• Title/Summary/Keyword: Direct quenching

Search Result 54, Processing Time 0.022 seconds

Effects of Doping in Organic Electroluminescent Devices Doped with a Fluorescent Dye

  • Kang, Gi-Wook;Ahn, Young-Joo;Lee, Chang-Hee
    • Journal of Information Display
    • /
    • v.2 no.3
    • /
    • pp.1-5
    • /
    • 2001
  • The effect of doping on the energy transfer and charge carrier trapping processes has been studied in organic light-emitting diodes (OLEDs) doped with a fluorescent laser dye. The devices consisted of N,N'-diphenyl-N,N'-bis(3-methylphenyl)-1,1-biphenyl-4,4'-diamine (TPD) as a hole transporting layer, tris(8-hydroxyquinoline) aluminum ($Alq_3$) as the host, and a fluorescent dye, 4-dicyanomethylene-2-methyl-6-[2-(2,3,6,7-tetrahydro-1 H,5H-benzo[i,j]quinolizin-8-yl) vinyl]-4H-pyran) (DCM2) as the dopant. Temperature dependence of the current-voltage-luminescence (I-V-L) characteristics, the electroluminescence (EL) and photoluminescence (PL) spectra are studied in the temperature ranging between 15 K and 300 K. The emission from DCM2 was seen to be much stronger compared with the emission from $Alq_3$, indicative of efficient energy transfer from $Alq_3$ to DCM2. In addition, the EL emission from DCM2 increasd with increasing temperature while the emission from the host $Alq_3$ decreased. The result indicates that direct charge carrier trapping becomes efficient with increasing temperature. The EL emission from DCM2 shows a slightly sublinear dependence on the current density, implying the enhanced quenching of excitons at high current densities due to the exciton-exciton annihilation.

  • PDF

Comparative Analysis on Antioxidative Ability of Muscle between Laiwu Pig and Large White

  • Chen, Wei;Zhu, Hong-Lei;Shi, Yuan;Zhao, Meng-Meng;Wang, Hui;Zeng, Yong-Qing
    • Asian-Australasian Journal of Animal Sciences
    • /
    • v.25 no.8
    • /
    • pp.1190-1196
    • /
    • 2012
  • This study was conducted to evaluate effects of storage temperatures ($4^{\circ}C$ and $20^{\circ}C$) and pig breeds (Laiwu pig and Large White pig) on the main antioxidative enzymes (superoxide dismutase, catalase, and glutathione peroxidase) activity and lipid oxidation in porcine Longissimus dorsi muscle. Activities of antioxidative enzymes (AOE) decreased slightly during storage, regardless of storage temperatures. Muscle antioxidative enzymes activities stored at $4^{\circ}C$ were higher than that stored at $20^{\circ}C$. Laiwu pig's enzymes activities were significantly (p<0.01) higher than Large White's. The level of malondialdehyde is a direct expression of the grade of lipid oxidation in meat. In our study, the malondialdehyde contents increased after 6 days storage. However, malondialdehyde contents of Laiwu pig were significantly (p<0.01) lower than Large White's. A lower content of malondialdehyde corresponds to a lower oxidation of lipids. These results indicated the muscle antioxidative ability of Laiwu pig was higher than Large White pig. It also implied that antioxidative enzymes were involved in the essentials and deciding mechanisms of meat quality by quenching oxygen free radicals and inhibiting lipid oxidation in muscle.

A Study on the Fuel Behaivor with Cavity Diameter in a Gasoline Direct Injection Engine (직분식 가솔린 엔진에서 피스톤 캐비티 반경에 따른 연료 거동 분석)

  • Kim, Tae-An;Kang, Jeong-Jung;Kim, Duck-Jool
    • Proceedings of the KSME Conference
    • /
    • 2003.11a
    • /
    • pp.472-477
    • /
    • 2003
  • This study was performed to investigate the behavior of vapor phase of fuel mixtures with different piston cavity diameters in a optically accessible engine. The images of vapor phases were measured in the motoring engine using exciplex fluorescence method. The conventional engine was modified as GDI engine with swirl flow. Fuel was injected into atmospheric nitrogen to prevent quenching phenomenon by oxygen. Injection pressure is 5.1MPa. Two dimensional spray fluorescence image of vapor phases was acquired to analyze spray behavior and fuel distribution inside of cylinder. Three injection timings were set at BTDC $180^{\circ}$, $60^{\circ}$and $60^{\circ}$. With a fuel injection timing of BTDC $60^{\circ}$, fuel-rich mixture was concentrated in near the cavity center. With a fuel injection timing of BTDC $60^{\circ}$, fuel-rich mixture level in the center region was highest in the S-type during the late compression stroke. With a fuel injection timing of BTDC $180^{\circ}$, fuel was not affected in a piston cavity and generally distributed as homogeneous mixture.

