• The Korean Journal of Rheology
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• v.10 no.3
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• pp.160-164
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• 1998

본 연구에서 Doi-Edwards 점탄성 조성방정식의 Hadamard 안정성 분석을 행하였 다. Hadamard 안정성은 방정식의 탄성 성질과 연관되는 특성으로 파장이 짧고 진동수가 큰 파동에 의한 외란 하에서 식의 안정성을 의미한다. 먼저 안정성을 위한 일반 3차원 조건을 수립하고 단순한 1차원과 2차원 외란하에서 필요조건을 구하였다. Doi-Edwards 이론을 따 르는 물질의 단순전단유동을 고려함에 의하여 순간 전단변형률이 1.8786을 넘어설 때 파장 이 짧고 진동수가 큰 외란에 의하여 불안정성이 나타남이 증명되었다. 이 안정성의 임계치 는 실제 고분자공정 뿐 아니라 실험실에서도 쉽게 도달할수 있는 값으로 이와 같은 불안정 유동은 mi-crophase separation과 같은 물리적 현상과는 관련이 있다는 증거가 없으므로 조 성방정식 자체가 지니는 수학적 모순점에 기인한 것이라 할수 있다.

• Korea-Australia Rheology Journal
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• v.14 no.1
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• pp.33-45
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• 2002

Recent results obtained for the port-pom model and the constitutive equations with time-strain separability are examined. The time-strain separability in viscoelastic systems Is not a rule derived from fundamental principles but merely a hypothesis based on experimental phenomena, stress relaxation at long times. The violation of separability in the short-time response just after a step strain is also well understood (Archer, 1999). In constitutive modeling, time-strain separability has been extensively employed because of its theoretical simplicity and practical convenience. Here we present a simple analysis that verifies this hypothesis inevitably incurs mathematical inconsistency in the viewpoint of stability. Employing an asymptotic analysis, we show that both differential and integral constitutive equations based on time-strain separability are either Hadamard-type unstable or dissipative unstable. The conclusion drawn in this study is shown to be applicable to the Doi-Edwards model (with independent alignment approximation). Hence, the Hadamardtype instability of the Doi-Edwards model results from the time-strain separability in its formulation, and its remedy may lie in the transition mechanism from Rouse to reptational relaxation supposed by Doi and Edwards. Recently in order to describe the complex rheological behavior of polymer melts with long side branches like low density polyethylene, new constitutive equations called the port-pom equations have been derived in the integral/differential form and also in the simplifled differential type by McLeish and carson on the basis of the reptation dynamics with simplifled branch structure taken into account. In this study mathematical stability analysis under short and high frequency wave disturbances has been performed for these constitutive equations. It is proved that the differential model is globally Hadamard stable, and the integral model seems stable, as long as the orientation tensor remains positive definite or the smooth strain history in the flow is previously given. However cautious attention has to be paid when one employs the simplified version of the constitutive equations without arm withdrawal, since neglecting the arm withdrawal immediately yields Hadamard instability. In the flow regime of creep shear flow where the applied constant shear stress exceeds the maximum achievable value in the steady flow curves, the constitutive equations exhibit severe instability that the solution possesses strong discontinuity at the moment of change of chain dynamics mechanisms.

• Macromolecular Research
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• v.10 no.5
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• pp.266-272
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• 2002

Although the reptational model of Doi and Edwards gives a successful description of viscoelasticity of flexible linear polymers, the success is restricted to the terminal region./sup 1/ There have been several attempts to modify the Doi-Edwards model to describe wider range of time or frequency./sup 2-6/ This paper suggests a simple phenomenological model which can describe wider range of molecular weight than such molecular models can. Although our model is a phenomenological one, it is practical and convenient to predict the effect of molecular weight distribution on linear viscoelastic data because of its simple mathematical form.

• Korea-Australia Rheology Journal
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• v.21 no.4
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• pp.203-211
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• 2009

In flows with deformation rates larger than the inverse Rouse time of the polymer chain, chains are stretched and their confining tubes become increasingly anisotropic. The pressures exerted by a polymer chain on the walls of an anisotropic confinement are anisotropic and limit chain stretch. In the Molecular Stress Function (MSF) model, chain stretch is balanced by an interchain pressure term, which is inverse proportional to the $3^{rd}$ power of the tube diameter and is characterized by a tube diameter relaxation time. We show that the tube diameter relaxation time is equal to 3 times the Rouse time in the limit of small chain stretch. At larger deformations, we argue that chain stretch is balanced by two restoring tensions with weights of 1/3 in the longitudinal direction of the tube (due to a linear spring force) and 2/3 in the lateral direction (due to the nonlinear interchain pressure), both of which are characterized by the Rouse time. This approach is shown to be in quantitative agreement with transient and steady-state elongational viscosity data of two monodisperse polystyrene melts without using any nonlinear parameter, i.e. solely based on the linear-viscoelastic characterization of the melts. The same approach is extended to model experimental data of four styrene-butadiene random copolymer melts in shear flow. Thus for monodisperse linear polymer melts, for the first time a constitutive equation is presented which allows quantitative modeling of nonlinear extension and shear rheology on the basis of linear-viscoelastic data alone.