• 제목/요약/키워드: Discharge Properties

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플라즈마 표면처리에 따른 고분자절연재료의 표면개질 (Surface Modification of Polymer Insulator by Plasma Surface Treatment)

  • 임경범;황명환;이백수;유도현;육재호;김형권;임헌찬;박강식;이덕출
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 춘계학술대회 논문집 유기절연재료 전자세라믹 방전플라즈마 일렉트렛트 및 응용기술
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    • pp.31-35
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    • 2002
  • It is hard to expect excellent electrical, mechanical and chemical properties from most of the composite materials presently used as insulators due to insufficient wettability property caused by the difference of interfacial properties between the matrix material and the reinforcer. Therefore, various interfacial coupling agents have been developed to improve the interfacial properties of composite materials. But if the wettable coupling agents are used outdoor for a long time, change in quality takes place in the coupling agents themselves, bringing about deterioration of the properties of the composite materials. In this study, composite materials were put to dry interfacial treatment by use of plasma technology. It has been presented that the optimum parameters for the best wettability of the samples at the time of generation of plasma were oxygen atmosphere, 0.1 torr of system pressure, 100 W of discharge power, and 3 minutes of discharge time. Also, the surface resistance rate and dielectric property were improved.

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리튬 2차전지용$ Li_xNi_{2-x}O_2$ 정극의 충방전 특성 (The Charge/discharge Properties of $ Li_xNi_{2-x}O_2$Cathode for Lithium Rechargeable Battery)

  • 김철중;전대규;이하니;박영철;김주승;구할본
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1996년도 추계학술대회 논문집
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    • pp.378-381
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    • 1996
  • This study is to research Li$_{x}$Ni$_{2-x}$O$_2$ cathode for lithium chargeable battery. We investigated morphology and cell resistance, capacity and Ah efficiency of Li$_{x}$Ni$_{2-x}$O$_2$/Li cells using Li$_{x}$Ni$_{2-x}$O$_2$ prepared under air and $O_2$ flow. The (003)I/(104)I intensity ratio was 1.4. The cell resistance was increased with increasing Li in Li$_{x}$Ni$_{2-x}$O$_2$. The discharge capacity based on Li$_{x}$Ni$_{2-x}$O$_2$of 1st and 15th cycles was 135㎃h/g and 108㎃h/g, respectively. The Li$_{x}$Ni$_{2-x}$O$_2$ prepared with hexan under $O_2$ flow had a good properties. properties. properties.

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Surface Coating and Electrochemical Properties of LiNi0.8Co0.15Al0.05O2 Polyaniline Composites as an Electrode for Li-ion Batteries

  • Chung, Young-Min;Ryu, Kwang-Sun
    • Bulletin of the Korean Chemical Society
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    • 제30권8호
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    • pp.1733-1737
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    • 2009
  • A new cathode material based on Li$Ni_{0.8}Co_{0.15}Al_{0.05}O_2$ (LNCA)/polyaniline (Pani) composite was prepared by in situ self-stabilized dispersion polymerization in the presence of LNCA. The materials were characterized by fourier transform infrared spectroscopy (FT-IR), ultraviolet-visible spectroscopy (UV-Vis), X-ray diffraction (XRD), and scanning electron microscopy (SEM). Electrochemical properties including galvanostatic charge-discharge ability, cyclic voltammetry (CV), capacity, cycling performance, and AC impedance were measured. The synthesized LNCA/Pani had a similar particle size to LNCA and exhibited good electrochemical properties at a high C rate. Pani (the emeraldine salt form) interacts with metal-oxide particles to generate good connectivity. This material shows good reversibility for Li insertion in discharge cycles when used as the electrode of lithium ion batteries. Therefore, the Pani coating is beneficial for stabilizing the structure and reducing the resistance of the LNCA. In particular, the LNCA/Pani material has advantageous electrochemical properties.

