• Title/Summary/Keyword: Direct Modification

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Modification of Nafion Membranes for Reduction of Methanol Transport Rate

  • Kang, Dong-Hoon;Kim, Duk-Joon
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.127-128
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    • 2006
  • Nafion/basic polymer composite membranes were prepared to reduce the methanol crossover for the application of direct methanol fuel cell. The thermal and mechanical properties increased with increasing basic polymer contents due to the formation of complex via acid/basic interaction. The water uptake, proton conductivity, methanol permeability decreased with increasing basic polymer concentration by reduction of acidity associated with the formation of acid/base complex. The molecular effect on those properties was not considerable.

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Failure Mechanism of Headed Reinforcement including Bond Failure (부착파괴를 고려한 Headed Reinforcement의 파괴메카니즘)

  • 박종욱;홍성걸
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.11a
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    • pp.234-237
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    • 2003
  • Previous researches about headed reinforcement have not been concerned about bond failure which is quite important is some cases. In this paper, failure mechanism including bond failure was presented in order to define the contribution of bond stress at the time failure occurs. Examined with design codes and test results, it is proved to be rational to consider the contribution of bond stress in determining the ultimate pull-out capacity of headed reinforcement. Direct adaptation of design code for anchor bolt without modification for the contribution of bond stress will lead to underestimate the capacity of headed reinforcement.

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Angle-resolved photoemission spectrscopy for chalcogenide and oxide heterostructures (칼코겐화물과 산화물 이종구조의 각도분해능 광전자분광 연구)

  • Chang, Young Jun
    • Vacuum Magazine
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    • v.5 no.2
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    • pp.10-17
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    • 2018
  • Chalcogenide and oxide heterostructures have been studied as a next-generation electronic materials, due to their interesting electronic properties, such as direct bandgap semiconductor, ferroelectricity, ferromagnetism, superconductivity, charge-density waves, and metal-insulator transition, and their modification near heterointerfaces, so called, electronic reconstruction. An angle-resolved photoemission spectroscopy (ARPES) is a powerful technique to unveil such novel electronic phases in detail, especially combined with high quality thin film preparation methods, such as, molecular beam epitaxy and pulsed laser deposition. In this article, the recent ARPES results in chalcogenide and oxide thin films will be introduced.

IV-TAP : Integrated Valve Train system Analysis Program (IV-TAP : 밸브트레인 통합 해석 프로그램)

  • 김지영;조명래;신흥주;한동철
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2000.06a
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    • pp.258-262
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    • 2000
  • This paper reports on the development of the analysis program of the valve train system, IV-TAP. It is essential to verify the stability of the design and to improve the performance of the system. In order to do that effi챠ently, it is required that integrated and interactive simulation analysis program. IV-TAP is developed in the base of the object-oriented, capsulation, modulization, OLE(objected linking and embedding) and variational design theory. So it contain the expandability and flexibility of the structure. In additon to that, it is programed to make the convenient user interface by using the visualization programming. It can support the modification of the valve element as well as the development of the valve system in the beginning. It is expected to reduce the money and effort for design the valve train system.

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Direct Duty-ratio Modulated Fault-tolerant Strategy for Matrix Converter-fed Motor Drives

  • Li, Yulong;Choi, Nam-Sup;Han, Byung-Moon;Nho, Eui-Cheol
    • Journal of Power Electronics
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    • v.12 no.1
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    • pp.24-32
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    • 2012
  • Direct duty-ratio PWM schemes for continuous fault tolerant operation of matrix converter-fed motor drives are presented. The proposed method features simple modular modulation structure based on per output phase concept, which requires no additional modification on the normal modulation schemes for fault-tolerant applications. Realizations of fault-tolerant strategy applied to different system configurations are also treated to enhance the system flexibility. The proposed method can be effectively applied to treat the motor open phase fault and converter switching device failure. Simulation and experimental results show the feasibility and validation of the proposed strategies.