  • PDF

Microstructural Feature and Aging Characteristics of Spray-Formed Cu-5Ni-10Sn Alloy (가스분무성형 Cu-5Ni-10Sn 합금의 미세조직 및 시효강화)

  • Roh, Dae-Gyun;Kang, Hee-Soo;Baik, Kyeong-Ho
    • Journal of Powder Materials
    • /
    • v.19 no.4
    • /
    • pp.317-321
    • /
    • 2012
  • In this study, Cu-5Ni-10Sn(wt%) spinodal alloy was manufactured by gas atomization spray forming, and the microstructural features and mechanical properties of Cu-5Ni-10Sn alloy have been investigated during homogenization, cold working and age-hardening. The spray formed Cu-5Ni-10Sn alloy consisted of an equiaxed microstructure with a mixture of solid solution ${\alpha}$-(CuNiSn) grains and lamellar-structure grains. Homogenization at $800^{\circ}C$ and subsequent rapid quenching formed a uniform solid solution ${\alpha}$-(CuNiSn) phase. Direct aging at $350^{\circ}C$ from the homogenized Cu-5Ni-10Sn alloy promoted the precipitation of finely distributed ${\gamma}$' or ${\gamma}-(Cu,Ni)_3Sn$ phase throughout the matrix, resulting in a significant increase in microhardness and tensile strength. Cold working prior to aging was effective in strengthening Cu-5Ni-10Sn alloy, which gave rise to a maximum tensile strength of 1165 MPa. Subsequent aging treatment slightly reduced the tensile strength to 1000-1100 MPa due to annealing effects.

Deep Impact: Molecular Gas Properties under Strong Ram Pressure Probed by High-Resolution Radio Interferometric Observations

  • Lee, Bumhyun;Chun, Aeree
    • The Bulletin of The Korean Astronomical Society
    • /
    • v.44 no.2
    • /
    • pp.39.3-39.3
    • /
    • 2019
  • Ram pressure stripping due to the intracluster medium (ICM) is an important environmental process, which causes star formation quenching by effectively removing cold interstellar gas from galaxies in dense environments. The evidence of diffuse atomic gas stripping has been reported in several HI imaging studies. However, it is still under debate whether molecular gas (i.e., a more direct ingredient for star formation) can be also affected and/or stripped by ram pressure. The goal of this thesis is to understand the impact of ram pressure on the molecular gas content of cluster galaxies and hence star formation activity. To achieve this, we conducted a series of detailed studies on the molecular gas properties of three Virgo spiral galaxies with clear signs of active HI gas stripping (NGC 4330, NGC 4402, and NGC 4522) based on high-resolution CO data obtained from the Submillimeter Array (SMA) and Atacama Large Millimeter/submillimeter Array (ALMA). As a result, we find the evidence that the molecular gas disk also gets affected by ram pressure in similar ways as HI even well inside of the stellar disk. In addition, we detected extraplanar 13CO clumps in one of the sample, which is the first case ever reported in ram pressure stripped galaxies. By analyzing multi-wavelength data (e.g., Hα, UV, HI, and CO), we discuss detailed processes of how ram pressure affects star formation activities and hence evolution of cluster galaxies. We also discuss the origin of extraplanar 13CO, and how ram pressure can potentially contribute to the chemical evolution of the ICM.

  • PDF

Optimization of $CO_2$ Direct Absorption Method for the Determination of Carbon-14 in Environmental Samples (환경시료중의 방사성탄소 측정을 위한 $CO_2$ 직접흡수법의 최적화 연구)

  • Cho, Soo-Young;Woo, Hyung-Joo;Chun, Sang-Ki
    • Journal of Radiation Protection and Research
    • /
    • v.23 no.4
    • /
    • pp.237-242
    • /
    • 1998
  • The goal of this work was to optimize the liquid scintillation counting techniques for the determination of C-14 in environmental samples such as biological and air samples. Carbon-14 activities in most environmental samples were measured with direct $CO_2$ absorption method. The highest figure of merit was found through the variation of Carbosorb $E^{TM}$ and Permatluor $V^{TM}$ ratio, in the measurement windows. The best condition was 1:1 volume ratio. Average 2.35 g of $CO_2$ was reproducibly absorbed in the 20 ml mixture within 40 min. The counting efficiency determined by repeated analysis of NIST oxalic acid standard and the background count rate were measured to be $58.8{\pm}1.4%$ and $1.88{\pm}0.06\;cpm$, respectively in case of saturated solution. The correction curves of counting efficiency for partially saturated solutions and for saturated solutions with quenching were prepared, respectively. The overall uncertainty of the sample specific activity for near background levels was estimated to be about 7 % for 4 hours counting at 95 % confidence level. The long-term stability of samples has been checked for all the counting techniques over a two week periods, and no apparent change in counting efficiency and background level was found at that time.