글루타티온이 캡핑된 ZnSe 나노 입자 발광 특성에 미치는 합성 조건의 영향 (Effects of Synthesis Conditions on Luminescence Characteristics of Glutathione Capped ZnSe Nano particles)

  • 백금지;송하연;이민서;홍현선
    • 한국분말재료학회지
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    • 제28권1호
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    • pp.44-50
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    • 2021
  • Zinc selenide (ZnSe) nanoparticles were synthesized in aqueous solution using glutathione (GSH) as a ligand. The influence of the ligand content, reaction temperature, and hydroxyl ion concentration (pH) on the fabrication of the ZnSe particles was investigated. The optical properties of the synthesized ZnSe particles were characterized using various analytical techniques. The nanoparticles absorbed UV-vis light in the range of 350-400 nm, which is shorter than the absorption wavelength of bulk ZnSe particles (460 nm). The lowest ligand concentration for achieving good light absorption and emission properties was 0.6 mmol. The reaction temperature had an impact on the emission properties; photoluminescence spectroscopic analysis showed that the photo-discharge characteristics were greatly enhanced at high temperatures. These discharge characteristics were also affected by the hydroxyl ion concentration in solution; at pH 13, sound emission characteristics were observed, even at a low temperature of 25℃. The manufactured nanoparticles showed excellent light absorption and emission properties, suggesting the possibility of fabricating ZnSe QDs in aqueous solutions at low temperatures.

PVDF 전구체를 이용한 탄소 도포 실리콘 재료의 개발 및 리튬이차전지 음극특성 (Development of Silicon Coated by Carbon with PVDF Precursor and Its Anode Characteristics for Lithium Batteries)

  • 도칠훈;정기영;진봉수;김현수;문성인;윤문수;최임구;박철완;이경직
    • 한국전기전자재료학회논문지
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    • 제19권7호
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    • pp.636-643
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    • 2006
  • Si-C materials were synthesized by the heating the mixture of silicon and polyvinylidene fluoride (PVDF). The electrochemical properties of the Si-C materials as the high capacitive anode materials of lithium secondary batteries were evaluated by the galvanostatic charge-discharge test through 2032 type $Si-C{\mid}Li$ coin cells. Charge-discharge tests were performed at C/10 hour rate(C = 372 mAh/g). Initial discharge and charge capacities of $Si-C{\mid}Li$ cell using a Si-C material derived from PVDF(20wt.%) were found to be 1,830 and 526 mAh/g respectively. The initial discharge-charge characteristics of the developed Si-C electrode were analyzed by the electrochemical galvanostatic test adopting the capacity limited charge cut-off condition(GISOC). The range of reversible specific capacity IIE(intercalation efficiency at initial discharge-charge) and IICs(surface irreversible specific capacity) were 216 mAh/g, 68 % and 31 mAh/g, respectively.

대기압 RF DBD 방전으로 개질된 폴리이미드의 표면특성 (Surface Properties of Polyimide Modified with He/O2/NF3 Atmospheric Pressure RF Dielectric Barrier Discharge)

  • 이수빈;김윤기;김정순
    • 한국재료학회지
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    • 제16권9호
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    • pp.543-549
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    • 2006
  • Polyimides (PI) are treated with $He/O_2$ and $He/O_2/NF_3$ atmospheric pressure rf dielectric barrier discharge in order to investigate the roles of $NF_3$ that is one of the PI etching gases. Surface changes are analyzed by x-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), and contact angle measurement. The surface roughness of PI and the ratio of C=O, which is hydrophilic functional group, is more increased by $He/O_2/NF_3$ discharge than by $He/O_2$ discharge. The C=O species on the PI surface is increased up to 30 percent with rf power. The surface roughness of PI is increased from 0.4 to 11 nm with rf power. The water drop contact angles on PI, however, are reduced from $65^{\circ}\;to\;9^{\circ}$ by plasma treatment independently of $NF_3$.

초고압 전력케이블용 중간 접속부 내의 부분방전신호 검출을 위한 박전극 응용 (The Application of Al-foil Electrode for Detecting Partial Discharge Signal in Middle Joint Box of EHV Power Cable)

  • 이용성;양종경;양종석;최용성;박대희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 추계학술대회 논문집 Vol.18
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    • pp.142-144
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    • 2005
  • To detect partial discharge of 154kV joint box, we have made experiment by using the Al-foil electrode sensor. Generally the signals which are detected in partial discharge test of underground power transmission cable are accompanied wi th both noises of high voltage and noises of surrounding power cable. The most noise in near to end part of joint box is corona, beside other noises flowed from surrounding area. Partial discharge test is difficulty due to these noises. First, we had used Al-Foi1 sensor on middle joint box of 154[kV] underground transmission power cable, and then analyzed reliability of calibration signal by using the Al-Foi1 electrode sensor of NJB. From above results, decrement properties measured highly. But incase of injecting calibration signal of 500[pC] after measuring signals in IJB, the S/N ratio had about 25[dB] acquisition.

