• Title/Summary/Keyword: Dispersing

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The Dispersibility and Adsorption Behaviour of Cement Paste with Molecular Structures of Polycarboxylates (폴리카복실레이트 분자 구조에 따른 시멘트페이스트의 분산 및 흡착 특성 연구)

  • Shin, Jin-Yong;Hong, Ji-Sook;Suh, Jeong-Kwon;Lee, Young-Seok;Hwang, Eui-Hwan
    • Journal of the Korea Concrete Institute
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    • v.18 no.4 s.94
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    • pp.489-496
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    • 2006
  • Graft copolymerized polycarboxylate(PC)-type superplasticizers which have carboxylic acid with $\pi$ bond among the molecular structure and polyethyleneglycol methyl ether methacrylate(PMEM) were synthesized by free radical reaction. To investigate their chemical structures and molecular weights, PCs were analyzed by FT-IR(fourier transform spectrometer), C-NMR(nuclear magnetic resonance spectrometer) and GPC(gel permeation chromatograpy). When types of carboxylic acids(methacrylic acid, acrylic acid, maleic anhydride, and itaconic acid) and molar ratios of carboxylic acid/PMEM) were varied, adsorptive and fluid characteristics in cement paste were discussed. As the molar ratio of carboxylic acid/PMEM) was higher, amount adsorbed on the cement particles and the fluidity of cement paste by mini-slump spread testing method were increased. When main chain of PC was methacrylic acid, a larger amount was adsorbed on the cement particles. PCs with acrylic acid as main chain showed higher dispersing power. However, it was confirmed that PCs with dicarboxylic acids(maleic anhydride, itaconic acid) didn't have good adsorption and dispersibility.

Preparation of Cellulose Nanofibrils and Their Applications: High Strength Nanopapers and Polymer Composite Films (셀룰로오스 나노섬유의 제조 및 응용: 고강도 나노종이와 고분자복합필름)

  • Lee, Sun-Young;Chun, Sang-Jin;Doh, Geum-Hyun;Lee, Soo;Kim, Byung-Hoon;Min, Kyung-Seon;Kim, Seung-Chan;Huh, Yoon-Seok
    • Journal of the Korean Wood Science and Technology
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    • v.39 no.3
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    • pp.197-205
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    • 2011
  • Cellulose nanofibrils (CNF) with 50~100 nm diameter were manufactured from micro-size cellulose by an application of a high-pressure homogenizer at 1,400 bar. High strength nanopapers were prepared over a filter paper by a vacuum filtration from CNF suspension. After reinforcing and dispersing CNF suspension, hydroxypropyl cellulose (HPC) and polyvinyl alcohol (PVA)-based composites were tailored by solvent- and film-casting methods, respectively. After 2, 4, 6 and 8 passes through high-pressure homogenizer, the tensile strength of the nanopapers were extremely high and increased linearly depending upon the pass number. Chemical modification of 1H, 1H, 2H, 2H-perfluorodecyl-triethoxysilane (PFDTES) on the nanopapers significantly increased the mechanical strength and water repellency. The reinforcement of 1, 3, and 5 wt% CNF to HPC and PVA resins also improved the mechanical properties of the both composites.

Silica/polymer Nanocomposite Containing High Silica Nanoparticle Content : Change in Proton Conduction and Water Swelling with Surface Property of Silica Nanoparticles (고농도의 Silica Nanoparticle을 함유한 Silica/polymer 나노복합체 : 실리카 표면 특성에 따른 수소이온 전도성 및 수팽윤도 변화)

  • Kim, Ju-Young;Kim, Seung-Jin;Na, Jae-Sik
    • Applied Chemistry for Engineering
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    • v.21 no.5
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    • pp.514-521
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    • 2010
  • A new one-shot process was employed to fabricate proton exchange membranes (PEMs) over conventional solvent-casting process. Here, PEMs containing nano-dispersed silica nanoparticles were fabricated using one-shot process similar to the bulk-molding compounds (BMC). Different components such as reactive dispersant, urethane acrylate nonionmer (UAN), styrene, styrene sulfuric acid and silica nano particles were dissolved in a single solvent dimethyl sulfoxide (DMSO) followed by copolymerization within a mold in the presence of radical initiator. We have successfully studied the water-swelling and proton conductivity of obtained nanocomposite membranes which are strongly depended on the surface property of dispersed silica nano particles. In case of dispersion of hydrophilic silica nanoparticles, the nanocomposite membranes exhibited an increase in water-swelling and a decrease in methanol permeability with almost unchanged proton conductivity compared to neat polymeric membrane. The reverse observations were achieved for hydrophobic silica nanoparticles. Hence, hydrophilic and hydrophobic silica nanoparticles were effectively dispersed in hydrophilic and hydrophobic medium respectively. Hydrophobic silica nanoparticles dispersed in hydrophobic domains of PEMs largely suppressed swelling of hydrophilic domains by absorbing water without interrupting proton conduction occurred in hydrophilic membrane. Consequently, proton conductivity and water-swelling could be freely controlled by simply dispersing silica nanopartilces within the membrane.

