• 한국염색가공학회지
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• 제15권2호
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• pp.93-101
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• 2003

To acquire dyeing ability on aramid(Nomex) spun yarn in supercritical fluid dyeing, supercritical fluid dying(SFD) machine of 3L scale was designed. C. I. Disperse Red 60 and Red 360 were used in this work. It was possible to increase dyeing ability and to get level dyeing of fiber by attaching assistance devices(controlling device of supercritical fluid, nozzle, cover of carrier, etc.) to SFD machine. Physical properties(tensile strength, elongation, shrinkage) of Nomex spun yam treated by SFD were not changed. K/S values of dyed Nomex spun yam with Red 360 were higher than that with Red 60 and color fastness of dyed Nomex spun yam by SFD was similar to that by conventional dyeing method.

• Fibers and Polymers
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• 제5권2호
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• pp.134-138
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• 2004

Dyeing properties of a series of 4-amino-4'-fluorosulfonylazobenzene disperse dyes on poly(ethylene terephthalate) (PET) were investigated. Build-up properties and color properties on PET were examined. In particular, the 4-aminoazobenzene dyes containing a nitro group instead of a fluorosulfonyl group at 4'-position were also synthesized in order to compare their dyeing properties on PET with that of 4'-fluorosulfonyl analogues.

• 한국염색가공학회지
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• 제13권4호
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• pp.249-255
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• 2001

To interpret the dyeing behavior of PTT fiber with C. I. Disperse Violet 1, the thermodynamic Parameters of dyeing, such as standard affinity, heat of dyeing(enthalpy change), entropy change, diffusion coefficient, and activation energy of diffusion, were obtained from isotherms and dyeing rates at various temperatures and compared with those of PET fiber. The heat of dyeing(enthalpy change) and the entropy change of PTT fiber showed smaller negative values than those of PET fiber. This means that the dye molecules in the PTT fiber are combined more loosely than in the PET fiber and that is due to the flexibility of polymer chains of PTT fiber. The diffusion coefficients of C. I. Disperse Violet 1 into the PTT fiber were larger than those for PET fiber, and the activation energy of diffusion on PTT fiber was smaller than that on PET fiber.

• 한국염색가공학회지
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• 제14권1호
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• pp.51-57
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• 2002

In the prior study, the mechanical properties and the dyeability of the easily dyeable polyester grim(EDY) were investigated. In this study, to interpret the dyeing behavior of EDY with C. I. Disperse Violet 1, the thermodynamic parameters of dyeing, such as the standard affinity, the heat of dyeing(the enthalpy change), the entropy change, the diffusion coefficient, and the activation energy of diffusion, were obtained from adsorption isotherms and dyeing rate at various temperatures and compared to these of regular polyester (REG-PET). The heat of dyeing(the enthalpy change) and the entropy change for EDY showed smaller negative values than those for REG-PET. This means that the dye molecules in the EDY are combined more loosely than in the REG-PET and that is due to the flexibility of polymer chains of EDY. The diffusion coefficients of C. I. Disperse Violet 1 into the EDY were larger than those for REG-PET, and the activation energy of diffusion on EDY was smaller than that on REG-PET.

• 한국염색가공학회지
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• 제26권2호
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• pp.79-87
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• 2014

Dyeing fabric weaved with two or more kinds of fiber in different section has various dyeing interactions caused by different material properties of them. Newly developed knit fabric was used in this study. It composited by two different blocks, each block is included PET fiber and CDP fiber separately. Build-up properties with cation dyes and disperse dyes were good having average 83% of dyeing exhaustion yield on 5% o.w.f. dye concentration. As depending on dyeing methods, there were not showed direct interaction between cation dyes and disperse dyes. This result could be considered their different dyeing mechanism. Compatibility was best in S-type disperse dyes investigated their critical absorption range as $120^{\circ}C{\sim}130^{\circ}C$. Wash fastness was generally good in most dye.

