• Title/Summary/Keyword: Direct dye

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A study on the power conversion system using Dye-Sensitized Solar cell (DSC를 활용한 상용전력변환 시스템에 관한 연구)

  • Kim, Jin-Young;Park, Sung-June;Park, Hae-Young;Kim, Woo-Sung;Kim, Hwi-Young;Kim, Hee-Je
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.06a
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    • pp.195-198
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    • 2006
  • The technology of Solar Power conversion System is defined as a solar cell that changes the sol ar energy into the direct electric energy, power conversion and control technology that convert the dc power into ac power The solar cell module, power conversion, and a control part in component parts consisting a solar power conversion system have influence on its performance. The roles of power conversion and a control part supply the direct current generated by solar cell module for a load with high efficiency as conveniently as possible in this study, the power conversion systen that can generate solar power using DSC module was developed and its characteristics was experimented. The characteristics of the DSC power conversion system including MOSFET and DSP micro processor, high speed devices, was simulated using Psim. According to the results, converter and inverter was manufactured in detail and the performance characteristics were studied.

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Effects of Ethanol and Phenobarbital on Hemoglobin Adducts Formation in Rats Exposed to Direct Black 38 (Direct Black 38 염료를 흰쥐에 투여 시 형성되는 헤모글로빈 부가체에 에탄올과 Phenobarbital이 미치는 영향)

  • Kim, Chi-Nyon;Lee, Se-Hoon;Roh, Jae-Hoon
    • Journal of Preventive Medicine and Public Health
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    • v.35 no.3
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    • pp.229-235
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    • 2002
  • Objectives : To evaluate the effects on the formation of benzidine-hemoglobin, and benzidine metabolite-hemoglobin adducts, caused by pretreatment with the known xenobiotic metabolism effectors, ethanol and phenobarbital, in rats administered Direct Black 38 dye. Methods : The experimental rats were divided into three groups: a control group, an ethanol group and a phenobarbital group. Rats were pretreated with ethanol (1g/kg) or phenobarbital (80mg/kg) 24 hours prior to the oral administration of Direct Black 38 (0.5mmol/kg), with the control group being administered the same amount of distilled water. Blood samples were obtained from the vena cava of 5 rats from each group prior to, and at 30 min, 3h, 5h, 9h, 12h, 24h, 48h, 72h, 96h, and 144h following the oral administration of Direct Black 38. Directly after sampling the blood was separated into hemoglobin and plasma, with the adducts being converted into aromatic amines by basic hydrolysis. Hydrolyzed benzidiene, monoacetylbenzidine and 4-aminobiphenyl were analyzed by reverse-phase liquid chromatography with an electrochemical detector, The quantitative amount of the metabolites was expressed by the hemoglobin binding index (HBI). Results : In the ethanol group, benzidine-, monoacetylbenzidine-, and 4-aminobiphenyl-HBI were increased to a greater extent than those in the control group. These results were attributed to the ethanol inducing N-hydrgxylation, which is related to the formation of the hemoglobin adduct, In the phenobarbital group, all the HBIs, with the exception of the benzidine-HBI, were increased to a greater extent than those of the control group. These results were attributed to the phenobarbital inducing N-hydroxylation related to the formation of the hemoglobin adduct. The N-acetylation ratio was only increased with the phenobarbital pretreatment due to the lower benzidine-HBI of the phenobarbital group compared to these of the control and ethanol groups. The N-acetylation ratios for all groups were higher than f for the duration of the experimental period. Although the azo reduction was unaffected by the ethanol, it was inhibited by the phenobarbital, The ratio of the benzidine-HBI in the phenobarbital group was lower than those of the ethanol the control groups for the entire experiment. Conclusion : Our results indicate that both ethanol and phenobarbital increase the formation of adducts by the induction of N-hydroxylation, but also induced N-acetylation. Phenobarbital decreased the formation of benzidine-HBI due to the decrease of the azo reduction. These results suggest that the effects or ethanol and phenobarbital need to be considered in the biochemical monitoring of Direct Black 38.

