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Removal Characteristics of Geosmin in a Slow Sand Filteration Process (완속 모래여과 공정에서의 Geosmin 제거 특성)

  • Son, Hee-Jong;Yoom, Hoon-Sik;Jang, Seong-Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.8
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    • pp.754-760
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    • 2010
  • Geosmin removal by biodegradation was investigated in lab-scale slow sand filtration column with different empty bed contact times (EBCTs) and water temperature. Schmutzdecke layer was built up after 30 days operation and biomass and activity were $4.5{\times}10^6\;CFU/g$ and $3.42\;mg{\cdot}C/m^3{\cdot}hr$, respectively. The attached bio-film microorganisms in schmutzdecke layer were isolated and identified. The dominant species was Pseudomonas sp. that had occupied 56%. Removal efficiencies of dissolved organic carbon (DOC) and geosmin were 27% and 95% after 30 days operation. In lab-scale slow sand filtration column, geosmin and DOC removal efficiencies were 62% and 10% at $5^{\circ}C$, respectively. And increasing water temperature ($15^{\circ}C$ and $25^{\circ}C$) increased the geosmin and DOC removal efficiencies (88~100% and 25~42%) in lab-scale slow sand filtration column. Geosmin and DOC biodegradation rates (k) in the schmutzdecke layer (in the upper 5 cm filter bed) were $1.842{\sim}15.965\;hr^{-1}$1 and $0.253{\sim}1.123\;hr^{-1}$, respectively. It were about 18~32 times and 20~51 times of the rates in the deeper filter bed (5~60 cm).

Construction of Pseudoalteromonas - Escherichia coli shuttle vector based on a small plasmid from the marine organism Pseudoalteromonas (극지해양 Pseudoalteromonas 유래의 소형 플라스미드에 기반한 Pseudoalteromonas - Escherichia coli 셔틀벡터 제작)

  • Kim, Dockyu;Park, Ha Ju;Park, Hyun
    • Korean Journal of Microbiology
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    • v.52 no.1
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    • pp.110-115
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    • 2016
  • A small plasmid (pDK4) from the Antarctic marine organism Pseudoalteromonas sp. PAMC 21150, was purified, sequenced and analyzed. pDK4 was determined to be 3,480 bp in length with a G+C content of 41.64% and contains three open reading frames encoding a replication initiation protein (RepA), a conjugative mobilization protein (Mob) and a hypothetical protein. PCR-amplified pDK4 was cloned in high-copy pUC19 to yield the fusion vector pDOC153. The chloramphenicol resistance gene was inserted into pDOC153 to give an ampicillin and chloramphenicol-resistant, Pseudoalteromonas - Escherichia coli shuttle vector (7,216 bp; pDOC155). The TonB-dependent receptor (chi22718_IV ) and exochitinase (chi22718_III ) genes from Arctic marine P. issachenkonii PAMC 22718 were cloned into pDOC155 to produce pDOC158 and pDOC165, respectively. Both vector derivatives were transferred into plasmid-free Pseudoalteromonas sp. PAMC 22137 by the triparental mating method. PCR experiments showed that the genes were stably maintained both in Pseudoalteromonas sp. PAMC 22137 and E. coli $DH5{\alpha}$ cells, indicating the potential use of pDOC155 as a new gene transfer system into marine Pseudoalteromonas spp.

An Investigation of Performance Change of Diesel Oxidation Catalyst for Diesel Vehicle (경유차 적용 디젤산화촉매장치의 성능 변화 분석)

  • Hwang, Jin-Woo;Lee, Chang-Sik
    • Journal of ILASS-Korea
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    • v.14 no.1
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    • pp.15-19
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    • 2009
  • This paper is to investigated the analysis of performance characteristics of diesel oxidation catalyst (DOC) for diesel vehicle with 2.5L piston displacement. The performance evaluation test of DOC applied to test diesel vehicle was carried out for four kinds of DOCs manufactured from different company. The testing DOCs were randomly selected from the retrofit vehicle and then standard test vehicle that was representative for the application group was equipped with DOC for the test. In this verification test, the reduction rate of particulate matter (P.M.) and the deviation of the performance of the DOC were examined through CVS-75 mode of the standard vehicle and SOF reduction rate of specific DOC was investigated. It was found that some DOCs failed to pass the criteria of the P.M. reduction rate because of the reason seen catalyst aging even if they were same devices. In the result of SOF analysis, the specific DOC showed more PM reduction than SOF of PM. reduction exceptionally.

