catalyst. We examined whether PEM fuel cell durability evaluation method can be applied to PEM electrolytic durability evaluation. During the PEM electrolytic degradation process, LSV(Linear sweep voltammetry), CV(Cyclic voltammetry), Impedance, SEM(Scanning Electron Microscope) and FT-IR(Fourier Transform Infrared spectroscopy) were analyzed and compared under the same conditions as the PEM fuel cell. As the PEM fuel cell, hydrogen passing through the membrane was oxidized at the Pt/C electrode, and the hydrogen permeation current density was measured to analyze the degree of degradation of the PEM membrane. Electrode degradation could be analyzed by measuring the electrode active area (ECSA) by CV under hydrogen/nitrogen flowing conditions. While supplying hydrogen and air to the Pt/C electrode and the IrO2 electrode, the impedance of each electrode was measured to evaluate the durability of the electrode and membrane.

A Study on Remodeling Period by Cost Analysis of Finished and Equipped Materials in Apartment Building (공동주택 내/외장재 및 설비재의 비용분석을 통한 리모델링시기 검토를 위한 연구)

  • Oh Jin-Soo;Kim Ki-Hyung;Lee Myung-Sik
    • Korean Institute of Interior Design Journal
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    • v.14 no.5 s.52
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    • pp.218-225
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    • 2005
  • In this apartment market, many apartments are being reconstructed within even less than 20 years from their first construction. This entails many problems in environmental and economical facets, for which many researches are under way in several institutions and universities. International cases show that the international trend goes for remodeling of maintenance, management, and repairing rather than new building. The purpose of this study is to investigate the factors of cost evaluation for establishing the time period of apartment based on durability of material and equipment while considering the economic feasibility of apartment, when remodeling as a concept of sustainability regarding building is being vitalized. This study investigates the proper period of remodeling in consideration of weight accruing to the LC(Life Cycle) and cost based on the standardized durability. The weight of cost, period establishment analysis, and LC according durability varies the data values of remodeling periods. The physical durability and cost from this data enable the investigation into not only the repair period of individual materials of the apartment but also remodeling period.

Durability Evaluation of Gangway Connections for the High Speed Railway Vehicles (고속철도차량 갱웨이 통로연결막의 내구성 평가)

  • Kang, Gil-Hyun;Woo, Chang-Su;Kim, Chul-Su
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.8
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    • pp.4796-4801
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    • 2014
  • To increase the riding comfort and running stability of articulated type high speed railway vehicles(HSRV), it is important that the gangway connections for the passenger car satisfied fire safety, sound proof and durability under triaxial angular displacement (rolling/yawing/pitching) modes. On the other hand, a domestic test standard on the durability of the rubber components has not been determined. In this study, the fatigue life was predicted using the results of the nonlinear finite element analysis and the fatigue properties. Moreover, a fatigue rig test of the component was constructed to examine the durability.

An Experimental Study on the Leakage Characteristics and Durability Evaluation of an LPLi Injector (LPLi 인젝터의 누설특성 및 내구평가에 관한 실험적 연구)

  • Choi, Young;Kim, Chang-Up;Oh, Seung-Mook;Kang, Kern-Yong
    • Journal of ILASS-Korea
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    • v.12 no.4
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    • pp.204-210
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    • 2007
  • The worldwide energy problem and global warming cause the need of alternative fuels which feature low carbon-dioxide emission and another energy source. Liquefied Petroleum Gas (LPG) is one of the alternative fuels widely used as domestic and transportational fuel. The third generation LPLi fuel supply system has merits in the increase of engine power and low emissions. The injectors used in LPLi system should overcome a leakage problem and satisfy the durability conditions. Therefore, 1000 hour durability test of the injectors was carried out throughout this research. First, the spray pattern and the penetration length of the selected injectors is graphically shown. Next, the leakage amount with respect to the injection cycle is introduced. Finally, the shapes of nozzle holder and nozzle tip after durability test was investigated by analyzing the microscopic image of the injector tip. The variation in the shape of nozzle tip mainly due to the residue of rubber materials is found to be the reason for leakage.

