Radial and Circumferential Variations in Hygroscopicity and Diffusion Coefficients within a Tree Disk

  • Kang, Wook (Dept. of Forest Products, College of Agriculture, Chonnam National University) ;
  • Chung, Woo Yang (Dept. of Forest Products, College of Agriculture, Chonnam National University) ;
  • Eom, Chang Deuk (Program in Environmental Materials Science, Department of Forest Science College of Agriculture & Life Science, Seoul National University) ;
  • Han, Yeon Jung (Program in Environmental Materials Science, Department of Forest Science College of Agriculture & Life Science, Seoul National University) ;
  • Yeo, Hwan Myeong (Program in Environmental Materials Science, Department of Forest Science College of Agriculture & Life Science, Seoul National University) ;
  • Jung, Hee Suk (Program in Environmental Materials Science, Department of Forest Science College of Agriculture & Life Science, Seoul National University)
  • Received : 2006.09.02
  • Accepted : 2006.12.26
  • Published : 2007.03.25

Abstract

This study was undertaken to investigate the variation of equilibrium moisture content (EMC) in transverse direction and three different directional (longitudinal, radial, and tangential) linear movements, and diffusion coefficients within a tree disc of Korean red pine (pinus densiflora). The EMC gradually increased in heartwood from pith. Therefore, the chemical components might differ even in heartwood and the radial variation in EMC might have a close relationship with the cellulose content within a cross section. The specific gravity increases gradually from pith and the porosity has not direct influence on the variation of EMC within a tree disk. Both the radial and tangential diffusion coefficients exhibited clear trend of increase from pith. The EMC change (${\Delta}EMC$) and tangential diffusion coefficient were close to be axisymmetrical but others were deviated from axisymmetry. The diffusion coefficient decreases with decreasing an activation energy and specific gravity, The diffusion coefficient increased with increasing ${\Delta}EMC$ and hygroscopicity of wood might be inversely proportional to the activation energy, The fJEMC may depend on the chemical constituents of cellulose, hemicellulose and lignin. As the number of sorption sites and sorption capacity of wood increase, therefore, it might be assumed that the hygroscopicity of wood increases while activation energy decreases. Modeling physico-mechanical behavior of wood, the variations should be considered to improve the accuracy.

Keywords

References

  1. Andersson S., H. Wikberg, E. Pesonen, S. L. Maunu, and R. Serimaa. 2004. Studies of crystallinity of Scots pine and Norway spruce cellulose. Trees 18: 346-353 https://doi.org/10.1007/s00468-003-0312-9
  2. Bao F. C., H. Jiang, X. M. Jiang, X. X. Lu, X. Q. Luo, and S.Y. Zhang. 2001. Differences in wood properties between juvenile wood and mature wood in 10 species grown in China. Wood. Sci. Technol 35: 363-375 https://doi.org/10.1007/s002260100099
  3. Bertaud F. and B. Holmbolm. 2004. Chemical composition of earlywood and latewood in Norway spruce heartwood, sapwood and transition zone wood. Wood Sci. Technol. 38: 245-256
  4. Choong E. T. and P. J. Fogg. 1968. Moisture movement in six wood species. Forest Prod. J. 18(5): 66-70
  5. Comstock, G. L. 1963. Moisture diffusion coefficients in wood as calculated from adsorption, desorption, and steady state data. Forest Prod. J. 3: 97-103
  6. Constant, T., G. Nepveu, and F. Huber. 2002. Intra- and inter-tree variability of moisture content in standing sessile oak (Quercus petraea Liebl.) Holzforschung 56: 117-124 https://doi.org/10.1515/HF.2002.020
  7. Constant, T., M. A. Badia, and F. Mothe. 2003. Dimensional stability of douglas fir and mixed beech-poplar plywood : experimental measurements and simulations. Wood. Sci. Technol. 37: 11-28 https://doi.org/10.1007/s00226-003-0165-9
  8. Gu, H., A. Zink-Sharp, and J. Sell. 2001. Hypothesis on the role of cell wall structure in differential transverse shrinkage of wood. Holz RohWekstoff 59: 436-442
  9. Kang, W. and N.H. Lee. 2002. Mathematical models to predict drying deformation and stress due to the differential shrinkage within a tree disk with radial variations. Wood Sci. Technol. 36: 463-476 https://doi.org/10.1007/s00226-002-0153-5
  10. Kang, W., N. H. Lee, and J. H. Choi. 2004. A radial distribution of moistures and tangential strains within a larch log cross section during radio-frequency/vacuum drying. Holz RohWekstoff 62: 59-63
  11. Kang, W. and N.H. Lee. 2004. Relationship between radial variations in shrinkage and drying defects of tree disks. J. Wood Sci. 50: 209-216
  12. Karki, T. 2001. Variation of wood density and shrinkage in European aspen. Holz Roh- Werkstoff 59: 79-84 https://doi.org/10.1007/s001070050479
  13. Koga, S. and S. Y. Zhang. 2004. Inter-tree and intra-tree variations in ring width and wood density components in balsam fir (Abies ba!samea) Wood Sci. Technol. 38: 149-162 https://doi.org/10.1007/s00226-004-0222-z
  14. Kolin, B. and T. S. Janezic. 1996. The effect .of temperature, density and chemical composition upon the limit of hygroscopicity of wood. Holzforschung 50: 263-268 https://doi.org/10.1515/hfsg.1996.50.3.263
  15. Koumoutsakos, A. and S. Avramidis. 2002. Mass transfer characteristics of western hemlock and western red cedar. Holzforschung 56: 185-190 https://doi.org/10.1515/HF.2002.031
  16. Rowell, R. M. 1984. The chemistry of soild wood. American Chemical Society, Washington, DC, pp. 139
  17. Sian, J. F. and S. Avramidis. 1996. The surface emission coefficient of wood. Wood & Fiber Sci. 28(2): 178-185
  18. Stamm, A. J. 1964. Wood and cellulose science. The Ronald Press Company, New York
  19. Zobel, B. J. and J. R. Sprague. 1998. Juvenile wood in Forest trees. Spinger-Verlag, Berlin Heidelverg