• Title/Summary/Keyword: Discharge Properties

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리튬 이온 이차전지 부극용 열분해 탄소 및 붕소첨가 탄소의 전기화학적 특성 (Electrochemical Properties of Pyrolytic Carbon and Boron-doped Carbon for Anode Materials In Li-ion Secondary Batteries)

  • 권익현;송명엽;방의용;한영수;김기태;이재영
    • 전기화학회지
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    • 제5권1호
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    • pp.30-38
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    • 2002
  • 탄화수소가스를 고온$(1000^{\circ}C)$에서 열분해 하여 고상화하는 기상 열분해법을 사용하여 저결정질 탄소재를 제조하고 같은 방법으로 붕소를 첨가한 저결정질 탄소재$C_{l-x}B_x(x=0.05,\;0.10,\;0.20)$를 제조하여, 리튬 이온 이차전지의 부극으로서의 전기화학적 특성을 조사하였다. 시료 대 PVDF를 95:5의 무게비로 첨가한 경우, 붕소를 첨가하지 않은 저 결정질 탄소재(x=0.00)는 초기 방전용량 374mAh/g을 나타내었으며, 제 2싸이클부터는 싸이클 성능이 비교적 우수하여 제 10싸이클에서 258mAh/g의 방전용량을 나타내었다. 시료 대 PVDF를 95:5의 무게비로 첨가한 경우, $C_{1-x}B_x(x=0.00,\;0.05,\;0.10\;0.20)$ 시료들 중에서 x=0.05 조성의 시료는 가장 큰 초기 방전용량 860mAh/g을 나타내었으며, 10번째 싸이클에서 181mAh/g의 방전용량을 나타내었다. 제 2싸이클부터 싸이클 성능은 모두가 비슷하게 나타났다 초기방전 용량(PVDF $10wt.\%$ 사용시, 853mAh/g), 싸이클 성능, 방전용량(PVDF $10wt.\%$사용시 10번째 싸이클에서 400mAh/g)면에서 $C_{0.90}B_{0.10}$ 시료가 리튬이온 이차전지의 부극으로서의 가장 우수한 전기화학적 특성을 나타내었다. 합성한 탄소에 NMP를 용매로 한 액상 혼합 바인더(PVDF)를 90:10의 무게비로 첨가한 경우가 95:5의 무게비로 첨가한 경우보다 대체로 모든 조성에서 충$\cdot$방전용량이 크게 나타났다. 붕소가 첨가되어 덜 disordered된 구조가 됨으로써 1.25V보다 낮은 전압 부분에서 평탄구역이 증가하는 것으로 판단된다. 붕소가 첨가된 경우 충$\cdot$방전용량이 제 2싸이클에서부터 급격히 감소하였는데, 이는 첨가된 붕소가 제 1싸이클에서 삽입되는 Li과 일부는 강하게 결합하여 추출이 안되고 일부만이 다시 가역적으로 추출$\cdot$삽입되기 때문으로 생각된다. 붕소 첨가에 의한 충$\cdot$방전용량의 증가는, 붕소가 electron acceptor로 작용하여 삽입된 Li와 붕소-탄소 host 사이의 결합 강도를 증가시킴으로써 붕소치환 된 탄소에서 Li의 전위를 상승시키기 때문에 일어난다고 사려된다.

방전에 의한 프라즈마에서의 마이크로파 전파특성 (The Properties of Microwave Propagation in Discharging Plasma)

  • 양인응;노방현;김봉열
    • 대한전자공학회논문지
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    • 제5권3호
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    • pp.31-39
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    • 1968
  • 외부자계가 가해진 냉프라즈마에서의 마이크로파 전파 특성을 측정하였다. 직류방전프라즈마는 두 전극판을 구형도파관에 삽입한것과, 또한 유리시설관을 구형도파관에 삽입한 것에서 이루어졌다. 마이크로파 전파방향, 방전관축, 외부자계는 각각 수직이고, 자속밀도, 방전유기, 기체압등이 증가할때 프라즈마를 전파하는 마이크로파의 감쇠 및 흡수는 증가함을 보았다.

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Corona 방전을 이용한 폴리에스테르 직물의 방염가공 (Flame Retardant Finish of Polyester Fabrics by Corona Discharge)

  • Ju, Yi Jung;Pak, Pyong Ki;Kim, Hwan Chul
    • 한국염색가공학회지
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    • 제8권6호
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    • pp.65-72
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    • 1996
  • Polyester(PET) fabrics were treated by corona discharge equipment with the small amount of flame retardants to enhance flame retardancy. The surface properties of corona discharged fabrics were investigated using water penetration time, SEM, ESCA, and TGA. When corona discharge was applied to PET fabrics, the flame retardants were evenly distributed. As a result, the oxygen-containing functional groups were produced, and the LOI value increased. Thermogravimetric analysis indicated that the flame retardancy was operative by gas-phase mechanism.

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양극 활물질의 입도에 따른 열전지 출력 특성 연구 (Effect of Particle Size of Cathode Materials on Discharge Properties of Thermal Batteries)

  • 이정민
    • 한국전기전자재료학회논문지
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    • 제27권6호
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    • pp.399-406
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    • 2014
  • Thermal batteries are used for military power sources that require robustness and long storage life such as missiles and torpedoes. $FeS_2$ powder is currently used for cathode materials because of its high specific energy density, environmental non-toxicity and low cost. However, large particle size of conventional $FeS_2$ has been deterred its possible application for higher power thermal batteries. In order to improve the power density, high energy ball milling of $FeS_2$ has been introduced to crush the micron-sized $FeS_2$. Discharge characteristics of the single cells fabricated with nano-materials and conventional $FeS_2$ powder were evaluated.

