• 대한전기학회:학술대회논문집
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• 대한전기학회 2011년도 제42회 하계학술대회
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• pp.1440-1441
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• 2011

Apatite-lanthanum silicate has attracted considerable interest in recent years due to its high oxide ion conductivity, In this paper, Bi-doped samples $La_8Bi_2(SiO_4)_6O_3$ were prepared by conventional solid-state method and the influences of Bi-dopant content on calcining temperature were reported. The Samples were characterized by X-ray diffraction (XRD) and scanning electron micrograph (SEM) and impedance analysis.

• 한국전기전자재료학회논문지
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• 제25권6호
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• pp.486-490
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• 2012

$La_{7.33}Bi_2(SiO_4)_6O_2$ specimens were fabricated by standard solid-state synthesis route for solid oxide electrolytes. The calcined powders exhibited uniform particles with a mean particle size of about $28{\mu}m$. The room-temperature structure of $La_{7.33}Bi_2(SiO_4)_6O_2$ specimens was analyzed as hexagonal, space group P63 or P63/m, and the unit cell volume increased with increase a sintering temperature. The specimens sintered at $1,175^{\circ}C$ showed X-ray patterns of homogeneous apatite single phase without the second phase such as $La_2Si_2O_7$ and $La_2SiO_5$. The specimen sintered at $1,175^{\circ}C$ showed the maximum sintered density of 5.49 $g/cm^3$. Increasing the sintering temperature, total conductivities increased, activation energy decreased and the values were $1.98{\times}10^{-5}Scm-1$ and 1.23 eV, respectively.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2007년도 제38회 하계학술대회
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• pp.234-235
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• 2007

We have fabricated superconductor ceramics by chemical process. A high Tc superconductorwith a nominal composition of $Bi_{2}Sr_{2}Ca_{2}Cu_{3}O_y$ was prepared by the organic metal salts method. Experimental results suggest that the intermediate phase formed before the formation of the superconductor phase may be the most important factor. During the sintering, doped $Ag_{2}O$ was converted to Ag particles which were finely dispersed in superconductor samples.

• 한국재료학회지
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• 제3권5호
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• pp.497-504
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• 1993

기본조성 52.5mol% $Fe_2O_3$, 25.5mol% MnO, 22mol% ZnO로 구성된 Mn-Zn페라이트에 $Bi_2O_3$ 및 $CaCO_3$을 각각 0.02, 0.05wt%첨가한 시편에 대해서 $Ta_2O_5,ZrO_2$및 $SiO_2$의 미량 첨가한 따른 미세구조와 자기적 특성변화를 조사하였다. $Ta_2O_5,ZrO_2$첨가에 따라 결정립 크기가 감소되었고, 전기시 균일한 입자로 형성된 미세구조를 가진 재료를 얻었다. $SiO_2$첨가에 따라 결정립의 이상성장이 관찰되었고 소결밀도, 전기저항, 초투자율은 감소하고 고주파 영역에서 상대손실이 증가되었다. 본 연구결과 초투자자율은 균일한 결정립에서 최대의 값을 가지며 0.02wt%$Bi_2O_3$, 0.05wt%$CaCO_3$, 0.1wt%$Ta_2O_5$ 첨가시편의 경우 10kHz, $25^{\circ}C$에서 초투자율($\mu_i$)은 6260이고 상대손실 계수(tan$\delta /\mu_i$)는 $4.2 \times 10^{-6}$ 인 높은 투자율과 낮은 손실 특성을 가진 자성재료를 얻었다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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• pp.260-260
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• 2013

Multiferroic materials have attracted much attention due to their fascinating fundamental physical properties and technological applications in magnetic/ferroelectric data-storage systems, quantum electromagnets, spintronics, and sensor devices. Among single-phase multiferroic materials, $BiFeO_3 $ is a typical multiferroic material with a room temperature magnetoelectric coupling in view of high magnetic-and ferroelectric-ordering temperatures (Neel temperature $T_N$~647 K and Curie temperature $T_C$~1,103 K). Rare-earth ion substitution at the Bi sties is very interesting, which induces suppressed volatility of Bi ion and improved ferroelectric properties. At the same time, Fe-site substitution with magnetic ions is also attracting, and the enhanced ferromagnetism was reported. In this study, $Bi_{1-x}Dy_xFe_{0.95}Co_{0.05}O_3$ (x=0, 0.05 and 0.1) bulk ceramic compounds were prepared by solid-state reaction and rapid sintering. High-purity $Bi_2O_3$, $Dy_2O_3$, $Fe_2O_3$ and $Co_3O_4$ powders with the stoichiometric proportions were mixed, and calcined at $500^{\circ}C$ or 24 h to produce $Bi_{1-x}Dy_xFe_{0.95}Co_{0.05}O_3$. The samples were immediately put into an oven, which was heated up to $800^{\circ}C$ nd sintered in air for 30 min. The crystalline structure of samples was investigated at room temperature by using a Rigaku Miniflex powder diffractometer. The field-dependent magnetization measurements were performed with a vibrating-sample magnetometer. The electric polarization was measured at room temperature by using a standard ferroelectric tester (RT66B, Radiant Technologies).

