• Title/Summary/Keyword: Direct emission

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Fabrication of Beta-phase Poly(9,9-dioctylfluorene) Nanowire Arrays for Polymer Light-Emitting Diode Using Direct Printing Method

  • Baek, Jang-Mi;Lee, Gi-Seok;Seong, Myeong-Mo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.560-560
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    • 2012
  • We report a one-step fabrication method of Poly(9,9-dioctylfluorene) (PFO) nanowire array with pronounced ${\beta}$-Phase. We use liquid-bridge-mediated nanotransfer molding (LB-nTM) which is a new direct nano-patterning method based on the direct transfer of various materials from a mold to a substrate via liquid layer. The formation of the ${\beta}$-phase morphology in the resulting PFO nanowire array was evidenced by the presence of an absorption peak at 435nm. With the collection polarizer oriented parallel to the wire long axis, the PL emission was most intense and an emission dichroic ratio, DRE, of 3.7 was determined. The nanowire array have been investigated by scanning electron microscopy (SEM). Also, we simply fabricated structure of device of ITO/PFO nanowire arrays/Al and the electroluminescence spectra were recorded at various applied voltage.

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Fabrication of ZnO Nanowires by Direct Melt Oxidation of Al-Zn Alloy (Al-Zn 합금의 직접용융산화법을 이용한 ZnO 나노와이어의 제작)

  • Lee, Geun-Hyoung;Kim, Il-Soo;Shin, Byoung-Chul;Lee, Won-Jae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.11
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    • pp.995-999
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    • 2008
  • ZnO nanowires with tetrapod shape were formed on the surface of the sample by direct melt oxidation of Al-Zn alloy at $1000^{\circ}C$ in air. X-ray diffraction (XRD) pattern revealed that the ZnO nanowires had wurtzite structure of hexagonal phase. Any other element except Zn and O was not detected in energy dispersive X-ray spectrum. The c- and a-axis lattice constants estimated from the XRD pattern were 0.520 and 0.325 nm, respectively. These are in well accordance with those of bulk ZnO single crystal, indicating high quality crystallinity. The green light emission at a wavelength of 510 nm was observed from the nanowires at room temperature, which was ascribed to high density of oxygen vacancies in nanowires.

A Basic Experimental Study on Potential Operating Range in Gasoline Direct-Injection Compression Ignition (GDICI) Engine (가솔린 직접분사식 압축착화 엔진의 가능한 운전영역에 관한 기초실험 연구)

  • Cha, Junepyo;Yoon, Sungjun;Lee, Seokhwon;Park, Sungwook
    • 한국연소학회:학술대회논문집
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    • 2013.06a
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    • pp.33-35
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    • 2013
  • The present work is an experimental investigation on potential operating range using directly injected gasoline fuel in a single-cylinder compression ignition (CI) engine. The objectives of present study were to apply auto-ignited combustion to gasoline fuel and to evaluate potential operating range. In order to auto-ignite gasoline fuel in CI engine, the fuel direct-injection system and the intake air system were modified that a flow rate and temperature of intake air were regulated. The heat-release rate (HRR), net indicated mean effective pressure (IMEP), start of combustion (SOC), and combustion duration were derived from in-cylinder pressure data in a test engine, which has 373.33cc displacement volume and 17.8 compression ratio. The exhaust emission characteristics were obtained emission gas analyzer and smoke meter on the exhaust line system.

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A Study of CO2 Emission Characteristics on the Vehicle with LPG Direct Injection and Mild Hybrid System (LPG 직분사 엔진과 마일드 하이브리드 시스템 적용 차량의 CO2배출 특성 연구)

  • An, Young kuk;Byeonggyu, Yang;Jinil, Park
    • Journal of ILASS-Korea
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    • v.27 no.4
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    • pp.211-218
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    • 2022
  • Recent vehicle regulations have become increasingly stringent in order to reduce greenhouse gases. Then not only movement to replace internal combustion engine vehicles with hybrid vehicles, but also studies of replacing internal combustion engine fuels with low-pollution fuels are increasing. In this study, the characteristics of a vehicle with LPG fuel engine and mild hybrid system is investigated. To avoid shortage of maximum power on LPG engine, a direct injection system of LPG is applied. In addition, P0 mild hybrid system is adopted to enhence the efficiency of the vehicle. The vehicle model is developed in order to predict fuel economy and CO2 emission of LPDi MHEV.

