• Title/Summary/Keyword: Dispersion analysis

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Comparison Study for Impact Range of Prediction Models Through Case Study about Gumi Hydrogen Fluoride Accident (구미 불산사고 사례연구를 통한 예측모델 피해영향범위 비교)

  • Kim, Jin Hyung;Jeong, Changmo;Kang, Seok Min;Yong, Jong-Won;Yoo, Byungtae;Seo, Jae Min
    • Korean Chemical Engineering Research
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    • v.55 no.1
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    • pp.48-53
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    • 2017
  • Since the number and the amount of toxic substances handled by domestic companies have been increased, the possibility of serious chemical accidents has become severe. According to Chemistry Safety Clearing-house (CSC), the number of chemical accidents for the last five years has been rapidly raised. A representative example which shows the serious impact of a chemical accident is HF (Hydrogen Fluoride) accident generated in Gumi in 2012. In order to make effective responses for mitigating losses of accidents, the most suitable consequence model has to be selected and implemented throughout the considerations of chemical properties and environments. Even if each consequence model has been verified by the results of experiments, it is necessary to analyze and compare the usability of them according to various scenarios. In this study, the Gumi HF accident is simulated by HGSYSTEM, which is the most specialized model for the release and dispersion of HF. It is found that the ending point of ERPG-2 is about 1 km from the accident point. In order to investigate the usability of the most representative consequence models (ALOHA and CARIS), the results of them are compared with one of HGSYSTEM.

Influence of Activation of Mesoporous Carbon on Electrochemical Behaviors of Pt-Ru Nanoparticle Catalysts for PEMFCs (고분자 전해질 연료전지 백금-루테늄 나노입자 촉매의 전기화학적 거동에 대한 중형기공 탄소 지지체의 활성화 효과)

  • Kim, Byung-Ju;Park, Soo-Jin
    • Polymer(Korea)
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    • v.35 no.1
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    • pp.35-39
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    • 2011
  • In this work, mesoporous carbons (CMK-3) were prepared by a conventional templating method using mesoporous silica (SBA-15) for using catalyst supports in polymer electrolyte membrane fuel cells (PEMFCs). The CMK-3 were chemically activated to obtain high surface area and small pore diameter with different potassium hydroxide (KOH) amounts, i.e., 0, 1, 3, and 4 g as an activating agent. And then Pt-Ru was deposited onto activated CMK-3 (K-CMK-3) by a chemical reduction method. The characteristics of Pt-Ru catalysts deposited onto K-CMK-3 were determined by surface area and pore size analysis, X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and inductive coupled plasma-mass spectrometry (ICP-MS). The electrochemical properties of Pt-Ru/K-CMK-3 catalysts were also analyzed by cyclic voltammetry (CV). From the results, the K3g-CMK-3 carbon supports activated with 3 g KOH showed the highest specific surface areas. In addition, the K3g-CMK-3 led to uniform dispersion of Pt-Ru onto K-CMK-3, resulted in the enhancement of elelctro-catalystic activity of Pt-Ru catalysts.

Relationship Between the Technology Innovation Performance of IT Venture Business and CEO Characteristics (기술혁신 성과와 경영자 특성에 관한 연구: IT벤처기업을 중심으로)

  • Park, Jae-Min;Kim, Hyo-Young
    • Journal of Digital Convergence
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    • v.9 no.6
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    • pp.173-186
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    • 2011
  • In this study, the influence of the CEOs' characteristics on the technology innovation performances of IT venture companies was analyzed. The relation between business performance and the characteristics of CEOs has been dealt with in earlier studies, but most paid attention to financial perspective, and few of these focused on the influence of managers on technology innovation. On the other hand, most of the studies related to the role of managers in technology innovation mainly focused on R&D investment and research infrastructure but did not delve on the characteristics of them in an in-depth way. In this study, the characteristics of CEOs and their technology innovation performances were empirically analyzed based on the results of a recently conducted survey on the IT venture companies. In the analytical aspect, a negative binominal model was applied to solve the over-dispersion problem that often appears in the count variable analysis. As a result, it was found that major, work type, and work experience, among managers' characteristics, have significant influences on managers' technology innovation performances, along with the company's innovation capacity, technological competitiveness, market competition, and support from the government.

Determination of the complex refractive index of $Ge_2Sb_2Te_5$ using spectroscopic ellipsometry (분광타원해석법을 이용한 $Ge_2Sb_2Te_5$ 의 복소굴절율 결정)