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The Removal of Natural Organic Matter and Disinfection By-Product Precursor by Ozone (오존처리에 의한 천연유기물질 변화 및 염소 소독부산물 전구물질 제어)

  • Son, Hee-Jong;Roh, Jae-Soon;Kim, Sang-Goo;Kang, Lim-Seok;Lee, Yong-Doo
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.10
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    • pp.1099-1107
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    • 2005
  • The purpose of this study was to find the transformation of organic matter as well as chlorine by product formation potential with ozone dosage. The removal percents of $UV_{254}$ and DOC were $23%{\sim}65%$ and $2%{\sim}15%$ and THMFP and HAAFP were $17%{\sim}52%$ and $9%{\sim}29%$ respectively at $0.5{\sim}3\;mgO_3/mgDOC$ ozone dosage. The hydrophobic and transphobic organic matter were reduced to $37%{\sim}68%$ and $35%{\sim}64%$, on the other hand the hydrophilir organic matter was increased to $40%{\sim}49%$ at $0.5{\sim}3\;mgO_3/mgDOC$ ozone dosage. The produced THMFP and HAAFP from the hydrophobic and transphilic organic matter were decreased greatly with increasing ozone dosage but these by products were increased in the hydrophilic matter. The produced THMFP and HAAFP per unit DOC were decreased and reactivity was reduced greatly with increasing crone dosage. The removal rate of THMFP per unit DOC was much higher than HAAFP by ozone treatment. The Br-THMFP per unit DOC was much more removed than chloroformFP per unit DOC with increasing ozone dosage. and The removal rate of TCAAFP per unit DOC was increased with increasing ozone dosage but TCAAFP was not affected by ozone treatment. Br-HAAFP was decreased at $1\;mgO_3/mgDOC$ ozone dosage but was not more removed above $1\;mgO_3/mgDOC$ ozone dosage. Br-HAAFP had lower removal effect than Br-THMFP by ozone treatment. The optimal ozone dosage can be determined about $1\;mgO_3/mgDOC$ by considering both disinfection by product formation and economical efficiency.

Removal of Odor and THM from the Raw Water of Daecheong Dam (대청호 원수내 냄새 및 THM 제거방안 연구)

  • Jeon, Hang-Bae;Yun, Gi-Sik
    • Journal of Korea Water Resources Association
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    • v.30 no.3
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    • pp.235-245
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    • 1997
  • A pilot scale study for removing odor and trihalomethane formation potential (THMFP) was investigated in the standard water treatment plant equipped with ozone oxidation and granular activated carbon (GAC) adsorption processes. The removal efficiency of dissolved organic carbon (DOC) in the pilot scale standard water treatment process (PSWTP) was about 25%, however, no more removal in the ozone oxidation process. On a GAC after 30 days operation, DOC removal efficiency was about 75%. Odor removal efficiency was about 30% in PSWTP, 60% in ozone oxidation, and almost complete in well as DOC. Mid-1 and 2 that showed breakthrough in odor inducing material as well as DOC. Mid-1 and 2 chlorination was able to reduce trihalomethanes (THM) by 25% compared to prechloringation, while postchlorination alone could reduce them by 30%.

