• Journal of Korean Society for Atmospheric Environment
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• v.22 no.1
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• pp.63-71
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• 2006

An automated carbonyl measurement system was constructed. Atmospheric carbonyl compounds were extracted onto DNPH containing collection solution while flowing through a glass coil. Each carbonyl species was separated on a HPLC column and quantified by UV absorption detector. Using this system, carbonyl compounds were continuously measured at the campus of Korea University in Seoul, Korea during June, 2005. Sampling resolution was 30 minutes and the detection limit of HCHO was 0.19 ppbv. Also, $\O_{3}$, it's precursors, and meteorological parameters were measured. The maximum, minimum, average, and median concentrations of HCHO during the whole experiment was 35.8 ppbv, 1.4 ppbv, 11.7 ppbv, and 9.3 ppbv respectively. Formaldehyde showed a distinct diurnal variation with a broad maximum around 13 $\sim$ 15, which was 1 $\sim$ 3 hours ahead of an ozone maximum. During a couple of days, however, HCHO concentrations were kept high through the night or increased concomitantly with NOx in the morning. These results imply that HCHO was mainly produced from the photochemical oxidation of VOCs, but local emission sources couldn't be ruled out. The differences between daily maximum and minimum of $O_{3}$ and HCHO were calculated for 11 days of June, when typical diurnal variations were observed for the two species. A strong positive correlation was found between $\Delta O_{3}$ and $\Delta HCHO$ and the average mole ratio of $\Delta HCHO$ to $\Delta O_{3}$ was 2.6. It indicates that formaldehyde played a key role in $\Delta O_{3}$ production as an indicator species in Metropolitan Seoul during June, 2005.

• Journal of Environmental Science International
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• v.16 no.10
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• pp.1157-1167
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• 2007

In an effort to interpret the characteristics of fine particle concentrations in Busan, time variations of hourly monitored concentrations $PM_{10}$ (Particulate Matter with aerodynamic Diameter ${\le}10\;{\mu}m$) in Busan are analyzed for the period from 2000 to 2005. The characteristics of aerosol second generation formation process is also interpreted qualitatively, by using the statistical analysis of the meteorological variables including temperature, wind speed, and relative humidity. The result shows some significant annual, seasonal, weekly and diurnal variations of $PM_{10}$ concentrations. In particular, seasonal(i.e., spring) variations are governed by frequency of yellow sand events even for the non-yellow sand cases where yellow-sand days are eliminated in our analysis. However, in seasonal variation, summer season predominate lower $PM_{10}$ concentrations due to the frequent precipitation, and weekly and diurnal variations are both found to be reflecting the emission rate from traffic amount. Correlation coefficients between $PM_{10}$ concentration and meterological variables for non-yellow sand days show overall negative correlation with visibility, wind speed, cloud amounts, and relative humidity. However for non-precipitation days, during non-yellow sand period positive correlation are found clearly with relative humidity, suggesting the importance of secondary aerosol formation in Busan that can be achieved by both homogeneous aerosol formation and heterogeneous transformations resulting from hygroscopic aerosol characteristics.

• 한국태양에너지학회:학술대회논문집
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• 2009.11a
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• pp.21-25
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• 2009

This study is about heat island as one of the urban climate variation factors in urbanized modern society, which compared and observed the thermal characteristics both the downtown location and the outskirt site in summer. The diurnal air temperature range at each point is $12.6^{\circ}C$ in the downtown location and $14.3^{\circ}C$ in the outskirt site, so, it was found that the diurnal air temperature range in the outskirt site was $1.7^{\circ}C$ higher than in the downtown location. There was 20 minutes difference to reach the highest temperature between globe temperature and air temperature in the downtown location, however, the time spent to reach the highest temperature between globe temperature and air temperature in the outskirt site was the same. When we compared the globe temperature between the downtown location and outskirt site, we found that the temperature in the outskirt site was lower than in the downtown location after sunset due to the sudden temperature drops, although the exposed time to insolation in the outskirt site is longer. The average of globe temperature difference on the sample days was $1.1^{\circ}C$, the average of surface temperature difference on the sample days was $1.0^{\circ}C$, and the average of air temperature difference on the sample days was $2.0^{\circ}C$ Thus, it was found that the average of air temperature difference was higher than the average of globe temperature and the average of surface temperature. The result of this study is that the urban environment factors have more effect on the air temperature difference than globe temperature and surface temperature.

• Journal of Environmental Science International
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• v.4 no.1
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• pp.63-70
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• 1995

Continuous measurements of ground-level ozone (O3) were made in five minutes intervals in the rural area of Korea from July 1993 to June 1994. This site is located in Chongwon, near latitude 36.4$^{\circ}$N, longitude 127.6$^{\circ}$E. The results show that the one-year mean value was 17 ppb, and monthly mean ranged from 6 to 47 ppb. A pronounced maximum in summer and a minimum in winter were found, and these were related to anthropogenic emission and photochemical reaction. Diurnal variations of ozone minimum at 07:00 - 08:00. During the period when ozone concentration was very high (> 80 ppb), the stable winds were from N and UW; on the other hand, when ozone concentration was very low, air movement in the large scale was from the North Pacific Ocean. This suggests that in the rural area the long range transport of anthropogenic pollutants from distant sources can contribute to the larger contribution than the generation of ozone from local sources in the rural area.