  • Kim, S. J.;Kim, S. Y.;Seo, H.;Park, J. W.;Chung, T. H.
    • Korean Journal of Optics and Photonics
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    • v.8 no.6
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    • pp.445-449
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    • 1997
  • The complex refractive indices of $Ge_2Se_2Te_5$ which show reversible phase change between the crystalline phase and an amorphous one depending upon the annealing process have been determined in the spectral range of 0.7-4.5 eV. The $Ge_2Se_2Te_5$ films were DC sputter deposited on the crystalline silicon substrate. The spectro-ellipsometry data of a thick film were analyzed following the modelling procedure where the quantum mechanical dispersion relation were used for the complex refractive indices of both the cryastalline phase $Ge_2Se_2Te_5$ and and amorphous phase $Ge_2Se_2Te_5$, respectively. On the other hand, with the surface micro-roughness layer whose effective thickness was determined from AFM analysis, the spectro-ellipsometry data were numerically inverted to yield the complex refractive index of $Ge_2Se_2Te_5$ at each wavelength. With these set of complex refractive indices, the reflectance spectra were calculated and those spectra obtained from the numerical inversion showed better agreement with the experimental reflection spectra for both the cryastalline phase and an amorphous phase. Finally, the thin $Ge_2Se_2Te_5$ film which has the optimum thickness of 26 nm as the medium for optical recording was also analyzed and the quantitative result of the film thickness and the surface microroughness has been reported.

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Influence of Different Slope Analysis during Pitching Wedge Swing on Plantar Pressure Distribution Pattern (경사면에서 골프스윙 동작시 족저압력 분석)

  • Son, Dong-Ju;Yang, Jeong-Ok;Lee, Joong-Sook
    • Korean Journal of Applied Biomechanics
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    • v.19 no.2
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    • pp.297-309
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    • 2009
  • The study analyzed the mechanism of plantar foot pressure distribution during pitching wedge swinging on a flat, an up hill lie and a down hill lie to provide the fundamental information regarding biomechanical motion data by using plantar foot pressure measuring instrument. In the results, time factor spanning according to slope differences, plantar foot pressure factor and swing motion on the slope could have negative effect on the coiling of lower limbs during back swing, as well as the blocking of the lower limbs to minimize the dispersion of the weight and the release of the lower limbs after the impact during the down swing process. Moreover, since slope is one of many external factors affecting swing motion, address motion on an up hill lie limits the lower limbs movement, therefore, a relatively narrow stance is better on a down hill lie. It is estimated that a relatively wide stance would be better in order to limit the bigger activation of the lower limbs. Not only for the address motion but also during the down swing on an up hill lie it is concluded that the weight should be on the left foot in order to keep the body balance.

Material Analysis and Coloring Characteristics of Korean Traditional Copper-red Pigment (Jinsa) (동화(진사) 안료의 재료과학적 분석 및 발색특성)

  • Kim, Ji-Young;Cho, Hyun-Kyung;Jun, Byung-Kyu;Cho, Nam-Chul;Lee, Chan-Hee
    • Journal of Conservation Science
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    • v.27 no.1
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    • pp.31-40
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    • 2011
  • Copper-red (Dongwha, Jinsa) is Korean traditional inorganic pigment used for red-coloring on the porcelain surface during Goryeo and Joseon Periods. Trace amounts of copper-red porcelains are handed down because of the technical difficulty of making and coloring of the pigment. It is known that copper ore sources were extensively distributed in Korea according to old literatures and some of them are still producing copper ore at this present. Main types of copper-bearing mineral in Korea are chalcopyrite ($CuFeS_2$) and malachite ($Cu_2CO_3(OH)_2$), and they are easily collected from the ground surface. This means Korea had geographical and economic geological advantages for supplying raw material of the pigment. These two minerals showed good red-coloring in color test for porcelain pigment. As a coloring element, copper showed micro size less than $5{\mu}m$ in diameter in glaze matrix. The dispersion of copper particle is the most decisive factor for red chromaticity of copper-red porcelain, as well as copper content of the pigment.

Study of the Spatial Distribution of Major Non-timber Forest Products - Focusing on Chestnut, Astringent Persimmon, and Oak Mushroom - (주요 단기소득임산물의 공간적 분포 특성에 관한 연구 - 밤, 떫은감, 표고버섯을 대상으로 -)

  • KIM, Won-Kyung;LEE, Jung-Min;KWON, Soon-Duk;JEON, Jun-Heon
    • Journal of the Korean Association of Geographic Information Studies
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    • v.19 no.2
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    • pp.73-85
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    • 2016
  • Systematic and efficient forestry management is required because of the long-term low profitability of timber production and forest products. In this situation, non-timber forest products can be the solution to secure stable sources of income for workers in the forestry field. However, the existing studies for non-timber forest products focus on effective production and economic analysis and provide plans for increasing the income and improving the marketing system. Therefore, this research intends to analyze the spatial distribution as well as quantitative concentration of non-timber forest production. To achieve this goal, this study examined the regional concentration and dispersion of non-timber forest production in 2001, 2007, and 2014 using the coefficient of localization(CL) and location quotient(LQ) and investigated the change in spatial distribution using spatial statistics. The production of chestnuts generally showed a concentrated pattern in 2014 based on the outputs of the CL and LQ, but the result of spatial autocorrelation indicated a decrease in the spatial concentration. In addition, astringent persimmon showed more concentration from the output of CL than oak mushroom, but Moran's I suggests the opposite. Therefore, it is necessary to examine the spatial distribution to understand and improve the marketing system and intensify the production of forest products.

