• Title/Summary/Keyword: Diffusion property

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Property changes of GDLs and water behaviors in PEFCs (고분자전해질 연료전지 체결조건에서 기체확산층의 특성변화 및 물거동 확인)

  • Park, Gu-Gon;Lim, Nam-Yun;Ahn, Eun-Jin;Park, Jin-Soo;Yoon, Young-Gi;Lee, Won-Yong;Lim, Tae-Won;Kim, Chan-Soo
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.313-315
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    • 2006
  • Proper water management is important to achieve high performance and durability of Polymer electrolyte fuel cell (PEFC). Among various stack components, gas diffusion layer (GDL) is considered as a core part to determine the gas and water transportation in a cell. To optimize the water management, the changes of properties as well as basic properties of GDLs were investigated before and after clamping of colls. Thickness, electric conductivity, porosity, hydroppobicity etc. were characterized by the same criteria. The amount of residual water after cell operation also was compared by direct measuring of weight. Based on the amount of residual water the endurance on the freeze condition was evaluated.

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Surface Characterization and Dyeing Property of PET Film Treated with Hydrazine Hydrate in Methanol (Hydrazine/Methanol 처리에 의한 PET film의 표면특성과 염색성)

  • 성우경;조현혹;김경환
    • Textile Coloration and Finishing
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    • v.1 no.1
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    • pp.26-34
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    • 1989
  • The selective chemical degradation or etching of PET based on an organic amine attack on the ester group. The techniques involves the chemical removal of loss ordered amorphous regions or crystalline regions, which are essentially unaffected by the degradative etchant. Thus, most of previous studies have limited to consideration which has been given to structural changes taking place. Therefore, this study was carried out to investigate surface characterization, dyeing properties of PET film hydrazinolyzed with hydrazine hydrate in methanol. PET film was treated with 30% hydrazine hydrate in methanol at $30^\circ{C}$ for various time intervals. The total surface tension of treated PET increased, the dispersion force decreased and the hydrogen bonding force increased. The equilibrium dye adsorption, dyeing rate and apparent diffusion coefficient of acid dyes increased, and the apparent activation energies of diffusion decreased.

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Design of the Lens Structure for COB type LED Safety Luminaires (COB형 LED 보안등을 위한 렌즈 구조 설계)

  • Jang, Sung-Whan;Jung, Byoung-Jo
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.27 no.8
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    • pp.1-8
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    • 2013
  • The study carried out in this dissertation focuses on the lens structure design and the light distribution for LED safety luminaires using COB type LED module. Lens structures for LED lights has been designed 1) to induce light diffusion by dual process of internal reflection and refraction, 2) to minimize the inherent LED lights' glittering, and 3) to have uniform brightness. The lens designed with the proposed structures function as diffusers for the divergence of the LED lights so that they form a wide angle of view and adjust the light distribution. We designed of lens with stable uniformity factor and average roughness using aspheric optics property. Finally we made the analysis data of the simulated data.

A Study of Hydrogen-Induced Metal Atom Rearrangement

  • Noh, Hak;Park, Choong-Nyeon;Flanagan, Ted B.
    • Journal of Hydrogen and New Energy
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    • v.7 no.1
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    • pp.111-115
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    • 1996
  • Metal atom rearrangement has been shown to take place under the influence of hydrogen-induced atomic diffusion (HIAD) in initially homogeneous fee palladiumalloys by electron microprobe analysis, optical microscopy, mechanical property tests and hydrogen isotherms. HIAD takes place in palladium alloys at moderate to elevated temperatures leading to phase segregation under conditions where segregation does not normally occur, i.e., in the absence of H over the time scale of the experiments. From these results, it is confirmed that dissolved hydrogen plays a dual role in some of these alloys, i.e. it catalyzes metal atom diffusion. This research demonstrates the potential utility of employing H-induced changes for phase diagram determination of Pd alloys and possibly for other alloy system.

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SIMS Investigation of Black Cr Solar Selective Coatings (Black Cr 태양 선택흡수막의 SIMS 연구)

  • Lee, Kil-Dong
    • Journal of the Korean Solar Energy Society
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    • v.34 no.4
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    • pp.39-44
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    • 2014
  • The elemental composition of electro-deposited black Cr solar selective coatings before and after heating in air by using secondary ion mass spectrometry (SIMS) was investigated for optical property analysis. In addition, black Cr selective coating exposed by solar radiation for 5 months was compared with heated sample. SIMS investigation shows that $OH^+$ bearing ions were related to a near surface region of CrOH and CrO compound. The optical degradation of this coating after heating at $500^{\circ}C$ reveals that diffusion of the Cu and Ni elements in substrate material, the chemical interactions adjacent to the interface, and the interface width broadening.

