• 한국수자원학회논문집
• /
• 제46권5호
• /
• pp.505-517
• /
• 2013

본 연구에서는 기후변화에 따른 금강유역의 미래 유출량을 산정해 댐별 용수공급 변화량을 산정하였다. GCM은 최근 국립기상연구소가 도입한 영국기후변화 예측모델인 HadGEM2-AO를 사용하였고 새로운 온실가스 시나리오인 RCP시나리오를 금강유역내 기상관측소로 추출하였다. ArcSWAT모형을 이용해 1988년부터 2011년까지의 과거 유출모의를 수행하였으며 금강권역 내 대표 지점인 용담댐 및 대청댐 지점의 유입량과 최종 방류부의 유출량 분석값을 비교한 결과 모의치와 실측치가 각각 92.25%, 95.40%로 일치하는 것으로 나타나 모형의 적용성을 확인하였다. 또한 새로운 온실가스 시나리오하에서의 미래 유출량을 분석한 결과 RCP4.5 시나리오 하에서 평균 47.76%, RCP8.5 시나리오 하에서 평균 36.52%가량 유출증가가 일어날 것으로 예측되었으며 특히 가을철과 겨울철에 증가율이 높았다. 유출변화에 따른 용수공급 변화를 전망하기 위하여 KModSim으로 물수지 모형을 구축하여 추가 취수량 변화를 분석하였다. 이수안전도 95%유지조건 하에서 취수가능량을 분석한 결과, RCP4.5 시나리오 하에서 용담댐과 대청댐 각각 $9.41m^3/s$, $24.82m^3/s$가 더 취수가능하며 RCP8.5 시나리오 하에서는 $6.48m^3/s$, $21.08m^3/s$가 더 취수 가능한 것으로 전망되었다.

• 대한토목학회논문집
• /
• 제28권6B호
• /
• pp.697-707
• /
• 2008

격자기반 운동파 강우유출모형 KIMSTORM(grid-based KIneMatic wave STOrm Runoff Model)은 유역의 지표흐름, 지표하흐름 및 하천흐름의 시간적 변화와 공간적 분포를 모의할 수 있다. 본 모형은 유닉스 운영체제의 C++언어로 개발되었으며, 각 셀에서의 흐름을 모의하기 위하여 단방향흐름 알고리즘과 격자기반 수문학적 물수지요소를 채택하고 있으나 운영에 몇몇 제약사항이 있다. 본 연구에서는 기존모형을 개선하고자 하였으며, MS Windows 운영체제에서 실행 가능하도록 FORTRAN 90 언어를 이용하여 ModKIMSTORM을 개발하였다. 기존모형에 비해 개선된 주요사항으로, 물리적 기반의 침투기법인 GAML(Green-Ampt & Mein-Larson) 침투모형 추가, 격자 유출심과 Manning 조도계수에 의한 논에서의 지표유출 제어, 지표격자의 기저유출 요소 추가, 공간강우와 지점강우의 처리, 전 후 처리부문 개발, 5개 평가항목(피어슨의 결정계수 $R^2$, Nash & Sutcliffe 모형효율 E, 유출용적 편차 $D_v$, 첨두유출의 상대오차 $EQ_p$, 첨두시간의 절대오차 $ET_p$)을 이용한 모의결과의 자동 평가 기능을 개발하였다. 추가적으로, 모형의 계산효율을 향상시키고 지표격자의 기저유출을 하천격자로 이송하기 위하여 쉘정렬 알고리즘을 채택하였다. 모형의 입력자료는 ESRI ArcInfo W/S 또는 ArcView와 같은 GIS 소프트웨어 및 MS Excel을 이용하여 간단히 구축할 수 있으며, 모의결과의 공간적 분포를 확인할 수 있는 토양수분, 지표유출, 유출심 및 유속분포도는 BSQ, ESRI ASCII Grid, ESRI Binary Grid 및 IDRISI Raster 형식으로 출력할 수 있도록 개선하였다.

• Carbon letters
• /
• 제28권
• /
• pp.31-37
• /
• 2018

This paper examines a simple one-step and catalyst-free method for synthesizing carbon nanoparticles from aliphatic alcohols and n-hexane with linear molecule formations by using a stable solution plasma process with a bipolar pulse and an external resistor. When the external resistor is adopted, it is observed that the current spikes are dramatically decreased, which induced production of a more stable discharge. Six aliphatic linear alcohols (methanol-hexanol) containing carbon with oxygen sources are studied as possible precursors for the massive production of carbon nanoparticles. Additional study is also carried out with the use of n-hexane containing many carbons without an oxygen source in order to enhance the formation of carbon nanoparticles and to eliminate unwanted oxygen effects. The obtained carbon nanoparticles are characterized with field emission-scanning electron microscopy, energy dispersive X-ray spectroscopy, and Raman spectroscopy. The results show that with increasing carbon ratios in alcohol content, the synthesis rate of carbon nanoparticles is increased, whereas the size of the carbon nanoparticles is decreased. Moreover, the degree of graphitization of the carbon nanoparticles synthesized from 1-hexanol and n-hexane with a high carbon (C)/oxygen (O) ratio and low or no oxygen is observed to be greater than that of the carbon nanoparticles synthesized from the corresponding materials with a low C/O ratio.

