• 제목/요약/키워드: Dipole Model

검색결과 233건 처리시간 0.023초

고속액체 크로마토그래피에서 PAH분자의 구조에 따른 용리시간 예측 (Prediction of Retention Time for PAH Molecule in HPLC)

  • 김영구
    • 대한화학회지
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    • 제44권2호
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    • pp.102-108
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    • 2000
  • 고속액체크로마트그래피에서 RAH분자들이 상대적 용리시간을 다변량선형회귀분석과 인공신경망분석방법을 사용하여 학습시킨 후, 시험 세트의 상대적 용리시간을 예측하였다. PAH의 QSRR에서 주요한 설명인자는 분자연결지수($^1X_v,\;^2X_v$),길이와 폭의 비율(L/B) 및 분자 쌍극자 모멘트(D)이었다, 슬롯 모델과 관계깊은 L/B은 인공신경망분석방법에서는 적절한 설명인자로 작용하나, 다변량회귀분석에서는 그러하지 못하다. 시험세트에서 용리시간 예측도를 나타내주는 분산은 각각 인공신경망분석방법에서 0.0099, 다변량회귀분석방법에서 0.0114이었다. 인공신경망분석방법이 다변량회귀분석보다 더 좋은 결과를 보여준다.

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Synthesis, Spectral, Characterization, DFT and Biological Studies of New 3-[(3-Chlorophenyl)-hydrazono]-pentane-2,4-dione Metal Complexes

  • Sadeek, Sadeek A.;Zordok, Wael A.;El-Farargy, Ahmed F.;El-Desoky, Sameh I.
    • 대한화학회지
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    • 제58권2호
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    • pp.169-178
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    • 2014
  • A new series of metal complexes of V(IV), Pd(II), Pt(IV), Ce(IV) and U(VI) with 3-[(3-chlorophenyl)-hydrazono]-pentane-2,4-dione (Cphpd) were synthesized and characterized by elemental analysis, molar conductivity, magnetic moment measurements, UV-vis, FT-IR and $^1H$ NMR as well as TG-DTG techniques. The data indicated that the Cphpd acts as a bidentate ligand through the hydrazono nitrogen and one keto oxygen. The kinetic parameters have been evaluated by using Coats Redfern (CR) and Horowitz-Metzeger (HM) methods. The thermodynamic data reflected the thermal stability for all complexes. The calculated bond length and the bond stretching force constant, F(U=O), values for $UO_2$ bond are $0.775{\AA}$ and $286.95Nm^{-1}$. The bond lengths, bond angles, dipole moment and the lowest energy model structure of the complexes have been determined with DFT calculations. The antimicrobial activity of the synthesized ligand and its complexes were screened.

방파제를 고려한 초대형 부유식 해양구조물의 응답 (Hydroelastic Responses for a Very Large Floating Structure with a Breakwater)

  • 이호영;신현경;임춘규;김외현;강점문;윤명철
    • 대한조선학회논문집
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    • 제38권2호
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    • pp.26-32
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    • 2001
  • 본 논문은 고정식 방파제를 포함한 초대형 부유식 해상공항의 파도 중에서 유탄성 응답을 계산하는 방법을 제시하였다. 방파제 효과를 고려한 방사문제와 산란문제를 해석하기 위하여 소오스-다이폴 분포법을 사용하였고, 구조물의 응답은 자유-자유 보의 고유 모드함수에 의한 모드 해석법을 사용하여 계산하였다. 계산 모델로 길이가 1000m의 해상공항 구조물을 도입하였고, 방파제의 효과를 살펴보기 위해 입사파의 주기, 강성, 방파제와 해상공항 사이의 간격을 변화시키면서 수직 응답 및 모우멘트 등을 계산하였다.