Biofilm Differentiation and Dispersal

  • Kjelleberg, Staffan;Barraud, Nicolas;Egan, Suhelen;Ho, Wing Ka;Huynh, Trieu Tran;Klebensberger, Janosch;Koh, Kai Shyang;Lucas-Elio, Patricia;Mai-Prochnow, Anne;Marshall, Dustin J.;Matz, Carsten;McDougald, Diane;Rice, Scott A.;Sanchez-Amat, Antonio;Schleheck, David;Shahbazi, Jeyran;Steinberg, Peter D.;Tan, Chuan Hao;Thomas, Torsten;Webb, Jermy S.;Woo, Jerry K.K.
    • Proceedings of the Microbiological Society of Korea Conference
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    • 2008.05a
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    • pp.42-44
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    • 2008
  • Bacterial biofilms are analogous to multi-cellular organisms or to clonal communities of higher organisms. In this respect, it can be demonstrated that biofilms display the type of genetic variation associated with macroorganisms. The formation of genetic variants from biofilms is the result of internally produced and regulated signals and the appearance of these variants coincides with dispersal from the biofilm. Moreover, the generation of such variation, has similar outcomes for the bacterial community, where diversification of phenotypic traits ensures that the bacterial community optimizes its chances of success when dispersing or surviving when challenged with environmental stress. These observations increase the complexity with which we view bacteria and also suggest that microbial systems can serve as models for the testing of eukaryotic ecological theories.

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Evaluation of Emulsion Stability for Cosmetic Facial Cream Emulsion Using Mixed Nonionic Emulsifier (비이온성 혼합유화제를 이용한 화장용 크림 유화액의 유화안정성 평가)

  • Hong, In Kwon;Kim, Su In;Park, Bo Ra;Choi, Junho;Lee, Seung Bum
    • Applied Chemistry for Engineering
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    • v.27 no.5
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    • pp.527-531
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    • 2016
  • Emulsification is a fundamental process of cosmetics manufacture which produces stabilized emulsion by dispersing the liquid from the one side to the other by adding an emulsifier in an immiscible liquid. Various types of emulsifiers can produce various cosmetics. In this study, we evaluated the stability of emulsifier by measuring variations in the viscosity, particle size and particle size distribution. HLB values of nonionic emulsifiers which are used in this paper are 12.9, 12.9, 12.6 and 12.5 for EMU-01, EMU-02, EMU-03 and EMU-04, respectively. All types of emulsions showed an increase in the particle size and a decrease in the viscosity with the time. Also they showed a decrease in the particle size and an increase in the viscosity with respect to increasing the stirring speed. However, the stability of emulsions up to 56 days was secured by observing the non-separation of emulsions. In addition, the viscosity of the emulsions was measured in the order of EMU-01 > EMU-02 > EMU-03 > EMU-04 while the size of particles was measured in the order of $EMU-01{\approx}EMU-02$ > $EMU-03{\approx}EMU-04$. This indicates that our emulsion can be potentially used for preparing a cosmetic facial cream.

Research Trends of Randomized Controlled Trials on Traditional Korean Medicine Treatment for Postpartum Depression (산후 우울증의 한방 치료에 대한 무작위대조군연구 중심의 연구 동향)

