• 제목/요약/키워드: Diffusion constant

검색결과 490건 처리시간 0.028초

종이내 수분확산 (제4보) - 종이의 비정상상태 수분확산 모델과 섬유상 수분확산 계수 - (Molecular Diffusion of Water in Paper (IV) - Mathematical model and fiber-phase moisture diffusivities for unsteady-state moisture diffusion through paper substrates -)

  • 윤성훈;박종문;이병철
    • 펄프종이기술
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    • 제34권3호
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    • pp.17-24
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    • 2002
  • An unsteady-state moisture diffusion through cellulosic fibers in paper was characterized from the moisture sorption experiment and the mathematical modeling. The sorption experiment was conducted by exposing thin dry paper specimens to a constant temperature-humidity environment. Oven dried blotting papers and filter papers were used as test samples and the gains of their weights were constantly monitored and recorded as a function of sorption time. For a mathematical approach, the moisture transport was assumed to be an one-dimensional diffusion in thickness direction through the geometrically symmetric structure of paper. The model was asymptotically simplified with a short-term approximation. It gave us a new insight into the moisture uptake phenomena as a function of square root of sorption time. The fiber-phase moisture diffusivities(FPMD) of paper samples were then determined by correlating the experimental data with the unsteady-state diffusion model obtained. Their values were found to be on the order of magnitude of $10^{-6}-10^{-7}cm^2$/min., which were equivalent to the hypothetical effective diffusion coefficients at the limit of zero porosity. The moisture sorption curve predicted from the model fairly agreed with that obtained from the experiment at some limited initial stages of the moisture uptake process. The FPMD value of paper significantly varied depending upon the current moisture content of paper. The mean FPMD was about 0.7-0.8 times as large as the short-term approximated FPMD.

다층 구조로부터 열 확산에 의한 $PbTiO_3$ 박막의 제조 (Formation of $PbTiO_3$ Thin Films by Thermal Diffusion from Multilayrs)

  • 서도원;최덕균
    • 한국세라믹학회지
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    • 제30권6호
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    • pp.510-516
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    • 1993
  • $PbTiO_3$ thin films have been formed by rapid thermal annealing(RTA) of $TiO_2$/Pb/$TiO_2$ multilayer films deposited on Si wafers by RF sputtering. Based on the optimal depositon conditions of TiO2 and Pb, $TiO_2$/Pb/$TiO_2$ three layers were deposited for 900$\AA$ each. These films were subjected to RTA process at the temperatures ranging from $400^{\circ}C$ to $900^{\circ}C$ for 30 seconds in air, and were analyzed by X-ray diffraction and transmission electron microscopy to investigate the phases and the microstructures. As a result, perovskite $PbTiO_3$ phases was obtained above $500^{\circ}C$ with the trace of unreacted $TiO_2$. RBS analysis revealed the anisotropic behavior of diffusion that the diffusivity of Pb to the bottom $TiO_2$ layer was faster than that of Pb to the top $TiO_2$ layer. The amorphous Pb-silicate was formed between film and Si substrate due to the diffusion of Pb, but Pb-silicate existed locally at the interface and the amount of that phase was very small. Therefore the effect of bottom $TiO_2$ layer as a diffusion barrier was confirmed. $PbTiO_3$ films formed by current technique showed a relative dielectric constant of 60, and the maximum breakdown field reached 170kV/cm.

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동전기 주입에 의한 점성토의 강도증가 특성 (Characteristic of Strength Increase in Clayey Soil by Electrokinetic Injection)

  • 김기년;김종윤;한상재;김수삼
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2005년도 춘계 학술발표회 논문집
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    • pp.910-915
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    • 2005
  • In this study a series of tests(bench scale test) are carried out for increasing in strength of clayey soil by EK-Injection method. In addition, the effects of strength increase in the treated sample are measured by operating the vane shear test device during 25 days at 5 days intervals in order to estimate the effect of ground improvement caused by diffusion. The test results show that the strength increase was developed approximately double to 7 times in comparison to initial shear strength, and outstanding strength increase was created as much as 7 times while injecting the sodium silicate and phosphoric acid in anolyte and catholyte. In addition, the measured shear strength with the influence of diffusion and reduction of water-content had a tendency to converge in constant value in proportion to elapsed time. As a result of this study, strength increment developed by the influence of EK-Injection and diffusion rather than the reduction of water-content were high as 1000% on average