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전두엽 뇌전도 전극 배치의 제안 및 JADE를 이용한 잡음제거 (Proposition of the EEG Electrode Arrangement at a Frontal Lobe and Rejection of Noise Using a JADE)

  • 박정제;이윤정;김필운;구성모;조진호;김명남
    • 대한의용생체공학회:의공학회지
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    • 제25권3호
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    • pp.227-233
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    • 2004
  • 본 논문에서는 뇌전도 바이오피드백 시스템을 위한 4채널 전두엽 전극 배치 및 JADE를 사용한 잡음 제거 방법을 제안하였다. 망막-각막 쌍극자 모델을 기반하여 4채널 전두엽 전극 배치를 제안하였으며, 이 배치에 의해서 얻은 신호에 대해서 JADE를 적용하여 4개의 독립 성분을 획득하였다. 각 독립 성분들 중에서 순수 뇌전도 성분을 추정하기 위해서 전체 신호에 대한 알파파비를 측정하여 그 값이 가장 큰 독립 성분을 잡음이 제거된 순수한 뇌전도로 추정하였다. 그 실험 결과 제안한 방법이 뇌전도 획득 과정에서 효과적으로 잡음을 제거함을 확인하였다.

Comparison of Three Modeling Methods for Identifying Unknown Magnetization of Ferromagnetic Thin Plate

  • Choi, Nak-Sun;Kim, Dong-Wook;Yang, Chang-Seob;Chung, Hyun-Ju;Kim, Hong-Joon;Kim, Dong-Hun
    • Journal of Electrical Engineering and Technology
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    • 제6권6호
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    • pp.799-805
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    • 2011
  • This study presents three different magnetization models for identifying unknown magnetization of the ferromagnetic thin plate of a ship. First, the forward problem should be solved to accurately predict outboard magnetic fields due to the magnetization distribution estimated at a certain time. To achieve this, three different modeling methods for representing remanent magnetization (i.e., magnetic charge method, magnetic dipole array method, and magnetic moment method) were utilized. Material sensitivity formulas containing the first-order gradient information of an objective function were then adopted for an efficient search of an optimum magnetization distribution on the hull. The validity of the proposed methods was tested with a scale model ship, and field signals predicted from the three different models were thoroughly investigated with reference to the experimental data.

Theoretical Consideration of Nondestructive Testing by use of Vertical Magnetization and Magneto-Optical Sensor

  • Lee, Jinyi;Tetsuo Shoji;Dowon Seo
    • Journal of Mechanical Science and Technology
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    • 제18권4호
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    • pp.640-648
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    • 2004
  • This paper describes a new magnetization method for non-destructive testing with magneto-optical sensor (denoted as MO sensor) which have the following characteristic : high observation sensitivity, independence of the crack orientation, and precise imaging of a complex crack geometry such as multiple cracks. When a magnetic field is applied normally to the surface of a specimen which is significantly larger than its defects, approximately the same magnetic charge per unit area occurs on the surface of the specimen. If there is a crack in the specimen, magnetic charge per unit area has the same value at the bottom of the crack. The distribution of the vertical component of the magnetic flux density, B$\_$Z/, is almost uniform over the no-crack area (denoted as B$\_$Z,BASE/), while the magnetic flux density is smaller in the surroundings of the crack(denoted as B$\_$Z,CRACK/) If B$\_$Z, BASE/ is a bit larger than the saturated magnetic flux density of the MO sensor (B$\_$s/) , then small magnetic domains occur over the crack area and a large domain over the non-crack area because B$\_$Z,CRACK/ is smaller than B$\_$s/.

Thermal Stability of Nanostructured Synthetic Ferrimagnets under Applied Magnetic Fields in the 45˚ Direction

  • Han, C.W.;Han, J.K.;Lim, S.H.
    • Journal of Magnetics
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    • 제15권3호
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    • pp.116-122
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    • 2010
  • An accurate analytical equation for the total energy in the framework of the single domain model is used to study the thermal stability of nanostructured synthetic ferrimagnets. Elliptical cells are considered that have lateral dimensions of 160 nm (long axis)$\times$80 nm (short axis) and varying values of thickness asymmetry for the two magnetic layers. The direction of the applied magnetic field, which points to the $45^{\circ}$ direction, is in the opposite direction to the thicker layer magnetization. A significant difference is observed in the applied magnetic field dependencies of the equilibrium magnetic configuration and the magnetic energy barrier when using the simplifying assumption that the self-demagnetizing field is identical in magnitude to the dipole field. At a small thickness asymmetry of 0.2 nm, for example, the magnetic energy barrier is reduced from 68 kT (T=300 K) to 6 kT at the remanent state and a progressive switching behavior changes into a critical behavior, as the simplifying assumption is used. The present results clearly demonstrate the need for an accurate analytical equation for the total energy in predicting the thermal stability of nanostructured synthetic ferrimagnets.

