• Title/Summary/Keyword: Dihydrate

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Effect of Gypsum on Hydration Properties of Natural Hydraulic Lime (천연 수경성 석회의 수화특성에 미치는 석고의 영향)

  • Moon, Ki-Yeon;Choi, Moon-Kwan;Cho, Kye-Hong;Cho, Jin-Sang;Ahn, Ji-Whan;Hong, Chang-Woo
    • Resources Recycling
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    • v.24 no.1
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    • pp.12-20
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    • 2015
  • In this study, change of hydration property with contents and type of gypsum in ternary natural hydraulic lime containing blast furnace slag and gypsum was investigated. Anhydrite, hemihydrate and dihydrate were added 3 % and 10 %, respectively in natural hydraulic lime adding blast furnace slag 20 %. Hydration and physical behavior due to solubility and reactivity of different types of gypsum were analyzed in early hydration. As a result of analysis of hydration properties, in all samples, hydrates such as ettringite and C-S-H were produced in early hydration, and amount of hydrates with increase of hydration time was increased. In the case of compressive strength, when contents of gypsum are 3 %, it was higher compressive strength than other specimens. At hydration 28 days, for addition of anhydrite and hemihydrate, compressive strength was more than adding dihydrate.

Stability Improvement of Esomeprazole Magnesium Dihydrate Enteric-Coated Tablet by Adding Alkalizing Agents (에스오메프라졸 마그네슘 이수화물을 함유하는 장용성 제제의 안정성 개선)

  • Cho, Young Ho;Jeon, Hyo Bin;Lee, Jong-Hwa;Lee, Gye Won
    • KSBB Journal
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    • v.32 no.2
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    • pp.108-116
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    • 2017
  • Omeprazole, a benzimidazole derivative, suppresses gastric acid secretion by inhibiting $H^+/K^+$ ATPase in gastric parietals cells, and by reducing $H^+$ concentration. To improve stability of esomeprazole magnesium dihydrate (ESMD), enteric-coated preperation was composed of core tablet, subcoating and enteric coating layer. We were evaluated in vitro dissolution characteristics between test and reference ESMD preparation and stability. We could prepare enteric-coated formulation of ESMD by controlling disintegrating agent and coating ratio which could rapidly dissolved in neutral or alkali medium. The formulation D5 with crospovidone of 1.25% and coating ratio of 16.25% had a similar dissolution behavior compare to reference preparation. Difference factor ($f_1$) and similarity factor ($f_2$) were 0~15 and 50~100 and there was no significant difference in bioequivalence between formulations. The content and dissolution rate of formulation D5 were $96.54{\pm}0.21$ and $78.56{\pm}0.87%$ without change of color in accelerated condition ($40^{\circ}C$, RH 75%, high density polyethylene (HDPE) container) for 6 months. This study concluded that our enteric coated preparation of ESMD could be an useful method to improve stability of unstable drug without direct contact with coating material.

Separation Characteristics of Barium Ion in Water Using Capacitive Deionization (CDI) Process (축전식탈염(CDI) 공정을 이용한 수용액 중 바륨 이온 분리 특성 연구)

  • Nam, Dong Hyun;Rhim, Ji Won
    • Membrane Journal
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    • v.29 no.6
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    • pp.355-361
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    • 2019
  • We studied the removal of barium ions that may be contained in industrial wastewater using the existing capacitive deionization (CDI). The 30 mg/L BaCl2 (barium chloride dihydrate) solution was used as the feed solution, and the flow rate was set to 10 mL/min. The adsorption conditions were varied from 1.2 V to 3, 5 and 7 min, and the desorption conditions were -1, -1.5, -2 V and 1, 2 and 3 min, respectively, to select the most efficient conditions. As a result, barium ion removal efficiency of 64.4% was obtained under the adsorption conditions of adsorption of 1.2 V/7 min and the desorption -1 V/1 min. For the desorption voltages and time, under the same experimental conditions, the removal efficiency of CDI for 30 mg/L NaCl aqueous solution with the same concentration as barium showed 69.9% removal efficiency under the adsorption conditions of and the desorption conditions of 1.2 V/7 min desorption -1 V/1 min, respectively.