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역확산 방정식을 이용한 영상복원 알고리즘 (Image Restoration Algorithm using Backward Diffusion Equation)

  • 이석호;최은철;강문기
    • 대한전자공학회논문지SP
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    • 제40권1호
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    • pp.34-42
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    • 2003
  • 본 논문은 영상복원을 역확산 과정으로 해석하여 복원된 영상을 역확산 방정식의 해로 구하는 알고리즘을 제안한다. 역확산 과정은 물리적으로 불량위치(ill-posed)과정이기 때문에, 이를 정규화 해주어야 하는데 이를 위해서 역확산 과정을 고유함수(eigenfunction)들의 전개로 나타낸 후에 고유함수들의 계수들을 조작하였다. 본 논문에서는 계수들을 조작할 때 영상이 가지고 있는 주파수 특성을 고려하여 한계주파수(cut-off frequency)를 넘은 경우에 계수들을 시간과 주파수의 감소함수로 나타내어 불량위치문제를 해결하였다. 계수를 주파수에 대찬 감소함수로 나타낸 것은 영상에 저주파 성분이 많고, 고주파 성분이 영상의 형성에 기치는 영향이 상대적으로 적다는 영상의 특성을 고려한 것이다. 이러한 감소함수를 사용하였을 때 불랑위치 문제를 해결할 수 있다는 것을 증명하였고, 실험적으로 양질의 영상을 산출함을 보였다.

확대유로내의 Bluff-Body 후류확산화염의 구조 및 특성 (1) (Structure and Characteristics of Diffusion Flame behind a Bluff-Body in a Divergent Flow(I))

  • 최병륜;이중성
    • 대한기계학회논문집
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    • 제19권5호
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    • pp.1269-1279
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    • 1995
  • An experimental study is carried out on turbulent diffusion flames stabilized by a circular cylinder in a divergent duct flow. A commercial grade gaseous propane is injected from two slits on the rod as fuel. Flame stability limits, as well as size and temperrature of recirculation zone, are measured by direct and schlieren photographs to clarify the characteristics and structure of diffusion flames and to assess the effect of various divergent angle of duct. The results of the present study are as follows. Temperature in the recirculation zone decreases with increasing divergent angle. The blow-off velocity in parallel duct is higher than that in divergent duct. Critical blow-off velocity is expected to be about 8-12 degree through blow-off velocity pattern. Regardless of divergent angles, the length of recirculation zone is nearly constant, and this length becomes longer with rod diameter. Pressure gradient has an effect on the eddy structure in shear layer behind the rod. With the increase of divergent angle, large scale eddies by dissipated energy in shear layer are split into small scale eddies, and the flame becomes a typical distributedreacting flame.

예혼합화염 영역에서 확산화염의 불안정성에 관한 연구 (Diffusion-flame instability in the premixed-flame regime)

  • 이수룡;김종수
    • 대한기계학회논문집B
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    • 제21권9호
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    • pp.1218-1229
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    • 1997
  • The diffusional-thermal instability of diffusion flames in the premixed-flame regime is studied in a constant-density two-dimensional counterflow diffusion-flame configuration, to investigate the instability mechanism by which periodic wrinkling, travelling or pulsating of the reaction sheet can occur. Attention is focused on flames with small departures of the Lewis number from unity and with small values of the stoichiometric mixture fraction, so that the premixed-flame regime can be employed for activation-energy asymptotics. Cellular patterns will occur near quasisteady extinction when the Lewis number of the more completely consumed reactant is less than a critical value( ~ =0.7). Parametric studies for the instability onset conditions show that flames with smaller values of the Lewis number and stoichiometric mixture fraction and with larger values of the Zel'dovich number tend to be more unstable. For Lewis number greater than unity, near-extinction flame are found to exhibit either travelling instability or pulsating instability.