• 한국해양학회지:바다
• /
• 제3권4호
• /
• pp.175-182
• /
• 1998

동해의 울릉분지 표층에서 1996년 9월 초부터 11월 사이에 염분$^*$ 32 이하의 저염 해수가 출현했음이 최근 학계에 보고되었으며, 이 해수의 기원으로 여름철에 제주도 부근까지 세력을 확장하는 장강 유출수가 지목되었다. 대한해협의 서수로를 통과하는 해수가 두 단성분(장강 회석수와 쿠로시오 해수) 간의 단순한 혼합에 의한다는 가정하에 $^{228}Ra/^{226}Ra$ 방사능 비를 보존적 추적자로 활용하여, 두 수괴가 대한해협 서수로를 통과하는 표층수를 형성하는데 얼마나 기여하는가를 산정하였다. 알려진 두 단성분의 $^{228}Ra$, $^{226}Ra$ 방사능 측정값과 대한해협 서수로에서 측정한 $^{228}Ra/^{226}Ra$ 방사능 비로써 계산한 결과, 장강 희석수는 평균 염분이 32.17이었던 1996년 9월에 대한해협 서수로 표층수의 $58{\pm}3%$ 그리고 평균 염분이 34.53이었던 1997년 2월에는 $10{\pm}3%$ 기여하였던 것으로 나타났다. 이것은 제한된 자료와 매우 단순한 모델로부터 얻은 결과이지만 장강 유출수가 동해 내부에까지 영향을 주고 있음을 지시하며, 현재 장강 수계에 건설중인 삼협댐이 완공되면 장강 희석수 자체의 변화로 인해 북부 동중국해와 울릉분지 부근에 걸쳐 수십년 시간 규모의 해양 환경 변화가 일어날 것으로 판단된다.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 1999년도 하계학술대회 논문집 D
• /
• pp.1504-1507
• /
• 1999

We have grown vertically aligned carbon nanotubes in a large area of Co-Ni codeposited Si substrates by the thermal CVD using $C_2H_2$ gas. Since the discovery of carbon nanotubes, Synthesis of carbon nanotubes for mass production has been achieved by several methods such as laser vaporization arc discharge, and pyrolysis. In particular, growth of vertically aligned nanotubes is of technological importance for applications to FED. Recently, vertically aligned carbon nanotubes have been grown on glass by PECVD Aligned carbon nanotubes can be also grown on mesoporous silica and Fe patterned porous silicon using CVD. Despite such breakthroughs in the growth, the growth mechanism of the alignment are still far from being clearly understood. Furthermore, FED has not been clearly demonstrated yet at a practical level. Here, we demonstrate that carbon nanotubes can be vertically aligned on catalyzed Si substrate when the domain density reaches a certain value. We suggest that steric hindrance between nanotubes at an initial stage of the growth forces nanotubes to align vertically and then nanotubes are further grown by the cap growth mechanism.

• Applied Microscopy
• /
• 제45권4호
• /
• pp.236-241
• /
• 2015

Carbon-coated Ni, Cu and Sn nanocapsules were investigated by means of X-ray diffraction (XRD), transmission electron microscopy (TEM) and a four-point probe device. All of these nanocapsules were prepared by an arc-discharge method, in which the bulk metals were evaporated under methane ($CH_4$) atmosphere. Three pure metals (Ni, Cu, Sn) were typically diverse in formation of the carbon encapsulated nanoparticles and their different mechanisms were investigated. It was indicated that a thick carbon layers formed on the surface of Ni(C) nanocapsules, whereas a thin shell of carbon with 1~2 layers covered on Cu(C) nanocapsules, and the Sn(C) nanocapsules was, in fact, a longger multi-walled carbon nanotubes partially-filled with metal Sn. As one typical magnetic/dielectric nanocomposite particles, Ni(C) nanocapsules and its counterpart of oxide-coated Ni(O) nanocapsules were compared in the electrically conductive behaviors for further applications as the electromagnetic materials.