Dielectric barrier discharge 플라즈마 펄스 레이져 증착법을 통해 성장한 nitrogen 도핑 된 산화아연 박막의 광학적 특성 (Optical properties of nitrogen doped ZnO thin films grown by dielectric barrier discharge plasma-assisted pulsed laser deposition)

  • 이득희;김상식;이상렬
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2009년도 제40회 하계학술대회
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    • pp.1256_1257
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    • 2009
  • We have grown, for the first time to our knowledge, N-doped ZnO thin films on sapphire substrate by employing novel dielectric barrier discharge in pulsed laser deposition (DBD-PLD). DBD guarantees an effective way for massive in-situ generation of N-plasma under the conventional PLD process condition. Low-temperature photoluminescence spectra of the N-doped ZnO film provided near band-edge emission after thermal annealing process. The emission peak was resolved by Gaussian fitting to find a dominant acceptor-bound exciton peak ($A^0X$) that indicates the successful p-type doping of ZnO with N.

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티타늄합금의 와이어 방전가공과 연삭가공시 기계적 특성 (Mechanical Characteristics when Wire Electrical Discharge Machining and Surface Grinding for Titanium Alloy)

  • 김종업;왕덕현;김원일;이윤경
    • 한국공작기계학회:학술대회논문집
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    • 한국공작기계학회 2001년도 추계학술대회(한국공작기계학회)
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    • pp.172-178
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    • 2001
  • Titanium alloys have lightness, high strength and good corrosion resistant characteristics, and broadly used in manufacturing parts for military and aerospace industries. And these alloys also are recognized for organism materials comparatively and used as fixing ones in the human body. Nevertheless thess alloys have excellent properties such as corrosion resistance, heat resistance, and good tensile strength, it is difficult to machine by traditional methods because of high hardness and chemically activated property. So higher tool wear is expected when cutting by tools. Therefore, it is required nontraditional machining process. And the mechanical characteristics such as surface structure and shape, hardness and bending strength are studied for wire electrical discharge machined and surface ground titanium alloys for various heat-treated conditions.

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Removal Characteristics of Benzene in Dielectric Barrier Discharge Process

  • Chung, Jae-Woo
    • Journal of Korean Society for Atmospheric Environment
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    • 제18권E1호
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    • pp.13-20
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    • 2002
  • The electrical and chemical properties of the dielectric barrier discharge (DBD) process for the benzene removal were investigated. The benzene removal was initiated with the applied voltage higher than the discharge onset value. The removal efficiency over 95 % was obtained at approximately 1.6 kJ lite $r^{r-1}$ of the electrical energy density. The increase of the inlet concentration decreased the removal efficiency. However, the benzene decomposition rate increased with the inlet concentration . While the increase of the gas retention time enhanced the removal efficiency, the decomposition rate decreased. Identification of the optimum condition between the decomposition rate and the removal efficiency is required for field applications of the DBD process.s.

플라즈마 아크방전(PAD)법으로 제조된 Fe Nanocapsules의 특성 (Characterization of Fe Nanocapsules synthesized by Plasma Arc Discharge Process)

  • 박우영;윤철수;유지훈;오영우;최철진
    • 한국분말재료학회지
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    • 제11권6호
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    • pp.510-514
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    • 2004
  • Iron-carbon nanocapsules were synthesized by plasma arc discharge (PAD) process under various atmosphere of methane, argon and hydrogen gas. Characterization and surface properties were investigated by means of HRTEM, XRD, XPS and Mossbauer spectroscopy. Fe nanocapsules synthesized were composed of three phases $({\alpha}-Fe,\;Y-Fe\;and\;Fe_{3}C)$ with core/shell structures. The surface of nanocapsules was covered by the shell of graphite phase in the thickness of $4{\~}5$nm.

Soft Switching Multi Level Inverter를 이용한 HID용 Ballast (HID Ballast using Soft Switching Multi Level Inverter)

  • 이장선;김윤호;김수홍
    • 전력전자학회논문지
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    • 제9권6호
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    • pp.628-634
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    • 2004
  • 차량용 전조등에 사용되어지는 HID(High Intensity Discharge) 발라스트(Ballast)의 특성 개선을 위하여 소프트 스위칭 방식의 멀티 레벨 인버터를 적용하였다. 멀티레벨 인버터의 모드(Mode)별 특성을 해석하고, 그 결과를 통해 발라스트의 출력 특성을 해석하고 시스템을 설계하였다. 그리고 실험을 통하여 해석결과를 확인하였다.

플라즈마 중합법에 의한 헥사메틸디실록산 박막의 전기적 특성 (Electrical Properties of Plasma Polymerized Hexamethyldisiloxane Thin Film)

  • 이상희;이덕출
    • 한국전기전자재료학회논문지
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    • 제14권1호
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    • pp.43-47
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    • 2001
  • Plasma polymerized hexamethyldisiloxane thin film was fabricated by employing an inter-electrode capacitively coupled type apparatus under the following conditions : carrier gas flow rate of 11 sccm, reaction pressure of 0.1 torr, discharge frequency of 13.56 MHz and discharge power of 30∼90 W. Polymerization rate of thin film fabricated at the discharge power of 90W is 32.5nm/min. Relative dielectric constant and dielectric loss tangent of thin film shows 3.2∼3.8 and 2.6x10$\^$-3/∼4.51x10$\^$-3/ respectively in the frequency range of 1 kHz∼1 MHz. As the annealing temperature is increased, the relative dielectric constant gradually decreases while the dielectric loss tangent increases. The current density increase gradually with increasing annealing temperature and electric field. The electric conduction of the heaxamethyldisiloxane thin film shows Schottky effect.

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