Idiopathic Calcium Pyrophosphate Dihydrate (CPPD) Crystal Deposition Disease in a Young Female Patient - A Case Report - (젊은 여자환자에서 발생한 특발성 칼슘 피로 인산염 침착질환 - 증례보고 -)

  • Choi, Eui-Sung;Park, Kyoung-Jin;Kim, Yong-Min;Kim, Dong-Soo;Shon, Hyun-Chul;Cho, Byung-Ki;Lee, Hyun-Chul
    • Clinics in Shoulder and Elbow
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    • v.12 no.1
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    • pp.84-88
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    • 2009
  • Purpose: Calcium pyrophosphate dihydrate crystal deposition disease(CPPD) is a disease of the elderly and extremely rare in young individuals. If young people develop CPPD crystal deposition disease, it may be associated with metabolic diseases, such as hemochromatosis, hyperparathyroidism, hypophosphatasia, hypomagnesemia, Wilson's disease, hypothyroidism, and gout. Materials and Methods: Therefore, in young-onset CPPD crystal deposition disease, an investigation of any predisposing metabolic conditions is warranted. Conclusion: We report a case of a young female patient who presented with idiopathic CPPD crystal deposition disease at 25 years of age.

Reaction Characteristics of the CAC with Various Gypsum Type and Mixing Ratio (석고 종류 및 혼입률에 따른 CAC 반응 특성)

  • Choi, Sun-Mi;Kim, Jin-Man;Koo, Ja-Sul
    • Resources Recycling
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    • v.30 no.1
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    • pp.83-91
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    • 2021
  • Ladle furnace slag is a byproduct of the steel-making process, and it contains the mineral β-C2Sandtherapid-settingmineral (dependingonwhichreducingagenthasbeenused). Ladle furnace slag is often treated through slow cooling, which causes the slag to lose its reactivity. In this study, the properties of air-quenched CAC and pulverized ladle furnace slag containing gypsum were evaluated, and the optimal mixing ratio was determined for broadening their usage. Consequently, the properties of CAC aredemonstrated by the dissolution of gypsum after a period of three hours and the content of gypsum after a period of one day. The optimal mixing ratio of anhydrate and hemihydrate gypsum is found to be within 30% and that of dihydrate gypsum is found to be higher than 35%. Furthermore, based on the results of CAC with dihydrate gypsum, the applicability of the by-product dihydrate gypsum has been verified.

A Study on the Characteristics of Mine Liner According to the Contents of CSA Using Industrial Byproducts (산업부산물을 활용한 CSA 첨가량에 따른 광산 차수재 특성에 관한 연구)

  • Kang, Suk-Pyo;Lee, Yeong-Hun;Kang, Hye-Ju;Cho, Sung-Hyun;Cho, Yong-Kwang
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.1
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    • pp.74-81
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    • 2019
  • In this study, to characterize the application of CSA and dihydrate gypsum Utilizing industrial byproducts, we investigated the characteristics of CSA and dihydrate gypsum to investigate the characteristics of Mine Liner according to the addition amount. As a result of compressive strength, length change and absorption rate of mining lime wastewater according to CSA addition amount, up to 30% of CSA showed a positive effect on shrinkage and absorption reduction effect as well as strength at initial age. However, due to excessive use of CSA 50%, it was reduced by 15% compared to OPC due to increase of absorption rate and decrease of cement amount due to over expansion rather than shrinkage compensation and void filling.

