• Title/Summary/Keyword: Diffusion study

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Radial and Circumferential Variations in Hygroscopicity and Diffusion Coefficients within a Tree Disk

  • Kang, Wook;Chung, Woo Yang;Eom, Chang Deuk;Han, Yeon Jung;Yeo, Hwan Myeong;Jung, Hee Suk
    • Journal of the Korean Wood Science and Technology
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    • v.35 no.2
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    • pp.29-38
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    • 2007
  • This study was undertaken to investigate the variation of equilibrium moisture content (EMC) in transverse direction and three different directional (longitudinal, radial, and tangential) linear movements, and diffusion coefficients within a tree disc of Korean red pine (pinus densiflora). The EMC gradually increased in heartwood from pith. Therefore, the chemical components might differ even in heartwood and the radial variation in EMC might have a close relationship with the cellulose content within a cross section. The specific gravity increases gradually from pith and the porosity has not direct influence on the variation of EMC within a tree disk. Both the radial and tangential diffusion coefficients exhibited clear trend of increase from pith. The EMC change (${\Delta}EMC$) and tangential diffusion coefficient were close to be axisymmetrical but others were deviated from axisymmetry. The diffusion coefficient decreases with decreasing an activation energy and specific gravity, The diffusion coefficient increased with increasing ${\Delta}EMC$ and hygroscopicity of wood might be inversely proportional to the activation energy, The fJEMC may depend on the chemical constituents of cellulose, hemicellulose and lignin. As the number of sorption sites and sorption capacity of wood increase, therefore, it might be assumed that the hygroscopicity of wood increases while activation energy decreases. Modeling physico-mechanical behavior of wood, the variations should be considered to improve the accuracy.

Study on Hindered Diffusion of Single Polyelectrolyte Chain in Micro-Pores by Employing Brownian Dynamics Simulations (브라운 동력학 시뮬레이션에 의한 미세기공에서 단일한 다가전해질 사슬의 제한확산 연구)

  • 전명석;곽현욱
    • Membrane Journal
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    • v.12 no.4
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    • pp.207-215
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    • 2002
  • The hindered diffusion in confined spaces is an important phenomenon to understand in a micro-scale the filtration mechanism determined by the particle motion in membrane pores. Compared to the case of spherical colloids, both the theoretical investigations and the experiments on the hindered diffusion of polyelectrolytes is actually more difficult, due to lots of relevant parameters resulting from the complicated conformational properties of the polyelectrolyte chain. We have successfully performed the Brownian dynamics simulations upon a single polyeiectrolyte confined in a slit-like pore, where a coarse-grained bead-spring model incorporated with Debye-Huckel interaction is properly adopted. For the given sizes of both the polyelectrolyte and the pore width, the hindered diffusion coefficient decreases as the solution ionic concentration decreases. It is evident that a charge effect of the pore wall enhances the hindered diffusion of polyelectrolyte. Simulation results allow us to make sense of the diffusive transport through the micro-pore, which is restricted by the influences of the steric hindrance of polyelectrolytes as well as the electrostatic repulsion between the polyelectrolytes and pore wall.

Improving Energy Consumption of Directed Diffusion with Mobile Sinks By Prefetching and Pruning (이동 싱크 환경에서 사전경로설정과 가지치기를 이용한 Directed Diffusion의 에너지 소모 개선)

  • Kim, Sung-Hoon;Lee, Sang-Mok;Yang, Hyun;Park, Chang-Yun
    • Journal of KIISE:Information Networking
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    • v.35 no.1
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    • pp.34-45
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    • 2008
  • In dynamic wireless sensor networks where sources and sinks are moving or are created/died, control overheads for route establishment are increased and thus become one of the major factors for energy consumption. This study introduces prefetching and pruning for Directed Diffusion to remove redundant control messages. Prefetching collects path information for each event with "AnyEvent" in advance and gives quick responses without further flooding of requests. Pruning accumulates history information from previous requests and replies, and then stops forwarding a request towards where the event does not exist. Simulation results with ns show that it is possible to build implicit and soft infrastructures within a Directed Diffusion system through these active collection and passive accumulation and they improve energy consumption more as control overhead goes higher.