Bioscouring of 100% Cotton Fabric with Alkaline Pectinase (알칼리 펙티나제를 이용한 면직물의 효소정련)

  • Choe Eon Kyung;Park Jong Ho;Kim Sung Dong
    • Textile Coloration and Finishing
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    • v.17 no.1
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    • pp.14-19
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    • 2005
  • Study on the use of enzymes for textile wet processing has been very active. The exploratory research conducted herein is related to the bioscouring process for cotton fabric. The optimum concentration of alkaline pectinase(BioPrep) was in the range of 0.05~0.2 g/l, the proper treatment time was 30~60 minutes, the appropriate treatment temperature was $60^{\circ}C$ for both the batch method and the padding method. The simultaneous desizing/bioscouring by padding method did not give water absorbency as good as the bioscouring after desizing. Color of fabrics which were bioscoured and dyed with direct dyes and a reactive dye was just a little darker than that of NaOH scoured one. K/S and Lab values of the bioscoured fabrics, regardless of the degree of water absorbency, were quite similar to each other.

Development of microporous activated carbon using a polymer blend technique and its behavior towards methylene blue adsorption

  • Manocha, S.;Brahmbhatt, Amit
    • Carbon letters
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    • v.12 no.2
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    • pp.85-89
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    • 2011
  • Coloured wastewater is released as a direct result of the production of dyes as well as from various other chemical industries. Many dyes and their breakdown products may be toxic for living organisms. Activated carbon is one of the best materials for removal of dyes from aqueous solutions. The present study describes the adsorption behaviour of methylene blue dye on three microporous activated carbons, where two samples (AC-1 and AC-2) were prepared by a polymer blend technique and the other is a microporous activated carbon (ARY-3) sample from viscose rayon yarn prepared by chemical-physical activation. The effects of contact time and activated carbon dosage on decolourisation capacity have been studied. The results show that activated carbon having mixed microporosity and mesoporosity show tremendous decolourisation capacity for methylene blue. In addition, the activated carbon in the powder form prepared by the polymer blend technique shows better decolourisation capacity for methylene blue than the activated rayon yarn sample.

Highly Laminated Electrospun ZnO Nanofibrous Film on the Transparent Conducting Oxide for Photovoltaic Device

  • Kim, Jinsoo;Yoon, Sanghoon;Yoo, Jung-Keun;Kim, Jongsoon;Kim, Haegyeom;Kang, Kisuk
    • Journal of Electrochemical Science and Technology
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    • v.3 no.2
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    • pp.68-71
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    • 2012
  • The electrospinning technique is a revolutionary template-catalyst-free method that can generate 1D nanostructure with the tunability and the potential for the mass production. This approach received a great deal of attention due to its ability to give direct pathways for electrical current and has been utilized in various electronic applications. However, the delamination of inorganic electrospun film has prevented the intense utilization due to the thermal expansion/contraction during the calcination. In this study, we propose an electrical grounding method for transparent conducting oxide and electrospun nanowires to enhance the adhesion after the calcination. Then, we examined the potential of the technique on ZnO based dye-sensitized solar cells.

Detection of Damage of Rd6G Film Using Surface Second-Harmonic Generation (표면 제2고조파 발생을 이용한 색소 Rd6G박막층의 손상 분석)

  • 유대혁;고춘수;임용식;이재형;장준성
    • Korean Journal of Optics and Photonics
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    • v.5 no.2
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    • pp.272-277
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    • 1994
  • The damage of a thin film of Rd6G dye was probed by Surface Second-Harmonic Generation(SSHG) method. A portion of the Rd6G thin film on glass substrate was damaged by 532 nm laser beam, and the damage was probed by detecting intensity variation of SSHG. The result was confirmed through direct observation with optical microscope.oscope.

