• 제목/요약/키워드: Disperse dyeing

검색결과 165건 처리시간 0.024초

초저욕비 염색을 위한 분산염료의 적용연구 (The Application of Disperse Dyes to the Ultra Low Liquor Ratio Dyeing System)

  • 김태경;김진수;박희문;남창우
    • 한국염색가공학회:학술대회논문집
    • /
    • 한국염색가공학회 2008년도 제38차 학술발표대회
    • /
    • pp.192-194
    • /
    • 2008
  • The study has focused on the dyeing properties of 4 kinds of high temperature type mono azo disperse dyes, widely used in the dyeing factory, under the ultra low liqour ratio (1:4) dyeing condition. Among those, C.I. Disperse Red 343 and C.I. Disperse Blue 79 showed un-levelled dyeing results from the ultra low liquor ratio dyeing bath as well as poor dispersion stability under the high temperature. We recommended some leveling agents to improve the leveling behavior of these dyes mentioned above. The milling technology should be further developed to achieve the dispersion stability.

  • PDF

Effects of Thermomigration on the Washfastness of Disperse Dyes Having Different Molecular Size

  • Kim, Sung-Dong;Kim, Min-Jung;Lee, Byung-Sun;Lee, Kwon-Sun
    • Fibers and Polymers
    • /
    • 제5권1호
    • /
    • pp.39-43
    • /
    • 2004
  • Effects of chemical structure of disperse dyes applied to conventional and microdenier polyesters on the dyeing property and washfastness were studied. It was found that washfastness of dyed polyester fabric is closely related to the degree of thermomigration of disperse dye during heatsetting. The bulky disperse dye, which was synthesized by substituting two acetoxy groups of C.I. Disperse Red 82 with two benzoxy groups, showed almost the same amount of absorbed dye by the microdenier polyester as C.I. Disperse Red 82, but the degree of thermomigration was low and subsequent washfastness was excellent. The high grade of washfastness of the bulky disperse dye might be caused by the increased dye-fiber interaction and the reduced mobility.

초임계 유체 염색용 염료에 따른 면 섬유의 염색 특성 : C.I. Disperse orange 155, C.I. Disperse red 167 (A Study of Dyeing Properties of Cotton Fabrics Under Supercritical CO2 Depending on Dyestuff : by C.I. Disperse orange 155, C.I. Disperse red 167)

  • 최현석;김훈민;전태영
    • 한국염색가공학회지
    • /
    • 제34권2호
    • /
    • pp.93-101
    • /
    • 2022
  • In this study, the dyeing properties of supercritical fluid dyed cotton fabrics were investigated which use two types of dyes, such as C.I. Disperse orange and C.I. Disperse red 167. Dyeing temperature, pressure and leveling time were equally applied at 130 ℃, 250 bar, and 60 minutes with reference to the related literature, and experiments were performed at concentrations of 0.04, 0.1, 0.4 and 0.8 % o.w.f with different concentrations. Dyeability was confirmed through measurement of washing fastness and color coordinate, and a calibration curve of each dye was drawn up and the absorbance of the residual dye was measured to confirm the amount of residual dye and the dye exhaustion rate at the corresponding concentration. As a result of color difference measurement, as the concentration increased, the L* value decreased and the K/S value increased. However, as the concentration increased, the increase in K/S value decreased compared to the input amount, and this tendency was more obvious in C.I. Disperse red 167 than in C.I. Disperse orange 155. The dye exhaustion rate which was calculated by using the amount of residual dye in the pot was also C.I. Disperse orange 155 was 96.16 % and C.I. Disperse red 167 was 94.57 %. However, as the dyeing concentration increased, the dye exhaustion rate decreased, that C.I. Disperse orange was 95.33 % and C.I. Disperse red 167 was 90.63 %. As a result of the washing fastness test for both dyes, dyed samples of which concentrations were 0.4 and 0.8 % o.w.f decreased by 0.5 ~ 1.0 grade. This is predicted because the dye did not completely adhere to the amorphous region of the cotton fiber and the dye simply adsorbed. The fastness to rubbing also maintained at least grade 3-4 up to the 0.1 % o.w.f concentration, but at the concentration of 0.4 % o.w.f or higher, it fell to grade 1 or lower, showing a very poor friction fastness.