Temperature Effect on Effective Diffusion Coefficients of Zn and Cd through Column Diffusion Tests (칼럼 확산 실험을 통한 아연 및 카드뮴의 유효확산계수에 미치는 온도영향)

  • Dho, Nam-Young;Lee, Seung-Rae
    • Journal of the Korean GEO-environmental Society
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    • v.3 no.1
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    • pp.13-26
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    • 2002
  • In this study, column diffusion tests for Cd and Zn were conducted at $15^{\circ}C$ and $55^{\circ}C$ to investigate a temperature effect on effective diffusion coefficient. An increase in temperature from $15^{\circ}C$ to $55^{\circ}C$ caused up to ten times larger diffusion coefficient for each heavy metal. Besides, it caused the increased retardation of heavy metals, and hence the effective diffusion coefficient should be overestimated as we use an overestimated retardation factor to calibrate the coefficient. The results of sequential extraction analyses showed that Zn was occluded in carbonate phase and this trend was getting prominent with the increase in temperature. As for Cd, it was partitioned mainly in the exchangeable phase(over 60%) at any temperature.

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Chloride Diffusion in Hardened Concrete with Concrete Properties and Testing Method (콘크리트 물성 및 시험법에 따른 콘크리트 염화물 확산)

  • Yang Eun-Ik;Kim Myung-Yu;Min Seok-Hong
    • Journal of the Korea Concrete Institute
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    • v.16 no.2 s.80
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    • pp.261-268
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    • 2004
  • Corrosion of reinforcement is the main cause of damage and early failure of reinforced concrete structures. The corrosion is mainly progressed by the chloride ingress. In this paper, an experimental study is executed to investigate the effect of concrete properties and testing methods on the coefficients of chloride diffusion. Also, it is surveyed the relationship between total chloride and free chloride in concrete. According to this experiment results, W/C ratio and testing method affect chloride diffusion coefficient of concrete. As W/C ratio is increased, diffusion coefficient in concrete is also increased. Diffusion coefficient obtained by each testing method show the different values, respectively. The model equation of diffusion coefficient with W/C ratio is proposed.

Determination of Self Diffusion Distributions of Molten Polyurethanes by Relaxation Spectra (용융 폴리우레탄의 완화 스펙트럼에 의한 자체확산분포 결정)

  • Kim, Nam-Jeong
    • Journal of the Korean Chemical Society
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    • v.50 no.3
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    • pp.196-202
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    • 2006
  • The self diffusion distributions of viscoelastic molten polyurethanes were determined from the relationship between the relaxation spectra and the distribution of self diffusion. The relaxation spectra of ester, PCL and PCL dyed type molten polyurethanes were obtained by applying the experimental stress relaxation curves to the theoretical equation of the Ree-Eyring and Maxwell non-Newtonian model(REM model) from computer calculation. The experiments were carried out at various temperatures using the physica rheometer with the temperature controller. The self diffusion and hole distance of amorphous region of polyurethane samples were investigated by experiments of stress relaxation. The diffusion coefficients and hole volumes were calculated from rheological parameters and crystallite size in order to study the diffusion of flow segments in amorphous region. It was observed that the relaxation spectra and self diffusions of these polymer samples are directly related to the distribution of molecular weights, viscosities, hole volumes and activation energies of flow segments.

Evaluation of the Usefulness of PROPELLER (periodically rotated overlapping parallel lines with enhanced reconstruction) Technique to Reduce the Magnetic susceptibility artifact (Magnetic susceptibility artifact를 줄이기 위한 PROPELLER 확산강조영상기법의 유용성에 대한 평가)

  • Cho, Jae-Hwan
    • Journal of Digital Contents Society
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    • v.11 no.1
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    • pp.73-78
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    • 2010
  • This study attempted to examine whether the propeller diffusion weighted image method may remove magnetic susceptibility artifacts caused by metallic materials. A comparison of occurrence rates of magnetic susceptibility artifacts in the four regions, both temporal lobes, pons, and orbit, between b = 0 and b = 1,000 s/mm2 images was made after obtaining echo-planar diffusion weighted image, propeller diffusion weighted image, and ADC map images, respectively, from a total of 20 patients who had MRI shots taken of their brain and were found to be with retained metallic foreign bodies within their teeth using a 3.0T MR scanner. In the case of echo-planar diffusion weighted image technique, the presence of metallic materials may bring in some limits on accurate diagnosis due to magnetic susceptibility artifacts, while the propeller diffusion weighted image technique where magnetic susceptibility artifacts decrease is expected to be more useful in ensuring accurate diagnosis in the clinical context.

