The geochemical evolution of mine drainage and leachate from waste rock dumps and stream water in Pb-As-rich abandoned Sechang mine area was investigated to elucidate mechanisms of trace metals. Total and sequential extractions were applied to estimate the distribution of trace metals in constituent phases of the waste rocks and to assess the mobility of trace metals according to physicochemical conditions. These discharged waters varied largely in chemical composition both spatially and temporally, and included cases with significant]y low pH (in the range 2.1-3.3), and extremely sulphate (up to 661 mg/l and metal contents (e.g. up to 169 mg/l for Zn, 27 mg/l for As, 3.97 mg/l for Pb, 2.99 mg/l for Cu, and 1.88 mg/l for Cd). Arsenic and heavy metal concentrations at the down-stream of Sechang mine have been decreased nearly to the background level in downstream sites (sites 8 and 16) without any artificial treatments. The oxidation of Fe-sulfides and the subsequent hydrolysis, of Fe(II), with precipitation of poorly crystallized minerals, constituted an efficient mechanism of natural attenuation which reduces considerably the transference of trace metals (i.e. Fe and As) to rivers. The dilution of drainage by mixing with pristine waters provoked an additional decrease of trace metal concentrations and a progressive pH increase. On the other hand, the most soluble cations (i.e. Zn) remained significantly as dissolved solutes until the pH was raised to approximately neutral values. With respect to ecotoxicity, it is likely that the Zn pollution is of particular concern in Sechang mine area. This was confirmed by the sequential extraction experiment, where Zn in wet waste-rock samples occurred predominantly in the exchangeable fraction (65-89% of total), while Pb was the highest in the reducible and carbonate fractions, and Cd, Cu and As in the residual fraction. Pb concentration in the readily available exchangeable fraction (34-48% of total) was dominated for dried waste rock samples. Considering the proportion of metals bound to the exchangeable and carbonate fractions, the comparative mobility of metals probably decreased in the order of Zn>Pb>Cd>As=Cu.
Cheon, Mi Geon;Lee, Young Suk;Chung, Yong Mo;Kim, Hee Dae;Hong, Kwang Pyo;Kumarihami, H.M. Prathibhani C.;Kim, Jin Gook
Journal of Bio-Environment Control
/
v.28
no.4
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pp.447-453
/
2019
In this study, the effect of supplying volume and frequency of a nutrient solution consisted with $NO_3-N$ 4.6, $NH_4-N$ 3.4, $PO_4-P$ 3, K 3, Ca 4.6 and Mg $2.2mmol{\cdot}L^{-1}$ on growth and fruit quality of 'Duke' blueberry was investigated. Three years old 'Duke' blueberry bushes cultivated in containers ($60{\times}80{\times}40cm$) filled with 130L peat moss and 40L pearlite (v/v) were selected for the experiment. The growth containers were mulched with sawdust. Two different volumes (4L and 8L) of nutrient solution was tested at three different supplying frequencies (one time, two times, and three times) per week and the drainage quality of nutrient solution and fruit quality of 'Duke' blueberry was evaluated. The optimal drainage rate for the vegetable cultivation is known to be 20-30%. The results revealed that the average drainage rates of 27% and 29% for the nutrient solution supplied in 'Duke' blueberry growth medium at 4L, 2 times/7 days and 4L, 3 times/7days, respectively. The highest shoot diameter (4.2mm) and shoot length (31cm) of 'Duke' blueberry was recorded with the 8L of nutrient solution supplied at 3 times per 7 days. According to the analysis of inorganic components in the drainage of nutrient solution, there was a tendency of absorbing nitrogen at the early stage of growth. The supplying volume and frequency of nutrient solution was not significantly affected on 'Duke' blueberry fruit weight, soluble solids content, and titratable acidity. The highest yield per bush (2.7kg) was recorded for the nutrient solution supplied with 4L at three times per 7 days, while the 4L nutrient solution supplied at one time per 7 days resulted the lowest yield of 1.4kg per bush. Consequently, the tested nutrient solution can be applied for the 'Duke' blueberry bushes with the volume of 4L at three times per week for the better crop growth.