A Study on the Effect of Containment Filtered Venting System to Off-site under Severe Accident (중대사고시 격납건물여과배기계통(CFVS)적용으로 인한 사고영향과 결과 고찰)

  • Jeon, Ju Young;Kwon, Tae-Eun;Lee, Jai-Ki
    • Journal of Radiation Protection and Research
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    • v.40 no.4
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    • pp.244-251
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    • 2015
  • The containment filtered venting system reduces the range of the contamination area around the nuclear power plant by strengthening the integrity of the containment building. In this study, the probabilistic assessment code MACCS2 was used to assess the effect of the CFVS to off-site. The accident source term was selected from a Probabilistic Safety Analysis report of SHINKORI 1&2 Nuclear Power Plant. The three source term categories from 19 STC were chosen to evaluate the effective dose and thyroid dose of residents around the power plant and the dose with CFVS and without CFVS were compared. The dose was calculated according to the distance from the nuclear power plant, so the damage scale based on the distance that exceeds the IAEA criteria for effective dose (100 mSv per 7 days) and thyroid dose (50 mSv per 7 days) were compared. The effective dose reduction rates of the STC-3, STC-4, STC-6 were about 95-99% in the whole range (0~35 km), 96-98% for the thyroid dose. There are similar results between effective dose and thyroid dose. After applying the CFVS, the damage scale that exceeds the effective dose criteria was about 1 km (mean). Especially, the STC-4 damage scale was decreased from 26 km (mean) to 1.2 km (mean) significantly. The damage scale that exceed the thyroid dose criteria was decreased to 2~3 km (mean). The STC-4 damage scale was also decreased significantly as compared to STC-3, STC-6 in terms of effective dose.

Microwave Dielectric Properties and Far Infrared Spectrum of $(Pb_{1-x}Ca_x)(Fe_{0.5}Ta_{0.5})O_3$ Ceramics ($(Pb_{1-x}Ca_x)(Fe_{0.5}Ta_{0.5})O_3$ 세라믹스의 마이크로파 유전특성 및 Far Infrared Spectrum)

  • 박흥수;윤기현;김응수
    • Journal of the Korean Ceramic Society
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    • v.37 no.3
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    • pp.256-262
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    • 2000
  • The dielectric properties of complex perovskite ($Pb_{1-x}Ca_{x}$)($Fe_{0.5}Ta_{0.5}$)$O_{3}$ with >($0.5{\le}x{\ge}0.65$ were investigated at microwave frequencies. Dilectric constant decreased with increasing Ca content, and was directly proportional to the cube of average ionic ra야 of A-site. For the specimen of x=0.6 sintered at $1250^{\circ}C$ for 3 h in air, dielectric constant (k) of 63, QF of 11000 GHz, and the temperature coefficient of resonant frequency(TCF) of -14ppm/$^{\circ}C$ were obtained. As Ca content increased, TCF of the specimen negatively increased due to the reduction of the tolerance factor(t). Changes in intrinsic loss with varying Ca content was investigated by the infrared reflectivity spectra ranging 50 to 4000 $cm^{-1}$, which were calculated by the Kramers-Kronig analysis and classical oscillator model. The relative tendency of microwave dielectric properties of the ($Pb_{1-x}Ca_{x}$)($Fe_{0.5}Ta_{0.5}$)$O_{3}$ specimens calculated from the reflectivity data were in good agreement with the results by the post resonant method.

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Development of Tomographic SASW Method to Evaluate Two-Dimensional Variability of Shear Stiffness (지반 및 구조물의 이차원적 전단강성 평가를 위한 토모그래픽 SASW 기법의 개발)

  • 조성호
    • Journal of the Korean Geotechnical Society
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    • v.15 no.2
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    • pp.29-42
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    • 1999
  • The SASW (Spectral-Analysis-of-Surface-Waves) method, which evaluates the stiffness structure of the subsurface and structures nonintrusively and nondestructively, has been successfully used in the civil engineering applications. However, the SASW method assumes that the subsurface or structures consist of horizontal multi-layers, so that the method has some difficulty in continuously evaluating the integrity of a tunnel lining and a pavement system. This difficulty prevents the SASW method from being used to generate a tomographic image of stiffness for the subsurface or structures. Recently, the GPR technique which has the advantage of continuously evaluating integrity of the subsurface and structures has been popular. This advantage of GPR technique initiated the efforts to make the SASW method, which is superior to GPR and other nondestructive testing methods due to its capability of evaluating stiffness and modulus, be able to do continuous evaluation of stiffness structure, and the efforts finally lead to the development of \ulcornerTomographic SASW Technique.\ulcorner Tomographic SASW technique is a variation of the SASW method, and can generate a tomographic image of stiffness structure along the measurement line. The tomographic SASW technique was applied to the investigation of lateral variability of a sand box placed by the raining method for the purpose of verifying its effectiveness. Tomographic SASW measurements on the sand box revealed that the investigated sand box has different shear stiffness along the measurement line, which gave a clue of how to make a better raining device.

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