• Title/Summary/Keyword: Dispersing

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A Study on Polyurethane Treatment of Fabric - Synthesis of Water Dispersing Agent, and Anti-static and Softening Finishing - (직물의 우레탄처리 가공 - 수분산성 가공제의 합성과 대전방지 및 유연가공에 대하여 -)

  • Ahn, Young-Moo
    • Fashion & Textile Research Journal
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    • v.3 no.1
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    • pp.42-47
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    • 2001
  • The hardening system of polyurethanes has usually caused by air pollution. bad working condition and fire hazard according to using orgarnic solvents. Therefore there have been researched on emulsion, water soluble and colloid-dispersion based water soluble instead of using organic solvents recently. This study synthesized polyurethane dispersing particle by means of mixing precursor and neutralized emulsion method. In the first step, polyurethane was preparated from isophorone diisocyanate and poly (ethylene-adipate) glycol, and got precursor by introducing dimethyl propionic acid as a hydrophilic group. Synthesized polyurethane was bonded to the surface of fiber and crosslinked as a anti-static agent, and then looked for the change of color and softening property.

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Microencapsulation of Dibutylphthalate by Interfacial Polymerization (계면중합에 의한 Dibutylphthalate의 마이크로 캡슐화)

  • 박차철;김호정;김한도
    • Textile Coloration and Finishing
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    • v.7 no.3
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    • pp.15-21
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    • 1995
  • Polyurethane microcapsules containing dibutylphthalate(DBP) were perpared by the interfacial polymerization using diisocyanates and polyois. Effects of chemical structure of PU, dispersing agent and polymerization time on the mean diameter of microcapsules were investigated. The releasing of DBP from microcapsules depended on the chemical structure of PU and solvents. The diameter decreased with increasing dispersing agent concentration, and it is decreased in the order of the dispersing agents using gelatine > PVA > arabic gum at the same concentration. A slight increase in the diameter was observed when the ratio C$H_2$/OOCNH of PU was increased. As the ratio C$H_2$/OOCNH of PU was increased, the amount of extracted DBP for hexane using as a extracting solvent was decreased, however, it was not changed for THF.

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A Study on the Bleeding Property of Flowed Concrete Due to Different Types of High Range Water Reducing Admixtures (고성능감수제 종류에 따른 유도화콘크리트의 Bleeding특성)

  • 김기수;하재담;김동석;신규연;유규홍
    • Proceedings of the Korea Concrete Institute Conference
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    • 1997.10a
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    • pp.321-326
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    • 1997
  • Recently, High Range Water Reducing Admixture be used increasingly in other to improve the demanded properties (fluidity, strength, durability etc.) and workability in concrete. These kinds of agent govern quality characteristics (air content, setting time, slump, bleeding etc) by the difference of its dispersing mechanism and performance in manufacture of flowed concrete. Accordingly, in this study, for the purpose of high quality construction in site, the comparative experiment of dispersing ability due to commercially available three types of agent were carried out in paste, mortar and concrete using tow types of cement (I, V). In conclusion, the bleeding reduction by the dispersing ability of agents was verified in the fresh properties of flowed concrete with sea water resistance.

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Colloidal-Chemical Parameters of Petroleum-collecting and Dispersing Surfactants Based on Vegetable Oil Acid Fractions and 2-(Chloromethyl) Oxirane

  • Asadov, Ziyafaddin H.;Ahmadova, Gulnara A.;Rahimov, Ravan A.;Mammadova, Khuraman A.
    • Journal of the Korean Chemical Society
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    • v.55 no.6
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    • pp.1012-1017
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    • 2011
  • Novel surfactants have been synthesized by catalytic chloropropoxylation reaction of carboxylic acid fractions of sunflower, olive, cottonseed, soya-bean, castor and corn oils with 2-(chloromethyl)oxirane. Colloidal-chemical parameters as well as petroleum-collecting and petroleum-dispersing capacities of the synthesized chloropropoxylate esters having heterochain of various lengths have been determined. Influence of carboxylic acid fractions composition and length of chloroxypropylene chain on petroleum-collecting and dispersing capacities has been revealed.