Cu 금속배선을 위한 카본-질소-텅스텐 확산방지막 특성 (Characteristics of W-C-N Thin Diffusion Barrier for Cu Interconnection)

  • 이창우
    • 마이크로전자및패키징학회지
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    • 제12권4호통권37호
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    • pp.345-349
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    • 2005
  • 300 mW-cm의 낮은 비저항을 갖는 카본-질소$\_$텅스텐 (W-C-N) 확산방지막을 원자층 증착법으로 제조하였으며, 반응기체로 $WF_6-N_2-CH_4$를 사용하였다. $N_2$$CH_4$ 반응기체를 주입 할 때는 고주파 펄스를 인가하여 플라즈마에 의한 반응물의 분리가 일어나도록 하였다. 다층금속배선에 사용하는 층간 절연층 (TEOS) 위에서 W-C-N 박막은 원자층 증착기구를 따르며, 10에서 100 사이클 동안 증착율이 0.2nm/cycles 로 일정한 값을 가진다. 또한 Cu 배선을 위한 확산방지막으로써 W-C-N 박막은 비정질 상을 가지며, $800^{\circ}C$에서 30분간 열처리해도 Cu의 확산을 충분히 방지할 수 있음을 확인하였다.

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Coupled diffusion of multi-component chemicals in non-saturated concrete

  • Damrongwiriyanupap, Nattapong;Li, Linyuan;Xi, Yunping
    • Computers and Concrete
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    • 제11권3호
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    • pp.201-222
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    • 2013
  • A comprehensive simulation model for the transport process of fully coupled moisture and multi-species in non-saturated concrete structures is proposed. The governing equations of moisture and ion diffusion are formulated based on Fick's law and the Nernst-Planck equation, respectively. The governing equations are modified by explicitly including the coupling terms corresponding to the coupled mechanisms. The ionic interaction-induced electrostatic potential is described by electroneutrality condition. The model takes into account the two-way coupled effect of moisture diffusion and ion transport in concrete. The coupling parameters are evaluated based on the available experimental data and incorporated in the governing equations. Differing from previous researches, the material parameters related to moisture diffusion and ion transport in concrete are considered not to be constant numbers and characterized by the material models that account for the concrete mix design parameters and age of concrete. Then, the material models are included in the numerical analysis and the governing equations are solved by using finite element method. The numerical results obtained from the present model agree very well with available test data. Thus, the model can predict satisfactorily the ingress of deicing salts into non-saturated concrete.

확산 모형을 이용한 줄기 세포 기술의 수명 주기 분석 : 연구 단계를 중심으로 (Life Cycle Analysis of Stem Cell Technology Based on Diffusion Model : Focused on the Research Stage)

  • 장인영;홍정식;김태구
    • 대한산업공학회지
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    • 제41권5호
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    • pp.488-498
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    • 2015
  • Research on stem cells can be divided into three categories : pluripotent stem cell, adult stem cell, and induced pluripotent stem cell. Technology life cycle (TLC) on research stage is analyzed for the three stem cell categories based on diffusion model. Three diffusion models-logistic, Bass, and Bass model with integration constant (BMIC)-are applied to the number of articles related to each stem cell category in SCOPUS lists. Two different parameter estimation methods is used for each of logistic and Bass model. Results show that (1) the current year, 2015, lies in growth period at pluripotent stem cell and adult stem cell, and lies in growth period or maturity period at induced pluripotent stem cell. (2) Model fitness is the highest at BMIC model. (3) Imitation effect works best at the research area of induced pluripotent stem cell.

실리콘 이방성 식각을 통한 LCD 프리즘 시트 제작 연구 (A Study on Manufacturing of LCD Prism Sheets Through Silicon Anisotropic Etching)

  • 전광석;류근걸
    • 대한금속재료학회지
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    • 제46권6호
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    • pp.377-381
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    • 2008
  • Prism sheet of LCD BLU which depends on supply from Japan and U.S.A was studied by using Si anisotropic etching and injection molding technologies. First, the prism sheet was patterned on Si wafer through photolithography, and the best conditions of Si etching were determined through etching Si wafer with TMAH to obtain straight optimized zigzag patterns, and a cross pattern to provide light diffusion and concurrent focusing. The etch rate of TMAH was concluded to be constant for $25wt%-70^{\circ}C$ condition. Ni stamp of prism sheet was made by electrodeposition using patterned Si wafer, normal or fast H/C(Heating/Cooling) injections were carried out to fabricate prism sheet. It was known that fast H/C injection could fabricate prism sheet more accurately than normal injection. Zigzag patterns and the cross pattern showed higher transmissivity than the straight patterns because of light diffusion through diagonal direction. The fast H/C injection for zigzag patterns showed lower transmissivity than normal injection because there occurred more light diffusion through precise injection patterns, but the fast H/C injection for straight patterns showed only refraction without diffusion, causing lower transmissivity than normal injection.