Surface Characteristics of Direct Fluorinated Single-walled Carbon Nanotubes

  • Seo, Min-Kang;Park, Soo-Jin
    • Bulletin of the Korean Chemical Society
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    • v.30 no.9
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    • pp.2071-2076
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    • 2009
  • The single-walled carbon nanotubes (SWCNTs) produced by chemical vapor deposition (CVD) were directly fluorinated with fluorine ($F_2$) gas in a temperature range 20 ~ 400 ${^{\circ}C}$. The surface properties and morphology of the SWCNTs were investigated in terms of fluorination temperature. As a result, Raman spectra showed a pair of bands at 1340 and 1590 $cm^{-1}$ peculiar to disordered $sp^2$-carbons. These results indicated that C-F bonds were formed on the rear surfaces of the nanotubes by fluorination, while the external surfaces as well as the layers between the internal and external surfaces retained their $sp^2$-hybridization. XPS analysis exhibited that fluorine atoms were bonded to carbon atoms on internal surfaces (rear surfaces) of the nanotubes and the amount of fluorine attached on the nanotubes was increased with increasing the fluorination temperature. Consequently, the direct fluorination of carbon nanotubes led to functionalization and modification of pristine nanotubes with respect to surface and morphological properties.

Advanced Powder Processing Techniques of Ti Alloy Powders for Medical and Aerospace Applications

  • Miura, Hideshi
    • Journal of Powder Materials
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    • v.20 no.5
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    • pp.323-331
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    • 2013
  • In this paper, two kinds of advanced powder processing techniques Metal Injection Molding (MIM) and Direct Laser Forming (DLF) are introduced to fabricate complex shaped Ti alloy parts which are widely used for medical and aerospace applications. The MIM process is used to strengthen Ti-6Al-4V alloy compacts by addition of fine Mo, Fe or Cr powders. Enhanced tensile strength of 1030 MPa with 15.1% elongation was obtained by an addition of 4 mass%Cr because of the microstructural modification and also the solution strengthening in beta phase. However, their fatigue strength was lower compared to wrought materials, but was improved by HIP. Subsequently, the effect of feeding layer height (FLH) on the characteristics of the DLF compacts was investigated. In the case of 100 ${\mu}m$ FLH, surface roughness was improved and nearly full density (99.8%) was obtained. Also, tensile strength of 1080 MPa was obtained, which is higher than the ASTM value.

Spectroscopic Studies of TP6F PI Switched by Hole-Injection

  • Lee, Gyeong-Jae;Im, Gyu-Uk;Kim, Dong-Min;Lee, Mun-Ho;Gang, Tae-Hui;Jeong, Seok-Min
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.297-298
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    • 2011
  • Metal/poly (4,4'-aminotriphen-ylene hexafluoroisopropylidenediphthalimide) (TP6F PI)/metal structure exhibited an electrically volatile phase transition with high (OFF) or low (ON) resistive states when voltage between electrodes swept. Here, we demonstrate a noble set-up in which holes are injected by photoelectron emission process during the voltage sweep instead of direct charge carrier injection via metal electrode, which enables direct investigation into changed electronic structures of TP6F PI both in ON and OFF states using photoemission spectroscopy methods. In the I-V measurement, TP6F PI shows a non-volatile behavior. In spectroscopic results, this non-volatile behavior is leaded from the structural modification of the O=C double bond in phthalimide of TP6F PI by hole injection.

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Bloating Mechanism for Artificial Light Weight Aggregate of Surface Modification with Coal ash

  • Lee, Ki Gang
    • Journal of the Korean Ceramic Society
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    • v.52 no.2
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    • pp.159-164
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    • 2015
  • We manufacture artificial lightweight aggregates (ALWAs) using bottom-ash as the primary raw material. We coat the ALWA surfaces with low-melting point materials in order to enable them to bloat, which is essential to reduce the bulk density of the aggregate. Then, we sinter the prepared aggregates at 1000, 1100, and $1200^{\circ}C$ using either the direct or two-step firing schedules. Finally, we evaluate the properties of the fired samples through analyzing their bulk density, water absorption, and microstructure. The surface-modified samples result in a reduction of their bulk density by $0.3{\sim}0.4g/cm^3$ regardless of the firing method used. Based on these results, we conclude that this approach could provide a viable method for the mass-production of ALWAs from industrial waste such as bottom-ash.