Experimental studies on the characteristics of the mortar using dispersing agent of cement and high fluid admxiture (시멘트 분산제(分産劑) 및 고류동화제(高流動化劑)를 사용(使用)한 모르터의 제(諸) 성질(性質)에 관(關)한 실험적(實驗的) 연구(硏究))

  • Kim, Seong Wan;Park, In-Gyu
    • Korean Journal of Agricultural Science
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    • v.11 no.1
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    • pp.146-159
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    • 1984
  • This study was the contrast of the compressive strength, the tensile strength, the reducing ratio and the flow of mortar using dispersing agent and high fluid admix. 1. The admix ratio of chemical admixtures espressing maximum strength appeared the same result high fluid admix SP was 0.6%, the dispersing agents LG and C211 were 0.2%, SK was 0.3%, C376 was 0.5%. But two or three times more than standard quantity made the strength's fast lowness, which influenced bad to wateriness and retard the soli-dification. 2. When proper quantity of chemical admixture was used, the increment of compressive strength was as follows. High fluid admix SP was 40.7% and the average increasing rate of dispersing agents(C211 was 19.5%, LG was 19.1%, C376 was 17.9%) was 18.7% more than normal mortar in the codition of 7 days. Also, in the condition of 28 days, high fluid admix SP was about 24.4% and the average of dispersing agents(LG was 21.1%, C211 was 16.4%, SK was 11.1%, C376 was 7.6%) was 14.1%. 3. When proper quantity of chemical admixture was used, the increment of tensile strength was as follows. High fluid admixture SP was 26.6% and the average increasing agents(SK was 16.0%, C376 was 14.7%, LG was 10%, C211 was 5.8%) was 11.6%. Also, in the condition of 28 days, high fluid admix SP was 16.5% and the average increasing rate of dispersing agents(LG was 19.1%, SK was 10.6%, C211 was 10.1%, C376 was 8.7%) was 12.1%. 4. As for the reducing ratio of each dispersing agent, he flow of mortar was less than the slump of concrete. That is; the reducing ratio of concrete was 15% adding each dispersing agent, but the reducing ratio of mortar was in the range of from 5.8% to 13.5% in 1 : 1 mixture, from 7.6% to 14.2% in 1 : 2, from 9.5% to 18.8% in 1 : 3. 5. The fluidity of each chemical admixture was as follows. High fluid admix SP in the condition of 1: 1 and 1 : 2 showed the best result than other dispersing agent and 1 : 3 showed the same result like other agents. Therefore these good dispersing agents were suitable in the prepact concrete construction using intrusion mortar.

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A Research on the Classification of Herbal Medicines based on the Sasang Constitution (Taeumin and Taeyangin Part) (사상(四象) 체질별(體質別) 약재(藥材) 분류(分類) 관한 연구(硏究)(태음인(太陰人) 및 태양인편(太陽人編))

  • Kim, Kyung-Yo;Kim, Jong-Yol
    • Journal of Sasang Constitutional Medicine
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    • v.14 no.1
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    • pp.1-9
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    • 2002
  • We analyzed 44 and 16 types of herbal medicines for Taeumin and Taeyangin, clinically applied in Dongyisoosebowon. In order to discover the standard of herbal classification for the Sasang constitutions, four concepts of Sasang Medicine were applied. These included 'Sadangron (theory of four groups)', 'Seungganggaehap (ascending-descending and gathering-dispersing)', 'Pyorihanyoul (exterior-interior and hot-cold)',and 'Hyungchiaekmi (fragrance, smell, bodily fluid and taste)'. According to these analyzing methods of herbal properties, we have reached the following conclusions: Herbal medicines for 'Taeumin' are characterized by opening energetics that reinforce dispersing Qi. The 'Exterior cold disease' is treated with herbs that ventilate the lungs and disperse dampness in three ways: by moistening the lungs, by releasing exterior, and by resolving dampness. The 'Interior heat disease' is treated with herbs that clear the liver and disperse heat in two ways. One by clearing liver heat through dispersing damp-heat of the small intestine and the other by opening orifices. Herbal medicines for Taeyangin are characterized by those that gather energy inward. They include herbs that treat beriberi, dystrophy of the extremities and vomiting, as well as, fish, shellfish, fruits and vegetable.