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A Critical Review for the Effect of Ozonation on Biodegradability in Drinking Water Treatment Systems (전오존처리에 의한 상수원수의 생물학적 처리효율제고에 관한 연구)

  • Nam, Sang-Ho
    • 수도
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    • v.24 no.4 s.85
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    • pp.79-87
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    • 1997
  • In an effort to prevent the formation of DBPs from disinfection and the microbial regrowth in distribution systems, the ozonation followed by biological filtration process in drinking water treatment train has been recently developed as an alternative process to reduce effectively water-born organic matter as precursor. There are, however, insufficient for the consistent information and data about the relation between ozone dosage based on organic surrogate parameter, TOC or DOC and effect of ozonation on BDOC formation. This study is to review critically for the effect of ozonation on biodegradability on the basis of published technical papers including the output from author's research laboratory. It truned out that : 1. ozonation in the presence of organic matter has a tendancy to increase in BDOC content, 2. the rate of BDOC formation was maximum below 1mg $O_3/mg$ DOC of ozone dose, but about maximum content of BDOC was obtainable at the range from 1.5mg $O_3/mg$ DOC to 2mg $O_3/mg$ DOC, 3. from above 1mg $O_3/mg$ DOC, the rate of BDOC formation became slow down, 4. from above 2mg $O_3/mg$ DOC, BDOC formation was quantitatively negligible, In conclusion, it needs further systematic study and research concerned to biodegradability and treatability by ozonation in terms of organic characteristics and experimental conditions because it was hard to find out the consistent experimental data comparable each other that were performed by numbers of research authors.

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The Fractionation Characteristics of Organic Matter in Pollution Sources and River (오염물질 배출원과 하천에서의 유기탄소 분포 특성)

  • Kim, Ho-Sub;Kim, Sang-Yong;Park, Jihyung;Han, Mideok
    • Journal of Korean Society on Water Environment
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    • v.33 no.5
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    • pp.580-586
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    • 2017
  • The fractionation characteristics of organic matter were investigated in inflow and effluent of each other pollution sources and river. While the DOC/TOC ratio in the influent of public sewage treatment plant and livestock disposal facilities was above 0.58, the POC/TOC ratio of human livestock Night soil treatment plant and stormwater runoff was more than 0.7. The TOC removal efficiency of public sewage treatment plant and human livestock Night soil treatment plant were 88.5 % and 99.6 %, respectively. Although the concentration distribution of organic matter pollution most of total organic carbon (TOC) in effluent of pollution sources accounted for dissolved organic carbon (DOC) type (DOC/TOC ratio >0.89) and Refractory-DOC (RDOC)/TOC ratio was higher (>0.65). The fractionation characteristics of organic matter in river were similar with that of sewage treatment plant and TOC concentration showed the positive correlation with DOC ($r^2=0.93$) and RDOC ($r^2=0.89$) concentration. The decay rate of Labile DOC (LDOC) (avg. $0.128day^{-1}$) was higher than labile particulate organic carbon (LPOC) ($0.082day^{-1}$), while that of DOC ($0.008day^{-1}$) was lower than POC ($0.039day^{-1}$) (paired t-test, p < 0.001, n = 5). These study results suggested that it should consider important both TOC and DOC as the target indicator to control refractory organic matter in pollution sources.

Issues on Particular Market Situation to Calculate Dumping Margin of Korean Steel Products by the USA