Characteristics of c-axis oriented sol-gel derived ZnO films (C-축으로 정렬된 sol-gel ZnO 박막의 특성)

  • 김상수;장기완;김인성;송호준;박일우;이건환;권식철
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.11 no.2
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    • pp.49-55
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    • 2001
  • ZnO films were fabricated on p-type Si(100) wafer ITO glass and quartz glass by the sol-gel process using zinc acetate dihydrate as starting material. A homogeneous and stable solution was prepared by dissolving the zinc acetate dihydrate in a solution of 2-methoxyethanol and monoethanolamine (MEA). ZnO films were deposited by spin-coating at 2800 rpm for 25 s and were dried on a hot plate at $250^{\circ}C$ for 10 min. Crystallization of the films was carried out at $400^{\circ}C$~$800^{\circ}C$ for 1 h in air. X-ray diffraction (XRD) analysis, scanning electron microscopy (SEM), UV-vis transmittance spectroscopy, FTIR transmittance spectroscopy and Photoluminescence (PL) spectroscopy measurements have been used to study the structural and optical properties of the films. ZnO films highly oriented along the (002)plane were obtained. In all cases the films were found to be transparent (above 70%) in visible range with a sharp absorption edge at wavelengths of about 380nm, which is very close to the intrinsic band-gap of ZnO(3.2 eV). The low temperature band-edge photoluminescence revealed a complicated multi-line structure in terms of bound exciton complexes and the phonon replicas.

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Reinforcement of Calcium Phosphate-Calcium Sulfate Injectable Bone Substitute Using Citric Acid and Hydroxypropyl-Methyl-Cellulose

  • Thai, Van Viet;Kim, Min-Sung;Song, Ho-Yeon;Lee, Byong-Taek
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.05a
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    • pp.45.1-45.1
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    • 2009
  • In this study, we investigated a calcium phosphate-calcium sulfate injectable bone substitute (IBS) with organic reinforcement of chitosan, citric acid and hydroxypropyl-methyl-cellulose (HPMC). The powder component of IBS consisted of tetra calcium phosphate (TTCP), dicalcium phosphate dihydrate (DCPD) and calcium sulfate dihydrate (CSD). The liquid component was a solution of citric acid and chitosan. The effect of HPMC in terms of setting time, compressive strength and apatite forming ability on this IBS was investigated. The mass content of HPMC in liquid phase was varied in array of 0%, 2%, 3% and 4%. The setting times obtained between 20 and 45 minutes. Compressive strength was achieved over 20 MPa after incubation at 370C and in 100% humidity for 28 days. Porosities were evaluated in relation with compressive strength. Elastic moduli of the 28 days after-incubation IBS were obtained around 4GPa

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Synthesis and Physico-Chemical Properties of Dicalcium Phosphate Dihydrate for Dental Abrasive (치아 연마용 인산일수소칼슘의 합성 및 물리화학적 성질)

  • 서성수;황성주;이기명;이계주
    • YAKHAK HOEJI
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    • v.37 no.1
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    • pp.66-75
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    • 1993
  • Dental abrasive, dicalcium phosphate dehydrate (DCPD) was prepared and the several important factors affecting on the quality of toothpaste were investigated by means of set test, glycerine absorption, Coulter counter test, color difference, BET adsorption, mercury porosimetery, and rheogram comparing with two foreign DCPDs, MFO4 and Dentphos K. Sample DCPD was prepared by reaction between 85% H$_{3}$PO$_{4}$ and 15% milk of lime at $39^{\circ}C$ (pH6.5), and stabilized with TSPP and TMP. The physicochemical properties of Sample DCPD were obtained as follows: whiteness (98.99), average particle size (15.5 $\mu\textrm{m}$), pH (7.9), remainder particle weight (0.49w/w%), glycerine absorption value (64 ml), and set test (passed). N$_{2}$ adsorption curves (BET) of three kinds of DCPD showed non-porous type III isotherm. BET adsorption parameters of sample DCPD showed that surface area was 24.9 m$^{2}$/g, total pore volume 0.09 cm$^{3}$/g and average pore radius 72.0 $\AA$. The rheogram of the toothpaste containing each DCPD showed bulged plastic flow with yield vlaue and thixotropic behavior. These results meet standard requirements as abrasive standard, and suggested that synthesized sample DCPD could be used a dental abrasive such as a high quality grade in practice as foreign DCPDs.

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