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Physical properties, released patterns and bio-efficacy of granular mixtures with chlomethoxyfen and butachlor formulated by different methods (제조방식을 달리한 chlomethoxyfen과 butachlor 혼합입제의 물리성, 수중용출도와 생물효과 비교)

  • Chung, Bong-Jin;Yeon, Jae-Heum
    • The Korean Journal of Pesticide Science
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    • v.2 no.3
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    • pp.36-44
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    • 1998
  • To develope cost-effective new granular formulation of mixture with 7.0% chlomethoxyfen and 3.5% butachlor, this study was conducted by investigation of floatability, dispersibility or collapsability and released concentration of active ingredients in water and bio-efficacies of the granules formulated by different formulation methods compared to commercial pellet-extruded granules. They were formulated by coating on or impregnation into extruded pellets, sands and zeolites with two active ingredients, binders, friction reducer, dispersing agents and bentonite. Pellet-coated method showed similar floatability, collapsability and bio-efficacy to the commercial pellet-extruded one or better than that but unstable patterns of released concentration of chlomethoxyfen because of easy isolation of coated technical particles from the surface of granules. Sand-coated methods showed similar physical properties, released pattern of two active ingredients, and bio-efficacy to the commercial one. Liquid binders and/or dispersing agents are more important than powdered ones to control released concentration of active ingredients from the granule mixtures, to improve the floatability and dispersibility, and to show good bio-efficacy. Sand-coated one might be a suitable method if types and amount of liquid binders and dispersing agents are selected.

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Study on Fabricating Bead Mill for Manufacturing Nano Powders (나노 파우더 제조용 비드밀 제작에 관한 연구)

  • Son, Jae-Yub;Nam, Kwon-Sun;Kim, Byeong-Hee
    • Journal of Industrial Technology
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    • v.25 no.B
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    • pp.127-133
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    • 2005
  • Manufacturing methods of Nano particles can be distinguished by top-down technology as physical method and bottom-up technology as chemical synthetic method. Top-down technology is a kind of method for making microstructure as like carving after forming a macroscopic structure in advance and its typical methods are ball milling, gas condensation method and so on. Nano Particles synthesized by bottom-up method have got to do dispersing process for using them as actual nano particles because their viscosity are very strong and so easy to shape cohesive substances. Therefore, this study is about a particle separating device which separates a certain constant size of grains processed already in mill and mixer because we mostly use media agitating mill as a device of milling and dispersing and we necessarily use very slight balls as media for manufacturing nano particles in the machine. The centrifugal device has been designed for passing and separating below a certain type of grain size after final process of particles in the mill.

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Application of Biosurfactant(Sophorolipid) Produced from Candida bombiocola (Candida bombiocola로 부터 생산된 미생물 계면활성제(Sophorolipid)의 응용에 관한 연구)

  • 김원경;김은기
    • KSBB Journal
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    • v.7 no.2
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    • pp.107-111
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    • 1992
  • Chayacterlstics of the sophorolipid produced from Candida bombiocola were investigated as an emulsifier of oil, a detergent or as a dispersant. Improved emulsification of crude oil was observed at high temperature ($70^{\circ}C$) with less than 1% concentration. Sophorolipid solution produced little foam even at reduced surface tension, however performance as a detergent of soiled cloths was poor. Dispersing and stabilizing abilities of sophorolipid solution were proved to be superior to those of chemical dispersants when examined by dispersing $Fe_2O_3$ or carbon black powders.

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