• Bulletin of the Korean Chemical Society
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• v.18 no.11
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• pp.1183-1185
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• 1997

Dimethylamine complexes of palladium(Ⅱ) [(PCP)Pd(NHMe2)](OTf) (PCP = 2,6-(R2PCH2)2C6H3); R = Ph (1), R = Cy (2)), have been prepared from the reaction of (PCP)Pd(OTf) and dimethylamine. The complex 1 is stable both in solution and in the solid state, while 2 is stable only in solution in the presence of dimethylamine although the formation of 2 in solution is quantitative by NMR Spectroscopy. A solution NMR spectroscopic study shows that dimethylamine favors over carbon monoxide in the coordination sphere of palladium(Ⅱ) having rigid terdentate ligands. The complexes 1 and 2 in chlorinated solvents undergo a chlorine abstract reaction yielding Pd(2,6-(R2PCH2)2C6H3)Cl in the presence of a base such as dimethylamine and DABCO (diazabicyclooctane), in which a transient dimethylamido palladium(Ⅱ) species likely involves.

• Journal of Korean Society of Environmental Engineers
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• v.30 no.8
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• pp.755-759
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• 2008

As a disinfection byproduct, N-nitrosodimethylamine(NDMA) formation was studied according to chlorine, nitrogen, and carbon composition related to monochloramine and dimethylamine(DMA) concentrations. The highest NDMA formation was observed when the dimethylamine/monochloramine ratio was close to 1, and the formation was rapidly decreased when the ratio was less or greater than 1. The formation of NDMA increased with increasing chlorine/nitrogen ratio indicating the chlorine is a limiting factor. A rapid disinfection byproduct was formed at 72 hour contact time in this study. As the previous researches, pH was a significant factor for the NDMA formation.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.7 no.3
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• pp.115-120
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• 1974

Secondary amines are known as one of the precursors of nitrosamines which are potent carcinogenic compounds of man and animals. Nitrosamines are formed when both secondary amines and nitrite are present. The nitrites are occurred naturally in vegetables, fruits and many others, and frequently used in fish product as a color fixative or a preservative. In this paper, to know the formation of nitrosamines in fish meat, the changes of dimethylamine (DMA) content during the heat treatment such as drying, roasting and fish cake processing are discussed. The results showed that generally DMA increased considerably during heat processing. During drying, DMA in cuttle fish increased 16 times higher, while in Alaska pollack doubled than the fresh. In the roasted mackerel, the DMA content appeared 6 times higher than the fresh, while 9 times higher in canning. In fish cake from yellow corvenia, DMA increased 4 times higher than the fresh. On the contrary diethylamine and diphenylamine were not found in this experiment.

• Rapid Communication in Photoscience
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• v.4 no.3
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• pp.63-66
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• 2015

When the molecule in the excited state is subject to prompt predissociation, it is quite nontrivial to obtain vibrational structure of the excited state in general. This applies to the case of photochemistry of dimethylamine (DMA:$(CH_3)_2NH$). When DMA is excited to its first electronically excited state ($S_1$), the N-H bond dissociation occurs promptly. Therefore, $S_1$ vibronic bands are homogeneously broadened to give extremely small ionization cross sections and heavily-congested spectral features, making infeasible any reasonable spectral assignment. Here, we demonstrate that the predissociation rate of the excited state could be significantly reduced by the NH/ND substitution to give the much better-resolved $S_1$ spectral feature, revealing the vibrational structure of the excited state of $DMA-d_1$ ($(CH_3)_2ND$) for the first time.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.11 no.1
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• pp.9-12
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• 1978

Contents of dimethylamine (DMA) in fresh fish muscle were analyzed by gaschromatography. DMA contents were in Pseudosciaena manchuria $10.367mg\%$, in Theragra chalcogramma $19.133mg\%$, in Sardinops melanosticta $22.833mg\%$, and in Scomber japonicus $26.300mg,\%$ respectively. Individual amines could not be separated with such a low content.

• Preventive Nutrition and Food Science
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• v.2 no.3
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• pp.197-201
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• 1997

To develop a rapid analytical method of dimethylamine(DMA) and trimethylamine(TMA) in fish, the contents of DMA and TMA in squid(Illex illecebrosus and Sepiell maindroni), cod(Gadus marcrocephalus) and plaice (Paralichthys olivaceus) by gas chromatographic (GC) and colorimetric method were determined. Recoveries for DMA in fish were 86.8~102.5% by GC and 74.2~94.5% by colorimetric method, while those for TMA were 93.0~101.1% by GC and 62.9~117.5% by colorimetric method. The contents of DMA and TMA in fish by GC were 29.7~325.3mg/kg and 145.6~356.0 mg/kg, respectively, and these by colorimetric method were 20.0~241.2mg/kg and 139.1~304.3mg/kg, respectively. The analysis of DMA and TMA in fishes by GC after the solvent extraction was simpler and faster and showed better recovery than colorimetric method.

• Bulletin of the Korean Chemical Society
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• v.19 no.11
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• pp.1268-1270
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• 1998

• Journal of the Korea Organic Resources Recycling Association
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• v.4 no.2
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• pp.71-75
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• 1996

A bacterium, capable of the degradation of trimethylamine(TMA), dimethylamine, and methylamine, was isolated from an enrichment culture on TMA basal mineral medium. The isolate was identified as Methylobacterium some carbon-carbon bonds compounds like malate, succinate, betaine. When the strain was immobilized to earthworm cast, the biofilter could remove the gaseous TMA of SV $30h^{-1}$, concentration of 120ppm, continuously.

• Journal of Korean Society on Water Environment
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• v.30 no.1
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• pp.95-101
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• 2014

Overall studies for the N-nitrosodimethylamine (NDMA) formation and treatment methods were conducted. In this study, occurrence in several countries and emerging treatment technologies of NDMA were generally reviewed. The NDMA formation was dependent on pH, contact time, and molar ratio (monochloramine/dimethylamine). The formation was rapidly increased when the molar ratio was greater than 1. It was likely that monochloramine could be related to stimulate NDMA formation. NDMA concentrations in water supply and wastewater plants after disinfection were approximately 10 ng/L and 100 ng/L, respectively. UV oxidation and adsorption processes are regarded as effective technologies for the NDMA removal. It is suggested that the UV oxidation with proper lamps is applied in water supply system.

• Proceedings of the Zoological Society Korea Conference
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• 1996.10a
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• pp.93.1-93
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• 1996

No Abstract, See Full Text