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Durability Evaluation of a Composite Carbody for Korean Tilting Train under Repeated Loadings (반복하중을 받는 틸팅열차용 복합재 차체구조의 내구성 평가)

  • Jeong, Jong-Cheol;Seo, Sung-Il;Kim, Jung-Seok
    • Journal of the Korean Society for Railway
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    • v.10 no.1 s.38
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    • pp.39-44
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    • 2007
  • This rafer explains a durability test of a large train car body made of carbon/epoxy composite material. The composite car body with the length of 23m was manufactured as a sandwich structure composed of an aluminum honeycomb core and CF1263 woven fabric carbon/epoxy faces. In order to evaluate durability of the composite car body, it was excited by two 500kN capacity hydraulic actuators installed underneath the body bolster. The natural frequency of the composite car body under full weight condition was found to be 4.33Hz. Based on this result, the excitation frequency and displacement of 5Hz and ${\pm}1.0mm$, respectively, were used as inputs for the durability test. The test was conducted for $2{\times}10^6$ cycles. During the test, the nondestructive tests using X-ray radiography and dye penetration method was performed to determine the presence of the cracks. Upon completion of the test, no cracks were found.

An Experimental Study on the Concrete Pore Structure Property (콘크리트의 공극 특성에 관한 실험적 연구)

  • Lee, Mun-Hwan;Jung, Mi-Kyung;Oh, Se-Chul;Seo, Chee-Ho
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.3 no.4
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    • pp.179-189
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    • 1999
  • This study attempts to propose an evaluation considering the property of concrete pore which affects the deterioration of neutralization and the rebar resistance of concrete. Understanding pore property of concrete in using extent, for practical using of concrete manufacturing condition. basic quality property and durability estimation etc, the results of the experiment are as follows. 1) The result of analysis pore property of every specimen with the method of area ratio, in limitation of $10^{-6}{\sim}10^{-5}m$, the pore distribution ratio was maximum. It was high value as W/C was increased and the unit cement content was decreased. 2) In case of using admixture. the volume of pores was some increased as variation of mixing content. In high W/C range, it was very increased compared with plain concrete. 3) Concerned with compressive strength and volume of pores in hardened concrete, it is possible compressive strength estimation using the property of concrete pores. 4) Direct measurement of concrete pore property is difficult. the valuation of the dynamic modulus of elasticity using ultrasonic wave velocity was available. 5) Quantitatively evaluation of concrete structure durability by past result of pore distribution estimation, and it can be estimative scale of property study on the concrete materials.

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Evaluation of Mechanical Properties and Durability of Fabric Concrete Binder for Emergency Repair (기상재해 대응 긴급보수용 패브릭 콘크리트 혼합물의 역학적 특성 및 내구성능 평가)

  • Jeon, Sang-Min;Jo, Sung-Mun;Oh, Ri-On;Kim, Hwang-Hee;Cha, Sang-Sun;Park, Chan-Gi
    • Journal of The Korean Society of Agricultural Engineers
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    • v.62 no.4
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    • pp.23-31
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    • 2020
  • Recently, meteorological disasters have been increasing by climate change, excessive rainfall, and landslide. The purpose is to develop new fabric concrete that can prevent and recover from damages because some of areas are vulnerable to meteorological disaster. Specifically, this technology can minimize time and space constraint when repairing the concrete structure and installing a formwork. The structure of fabric concrete is a mixture of fabric concrete and a high-speed hardened cement, Silica sand, wollastonite mineral fiber, fabric material and waterproof PVC fabric. In this study, the ratio of mechanical properties and durability of the fabric concrete mixture was evaluated by deriving the binder: silica sand mix ratio of the fabric concrete mixture and substituting part of the cement amount with wollastonite mineral fiber. Best binder in performance evaluation: Silica sand mix ratio is 6: 4 and the target mechanical performance and durability are the best when over 15% wollastonite binder is replaced by silicate mineral fiber.