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코로나 방전처리에 의한 폴리에스테르 및 P/C 혼방직물의 복합기능화 가공(I) -난연 및 위생가공- (Multi-Functional Finish of Polyester and P/C blend Fabrics by Corona Discharge(I) -Flame-Retardant and Sanitary Finish-)

  • Lee, Bang One;Pak, Pyong Ki;Lee, Hyun Ja;Lee, Hwa Sun
    • 한국염색가공학회지
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    • 제9권2호
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    • pp.1-9
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    • 1997
  • This paper was carried out to introduce flame retardant and antibiotic properties to polyester(PET) and polyester/cotton(P/C) blend fabrics. PET and P/C blend fabrics were treated by a paddry-cure method in the aqueous solutions of the finishing agents(JA 6034, JA 6050, DC-5700). The corona discharge technique was applied to increase the polar group of the polymer surface. The characteristics of the treated fabric were investigated by means of scanning electron microscope (SEM) and electron spectroscopy for chemical analysis(ESCA), and water penetration time, limiting Oxygen index(LOI), and K/S value were also measured. Wettability of the fabrics was increased considerably with the corona discharge treatment. ESCA was used to elucidate the surface chemical composition of the fabrics treated with the corona discharge. Relative Ols intensity increased and oxygen was incorporated in the form of -C-O-, -C=O, and O=C-O on the polymer surface. The current study indicated that corona discharge treatment was effective for modifying the polymer surface.

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불평형 마그네트론 스파터링에 의해 형성된 MgO 박막의 글로우 방전특성에 관한 연구 (A Study on the Glow Discharge Characteristics of MgO thin film prepared by Unbalanced Magnetron Sputtering)

  • 김영기;박정태;고광식;김규섭;박정후;조정수
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1999년도 하계학술대회 논문집 E
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    • pp.2236-2238
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    • 1999
  • This paper deals with the surface glow discharge characteristics and some physical properties of MgO thin films prepared by RF unbalanced magnetron sputtering(UBMS) in surface discharge type AC PDP. The minimum discharge voltage is obtained for the sample of substrate holder bias voltage -10V. The main factors that improves the discharge characteristics by applied bias voltage is considered to be due to the morphology changes or crystal structure of the MgO thin film by ion bombardment during deposition process Moreover, the anti-sputtering characteristics of MgO thin film by UBMS is more excellent than that of balanced magnetron sputtering(BMS) and E-beam evaporation method.

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Estimating Groundwater Level Change Associated with River Stage and Pumping using Time Series Analyses at a Riverbank Filtration Site in Korea

  • Cheong, Jae-Yeol;Hamm, Se-Yeong;Kim, Hyoung-Soo;Lee, Soo-Hyoung;Park, Heung-Jai
    • 한국환경과학회지
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    • 제26권10호
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    • pp.1135-1146
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    • 2017
  • At riverbank filtration sites, groundwater levels of alluvial aquifers near rivers are sensitive to variation in river discharge and pumping quantities. In this study, the groundwater level fluctuation, pumping quantity, and streamflow rate at the site of a riverbank filtration plant, which produces drinking water, in the lower Nakdong River basin, South Korea were interrelated. The relationship between drawdown ratio and river discharge was very strong with a correlation coefficient of 0.96, showing a greater drawdown ratio in the wet season than in the dry season. Autocorrelation and cross-correlation were carried out to characterize groundwater level fluctuation. Autoregressive model analysis of groundwater water level fluctuation led to efficient estimation and prediction of pumping for riverbank filtration in relation to river discharge rates, using simple inputs of river discharge and pumping data, without the need for numerical models that require data regarding several aquifer properties and hydrologic parameters.