Specific Heat Measurement of Insulating Material using Heat Diffusion Method

  • Choi, Yeon-Suk;Kim, Dong-Lak
    • Progress in Superconductivity and Cryogenics
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    • v.14 no.2
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    • pp.32-35
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    • 2012
  • The objective of the present work is to develop a precise instrument for measuring the thermal property of insulating material over a temperature range from 30 K to near room temperature by utilizing a cryocooler. The instrument consists of two thermal links, a test sample, heat sink, heat source and vacuum vessel. The cold head of the cryocooler as a heat sink is thermally anchored to the thermal link and used to bring the apparatus to a desired temperature in a vacuum chamber. An electric heater as a heat source is placed in the middle of test sample for generating uniform heat flux. The entire apparatus is covered by thermal shields and wrapped in multi-layer insulation to minimize thermal radiation in a vacuum chamber. For a supplied heat flux the temperature distribution in the insulating material is measured in steady and transient state. The thermal conductivity of insulating material is measured from temperature difference for a given heat flux. In addition, the specific heat of insulating material is obtained by solving one-dimensional heat diffusion equation.

Electrical and Optical Properties of p-type ZnO:P Fabricated by Ampoule-tube Vapor-state Diffusion

  • So, Soon-Jin;Oh, Sang-Hyun;Park, Choon-Bae
    • Transactions on Electrical and Electronic Materials
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    • v.9 no.1
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    • pp.24-27
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    • 2008
  • ZnO has intensively attracted interest for the next generation of short wavelength LEDs and semiconductor lasers. However, for the development and application of the devices based on this material, the fabrication of p-type ZnO thin films is pivotal. Generally, the process of preparation of ZnO is unavoidably accompanied by the natural donor ions such as interstitial Zn ions and oxygen vacancy ions that show n-type electrical property and make fabrication of p-type ZnO to be a hard problem. On this study, to realize stable high-quality p-type ZnO thin films, the undoped ZnO thin films were diffused with P in vapor state. The ZnO:P thin films showed high-quality p-type properties electrically and optically.

Analysis for Local Structure of Gaseous Hydrogen/liquid Oxygen Flame at Supercritical Pressures (초임계 압력상태에서 기체수소/액체산소 국소화염구조 해석)

  • Kim, Tae-Hoon;Kim, Seong-Ku;Kim, Yong-Mo
    • Journal of ILASS-Korea
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    • v.15 no.4
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    • pp.182-188
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    • 2010
  • Significant real fluid behaviors including rapid property changes take place where high pressure combustion devices such as rocket engines. The flamelet model is the reliable approach to account for the real fluid effects. In the present study, the flamelet equations are extended to treat the general fluids over transcritical and supercritical states. The real fluid flamelet model is carried out for the gaseous hydrogen and cryogenic liquid oxygen flames at the wide range of thermodynamic conditions. Based on numerical results, the precise discussions are made for effects of real fluid, pressure, and differential diffusion on the local flame structure.

Molecular Dynamics Simulation Study of the Transport Properties of Liquid Argon: The Green-Kubo Formula Revisited

  • Lee, Song-Hi
    • Bulletin of the Korean Chemical Society
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    • v.28 no.8
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    • pp.1371-1374
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    • 2007
  • The velocity auto-correlation (VAC) function of liquid argon in the Green-Kubo formula decays quickly within 5 ps to give a well-defined diffusion coefficient because the velocity is the property of each individual particle, whereas the stress (SAC) and heat-flux auto-correlation (HFAC) functions for shear viscosity and thermal conductivity have non-decaying, long-time tails because the stress and heat-flux appear as system properties. This problem can be overcome through N (number of particles)-fold improvement in the statistical accuracy, by considering the stress and the heat-flux of the system as properties of each particle and by deriving new Green-Kubo formulas for shear viscosity and thermal conductivity. The results obtained for the transport coefficients of liquid argon obtained are discussed.

The Apparent Mass Capacity Method for Transient Diffusion Problems with Change of Phase

  • Kim, Yongsoo;Wonmok Jae;D. R. Olander
    • Proceedings of the Korean Nuclear Society Conference
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    • 1995.05b
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    • pp.643-650
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    • 1995
  • A numerical method for treating transient diffusion Involving change of phase is presented. In other methods of dealing with this class of problems, the mass flux balance at the moving phase boundary requires explicit treatment of two distinct phases. The technique, originating from the apparent heat capacity method in transient heat conduction with the phase change, avoids the difficulty by transferring the concentration discontinuity at the boundary to smoothed physical property variations near the moving front. This technique accomodates the nonlinearities which preclude use of analytical solutions. It was tested against known analytical solutions for simple cases and turned out to be quite accurate.

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