• Bulletin of the Korean Chemical Society
• /
• v.31 no.2
• /
• pp.365-371
• /
• 2010

The multiconfiguration molecular mechanics (MCMM) algorithm was used to generate potential and vibrationally adiabatic energy surfaces for excited-state tautomerization in the 1:1 7-azaindole:$H_2O$ complex. Electronic structures and energies for reactant, product, transition state were computed at the CIS/6-31G(d,p) level of theory. The potential and vibrationally adiabatic energies along the reaction coordinate were generated step by step by using 16 high-level Shepard points, which were computed at the CIS/6-31G(d,p) level. This study shows that the MCMM method was applied successfully to make quite reasonable potential and adiabatic energy curves for the excited-state double proton transfer reaction. No stable intermediates are present in the potential energy curve along the reaction coordinate of the excited-state double proton transfer in the 1:1 7-azaindole:$H_2O$ complex, indicating that these two protons are transferred concertedly. The change in the bond distances along the reaction coordinate shows that two protons move very asynchronously to make an $H_3O^+$-like moiety at the transition state.

• Journal of Electrical Engineering and Technology
• /
• v.8 no.1
• /
• pp.130-136
• /
• 2013

This paper presents the magnetic equivalent circuit analysis of a double-excited, two-degree-of-freedom (DOF) motor. The double-excited, 2-DOF motor is a laminated structure, making it easy to manufacture and giving it simple operating principles. We explain the structure of the 2-DOF motor and analyze the static characteristics using a magnetic equivalent circuit (MEC) to reduce analysis time. The feasibility of MEC analysis was confirmed by experimental results of the tilting, panning motion. We also confirmed the occurrence of holding torque in every motion.

• Journal of Electrical Engineering and Technology
• /
• v.6 no.5
• /
• pp.618-625
• /
• 2011

This paper presents a double excited three degree-of-freedom (3DOF) motor. The proposed 3DOF motor is designed with a laminated structure, making it easy to manufacture. In addition, it has windings on the stator and rotor, and does not require an expensive permanent magnet. We explain the structure, principle of motion, and design of the proposed motor, and perform an analysis of the static characteristics using the two- and three-dimensional finite element methods (3D FEM). The feasibility of 3D FEM analysis is confirmed by comparing the 3D FEM analysis and experimental results for the rolling and pitching motion. We also confirm the occurrence of holding torque in every motion.

• Bulletin of the Korean Chemical Society
• /
• v.10 no.6
• /
• pp.543-546
• /
• 1989

The photocycloaddition reaction of khellin with several olefins has been investigated. The photocycloadducts are formed regioselectively on furanyl 4',5'-double bond of khellin probably due to the localization of excitation energy on the furanyl 4',5'-double bond in the reactive excited state. The photocycloaddition reaction proceeds through the excited triplet state and the same product was formed when khellin is irradiated with dimethylfumarate or dimethylmaleate indicating the formation of common intermediate. The quantum yields of photocycloadduct formation, fluorescence, and intersystem crossing are very sensitive to proton-donating ability of solvents.

• Korean Journal of Optics and Photonics
• /
• v.6 no.2
• /
• pp.165-171
• /
• 1995

Infrared-Radio frequency double resonance (IRRFDR) and Infrared-Microwave double resonance (IRMWDR) spectroscopy have been used to probe a level of A symmetry for $CD_{3}$OH. Double resonance spectra of $CD_{3}$OH have been investigated over the range of 940 to 1020 $cm ^{-1}$ . Twenty K-type doublet transitions have been observed in both the radio frequency region, which covers 50 MHz to 1 GHz, and the microwave region, which covers 8 GHz to 12 GHz. The results propose new assignments of infrared (IR) absorption transitions and far-infrared (FIR) laser emission lines. These involve torsional excited levels and CO stretch states. Measurements of the A state splitting have permitted the determination of the asymmetry splitting parameters $S^{o}$(n, K) and $^{co}$ (n, K) for (n, K)=(0.3) and (1.3)