Lee, Joon Hak;Ji, Won Hyun;Lee, Jin Soo;Park, Seong Sook;Choi, Kung Won;Kang, Chan Ung;Kim, Sun Joon
Economic and Environmental Geology
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v.53
no.6
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pp.667-675
/
2020
An Alum-sludge based adsorbent (ASBA) was synthesized by the hydrothermal treatment of alum sludge obtained from settling basin in water treatment plant. ASBA was applied to remove fluoride and arsenic in artificially-contaminated aqueous solutions and mine drainage. The mineralogical crystal structure, composition, and specific surface area of ASBA were identified. The result revealed that ASBA has irregular pores and a specific surface area of 87.25 ㎡ g-1 on its surface, which is advantageous for quick and facile adsorption. The main mineral components of the adsorbent were found to be quartz(SiO2), montmorillonite((Al,Mg)2Si4O10(OH)2·4H2O) and albite(NaAlSi3O8). The effects of pH, reaction time, initial concentration, and temperature on removal of fluoride and arsenic were examined. The results of the experiments showed that, the adsorbed amount of fluoride and arsenic gradually decreased with increasing pH. Based on the results of kinetic and isotherm experiments, the maximum adsorption capacity of fluoride and arsenic were 7.6 and 5.6 mg g-1, respectively. Developed models of fluoride and arsenic were suitable for the Langmuir and Freundlich models. Moreover, As for fluoride and arsenic, the increase rate of adsorption concentration decreased after 8 and 12 hr, respectively, after the start of the reaction. Also, the thermodynamic data showed that the amount of fluoride and arsenic adsorbed onto ASBA increased with increasing temperature from 25℃ to 35℃, indicating that the adsorption was endothermic and non-spontaneous reaction. As a result of regeneration experiments, ASBA can be regenerated by 1N of NaOH. In the actual mine drainage experiment, it was found that it has relatively high removal rates of 77% and 69%. The experimental results show ASBA is effective as an adsorbent for removal fluoride and arsenic from mine drainage, which has a small flow rate and acid/neutral pH environment.
Kim, Jung Soo;Kwak, Sang Ho;Ryu, Taek Hee;Yoon, Sei Eui
Journal of Korea Water Resources Association
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v.49
no.6
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pp.537-549
/
2016
The grate inlets generally were installed to intercept surface runoff on the roads and intercepted flow was drained to the underground sewer system. The equation of interception flow was used to determine the size and spacing of grate inlet on the roads. Therefore, it is necessary to analyze the interception capacity of grate inlet. Hydraulic experimental apparatus which can be changed with the longitudinal slopes(2, 4, 6, 8, 10%) of street, the transverse slopes(2, 4, 7, 10%), and the lengths(50, 100, 150cm) of grate inlet was installed for this study. The range of the experimental discharges were calculated with change of road lanes(2, 3, 4) and design frequencies(5, 10, 20, 30year). As the transverse slope increased, it led to the increase of interception capacity at grate inlets. The long lengths of grate inlet with direction of flow increased the interception capacity by the increase of side inflow. On the basis of the hydraulic model experiment results, the empirical equations for calculation of the interception capacity were derived with regression analysis. As a result of comparison with equations, the suggested equation of this study was estimated reasonable one for increased design frequency. Therefore, this study can suggest the basic data for design of drainage facility at road.
An experiment was carried out to study the effects of Zn application on the rice plant of IR-667 and Jinheung varieties grown under the conditions of poor drainage and low available Zn. The results obtained were an follows; 1. The poor drained condition of the paddy field was more favorable for Zn utilization by the rice plants than the well drained condition. Also Zn application in the form of Zinc chloride $(ZnCl_2)$ seemed to significantly increased the rice yield of both IR-667 and Jinheung. 2. Zn content of IR-667 was much higher than that of Jinheung. The concentration of Zn in IR-667 rice plant treated by Zn fertilizer was about 200 ppm while that of control plot (not received Zn fertilizer) only 30 ppm. This result suggests that Zn application might improve the yield under the condition of poor drained soil when Zn concentration of IR-667 rice plant is around 30 ppm. 3. Absorption of Zn-65 by the rice plant was greater in the plants grown without Zn fertilizer than those with Zn fertilizer application, At harvest, the higher amount of Zn-65 was accumulated in the gram than in the straw. 4. Zn fertilization increased the grain yield in the soil of Paju, Dalsung, Chilg ok and Chungwon with low available Zn.
Journal of the korean academy of Pediatric Dentistry
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v.30
no.1
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pp.124-131
/
2003
The concentration of nitrous oxide in dental environment has increased especially in pediatric department. In pediatric department frequently met the behavior disordered patients who need the deep sedation. As the deeply sedated patients could not respond well to verbal command, the amount of mouth breathing would be increased especially with mouth prop which backward transposition of mandible. Inhalation of low concentration of nitrous oxide for a long duration has caused various side effects such as spontaneous abortion and inhibition of methionine synthetase activity which is harmful to DNA synthesis. For evaluation of factors of mouth breathing during deep sedation. The author measured the concentration of nitrous oxide in breathing zone by the change of the scavenging methods. One is drain the gas through the tail part of reservoir bag of Jackson Ree's system naturally. Another is scavenge from tail portion of reservoir bag with negative pressure. Last one is scavenge from nasal mask with negative pressure. The nitrous oxide concentration in breathing zone was the lowest in nasal part drainage but high above the recommended concentration of NIOSH. The order of nitrous concentration in breathing zone was: natural drainage, tail part with negative pressure, nasal part with negative pressure. This would reflect the order of resistance of nasal airway and showed the amount of mouth breathing. From the above experiment, the resistance of nasal airway by the increment of gas flow in corrugating tube and reservoir bag would be one of the causative factors of mouth breathing in deeply sedated patients.
