• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.95.2-95.2
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• 2011

In order to achieve high performance and low cost for commercial applications, the development of membrane electrode assemblies (MEA), in which the electrochemical reactions actually occur, must be optimized. Expensive platinum is currently used as an electrochemical catalyst due to its high activity. Although various platinum alloys and non-platinum catalysts are under development, their stabilities and catalytic activities, especially in terms of the oxygen reduction (ORR), render them currently unsuitable for practical use. Therefore, it is important to decrease platinum loading by optimizing the catalysts and electrode microstructure. In this study, we prepared several different MEAs (non-uniform Nafion$^{(R)}$ ionomer loading electrode) which have dual catalyst layers to find the optimal Nafion$^{(R)}$ ionomer distribution in the electrodes. We changed Nafion$^{(R)}$ ionomer content in the layers to find the ideal composition of the binder and Pt/C in the electrode. For MEAs with various ionomer contents in the anodes and cathodes, the electrochemical activity (activation overpotential) and the mass transport properties (concentration overpotential) were analyzed and correlated with the single cell performance. The dual catalyst layers MEA showed higher cell performance than uniformly fabricated MEA, especially at the high current density region.

• Transactions of the Korean Society of Machine Tool Engineers
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• v.14 no.4
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• pp.104-109
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• 2005

The catalyst layer design is one of the most important factors to enhance the performance of PEMFC(Proton Exchange Membrane Fuel Cell) system. The hydrophobic and ion conductive type is studied for the MEA(Membrane Electrolyte Assembly). It is found that those have some limitations for performance enhancement when they are used separately. Thus, the dual catalyst type, a mixed model, is developed for the better MEA performance. In the meantime, the design of flow field plate is subsequently carried out in order to give more enhanced output during its operation. The conductivity of flow field plate showed better performance in the case of manufactured by the more compressed process(20MPa) than by the less compressed process(10MPa). The micro-structure of the flow field plate is examined in details using SEM(Scanning Electron Microscope) to analyse the effects on the different compression processes.

• Journal of information and communication convergence engineering
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• v.6 no.3
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• pp.305-309
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• 2008

This paper presents an innovative prototype of a new conceptual electromagnetic induction eddy current based fluid heating appliance using voltage-fed quasi resonant zero voltage soft switching PWM high-frequency inverter using IGBTs, which can operate at a constant frequency variable power regulation scheme. The promising simple high efficient low noise inverter type electromagnetic induction eddy current based pipeline fluid heating appliance is proposed for saturated steam generator, superheated steam generator, hot water and hot air producer, metal catalyst heating for exhaust gas cleaning in engine. Under these technological backgrounds, a novel electromagnetic induction eddy current Dual Packs Heater(DPH) based pipeline fluid heating incorporates thin metal layer type package for continuous fluid heating appliances applying two types of voltage-fed quasi load resonant ZVS-PWM high frequency inverter. The unique features of a novel electromagnetic induction eddy current DPH based continuous pipeline fluid heating appliance is illustrated on the basis of simulation and discussed for the steady state operating characteristics and experimental results.

• Applied Chemistry for Engineering
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• v.10 no.8
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• pp.1200-1209
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• 1999

Prediction model was composed by optimal parameter estimation from best fitting on reactant temperature profile, inlet and outlet temperature of coolant and yield of dual fixed-bed catalytic reactor(FBCR) which was measured in the industrial field. In order to design the FBCR which could obtain maximum conversion and yield, we investigated the effect of catalyst bed length and reactor radius changes. An uniform activity FBCR showed the best performance at z = 2.8 m of total catalysst bed length in case of reactor radius r = 0.01241 m and z =2.80 m(upper layer: 1.88 m, lower layer: 0.92 m) under reactor radius r = 0.01254 m for a dual activities FCBR. In case of reactor radius changes, the axial temperature profile and maximum radial temperature was rapidly risen for radius increase. The reactor radius decrease showed the opposite result.

• Journal of Electrochemical Science and Technology
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• v.9 no.3
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• pp.212-219
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• 2018

Perovskite type ceramic membranes which exhibit dual ion conduction (proton and oxygen ion conduction) can permeate water and can aid solving operational problems such as temperature gradient and carbon deposition associated with a working solid oxide fuel cell. From this point of view, it is crucial to reveal water transport mechanism and especially the nature of the surface sites that is necessary for water incorporation and evolution. $BaCe_{0.8}Y_{0.2}O_{3-{\alpha}}$ (BCY20) was used as a model proton and oxygen ion conducting membrane in this work. Four different catalytically modified membrane configurations were used for the investigations and water flux was measured as a function of temperature. In addition, CO was introduced to the permeate side in order to test the stability of membrane against water and $CO/CO_2$ and post operation analysis of used membranes were carried out. The results revealed that water incorporation occurs on any exposed electrolyte surface. However, the magnitude of water permeation changes depending on which membrane surface is catalytically modified. The platinum increases the water flux on the feed side whilst it decreases the flux on the permeate side. Water flux measurements suggest that platinum can block water permeation on the permeate side by reducing the access to the lattice oxygen in the surface layer.