• Proceedings of the KIEE Conference
• /
• 1993.07b
• /
• pp.1095-1097
• /
• 1993

The double excited induction motor has two sets of three-phase system : One is connected to the ac source to take care of energy convertion, and the other is to the inverter controlable frequency and/or magnitude of voltage, both of the induction mode and the synchronous mode are possible in double excitation motor, and the proposed double excitation motor can be driven as a synchronous motor by the extra three-phase input. At the synchronous mode the efficiency is improved so higher than that at induction mode or induction motor. The rating of the inverter used for speed control can be reduced upto one-fifth of that for conventional induction motor. Also the cost and maintenance fee of double excitation induction motor can be reduced compared to any other motors.

• Bulletin of the Korean Chemical Society
• /
• v.28 no.12
• /
• pp.2343-2353
• /
• 2007

We report the application of time-dependent density functional theory (TDDFT) to the calculation of potential energy profile relevant to the excited state intramolecular proton transfer (ESIPT) processes in title molecules. The TDDFT single point energy calculations along the reaction path have been performed using the CIS optimized structure in the excited state. In addition to the Stokes shifts, the transition energies including absorption, fluorescence, and 0-0 transition are estimated from the TDDFT potential energy profiles along the proton transfer coordinate. The excited state TDDFT potential energy profile of SA and 3ASA resulted in very flat function of the OH distance in the range ROH = 1.0-1.6 A, in contrast to the relatively deep single minimum function in the ground state. Furthermore, we obtained very shallow double minima in the excited state potential energy profile of SA and 3ASA in contrast to the single minimum observed in the previous work. The change of potential energy profile along the reaction path induced by the substitution of electron donating groups (-NH2 and -OCH3) at different sites has been investigated. Substitution at para position with respect to the phenolic OH group showed strong suppression of excited state proton dislocation compared with unsubstitued SA, while substitution at ortho position hardly affected the shape of the ESIPT curve. The TDDFT results are discussed in comparison with those of CASPT2 method.

• Journal of Electrical Engineering and Technology
• /
• v.10 no.3
• /
• pp.958-964
• /
• 2015

This paper implements a model of a double excited three-degree-of-freedom motor (3-DOF) coupled with a PI current controller for position control. The rotational trends of the rotor according to the applied steps are identified using a motion equation. The simulation model is a complete electrical and mechanical model of a 3-DOF motor, which mainly consists of mechanical torque equations, a nonlinear equivalent magnetic circuit, and a PI current controller. This machine is tested using the manufactured control board using the same conditions as in the simulation, where the experimental results also verify the accuracy of the simulation results.

• Journal of the Earthquake Engineering Society of Korea
• /
• v.21 no.5
• /
• pp.237-244
• /
• 2017

This study proposes a numerical model to explain the closely placed double modes in the vibration of a layered stone pagoda system. The friction surface between the stones is modelled as the Timoshenko finite element while each stone layer is modelled as a rigid body. It is assumed that the irregular asperity on the friction surface enables the stone to be excited. This results in the closely placed modes that are composed of natural modes and self-excited modes. To examine the validity of the proposed model, a set of modal testing and analysis for a layered stone pagoda mock-up model has been conducted and a set of closely placed double modes are extracted. Applying the extended sensitivity-based system identification technique, the various system parameters are identified so that the modal parameters of the proposed numerical model are the same with those of the experimental mock-up. For a horizontal impulse excitation, the simulated acceleration responses are compared with measurements.

• Proceedings of the KIEE Conference
• /
• 2005.04a
• /
• pp.76-79
• /
• 2005

This paper describes the performance analysis and design of 1-phase self-excited induction generators. The minimum parallel capacitance of self-excited capacitor connected auxiliary winding and the series capacitance of regulating voltage capacitor connected main winding is proposed the suitable value using circuit equations of main and auxiliary winding. For the steady state analysis, the equivalent circuit of 1-phase induction generators is used as circuit modeling using the double-revolving field theory. The validity of designed generator system will be confirmed by experimental and computed results.