• 조명전기설비학회논문지
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• 제21권7호
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• pp.75-83
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• 2007

일반적으로 변압기의 고장진단을 위해 IEC 코드법이 사용되지만, 이 방법은 가스비율이 규정된 범위 내에 존재하지 않거나 경계조건에 있는 경우 숙련된 진단 전문가에게 의뢰하지 않고는 정확한 고장의 원인을 판정하는데 어려움이 있다. 이러한 문제점을 해결하기 위하여 본 논문에서는 SOM을 이용한 전력용 변압기의 고장진단 알고리즘을 제안한다. 제안된 방법은 훈련 데이터의 경쟁학습을 통하여 자기 구성 맵을 구축한 후, 실증 데이터를 구축된 맵에 적용하여 고장의 진단이 이루어진다. 또한 클러스터링 기법에 의해 구축된 정상/고장모델과 정상 데이터를 비교함으로써 고장의 추이 및 열화정도를 분석한다. 제안된 방법의 유용성을 보이기 위한 실험결과에서 기존의 방법들에 비해 향상된 진단결과를 보임을 확인할 수 있었다.

• Journal of Electrical Engineering and Technology
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• 제9권2호
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• pp.615-621
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• 2014

Power transformer is one of the most important equipments in electrical power system. The detection of certain gases generated in transformer is the first indication of a malfunction that may lead to failure if not detected. Dissolved gas analysis (DGA) of transformer oil has been one of the most reliable techniques to detect the incipient faults. Many conventional DGA methods have been developed to interpret DGA results obtained from gas chromatography. Although these methods are widely used in the world, they sometimes fail to diagnose, especially when DGA results falls outside conventional method codes or when more than one fault exist in transformer. To overcome these limitations, fuzzy inference system (FIS) is proposed. 250 different cases are used to test the accuracy of various DGA methods in interpreting the transformer condition.

• 한국재료학회지
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• 제4권7호
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• pp.741-749
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• 1994

The planar solid oxide fuel cell(SOFC) contains several ceramic materials depending on its structure and has rdfractory metal parts for manifolds, shrouds and current leads. Among ceramic materials for planar SOFC, joining of lanthanum chromite separator and yttria stabilized zirconia(YSZ) electoyte in planar SOFC stack to give strong gas tight seals is necessary for satisfactory operation and high performance. Nevertheless, for planar SOFC/sub s/, how to seal the cell stack and gas manifold remains as one of the unsolved problems. Therefore, in this study. we investigated the joining of sintered lanthanum chromite and YSZ pellets using unsintered lanthanum chromite green films as sealent. Scanning electron microscopy(SEM) and energy dispersive X-ray analysis(EDX) revealed that Ca in the sealing material diffused and dissolved into YSZ and sintered lanthanum chromite, and unsintered lanthanum chromite green films reacted with YSZ to from a new phase at the interface. Also, the densification of unsintered lanthanum chromite green films was inpeded by the Ca migration.

• Bulletin of the Korean Chemical Society
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• 제19권5호
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• pp.524-526
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• 1998

A sensitive and specific method is described for the determination of midazolam in human plasma. The drug was extracted from 1 mL of carbonate buffered plasma (pH 9.6) with 8 mL of diethyl ether. Famprofazone was used as internal standard. The organic phase was evaporated to dryness. The residue was dissolved in methanol for the direct analysis by gas chromatograph-nitrogen phosphorus detector system. In the concentration range of 1-5000 ng/mL, the calibration curve was linear. The coefficients of variation from the precision test were <6% at the range of the concentration of 0.10-2.00 μg/mL and the detection limit for midazolam in 1 mL of plasma was o.5 ng. This assay is more sensitive, selective, simple and rapid than earlier methods. Plasma midazolam concentrations were determined by this method after administration of midazolam.

• Archives of Pharmacal Research
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• 제27권5호
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• pp.539-543
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• 2004

An efficient analytical method was devised for the accurate L-muscone assay in aqueous samples. It involves solid-phase extraction of L-muscone in adsorption mode using XAD-4 as the sorbent and dichloromethane modified with 10% (v/v) methanol as the eluting solvent. The gas chromatographic analysis of the eluate residue dissolved in toluene on a DB-5MS capillary column provided complete resolution of L-muscone from the co-extracted interferences. The overall method showed excellent linearity ($r^2{\geq}$ 0.9994) in the range of 0.1 to 2.0 $\mu\textrm{g}$/mL with good intra- and inter-day precisions (% RSD = 2.5～7.3) and with high extraction recovery rates ($\geq$ 98.1 %). When the present method was applied to a L-muscone herbal drink product, the within-batch RE (%) in the labeled concentration (1.5 $\mu\textrm{g}$/mL) for the three randomly chosen bottles were -2.4, -1.3 and -3.3 with high precision (% RSD $\leq$ 3.1). The present method is considered to be suitable for quality control evaluation on liquid drinks and other complex formulations fortified with L-muscone.