• Journal of Environmental Science International
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• v.28 no.1
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• pp.107-123
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• 2019

The aerosol chemical components in $PM_{2.5}$ in several regions (Seoul, Busan, Daejeon, and Jeju Island) were investigated with regard to their concentration characteristics and optical properties. The optical properties of the various aerosol components (e.g., water-soluble, insoluble, Black Carbon (BC), and sea-salt) were estimated using hourly and daily aerosol sampling data from the study area via a modeling approach. Overall, the water-soluble component was predominant over all other components in terms of concentration and impact on optical properties (except for the absorption coefficient of BC). The annual mean concentration and Aerosol Optical Ddepth (AOD) of the water-soluble component were highest in Seoul (at the Gwangjin site) ($26{\mu}g/m^3$ and 0.29 in 2013, respectively). Further, despite relatively moderate BC concentrations, the annual mean absorption coefficient of BC ($21.7Mm^{-1}$) was highest in Busan (at the Yeonsan site) in 2013, due to the strong light absorbing ability of BC. In addition, high AODs for the water-soluble component were observed most frequently in spring and/or winter at most of the study sites, while low values were noted in summer and/or early fall. The diurnal variation in the AOD of each component in Seoul (at the Gwangjin site) was slightly high in the morning and low in the afternoon during the study period; however, such distinctions were not apparent in Jeju Island (at the Aweol site), except for a slightly high AOD of the water-soluble component in the morning (08:00 LST). The monthly and diurnal differences in the AOD values for each component could be attributed to the differences in their mass concentrations and Relative Humidities (RH). In a sensitivity test, the AODs estimated under RH conditions of 80 and 90% were factors of 1.2 and 1.7 higher, respectively, than the values estimated using the observed RH.

• Journal of Korean Society for Atmospheric Environment
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• v.7 no.3
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• pp.227-234
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• 1991

This study deals with concentration and light extinction of atmospheric aerosol in Seoul. From the measured aerosol size distribution for particle diameter ranging from 0.01 $\mum \sim 1.0 \mum$, extinction coefficient is calculated using the Mie theory. The results show that the diurnal variation of aerosol concentration, in general, reveals the lowest concentration in early morning and afternoon, while the highest at about 8 O'clock owing to the heavy traffic and accumulation of air pollution in the low atmosphere. However, aerosol concentration and extinction coefficient on April 7 give low values due to the advective wind. On the other hand, high aerosol concentration and extinction coefficenat are recorded on April 10 although solar radiation is weak. From the distribution of extinction coefficient we can find that aerosol particles of 0.1 $\mum \sim 1.0 \mum$ in diameter are highly effective on light extinction.

• Journal of Environmental Science International
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• v.3 no.4
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• pp.381-391
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• 1994

This paper presents the disributions and variations of CO, $CO_2$, number of people and temperature in underground shopping center and subway of Seomyeon and Jagalchi in Pusan, Korea for two times during October and November in 1993, respectively. NDIR analyzer is used for the analysis of CO and $CO_2$. The temperature is obtained from a mercury therometer. The results o( observation and analysis show that the variation of $CO_2$ is strongly related to number of people and temperature. The correlation coefficients between temperature, COB and Number of people are higher than 0. at both of places. The pollution of CO2 of Seomyeon is higher than that of Jagachi in underground shopping center. However, CO is not correlated with the temperature and the Number of people. From the results, we found that the indoor air quality monitoring system is needed for the prevention of the underground air Pollution.

• Journal of Environmental Science International
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• v.8 no.3
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• pp.287-292
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• 1999

This study was performed to investigate the characteristics of nocturnal maxiumu ozone occurrence and the meteorological relevance using to hourly ozone data and meteorological data for 1995~1996 in Pusan coastal area. Kwangbokdong showed the highest occurrence of nocturnal maximum ozone as 36.9%, and Deokcheondong showed the lowest occurrence(9.2%) for research period in Pusan. The occurrence rates of nocturnal maximum ozone concentration were decreased toward land area. The low maximum temperature, high minimum temperature, low diurnal range, high relative humidity, high wind speed, high could amount, low sunshine and low radiation were closely related to the main meteorological characteristics occuring the nocturnal maximum concnetration of ozone. It was shown that normal daily variation of ozone concentration by strong photochemical reaction at the before day of nocturnal maximum ozone. The concnetration of nocturnal maximum ozone were occured by entrainment of ozone from the upper layer of developed mixing layer. There are no ozone sources near the ground at night, so that the nighttime ozone should be entrained from the upper layer by forced convection.

• Journal of Environmental Science International
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• v.18 no.8
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• pp.825-831
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• 2009

A first step review is completed on the suitability of European designed wind turbines in an East Asia climate. Six parameters are chosen for detailed analysis of proper meteorological measures from flat, hilly, forested, coastal and offshore sites in West Europe and East Asia: mean wind speed, 10 minute mean wind speed distribution, turbulence intensity, wind shear, 3 second extreme wind speed and 10 minute direction change. All six parameters are assessed with a view for contrast with the wind turbine design standard IEC61400. The diurnal and seasonal variation, average and extreme values of each parameter are calculated where appropriate. Industry standard software and analysis techniques have been employed to assess the applicability of existing wind turbine design standards and design guidelines for the East Asian market.

• Proceedings of the KSRS Conference
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• 2003.11a
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• pp.537-539
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• 2003

We present a GPS-derived regional ionosphere model, which estimates Total Electron Content (TEC) in rectangular grids on the spherical shell over Korea. The GPS data from nine GPS stations were used. The pseudorange data were phase-leveled by a linear combination of pseudoranges and carrier phases. During a quiet day of solar activity, the regional ionosphere map indicated 30-45 Total Electron Content Unit (TECU) at the peak of the diurnal variation. In comparison with the Global Ionosphere Map of the Center for Orbit Determination in Europe, RMS differences were at the level of 4-5 TECU for five days.