  • Choi, Seok-Young;Park, Kyoung-Sun;Hwang, Deok-Sang;Lee, Jin-Moo;Lee, Chang-Hoon;Jang, Jun-Bock
    • The Journal of Korean Obstetrics and Gynecology
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    • v.31 no.3
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    • pp.1-19
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    • 2018
  • Objectives: The purpose of this study was to analyze the research trends of randomized controlled trials on Traditional Korean Medicine treatment for postpartum depression in women. Methods: In order to investigate the effect of Traditional Korean Medicine on postpartum depression, randomized controlled trials on postpartum depression were searched using domestic and foreign search engines and a total of 11 studies were selected. Results: 1. There were 6 studies comparing Traditional Korean Medicine treatment methods with western medicine: fluoxetine hydrochloride (4), paroxetine (1), and mirazapine (1). 2. There were 5 studies comparing methods of Traditional Korean Medicine or sham acupuncture: 1 study evaluated the efficacy of Balance Acupuncture and Guipi Decoction, 1 study compared the effects of conventional acupuncture and Dispersing Liver Regulating Spirit Acupuncture, 1 study evaluated the efficacy of acupuncture and Heat-sensitive Moxibustion, 1 study compared the effects of conventional acupuncture and Musical Electroacupuncture, and 1 study compared the effects of conventional acupuncture and non-invasive sham acupuncture. 3. Postpartum depression is closely related to Heart and Liver, and there were many studies using acupoints Taichong (LR3) and Shenmen (HE7). Cranial acupoints Baihui (DU20) and Yintang (EX-HN3) were also frequently used. 4. Xiaoyaosan and Guipi Decoction were used in herbal medicine treatment for postpartum depression. 5. Novel treatment methods such as Heat-sensitive Moxibustion and Musical Electroacupuncture were used to treat postpartum depression. Conclusion: Traditional Korean Medicine treatment is a good treatment option for postpartum depression. Further systematic studies are needed to establish the basis for Traditional Korean Medicine treatment for postpartum depression.

Behavior Characteristics of Ballasted Track on Asphalt Roadbed Using Real Scale Test (실대형 실험을 통한 아스팔트 노반상 자갈궤도의 거동 특성)

  • Lee, Seonghyeok;Lee, Jinwook;Lee, Hyunmin
    • Journal of the Korean Society for Railway
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    • v.18 no.3
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    • pp.252-260
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    • 2015
  • Ballasted track on an asphalt roadbed can be beneficial for its various effects such as (i) decreasing of roadbed thickness by dispersing train load; (ii) prevention of both strength reduction and weakening in roadbed system by preventing rainwater penetration; and (iii) reducing maintenance cost by preventing roadbed mud-pumping and frostbite. With these beneficial effects, ballasted track on asphalt roadbed has been widely used in Europe and Japan, and relevant research for applying such ballasted track on asphalt roadbed systems in Korea is ongoing. In this study, full-scale static and dynamic train load tests were performed to compare the performance of ballasted track on asphalt roadbed and ballasted track. The optimum thickness levels of asphalt and reinforced roadbeds, corresponding to the design criteria for reinforced roadbed of high-speed railway, was estimated using the FEM program ABAQUS. Test results show that the earth pressure on reinforced roadbed of ballasted track on the asphalt roadbed was relatively low compared with that of simple ballasted track. The elastic and plastic displacements of simple ballasted track on the asphalt roadbed were also lower than those of ballasted track. These test results may indicate that the use of ballasted track on asphalt roadbed is an advantageous system in view of long-term maintenance.

Pervaporation Characteristics of Water/Ethanol and Water/Isopropyl Alcohol Mixtures through Zeolite 4A Membranes: Activity Coefficient Model and Maxwell Stefan Model (제올라이트 4A 분리막을 이용한 물/에탄올, 물/이소프로필알코올 혼합물의 투과증발 특성 연구 : 활동도계수모형 및 Generalized Maxwell Stefan 모형)

  • Oh, Woong Jin;Jung, Jae-Chil;Lee, Jung Hyun;Yeo, Jeong-gu;Lee, Da Hun;Park, Young Cheol;Kim, Hyunuk;Lee, Dong-Ho;Cho, Churl-Hee;Moon, Jong-Ho
    • Clean Technology
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    • v.24 no.3
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    • pp.239-248
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    • 2018
  • In this study, pervaporation experiments of water, ethanol and IPA (Isopropyl alcohol) single components and water/ethanol, water/IPA mixtures were carried out using zeolite 4A membranes developed by Fine Tech Co. Ltd. Those membranes were fabricated by hydrothermal synthesis (growth in hydrothermal condition) after uniformly dispersing the zeolite seeds on the tubular alumina supports. They have a pore size of about $4{\AA}$ by ion exchange of $Na^+$ to the LTA structure with Si/Al ratio of 1.0, and shows strong hydrophilic property. Physical characteristics of prepared membranes were evaluated by using SEM (surface morphology), porosimetry (macro- or meso- pore analysis), BET (micropore analysis), and load tester (compressive strength). Pervaporation experiments with various temperature and concentration conditions confirmed that the zeolite 4A membrane can selectively separate water from ethanol and IPA. Water/ethanol separation factor was over 3,000 and water/IPA separation factor was over 1,500 (50 : 50 wt%, initial feed concentration). Pervaporation behaviors of single components and binary mixtures were predicted using ACM (activity coefficient model), GMS (generalized Maxwell Stefan) model and DGM (Dusty Gas Model). The adsorption and diffusion coefficients of the zeolite top layer were obtained by parameter estimation using GA (Genetic Algorithm, stochastic optimization method). All the calculations were carried out using MATLAB 2018a version.