• 한국염색가공학회지
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• 제30권2호
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• pp.70-76
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• 2018

The dyeing behaviors of poly(ethylene terephthalate)(PET) bulky yarns, DTY(draw textured yarn) and SSY(latent crimped yarn), were investigated with different energy type disperse dyes compared with those of SDY(spin draw yarn). The maximum exhaustions of E-type disperse Red 60, Blue 56 and Yellow 54 on SSY were 99%, 94% and 93%, respectively. The maximum exhaustions of S-type disperse Red 179, Blue 79 and Orange 30 on SSY were 96%, 97% and 97%, respectively. The K/S values of SSY were significantly higher than those of DTY and SDY in all energy type of disperse dyes. The knit fabric composed of SSY became bulky at the end of high temperature dyeing process because of their thermal shrinkage property due to melt viscosity difference.

• 한국염색가공학회지
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• 제32권4호
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• pp.208-216
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• 2020

In this study, C.I. Disperse Red 60 (DR60), C.I. Disperse Yellow 54 (DY54) dyes were used to investigate the washing fastness characteristics of PET fibers according to supercritical CO2 and aqueous dyeing process. The changes in K/S values and L⁎ values before and after washing of dyed PET fibers were observed according to the KS K ISO 105 washing fastness measurement method. In addition, it was confirmed by changing the ΔE⁎ and ΔL⁎ values of control PET fibers. Overall, it was confirmed that both the supercritical CO2 and aqueous dyeing process had excellent washing fastness ratings of 4-5 for DR60 and DY54 dyes. Comparatively, the K/S and L⁎ values for before and after washing of PET fibers with supercritical CO2 dyeing process was higher than that of the aqueous dyeing process and the ΔE⁎ and ΔL⁎ values of the control PET fibers were low. From the results, we observed that the supercritical CO2 dyeing process of PET fibers has better washing fastness characteristics than the aqueous dyeing process.

• 한국염색가공학회지
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• 제18권6호
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• pp.10-15
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• 2006

In this article, effect of the dyeing and mechanical properties were investigated on the polyester ultramicro fiber(UMF) and knitted fabric varying fiber fineness(0.01d and 0.05d). By a treatment with NaOH solution, sea-ingredient was removed and polyester micro-fiber was revealed. The dyeing, build-up and fastness properties of the fiber and fabrics were observed. We used C.I. Disperse Red 60 and Blue 56 for dyeing property and eight Lumacron dyes for build-up property and colorfastness. At low temperature dyeing($100^{\circ}C$), the dyeing rate of 0.01d-polyester UME increased more than that of 0.05d-polyester UMF with Disperse Red 60 and Blue 56 whereas dyeing rate of 0.05d-polyester UMF were increased more than that of 0.01d-polyester UMF at high temperature($120^{\circ}C$), The colorfastnesses of the 0.05d-fiber knitted fabric such as washing, rubbing and light was higher than those of the 0.01d-fiber knitted fabric.

• 한국염색가공학회지
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• 제22권2호
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• pp.140-144
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• 2010

In this study, we investigated the clean appearance and good stretch properties. Usually, clean appearance concerned with the dyeing properties of core and effect yarns. The dyeing properties between core yarn (conjugate yarn) and effect yarn were determined by the build-up and the color differences using the four different yarns of SDY FD(spindraw yarn full dull), SDY CD(spindraw yarn cation dyeable), POY FD( partially-oriented yarn full dull) and POY CD(partially-oriented yarn cation dyeable). We used the single color dye of C. I. Disperse Blue 79 and mixed colors made by C. I. Disperse Red 60, C. I. Disperse Blue 56, and C. I. Disperse Yellow 54.

• Fibers and Polymers
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• 제7권2호
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• pp.169-173
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• 2006

Six nano disperse dyes were prepared using corresponding O/W nanoemulsions which were obtained with sodium laurylsulphate and caprylic triglyceride. The average particle size of the dyes prepared were in the range of $110{\sim}130nm$. Exhaust dyeing using nano dyes resulted in low exhaustion yields of $17{\sim}26%$ on regular polyester fiber and $28{\sim}38%$ on ultramicrofiber polyester. The observed low exhaustion yields of nano disperse dye can be explained by the solubilization of dye particles into surfactant micelles as well as the high stability of the nanoemulsions, these might reduce the capacity of dye uptake onto the fibers. However, higher K/S values of dyeings with nano dyes on ultramicrofiber sites compared to those on regular polyester sites suggested their potential to be more efficient dyes for finer denier microfiber polyesters.