Combustion Characteristics of Gasoline HCCI Engine with DME as an Ignition Promoter (DME를 착화촉진제로 사용한 가솔린 예혼합 압축 착화 엔진의 연소 특성)

  • Yeom, Ki-Tae;Jang, Jin-Young;Bae, Choong-Sik
    • Transactions of the Korean Society of Automotive Engineers
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    • v.14 no.3
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    • pp.178-185
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    • 2006
  • This paper investigates the steady-state combustion characteristics of the Homogeneous charge compression ignition(HCCI) engine with variable valve timing(VVT) and dimethyl ether(DME) direct injection, to find out its benefits in exhaust gas emissions. HCCI combustion is an attractive way to lower carbon dioxide($CO_2$), nitrogen oxides(NOx) emission and to allow higher fuel conversion efficiency. However, HCCI engine has inherent problem of narrow operating range at high load due to high in-cylinder peak pressure and consequent noise. To overcome this problem, the control of combustion start and heat release rate is required. It is difficult to control the start of combustion because HCCI combustion phase is closely linked to chemical reaction during a compression stroke. The combination of VVT and DME direct injection was chosen as the most promising strategy to control the HCCI combustion phase in this study. Regular gasoline was injected at intake port as main fuel, while small amount of DME was also injected directly into the cylinder as an ignition promoter for the control of ignition timing. Different intake valve timings were tested for combustion phase control. Regular gasoline was tested for HCCI operation and emission characteristics with various engine conditions. With HCCI operation, ignition delay and rapid burning angle were successfully controlled by the amount of internal EGR that was determined with VVT. For best IMEP and low HC emission, DME should be injected during early compression stroke. IMEP was mainly affected by the DME injection timing, and quantities of fuel DME and gasoline. HC emission was mainly affected by both the amount of gasoline and the DME injection timing. NOx emission was lower than conventional SI engine at gasoline lean region. However, NOx emission was similar to that in the conventional SI engine at gasoline rich region. CO emission was affected by the amount of gasoline and DME.

Spinning Multi Walled Carbon Nanotubes and Flexible Transparent Sheet Film

  • Jang, Hun-Sik;Lee, Seok-Cheol;Kim, Ho-Jong;Jeong, In-Hyeon;Park, Jong-Seo;Nam, Seung-Hun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.200-200
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    • 2012
  • We investigated a flexible transparent film using the spinning multi-walled carbon nanotubes (MWCNTs). Spin-capable MWCNTs on iron catalyzed on a SiO2 wafer was grown by chemical vapor deposition, which was performed at $780^{\circ}C$ using C2H2 and H2 gas. The average diameter and length of MWCNTs grown on the substrate were ~15 nm and $250{\sim}300{\mu}m$, respectively. The MWCNT sheets were produced by continuously pulling out from well-aligned MWCNTs on a substrate. The MWCNT sheet films were produced simply by direct coating on the flexible film or grass. The thickness of sheet film was remarkably decreased by alcohol spraying on the surface of sheet. The alcohol splay increased transmittance and decreased electrical resistance of MWCNT sheet films. Single and double sheets were produced with sheet resistance of ~699 and ${\sim}349{\Omega}/sq$, respectively, transmittance of 81~85 % and 67~72%, respectively. The MWCNT sheet films were heated through the application of direct current power. The flexible transparent heaters showed a rapid thermal response and uniform distribution of temperature. In addition, MWCNT yarns were prepared by spinning a bundle of MWCNTs from vertically super-aligned MWCNTs on a substrate, and field emission from the tip and side of the yarns was induced in a scanning electron microscope. We found that the field emission behavior from the tip of the yarn was better than the field emission from the side. The field emission turn-on voltages from the tip and side of MWCNT yarns were 1.6 and $1.7V/{\mu}m$, respectively, after the yarn was subjected to an aging process. Both the configuration of the tip end and the body of the yarn were changed remarkably during the field emission. We also performed the field emission of the sheet films. The sheet films showed the turn on voltage of ${\sim}1.45V/{\mu}m$ during the field emission.