• 한국반도체및디스플레이장비학회:학술대회논문집
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• 한국반도체및디스플레이장비학회 2006년도 춘계학술대회
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• pp.194-197
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• 2006

Lead-free bismuth-layered perovskite ferroelectric europium-substituted $Bi_{4}Ti_{3}O_{12}(BTO)$ thin films have been successfully deposited on Pt/Ti/$SiO_2$/Si substrate by a sol-gel spin-coating process. $Bi(TMHD)_3,\;Eu(THMD)_3,\;Ti(OiPr)_4$ were used as the precursors, which were dissolved in 2-methoxyethanol. The thin films were annealed at various temperatures from $600^{\circ}\;to\;720^{\circ}C$ in oxygen ambient for 1 hr, which was followed by post-annealed for 1 hr after depositing a Pt electrode to enhance the electrical properties. X-ray diffraction (XRD) and scanning electron microscopy (SEM) were used to analyze the crystallinity and surface morphology of layered perovskite phase, respectively. The remanent polarization value of the BET thin films annealed at $720^{\circ}C\;was\;25.95{\mu}C/cm^2$ at an applied voltage of 5 V.

• 한국전기전자재료학회논문지
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• 제24권7호
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• pp.559-562
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• 2011

In this study, the effect of $Nb_2O_5$ and sintering time on the positive temperature of coefficient of resistivity (PTCR) behavior of lead free $Ba_{0.99}(Bi_{0.5}Na_{0.5})_{0.01}TiO_3$ (BBNT) ceramics were investigated in order to fabricate a PTC thermistor with high $T_c$ temperature more than $140^{\circ}C$. In particular, BBNT ceramic doped with 0.1mol% $Nb_2O_5$ and sintered at $1350^{\circ}C$ for 4 h has significantly increased Curie temperature ($T_c$) of about $200^{\circ}C$, showed good PTCR behavior of room-temperature resistivity ($\rho_{rt}$) of $40{\Omega}{\cdot}cm$, a high $\rho_{max}/\rho_{min}$ ratio of $43.78{\times}10^3$ and a large resistivity temperature factor (${\alpha}$) of 16.1%/$^{\circ}C$. With increasing addition of $Nb_2O_5$ content, the $\rho_{rt}$ decreased to a minimum value of $40\;{\Omega}cm$ at 0.1mol% $Nb_2O_5$ and the $\rho_{rt}$ increased for x value over 0.1 mol%.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2007년도 추계학술발표대회 및
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• pp.97.2-97.2
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• 2007

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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• pp.331-332
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• 2008

Couplings between electric, magnetic, and structural order parameters result in the so-called multiferroic phenomena with two or more ferroic phenomena such as ferroelectricity, ferromagnetism, or ferroelasticity. The simultaneous ferroelectricity and ferromagnetism (magnetoelectricity) permits potential applications in information storage, spintronics, and magnetic or electric field sensors. The perovskite BiFeO3(BFO) is known to be antiferromagnetic below the Neel temperature of 647K and ferroelectric with a high Curie temperature of 1043K. It exhibits weak magnetism at room temperature due to the residual moment from a canted spin structure. It is likely that non-stoichiometry and second-phase formation are the factors responsible for leakage current in BFO. It has been suggested that oxygen non-stoichiometry leads to valence fluctuations of Fe ions in BFO, resulting in high conductivity. To reduce the large leakage current of BFO, one attempt is to make donor-doped BFO compounds and thin films. In this study, (Bi1-x,Ndx)(Fe1-y,Tiy)O3 thin films have been deposited on Pt(111)/TiO2/SiO2/Si substrates by pulsed laser deposition. The effect of dopants on the phase evolution and surface morphology are analyzed. Furthermore, electrical and magnetic properties are measured and their coupling characteristics are discussed.

• 한국결정성장학회지
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• 제9권3호
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• pp.327-333
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• 1999

Ion implantation, photo-lithography, Ar ion milling, hot press를 이용한 micro-fabrication 방법으로 고순도 단결정 알루미나 표면에 Ca를 제한된 양으로 첨가하고, 내부에 여러 가지 형태의 기공을 갖는 bi-crystal을 만들었다. 이 bi-crystal 고순도 알루미나에 미치는 Ca의 영향을 평가하기 위하여 내부 기공의 형태 변화와 결정의 성장을 열처리에 따라 광학현미경으로 관찰하였다. 열처리에 따라 inner crack-like pore의 내부표면에 dot와 육각형의 형태를 갖는 결정 입자가 생성되는 것을 관찰할 수 있었다. $1,500^{\circ}C$로 열처리한 경우에 CaO . $6Al_2O_3$로 생각되는 bar 형태의 결정이 표면에 석출되는 것이 관찰되었으며, 이 결정이 $1,600^{\circ}C$에서 열처리하면 사라지는 것으로 보아 이 온도 부근에서 알루미나에 대한 Ca의 solubility limit 또는 diffusion rate가 변화하는 것으로 생각된다.