Dispersant-free Dyeing of Polyester with Temporarily Solubilized Azo Disperse Dyes from Indole Derivatives

  • Lee, Jung-Jin;Lee, Won-Jae;Kim, Jae-Pil
    • Fibers and Polymers
    • /
    • 제4권2호
    • /
    • pp.66-70
    • /
    • 2003
  • Temporarily solubilized azo disperse dyes based on 1,2-substituted indoles were synthesized and characterized. Dispersant-free dyeing of polyester by using the synthesized dyes has been investigated. The colour yields of the dyes on the polyester fabric were found to be highly dependent on the dyeing pH, optimum results being obtained at pH 5. The dyes exhibited good to excellent fastness properties on polyester while lightfastness was moderate.

폴리에스테르/카티온화 면 혼방품의 분산염료/반응성염료에 의한 일욕염색계에 관한 연구 (Studies on the One Bath Exhaust Dyeing System of Polyester/Cationized Cotton Blends with Disperse Dye/Reactive Dye)

  • 성우경
    • 한국염색가공학회지
    • /
    • 제10권2호
    • /
    • pp.18-28
    • /
    • 1998
  • in order to overcome disadvantage of the conventional two bath dyeing method of polyester/cotton blends, it had prompted significant effort to the development of the one bath dyeing method which can accomplish sayings in time, energy and water usage. Also, when dyeing polyester/cotton blends by the one bath dyeing method, the high salt concentrations needed for the reactive dye can cause particles of disperse dye, used for the polyester component, to aggregate. A supplementary problem that can occasionally be happened is the change of hue that occurs on dyed polyester in an alkaline dyebath. To improve dyeing property of polyester/cotton blends, cotton component was pretreated with epichlolohydrine-trimethylamine hydrochloride in aqueous solution of sodium hydroxide to produce a cationized cotton that can be dyed under neutral conditions with reactive dye in a non-electrolytic or il little electrolytic dyebath. The one bath dyeing method of polyester/cationized cotton blends with disperse dye/reactive dye mixture resulted in a satisfactory dyeing property and color yield in comparison with ordinary two bath dyeing method.

  • PDF

DMDHEU/PEG와 분산염료를 이용한 면/폴리에스테르 혼방직물의 염색 (Dyeing of Cotton/Polyester Blends with Disperse Dyes in the Presence of DMDHEU/PEG)

  • 김은아;유효선
    • 한국의류학회지
    • /
    • 제24권7호
    • /
    • pp.1025-1034
    • /
    • 2000
  • Cotton differs from polyester in physical and chemical properties. When cotton/polyester blends are dyed, water-soluble dyes are generally used for cotton and disperse dye for polyester. Thus, two bath or one bath-two step dyeing process are usually accepted. These processes consume more energy and cost compared to a single step process. To save energy and cost, a single step dyeing and finishing is carried out with disperse dyes in the presence of a crossslinking agent. K/S values of the dyed fabrics were determined to examine the dyeing property of cotton, cotton/polyester, polyester fabrics dyed with disperse dyes in the presence of DMDHEU/PEG. The concentration of DMDHEU, molecular weight and concentration of PEG, curing time and curing temperature were varied.

  • PDF

Dispersant-free dyeing of acetate with temporarily solubilized azo disperse dyes

  • Lee, Jung-Jin
    • 한국염색가공학회지
    • /
    • 제18권5호
    • /
    • pp.15-21
    • /
    • 2006
  • Temporarily solubilized azo disperse dyes containing ${\beta}$-sulfatoethylsufonyl group were applied to acetate fabric and the feasibility of dispersant-free dyeing was investigated. The color yields of the dyes on acetate fabric were found to be dependent on dye bath pH as well as dyeing temperature. The optimum results were obtained at pH 6 and $80^{\circ}C$. The dyes showed good exhaustion and levelling properties. Vinylsulfone derivatives of the dyes were prepared and applied to acetate with dispersant. Dyeing properties of the temporarily solubilized disperse dyes were similar to or better than those of the vinylsulfone dyes. The dyes showed moderate to good fastness properties on acetate.