  • Wang, Jingjing;Choi, Chang Hwan
    • Journal of Korea Trade
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    • v.25 no.1
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    • pp.89-111
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    • 2021
  • Purpose - The U.S. Trade Preference Expansion Act (TPEA) of 2015 enables the US Department of Commerce (DOC) to inflate dumping margin when the particular market situation (PMS) exists in the exporter's home market. DOC applied PMS provisions to the steel products from Korea. This paper analyzes whether DOC's calculation by using the regression analysis is consistent with WTO rules. Design/methodology - This paper analyzes the PMS application in law and regression analysis that extends the data period from 10 years to 18 years using the same economic model with DOC, and changes the country group according to the quantities of steelmaking capacity. Findings - Results show that DOC's argument conflating the sales-based with cost-based PMS designed to inflate dumping margins might not be consistent with WTO Antidumping Agreement Article 2.2 and 2.2.1.1 in which costs shall normally be calculated on the basis of records kept by the exporter, providing generally accepted accounting principles and reasonably reflection of the costs and PMS that exists in the Korean steel product markets. Even if it will be consistent, DOC's calculated margin by the regression analysis using a 10-year data is a big gap (5 times) compared with an 18-year data projection and different countries' data through the same methodology, which is a huge gap of regression coefficient. It means that dumping margin would be very wide range from 7.8% to 38.54% and unstable to calculate. Inflating dumping margin by DOC using regression analysis would not only be inconsistent with WTO rules, but also projection result is unreliable. Originality/value - Literature papers have mainly analyzed WTO law itself. This paper however, would be the first attempt to analyze the DOC's new way of dumping margin calculation in both manners of law and an empirical methodology perspective at the same time.

Characteristics of Apparent Molecular Weight Distribution and Removal of DOC by Coagulation and Sedimentation Process with Polyaluminum Chloride in Nakdong River Water (응집·침전 공정에서 PAC를 이용한 낙동강 원수의 DOC 제거 및 분자량 분포 특성)

  • Kim, Yeong-Tak;Kim, Eun-Hee;Rhim, Jung-A;Yoon, Jeong-Hyo;Kim, Dong-Youn
    • Journal of Korean Society of Water and Wastewater
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    • v.13 no.1
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    • pp.125-133
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    • 1999
  • The objective of present work is to evaluate the optimum coagulation conditions in order to decrease dissolved organic carbon(DOC) and turbidity at different polyaluminum chloride dosage and pH from Nakdong River water. This studies were carried out to examine distribution on apparent molecular weight(AMW) of DOC in the Nakdong River water and its coagulation-sedimentation water. On the basis of jar tests, at the optimum coagulation pH in order to decrease DOC and turbidity were pH 5.0~6.0 and optimum dosage of polyaluminum chloride were 10~15mg $Al_2O_3/L$. The removal percentage of DOC and UV-254 absorbance were 35~40%, 45~60%, respectively. In pilot plant, at the optimum coagulation pH in order to decrease DOC and turbidity were 5.0-6.5, and the removal percentage of DOC were 30~45%. Distributions of AMW in the Nakdong River, less than 6,800dalton were 60.7% 6,800~11,000dalton were 32.8%, more than 11,000dalton were 6.4%. When the polyaluminum chloride dosage was 12~20mg/L, the removal percentages of each AMW for AMW of Nakdong River water, less than 6,800dalton were 25~28%, 6,800~11,000dalton were 65~68% more than 11,000dalton were 10~60%.

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Runoff Characteristics of Refractory Organic Matters from Kyongan River Watershed during Rainfall Event and Dry Season (경안천 유역의 강우 시, 비 강우 시 난분해성 유기물질 유출 특성)

  • Kim, Taewon;Gil, Kyungik
    • Journal of Korean Society on Water Environment
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    • v.27 no.4
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    • pp.397-404
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    • 2011
  • This research investigates the runoff characteristics of refractory organic matters from Kyongan river watershed. Samples were taken 27 times during dry season, 4 times during rain events and analyzed into flow rate, Dissolved Organic Carbon (DOC), Particulate Organic Carbon (POC), Refractory Dissolved Organic Carbon (R-DOC), Refractory Particulate Organic Carbon (R-POC). R-DOC during dry season was the lowest in winter and showed a rising tendency in spring and R-POC changes less than R-DOC. The mass loading of Refractory Total Organic Carbon (R-TOC) in summer takes approximately 80% of 1 year mass loading. During rainy season, EMC of R-DOC was similar to R-DOC in dry season. But maximum EMC of R-POC was 12 times higher than that of R-POC in dry season. Results of the survey show that enhanced management of R-DOC in dry season and R-POC in rainy season is needed.