  • PDF

The Fluorescence Study on the Inducing Orientation of 4-Biphenyl Acetonitrile Adsorbed on Metal Colloids (금속콜로이드 표면에 흡착된 4-Biphenyl Acetonitrile의 흡착배향 유도에 관한 형광 연구)

  • Song, Won-Sik;Lee, Jun-Kyeng;Yu, Soo-Chang
    • Journal of the Korean Chemical Society
    • /
    • v.53 no.4
    • /
    • pp.399-406
    • /
    • 2009
  • The fluorescence study was performed to see whether the adsorption orientation of 4-biphenyl acetonitrile(BPAN) on metal colloids can be changed by forming an inclusion complex with $\alpha$-cyclodextrin($\alpha$-CD). The fluorescence quenching was observed with increasing temperature to confirm the direct adsorption of BPAN to the Au and Ag colloidal surfaces. BPAN adsorbed on the metal colloids formed inclusion complex with $\alpha$-CD regardless of the kinds of metal colloids. The formation constants, 32 $M^{-1}$ and 13 $M^{-1}$ for Au and Ag colloids respectively, were obtained with Benesi-Hildebrand plot. The molecules adsorbed on both the Au and Ag colloidal surfaces behaved similarly to each other, leading to the conclusion that the orientation of BPAN adsorbed on the metal colloids can be modified with $\alpha$-CD.

다채널 표면 플라즈몬 공명 영상장치를 이용한 자기조립 단분자막의 표면 분석

  • Pyo, Hyeon-Bong;Sin, Yong-Beom;Yun, Hyeon-Cheol
    • 한국생물공학회:학술대회논문집
    • /
    • 2003.04a
    • /
    • pp.74-78
    • /
    • 2003
  • Multi-channel images of 11-MUA and 11-MUOH self-assembled monolayers were obtained by using two-dimensional surface plasmon resonance (SPR) absorption. Patterning process was simplified by exploiting direct photo-oxidation of thiol bonding (photolysis) instead of conventional photolithography. Sharper images were resolved by using a white light source in combination with a narrow bandpass filter in the visible region, minimizing the diffraction patterns on the images. The line profile calibration of the image contrast caused by different resonance conditions at each points on the sensor surface (at a fixed incident angle) enables us to discriminate the monolayer thickness in sub-nanometer scale. Furthermore, there is no signal degradation such as photo bleaching or quenching which are common in the detection methods based on the fluorescence.

  • PDF

Die Stress Reduction Design and Mechanical Properties Analysis of Warm Forging Process for the Application of Warm-Closed Forging of Automative Steering Unit Yoke (자동차 조향장치 부품 요크의 온간 밀폐 단조 적용을 위한 금형 응력 저감 설계 및 온간 단조품의 기계적 특성 분석)

  • Seong, S.G.;Kim, K.H.;Lee, Y.S.;Lee, S.Y.;Yoon, E.Y.
    • Transactions of Materials Processing
    • /
    • v.31 no.2
    • /
    • pp.51-56
    • /
    • 2022
  • In this study, finite element analyses were performed by applying a stress ring and split die design to relieve the tensile stress acting on the die due to high surface pressure during warm-closed forging. The applied material was a yield-ratio-control-steel (YRCS). It was used without quenching or tempering after forging. In the case of stress rings design, the number of stress rings and the tolerance for shrink fit were different. Vertical and horizontal splits were applied for insert die split design. Case 5 die with three stress rings, 0.2 % shrink fit tolerance, and vertical split was selected as an effective die design for tensile stress reduction. Based on die stress reduction analyses, Case 5 die for warm-closed forging was produced and smooth forgeability was secured, making it possible to manufacture forging product of yoke with the required geometry. In addition, controlled cooling using warm forging heat was applied to secure mechanical properties of yokes. When oil cooling was used for direct controlled cooling after warm-closed forging, a relatively uniform Rockwell hardness distribution and high mechanical properties could be obtained.

Antioxidant Activity of Ethanolic Extract from Germinated Giant Embryonic Rices (발아 거대배아미 에탄올 추출물의 항산화 활성)

  • Kang, Mi-Young;Kim, Sul-Yi;Koh, Hee-Jong;Nam, Seok-Hyun
    • Applied Biological Chemistry
    • /
    • v.47 no.3
    • /
    • pp.293-299
    • /
    • 2004
  • Antioxidant activity of ethanolic extract of two giant embryonic rices, Nampung giant embryonic rice and Hwachung giant embryonic rice, were investigated mainly focusing on their ability to inhibit lipid peroxidation and scavenge reactive oxygen species in comparison with those of general rice. The results showed that germination process increased reducing power, inhibitory activity on lipid peroxidation and scavenging ability either on superoxide or hydroxyl radicals. Among the cultivars tested, increase in antioxidative action was found to be most prominent for Hwachung giant embryonic rice cultivar. For scavenging of superoxide radicals, the extract from Nampung giant embryonic rice has the most potent activity, however, increasing rate of scavenging activity by germination process was also found to be the greatest for Hwachung giant embryonic rice. We found that the scavenging mechanism for superoxide radicals was attributed to the direct scavenging of the radicals. The scavenging of hydroxyl radicals, the most toxic oxygen radical to biological system, by the rice extracts were also examined, and the results showed that either overall activity or the increasing rate of the activity to scavenge hydroxyl radicals by germination process was the greatest for Hwachung giant embryonic rice. Moreover, the results suggested that the scavenging action to hydroxyl radicals might be mediated by direct quenching of the radicals, not by chelating $Fe^{2+}$. Further studies showed that the antioxidant action of the rice extracts tested in vitro was also operative for suppressing ROS production induced in TPA-stimulated HL-60 cells.