견/합성섬유 혼방품의 일욕염색 (V) -견/나일론 혼방품의 일욕염색- (One Bath Dyeing of Silk/Synthetic Fiber Blends (V))

  • 이재덕;전재홍;김공주
    • 한국염색가공학회지
    • /
    • 제6권3호
    • /
    • pp.67-73
    • /
    • 1994
  • The adsorption behaviors of acid dye and disperse dye on silk and nylon fabrics were examined, in one bath dyeing system on silk/nylon blend fabric with disperse dyes and acid dyes. In the dyeing of nylon fabric with C. I. Disperse Red 19 (Red 19) and C. I. Disperse Red 60 (Red 60), dye uptake of Red 19 was higher than that of Red 60. When silk/nylon blend fabric was dyed with Red 19 and Red 0, the dye uptake on nylon was influenced by the ffinity of the dye to the silk fabric. In the dyeing of silk/nylon with C. I. Acid Blue 80 and C. I. Acid Yellow 121, solid shade could not be obtained with the conventional method but could be obtained with the dyeing resist agent for nylon. There was not any relationship between K/S value and Munsell value, but Munsell value tended to change with the K/S value.

  • PDF

트리아세테이트/PET 혼방 직물의 분산염료 혼합염색 (Combination Dyeing of Triacetate/PET Blended Fabric with Disperse Dye)

  • 김명옥;이정순
    • 감성과학
    • /
    • 제19권4호
    • /
    • pp.3-12
    • /
    • 2016
  • 본 연구의 목적은 트리아세테이트와 흡한속건성 PET 합연사로 구성된 복합직물의 염착량 증진 및 동일색상 염색(union dyeing)을 위한 최적 혼합염색 조건을 찾는 것이다. 이를 위하여 E-type 분산염료(C.I. Disperse red 50)와 S-type 분산염료(C.I. Disperse red 92)를 혼합하여 1욕 혼합염색으로 염색온도, 염색시간, 염료의 혼합비율에 따른 염색직물의 흡진율, 염착율, 색상 및 색차를 측정하였다. 혼합염색의 염착평형은 $100^{\circ}C$에서 일어났으나 염색된 직물의 K/S 값과 겉보기 색상을 비교해보았을 때 트리아세테이트와 흡한속건성 PET의 색이 동일한 색으로 발현되는 온도는 $120^{\circ}C$임을 확인하였다. 염색 시간 증가에 따른 혼합염료 흡진율과 염착량의 변화는 크게 나타나지 않았으나 염색시간이 길수록 그리고 혼합염료를 사용할 경우 균일한 색상을 얻을 수 있었다. E-type에 S-type염료의 혼합비율을 적절히 조절하여 혼합염색 하면 단독염색 보다 E-type 염료의 색상과 차이 없이 염착량을 증대시킬 수 있었다.

Dyeing Properties of Polyurethane-impregnated PET Knit

  • Park, Jong-Ho;Kim, Sung-Dong
    • 한국염색가공학회지
    • /
    • 제20권5호
    • /
    • pp.35-40
    • /
    • 2008
  • Dyeing and washing fastness properties of polyurethane-impregnated polyester (PU-impregnated PET), and the distribution of two disperse dyes between PET and PU film were studied to investigate the effect of PU portion to exhaustion and washing fastness. Dyeing properties of PU-impregnated PET were quite different with those of PET: PU-impregnated PET absorbed disperse dye linearly from the early stage of dyeing to equilibrium, and it exhibited excellent build-up property up to 4 %owf dyeing. The absorbed dye on PU film at early dyeing stage migrated to more substantive PET at the temperature higher than $115^{\circ}C$. The amount of exhausted dye on PET portion was larger than on PU film and the distribution ratio was $2.08{\sim}2.34$. The grade of washing fastness of PU-impregnated PET was the same as or lower by $0.5{\sim}1$ grade than PU film whose washing fastness was lower by $0.5{\sim}1$ than PET.