소형 안테나의 성능 향상을 위한 직교 배치에 관한 연구 (A Study of Cross Alignment for Increasing the Performance of Small Antenna)

  • 김종성;최경;김재흥
    • 산업기술연구
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    • 제22권B호
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    • pp.155-161
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    • 2002
  • As the wireless communications are gradually developed, the higher frequency is demanded and the smaller the size of antenna shall be reduced by the wavelength of the operating frequency. However, the smaller the size of antenna becomes, the less the gain is obtained according to the frequency, so that a new attempt such as an array antenna has been examined to improve the characteristics. Also, for the convenience of communication, the omni-directional property is required. In this paper, two antennas system which is aligned in cross direction in tested and analyzed. The main scope is focused to get an appropriated distance between the two small antennas to get better properties. There are various ways of array arrangement, but in this study, it should be placed on the same PCB for easy implementation and the direction of each antenna are aligned to be a cross($90^{\circ}$) position. The study is carried out by comparing the radiation patterns mainly, and the theoretical expectation and the computer simulation are also executed. The final model is the folded IF-antennas system printed on PCB and the ideal dipole-antenna arrangement in also test to verify the possibility of our implementation. And it is finally proved by measuring experiments.

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무선전력전송의 조사량 평가 시 전기장 영향 (Electric Field Effect on Numerical Dosimetry for Wireless Power Transfer System)

  • 박상욱
    • 한국전자파학회논문지
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    • 제26권5호
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    • pp.499-505
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    • 2015
  • 전자기 공진 현상을 이용한 무선전력전송 시스템에 대한 조사량 평가 시 전기장의 고려 여부를 검토하였다. 인체로 인가되는 전기장과 자기장의 상대적인 크기가 조사량 평가 시에 중요한 지표가 되기 때문에, 이를 검토하기 위해 자기 다이폴 인근의 다양한 전자기장의 크기를 갖는 곳에 구형의 간이 인체 모델을 위치시키고, 구 모델 내부로 유도되는 전기장의 값을 이론과 수치해석을 통하여 구하고 비교하였다. 그 결과, 전기장을 무시할 수 없는 영역이 존재함을 확인하였으며, 이는 무선전력전송의 조사량 평가 시 외부 전기장에 대한 고려가 필요함을 알 수 있었다.

Numerical Modeling of Tip Vortex Flow of Marine Propellers

  • Pyo, Sang-woo
    • Journal of Ship and Ocean Technology
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    • 제1권2호
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    • pp.19-30
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    • 1997
  • The accurate prediction of the flow and the pressure distribution near the tip of the blade is crucial in determining the tip vortex cavitation inception which usually occurs on the blade tip or inside the core of the tip vortex just downstream of the blade tip. An improved boundary element method is applied to the prediction of the flow around propeller blades, with emphasis at the tip region. In the method, the Blow adapted grid and a higher order panel method, which combines a hyperboloidal panel geometry with a hi-quadratic dipole distribution, are used in order to accurately model the trailing wake geometry and the highly rolled-up regions in the wake. The method is applied to several propeller geometries and the results have been found to agree well to the existing experimental data. Inviscid flow methods are able to predict the pressures at the tip as well as the shape of the trailing wake. On the other hand, they are unable to determine the flow inside the viscous core of the tip vortex, where cavitation inception often occurs. Thus, a method is presented that treats the flow inside the viscous core. The inner flow is treated with a 2-D Clavier-stokes solution without making any assumptions for axisymmetric flow and conicity of the flow along the tip trajectory. The method can thus allow the treatment of general propeller blade configurations. The velocity and pressure distributions inside the core are shown and compared to those from other numerical methods.

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