Spacio-temporal Characteristics of Cultural Contents Diffusion: The Case of PSY's "Gangnam Style" Music Video (문화콘텐츠 상품 확산의 시·공간적 특성 -싸이의 "강남스타일" 뮤직비디오를 중심으로-)

  • Lee, Keumsook;Kim, Ho Sung
    • Journal of the Economic Geographical Society of Korea
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    • v.18 no.2
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    • pp.224-241
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    • 2015
  • This study investigates the time-space characteristics of the consumptions of cultural-contents commodities and their spatial diffusion progresses via digital media. For the purpose, we examine the spatial diffusion patterns of PSY's Music Video "Gangnam Style" since it has been launched on the YouTube. By visualizing the spacio-temporal progresses of YouTube, Tweet, and Google searching data during four months after launching, we examine the time-space characteristics of diffusion patterns of the music video via each media. We found that the adapting time and the diffusion progress were not in accordance at each country. The results revel that cultural distance such as characterized by language, cultural linkage, exclusivism or courtesy for the 'Hanrue' affects quite strongly on the spatial diffusion of music video rather than physical distance.

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Analysis Technique for Chloride Penetration in High Performance Concrete Behavior Considering Time-Dependent Accelerated Chloride Diffusivity (촉진염화물 확산계수의 시간의존성을 고려한 고성능 콘크리트의 염화물 침투 해석기법)

  • Kwon, Seung-Jun;Park, Sun-Gyu
    • Journal of the Korea Concrete Institute
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    • v.25 no.2
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    • pp.145-153
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    • 2013
  • Recently, accelerated chloride diffusion coefficients are used for an evaluation of chloride behavior. Similar as apparent diffusion coefficients, accelerated diffusion coefficients decrease with time. In this study, decrease in diffusion coefficient with time is simulated with porosity. Utilizing DUCOM-program, porosities from 15 mix proportions are obtained and diffusion coefficients are modelled with regression analysis of porosity for 270 days. Considering non-linear binding capacity which means the relation between free and bound chloride ion, chloride behavior in high performance concrete is evaluated. Through utilizing the previous test results for concrete under chlorides for 180 days, the applicability of the proposed technique is verified. The proposed technique is evaluated to reasonably predict the chloride behavior in concrete with various w/c (water to cement) ratios and mineral admixtures (GGBFS and FA). It is also shown that decrease in chloride diffusion should be considered for chloride prediction in concrete with mineral admixture since it has very clear decrease in diffusivity with time.

Study on the Optical Properties of Light Diffusion Film with Plate Type Hollow Silica

  • Lee, Ji-Seon;Moon, Seong-Cheol;Noh, Kyeong-Jae;Lee, Seong-Eui
    • Journal of the Korean Ceramic Society
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    • v.54 no.5
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    • pp.429-437
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    • 2017
  • Micro hollow plate type silica with low refraction properties was synthesized and its hollow structure was applied as an optical structure to develop a light diffusion material that simultaneously satisfies the requirements of good light diffusibility, high transmissibility, and high luminance. The developed light diffusion material was applied to a light diffusion film and the film's optical properties were assessed. Hollow silica was synthesized by precipitation method using $Mg(OH)_2$ core particles, sodium silicate, and ammonium sulfate as the silica precursors. The concentration of the silica precursor was adjusted to control hollow silica shell thickness. The total light transmittance of the light diffusion film composed of the hollow silica was 94.55%, which was 4.57% higher than that of the PC film; new film's haze was 71.20%, which was 70.9% higher. Furthermore, the luminance increased by 5.34% compared to that of the light source. The reason for the results is not only that the micro plate type hollow silica, which has a low refractive property, played a role in reducing the difference in refractive index between the medium boundaries, but also that there was a light-concentrating effect due to the changing of light paths to the front direction inside the hollow structure. Optical simulation verified the enhanced optical properties when hollow silica was applied to the light diffusion film.