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Er(III)-chelated Prototype Complexes Based on Benzoate and Pentafluorobenzoate Ligands : Synthesis and Key Parameters for Near IR Emission Enhancement

  • Roh, Soo-Gyun;Oh, Jae-Buem;Nah, Min-Kook;Baek, Nam-Seob;Lee, Young-Il;Kim, Hwan-Kyu
    • Bulletin of the Korean Chemical Society
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    • v.25 no.10
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    • pp.1503-1507
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    • 2004
  • New synthetic methodology of the saturated and unsaturated Er(III)-chelated prototype complexes based on benzoate and pentafluorobenzoate ligands was developed through ligand-exchange reaction. The saturated 8-coordinated Er(III) complexes exhibit stronger near-IR emission than those of the unsaturated 6-coordinated Er(III) complexes, obtained from the direct photoexcitation of Er ions with 488 nm. Three $H_2O$ molecules coordinated in the unsaturated 6-coordinated complexes seriously quenched the near IR emission by the harmonic vibration relaxation decay of O-H bonds. Also, the stronger emission of the Er(III) complexes was obtained by the indirect photoexcitation of ligands than by the direct photoexcitation of the Er(III) ions, due to the energy transfer between the excited ligand and the erbium ion. Furthermore, the saturated Er(III)-chelated complex with C-F bonds shows much stronger near IR emission than that of the saturated Er(III)-chelated complex with C-H bonds. It is attributed to the influence of C-F bonds on near IR emission.

An Experimental Study on the Characteristics of Combustion and Emission in a Gasoline Direct Injection Type HCCI Engine by Controlling Mixture Formation (가솔린 직접분사식 HCCI 엔진의 혼합기 제어에 의한 연소 및 배기 특성에 관한 실험적 연구)

  • 김형민;류재덕;이기형
    • Transactions of the Korean Society of Automotive Engineers
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    • v.12 no.4
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    • pp.24-30
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    • 2004
  • As the environmental pollution becomes serious global problem, the regulation of emission exhausted from automobiles is strengthened. Therefore, it is very important to know how to reduce the NOx and PM simultaneously in diesel engines, which has lot of merits such as high thermal efficiency, low fuel consumption and durability. By this reason, the new concept called as Homogeneous Charge Compression Ignition(HCCI) engines are spotlighted because this concept reduced NOx and P.M. simultaneously. However, there is trade off between output and NOx in a HCCI engine. In this study, output and emission characteristics for a gasoline direct injection type HCCI engine were investigated to clarify the effects of intake air temperature, injection time and mixture formation. From these experiments, we found that the smoke was not produced when the fuel was injected earlier than BTDC 90$^{\circ}$. In addition, the output was increased because of delay of ignition time and NOx emission was decreased because of homogeneous charge of first injection in case of split injection.

The Application of Oxygenated Component(Butyl Ether) and EGR in a DI Diesel Engine (직접분사식 디젤기관에서 함산소성분(Butyl Ether) 및 EGR의 적용)

  • Choi, Seung-Hun;Oh, Young-Taig
    • Transactions of the Korean Society of Automotive Engineers
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    • v.16 no.5
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    • pp.134-139
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    • 2008
  • This research investigated variations of the engine performance and the exhaust emission characteristic of a direct injection diesel engine by fueling a commercial diesel fuel, which was blended with the di-ether group (butyl-ether: BE). The smoke emission reduced to 26% from the diesel engine with the blending fuel (diesel fuel 80 vol-% + BE 20 vol-%)at the full engine load of 2500 rpm compared to it with the diesel fuel only. The power, torque and brake specific energy consumption of the diesel engine showed very slight differences. The NOx emission from the diesel engine, however, with the blended fuel was higher than with the commercial diesel fuel only. By applying EGR method, as a counter plan of the NOx reduction, this research obtained reductions of the smoke and NOx emission at the same time from the diesel engine with the BE blended diesel fuel.

Emission Characteristics of Fluorescent OLED with Alternating Current Power Source Driving Method (교류전원 구동방식에 의한 형광 OLED의 발광 특성)

  • Seo, Jung-Hyun;Kim, Ji-Hyun;Ju, Sung-Hoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.2
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    • pp.104-109
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    • 2014
  • To operate organic light emitting device (OLED) with alternating current (AC) power source without AC/DC(direct current) converter, we fabricated the fluorescent OLED and measured the emission characteristics with AC and DC. The OLED operated by AC showed higher maximum current efficiency of 8.2 cd/A and maximum power efficiency of 8.3 lm/W. But current efficiency and power efficiency of AC driven OLED showed worse than DC driven OLED at high voltage above 10 V. This result can be explained by the peak voltage of AC was $\sqrt{2}$ times than DC, In case of low driving voltage the emission characteristics were improved by the peak voltage of AC, but in case of high driving voltage the emission efficiencies were decreased by the roll off phenomena. Finally, serial OLED arrays using twelve OLEDs driven by AC 110 V showed average voltage of 9.17 V, voltage uniformity of 99.0%, average luminance of $1,175cd/m^2$, luminance uniformity of 94.4%.