Preparation and Effect of Eudragit E100 Microcapsules Containing Grapefruit Seed Extract on Kimchi (자몽씨 추출물을 함유한 Eudragit E100 미세캡슐의 제조 및 김치에 대한 영향)

  • 김한수;정성기;조성환;구재관;이승철
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.32 no.8
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    • pp.1239-1244
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    • 2003
  • Microcapsules were prepared by coacervation method using acetone/liquid paraffin system to control the ripening of kimchi. Eudragit E100, which was soluble at below pH 5.0 in aqueous solution, was used to make microcapsules to be sensitive to acidity of kimchi. The microcapsules with Eudragit E100 containing grapefruit seed extract (GFSE) showed the highest yield of 92.13%, the size of microcapsules was decreasing as increasing the amount of aluminium stearate, a dispersing agent. Morphology of the microcapsules determined by scanning electron microscopy showed spherical forms. GFSE, encapsulated antimicrobial agents, was quickly released at acidic buffer (pH 4,5,6) within 1 storage day. However, 70% of encapsulated GFSE in Eudragit E100 microcapsules was continuously released at pH 7 till 3 days, and it was sustained till 9 days. Characteristics of kimchi containing microcapsules of GFSE were analysed with ripening period. Decease of pH in kimchi was retarded with the added GFSE microcapsules till 2 days of fermentation, but GFSE did not affect pH in kimchi after 3 days. Total numbers of microorganisms and lactic acid microorganisms in kimchi were decreased with increasing the amount of the added GFSE microcapsules, however, the effect of controlled released GFSE from pH sensitive Eudragit E100 microcapsules was hard to detect. These results suggest the possibility of pH sensitive microcapsules for high qualify of kimchi.

IGRINS First Light Instrumental Performance

  • Park, Chan;Yuk, In-Soo;Chun, Moo-Young;Pak, Soojong;Kim, Kang-Min;Pavel, Michael;Lee, Hanshin;Oh, Heeyoung;Jeong, Ueejeong;Sim, Chae Kyung;Lee, Hye-In;Le, Huynh Anh Nguyen;Strubhar, Joseph;Gully-Santiago, Michael;Oh, Jae Sok;Cha, Sang-Mok;Moon, Bongkon;Park, Kwijong;Brooks, Cynthia;Ko, Kyeongyeon;Han, Jeong-Yeol;Nah, Jakyuong;Hill, Peter C.;Lee, Sungho;Barnes, Stuart;Park, Byeong-Gon;T., Daniel
    • The Bulletin of The Korean Astronomical Society
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    • v.39 no.1
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    • pp.52.2-52.2
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    • 2014
  • The Immersion Grating Infrared Spectrometer (IGRINS) is an unprecedentedly minimized infrared cross-dispersed echelle spectrograph with a high-resolution and high-sensitivity optical performance. A silicon immersion grating features the instrument for the first time in this field. IGRINS will cover the entire portion of the wavelength range between 1.45 and $2.45{\mu}m$ accessible from the ground in a single exposure with spectral resolution of 40,000. Individual volume phase holographic (VPH) gratings serve as cross-dispersing elements for separate spectrograph arms covering the H and K bands. On the 2.7m Harlan J. Smith telescope at the McDonald Observatory, the slit size is $1^{\prime\prime}{\times}15^{\prime\prime}$. IGRINS has a $0.27^{\prime\prime}$ pixel-1 plate scale on a $2048{\times}2048$ pixel Teledyne Scientific & Imaging HAWAII-2RG detector with SIDECAR ASIC cryogenic controller. The instrument includes four subsystems; a calibration unit, an input relay optics module, a slit-viewing camera, and nearly identical H and K spectrograph modules. The use of a silicon immersion grating and a compact white pupil design allows the spectrograph collimated beam size to be 25mm, which permits the entire cryogenic system to be contained in a moderately sized rectangular vacuum chamber. The fabrication and assembly of the optical and mechanical hardware components were completed in 2013. In this presentation, we describe the major design characteristics of the instrument and the early performance estimated from the first light commissioning at the McDonald Observatory.

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