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Development of Metal Complex Dyestuffs with High Fastness and High Adsorption (고견뢰도 및 고흡진율 특성의 금속 착염 염료의 개발)

  • Kim, Woon-Tai;Nam, Won-Woo;Sohn, Byoung-Chung
    • Journal of the Korean Applied Science and Technology
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    • v.12 no.2
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    • pp.115-120
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    • 1995
  • Diazotization of 2-Amino-5-nitrophenol was Synthesized by the direct diazotization method. The diazonium salts are usually stabilized in the from of double salts. The double salts of zinc chloride are the Commonest, and the double salt method is Specially applicable to the yield-up of coupling. The azo dye(2-naphthol-1-(2'-diazo-5'-nitrophenol)) is Converted into a chromium Complex by heating($100^{\circ}C$) with chromic formate, and DMF. The removal of inorganic salts from dyestuffs was performed in DMF solvent. This effect was more pronounced. From these results, It was obtained to liquid dyestuffs of metal complex with High fastness and high adsorption.

The Dyeability of Cellulosic Fiber treated with N-methylmorpholine-N-oxide (N-Methylmorpholine-N-Oxide 처리에 의한 셀룰로오스 직물의 염색성)

  • 조규민;강건우;임용진;김미경;김태경;이혜정
    • Textile Coloration and Finishing
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    • v.15 no.5
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    • pp.333-339
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    • 2003
  • The cotton fabrics treated with 50% N-methylmorpholine-N-oxide(50% NMMO) and 75% N-methylmorpholine-N-oxide(75 % NMMO) aqueous solution were examined in terms of the dyeability comparing with those of regular cotton fabrics. The dyeing rate was increased with the increase of the concentration of NMMO in the treatment aqueous solution. The NMMO treatment increased the diffusion coefficients and decreased the activation energy of direct dye onto cotton fabrics. This means that the NMMO could change the micro-structure of cotton fabrics.

Studies on the Synthesis of Bisphenol Sulfonate Polymers and Their Staining Resist Effect in the Dyeing of Nylon/cotton Union (I) (Bisphenol sulfone산계 고분자의 합성 및 나일론 오염방지성에 관한 연구 (I))

  • 최영주;송승종;윤남식
    • Textile Coloration and Finishing
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    • v.12 no.4
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    • pp.256-263
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    • 2000
  • A series of poly[3-methylene-3'-methylenesodiumbisulfite-bis(4-hydroxyphenyl) sulfone] (PMSBPS) was synthesized by the reaction of bis-(4-hydroxyphenyl)sulfone(BPS), formalin, and formaldehyde sodium bisulfite(FSB), and their effect on the staining of direct dye on nylon in the dyeing of nylon/cotton union fabric was investigated. PMSBPSes have good staining resist effect on nylon in the dyeing of nylon/cotton union. Prolonged reacting time between BPS and formalin is effective in improving the staining resist of final PMSBPS. Too many sulfonic acid groups than necessary in the PMSBPS increase the staining of nylon, presumably by increasing the solubility of PMSBPS. Staining resist effect of PMSBPS was evident in the measurement of color diffence of dyed goods.

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Dyeability of Cotton Fabrics Treated with Liquid Ammonia - Color strength of the dyeings with low-temperature and high-temperature reactive dyes - (액체암모니아 처리 면직물의 염색성 - 저온형과 고온형 반응성 염료에 의한 염색물의 색상강도 -)

  • 전성기;이창수;임용진;김태경
    • Textile Coloration and Finishing
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    • v.16 no.2
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    • pp.1-7
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    • 2004
  • The dyeability of cotton fabrics treated with liquid ammonia was investigated using low-temperature and high-temperature reactive dyes. From the results of dyeing rates of direct dye, the inversion time was shown at 600 hours at $40^{\circ}C$, and however it was shown at 10 minutes at $80^{\circ}C$. This was applied to reactive dyeings. In the low-temperature reactive dyes, the color strength of the fabrics treated with liquid ammonia was lower than that of mercerized fabrics. By contrast, in the high-temperature reactive dyes, the color strength of the fabrics treated with liquid ammonia was higher than that of mercerized one.