• Archives of Pharmacal Research
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• 제26권5호
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• pp.416-420
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• 2003

The analytical method of antispasmodic agent tiropramide {$(\pm)\alpha$-(benzoylamino)-4-[2-(diethylamino)ethoxy]-N,N-dipropylbenzenepropanamide hydrochloride} was developed by gas chromatography/nitrogen-phosphorus detector (GC/NPD) in human plasma. Two kinds of tiropramide tablets were orally administered to volunteers by Latin square crossover design, and blood was withdrawn as designed schedule. The plasma of 1 mL was loaded on Sep-pak $C_{18}$ cartridge and eluted with methanol after washing with 30% methanol. The residue dissolved in 100 $\mu$L of methanol after evaporation was analyzed by GC/NPD. Precision (CV%) of intra-day was located within 2.6% and accuracy was less than 9.7%. Inter-day precision was below 8.7% and accuracy was relatively good as less than 14%. Plasma samples obtained from human volunteers were analyzed for the determination of tiropramide concentration by using this method. The method was sensitive, rapid and suitable enough to be applied for pharmacokinetic and bioequivalence studies of tiropramide in human volunteers.

• Transactions on Electrical and Electronic Materials
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• 제13권5호
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• pp.229-232
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• 2012

DGA is one of the most recent techniques developed to diagnose the fault condition on oil filled insulation transformers. There are more than 6 known different methods of DGA fault interpretation technique and so there is the likelihood that they may vary in their interpretations. A series of combined interpretation methods that can determine the power transformer condition faults in one assessment is therefore needed. This paper presents a computer program- based system developed to combine four DGA assessment techniques; Rogers Ratio Method, IEC Basic Ratio Method, Duval Triangle method and Key Gas Method. An easy to use Graphic User Interface was designed to give a visual display of the four techniques. The result shows that this assessment method can increase the accuracy of DGA methods by up to 20% and the no prediction result had been reduced down to 0%.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제53권10호
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• pp.523-529
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• 2004

Faults of cellulosic insulations greatly affect the life span of oil immersed transformers because their performance recovery is impossible. Therefore, the reliable diagnosis technologies are needed for detection of the faults. Dissolved gas analysis technologies using CO and $CO_2$ gases have been widely used for fault diagnosis of cellulosic insulations. In this research, we described Degradation diagnosis of insulation paper CO and $CO_2$ gases in oil immersed Transformers using. We considered the distribution characteristics of CO, $CO_2$ gases' concentrations and ratios of $CO_2$/CO not only in serviced transformers but in experiments with typical fault causes such as heat, partial discharge and moisture. As result, the reliability of diagnosis results for the cellulosic insulations can be improved when the concentrations of CO, $CO_2$ and the ratio of CO/$CO_2$ satisfy each diagnosis criterion at a tim

• 전기학회논문지
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• 제56권9호
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• pp.1561-1565
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• 2007

According to thermal degradation on power transformers, it is known that electrical, mechanical and chemical characteristics for power transformer's oil-paper are changed. In the chemical property, especially, when the kraft paper is aged, the cellulose polymer chains break down into shorter lengths. It causes decrease in both tensile strength and degree of polymerization of paper insulation. Also the paper breakdown is accompanied by an increase in the content of various furanic compounds within the dielectric liquid. It is known that furanic components in transformer oil come only from the decomposition of insulating paper rather than from the oil itself. Therefore the analysis of furanic degradation products provides a complementary technique to dissolved gas analysis for monitoring transformers when we evaluate the aging of insulating paper by the total concentration of carbon monoxide and carbon dioxide dissolved in oil only. Recently, the analysis of furanic compounds by high performance liquid chromatography(HPLC) using IEC 61198 method for estimating degradation of paper insulation in power transformers has been used more conveniently for assessment of oil-paper. It is know that the main products which is produced by aging are 2-furfuryl alcohol, 2-furaldehyde(furfural), 2-furoic acid, 2-acetylfuran, 5-methyl-2-furaldehyde, and 5-hydroxymethyl-2-furaldehyde. For investigating the accelerated aging process of oil-paper samples we manufactured accelerating aging equipment and we estimated variation of insulations at $140^{\circ}C$ temp. during 500 hours. Typical transformer proportions of copper, silicon steel and iron have been added to oil-paper insulation during the aging process. The oil-paper insulation samples have been measured at intervals of 100 hours. Finally we have analyzed that 2-furoic acid and 2-acetylfuran products of furanic compounds were detected by HPLC, and their concentrations were increased with accelerated aging time.

• 한국환경과학회지
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• 제24권12호
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• pp.1629-1637
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• 2015

To develop various usable water from coal seam gas (CSG) water that needs to be pumped out from coal seams for methane gas production, a feasibility study was carried out, evaluating and analysing a recent report (Coal Seam Gas Water Management Policy 2012) from Queensland State Government in Australia to suggest potential CSG water treatment options for fit-for-purpose usable water production. As CSG water contains intrinsically high salinity-driven total dissolved solid (TDS), bicarbonate, aliphatic carbon, $Ca^{+2}$, $Mg^{+2}$ and so on, it was found that appropriate treatment technologies are required to reduce the hardness below 60 mg/L as $CaCO_3$ by setting the reduction rates of $Ca^{+2}$, $Mg^{+2}$ and Na+ concentrations, as well as TDS reduction. Also, Along with fiber filtration and membrane separation, an oxidation degradation process was found to be required. Along with salinity reduction, as CSG water contains organic compounds (TOC: 248 mg/L, $C_6-C_9$: <20 mg/L and $C_{10}-C_{36}$: <60 mg/L), compounds with relatively high molecular weights ($C_{10}-C_{36}$) need to be treated first. Therefore, this study suggests a combined system design with filtration (Reverse osmosis) and oxidation reduction (electrolysis) technologies, offering proper operating conditions to produce fit-for-purpose usable water from CSG water.