Water quality model applicable paddy field was developed using field experiment during 1999 ${\sim}$ 2002. This model involves inputs from fertilization and sediment release as dirac delta function and continuous source function, respectively, and can simulate various processes such as ponded depth, surface drainage, total nitrogen concentration and total phosphorus concentration in a daily basis. The model was calibrated using data collected from field experiments which was irrigated with ground water and validated from field experiments which was irrigated with surface water. The nutrient concentration of surface water depended on the fertilization and dirac delta function can efficiently explain the valiance of nutrient concentration of surface water by fertilizer. As a result of calibration and validation, this model demonstrates good agreement. The model fit efficiencies ($R^2$) of ponded depth, surface concentration of TN and TP were 0.93,0.98 and 0.95, respectively for calibration, and those of TN and TP were 0.99 and 0.70, respectively for validation. We can apply lake and reservoir model to analysis paddy field considered with shallow ponded system, but it will need so many parameters and have much uncertainty. Fortunately, paddy field have a series of cultural practices yearly basis, such as irrigation-fertilization-forced drain-harvest with a similar time , so simple model may explain the mechanism for paddy field. Water quality model for paddy field developed in this study is simply, needs little parameters, but appeared high applicability to evaluate paddy filed drainage. We recommend this model to estimate nutrient loading from paddy field and establish best management practice.
This experiment was conducted to find out the useful data for upland crop cultivation in the newly reclaimed tidal land. Poseung silty clay loam soil was selected, and cotton(Mogpo VII) and tall fescue were cultivated under different drainage systems and soil ameliorator applications. Soil hardness and bulk density were decreased by subsurface drainage and plastic film installed at 40cm depth of the soil. Red earth application was also effective to loosen the soil, but zeolite and gypsum made the subsoil compact. Water content of the soil was high in surface drain than that of subsurface drain or plastic film curtain plot during dry season. The water content was in order of plastic film curtain, surface drain and subsurface drain. Electrical conductivity(EC) was decreased to lower than 0.4 Simens $meter^{-1}$ ($SM^{-1}$) in the subsurface drain during rainy season, and the EC of subsurface drain was maintained a quater to an half of surface drain. The yield of cotton and tall fescue were high in order of subsurface drain, plastic film curtain and surface drain plot. The yields of cotton were increased to 36-73 % by ameliorator application, and the red earth application was more effective for tall fescue growth compare to gypsum and zeolite.
Kim, Dong-Hwi;Noh, Yoojeong;Lim, O-Kaung;Choi, Eun-Ho;Choi, Ju Yong
Journal of the Computational Structural Engineering Institute of Korea
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v.31
no.2
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pp.79-85
/
2018
A two-way pump can reduce costs by draining and circulating water out and into the drum of the washing machine using a single motor whereas a conventional one-way pump uses two motors for doing the same function. However, when the water is drained through the drainage outlet in the two-way pump casing, a backward or inhalation flow occurs and the water flows to the circulation outlet. Likewise, when the water is circulated, the backward flow or inhalation makes the water flow to the drainage outlet. In this study, design optimization of the two-way pump casing is performed to maximize its performance while improving backward flow and inhalation occurring inside of the pump casing. For this, design variables of the pump casing that mainly affect the performance of the pump such as flow rate and torque of the motor were selected through the analysis of mean. Using response surface models for the performances, the ratio of the flow rate to the torque was maximized with satisfying the constraints for the back flow and inhalation through design optimization.
The levee is the facility which is constructed along with river for the protection of landside and for passage of water when there is a flood. When the seepage is exposed to the atmosphere on the landside surface of levee, it may eventually lead to levee failure. The seepage water may be removed from the landside surface by a properly designed drainage system. The purpose of the study is to show seepage control effect of a pervious toe drain, and to compare two drainage methods of a pervious toe drain. One is the pervious toe drain suggested by U.S. Army Corps of Engineers (USACE) and the other is that suggested by Japan Institute of Construction Engineering (JICE). The levee model constructed has the following dimension: the base width is 2.6 m; the crest width is 0.4 m; the side slope 1 : 2. The water depth in the riverside is 0.5 m. The shape of the toe drain by USACE is triangular. The shape of the toe drain by JICE is rectangular. They were installed with the base length of 0.4 m. The levee model without the toe drain showed saturation surface on the land side in the experiment but not with the toe drain. The experiment results was applied to a numerical analysis model using SEEP/W to calibrate and verify. The numerical analysis results for 35 cm and 30 cm drain width showed that the drain by JICE is a little bit safer than the drain by USACE. It is also easier to construct the toe drain by JICE. The results in the study would be applied to plan the seepage control for a levee with pervious toe drain.
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