• 한국수소및신에너지학회논문집
• /
• 제17권4호
• /
• pp.362-370
• /
• 2006

The purpose of this paper was to investigate the reforming characteristics and optimum operating condition of the plasmatron assisted $CH_4$ reforming reaction for the hydrogen-rich gas production. Also, in order to increase the hydrogen production and the methane conversion rate, parametric screening studies were conducted, in which there were the variations of the $CH_4$ flow ratio, $CO_2$ flow ratio, vapor flow ratio, mixing flow ratio and catalyst addition in reactor. High temperature plasma flame was generated by air and arc discharge. The air flow rate and input electric power were fixed 5.1 l/min and 6.4 kW, respectively. When the $CH_4$ flow ratio was 38.5%, the production of hydrogen was maximized and optimal methane conversion rate was 99.2%. Under these optimal conditions, the following synthesis gas concentrations were determined: $H_2$, 45.4%; CO, 6.9%; $CO_2$, 1.5%; and $C_2H_2$, 1.1%. The $H_2/CO$ ratio was 6.6, hydrogen yield was 78.8% and energy conversion rate was 63.6%.

• 한국재료학회지
• /
• 제26권4호
• /
• pp.187-193
• /
• 2016

Fabrication of iron oxide/carbon nanotube composite structures for detection of ammonia gas at room temperature is reported. The iron oxide/carbon nanotube composite structures are fabricated by in situ co-arc-discharge method using a graphite source with varying numbers of iron wires inserted. The composite structures reveal higher response signals at room temperature than at high temperatures. As the number of iron wires inserted increased, the volume of carbon nanotubes and iron nanoparticles produced increased. The oxidation condition of the composite structures varied the carbon nanotube/iron oxide ratio in the structure and, consequently, the resistance of the structures and, finally, the ammonia gas sensing performance. The highest sensor performance was realized with $500^{\circ}C/2h$ oxidation heat-treatment condition, in which most of the carbon nanotubes were removed from the composite and iron oxide played the main role of ammonia sensing. The response signal level was 62% at room temperature. We also found that UV irradiation enhances the sensing response with reduced recovery time.

• 한국재료학회:학술대회논문집
• /
• 한국재료학회 2011년도 추계학술발표대회
• /
• pp.43.2-43.2
• /
• 2011

Single-walled carbon nanotubes (SWCNT) are transparent in the visible and show conductivity comparable to copper, and are environmentally stable. SWCNT films have high flexibility, conductivity and transparency approaching that indium tin oxide (ITO), and can be prepared inexpensively without vacuum equipment. Transparent conducting Films (TCF) of SWCNTs has the potential to replace conventional transparent conducting oxides (TCO, e.g. ITO) in a wide variety of optoelectronic devices, energy conversion and photovoltaic industry. However, the sheet resistance of SWCNT films is still higher than ITO films. A decreased in the resistivity of SWCNT-TCFs would be beneficial for such an application. We fabricated SWCNT sheet with $KAuBr_4$ on PET substrate. Arc-discharge SWCNTs were dispersed in deionized water by adding sodum dodecyl sulfate (SDS) as surfactant and sonicated, followed by the centrifugation. The dispersed SWCNT was spray-coated on PET substrate and dried on a hotplate at $100^{\circ}C$. When the spray process was terminated, the TCF was immersed into deionized water to remove the surfactant and then it was dried on hotplate. The TCF film was then treated with AuBr4-, rinsed with deionized water and dried. The surface morphology of TCF was characterized by field emission scanning electron microscopy. The sheet resistance and optical transmission properties of the TCF were measured with a four-point probe method and a UV-visible spectrometry, respectively. $HNO_3$ treated SWCNT films with Au nano-particles have the lowest 61 ${\Omega}$/< sheet resistance in the 80% transmittance. Sheet resistance was decreased due to the increase of the hole concentration at the washed SWCNT surface by p-type doping of $AuBr_4{^-}$.

• 한국재료학회지
• /
• 제20권4호
• /
• pp.199-203
• /
• 2010

Hybridization of semiconductor materials with carbon nanotubes (CNTs) is a recent field of interest in which new nanodevice fabrication and applications are expected. In this work, nanowire type GaAs structures are synthesized on porous single-wall carbon nanotubes (SWCNTs) as templates using the molecular beam epitaxy (MBE) technique. The field emission properties of the as-synthesized products were investigated to suggest their potential applications as cold electron sources, as well. The SWCNT template was synthesized by the arc-discharge method. SWCNT samples were heat-treated at $400^{\circ}C$ under an $N_2/O_2$ atmosphere to remove amorphous carbon. After heat treatment, GaAs was grown on the SWCNT template. The growth conditions of the GaAs in the MBE system were set by changing the growth temperatures from $400^{\circ}C$ to $600^{\circ}C$. The morphology of the GaAs synthesized on the SWCNTs strongly depends on the substrate temperature. Namely, nano-crystalline beads of GaAs are formed on the CNTs under $500^{\circ}C$, while nanowire structures begin to form on the beads above $600^{\circ}C$. The crystal qualities of GaAs and SWCNT were examined by X-ray diffraction and Raman spectra. The field emission properties of the synthesized GaAs nanowires were also investigated and a low turn-on field of $2.0\;V/{\mu}m$ was achieved. But, the turn-on field was increased in the second and third measurements. It is thought that arsenic atoms were evaporated during the measurement of the field emission.