• Title/Summary/Keyword: Diffusion constant

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Analysis of Chloride Ion Penetration for Harbor Concrete Structure with In-situation Environment (항만 콘크리트 구조물의 현장환경변화에 따른 염소이온 침투해석)

  • Han, Sang-Hun;Jang, In-Sung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.225-228
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    • 2004
  • In order to estimate the chloride ion penetration, the model, which considers diffusion and sorption, is proposed on the basis of Finite Element Method (FEM). The FEM program provides the estimation of chloride concentration according to cyclic humidity and sorption. After the humidity diffusion analysis is carried out, the chloride ion diffusion and sorption analysis are conducted on the basis of the preestimated humidity data in each element. Each element has different analysis variables at different ages and locations. At early ages and constant outer humidity, the difference between inner and outer relative humidity causes the chloride ion penetration by sorption. As the humidity diffusion reduces the difference with age, the effect of sorption on the chloride ion penetration decreases. By the way, the cyclic humidity increases the effect of sorption on the chloride ion penetration at early ages, and the quantity of chloride ion around steel at later ages. Therefore, the in-situ analysis of chloride ion penetration for marine concrete structures must be performed considering the cyclic humidity condition and the long term sorption.

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On the use of spectral algorithms for the prediction of short-lived volatile fission product release: Methodology for bounding numerical error

  • Zullo, G.;Pizzocri, D.;Luzzi, L.
    • Nuclear Engineering and Technology
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    • v.54 no.4
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    • pp.1195-1205
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    • 2022
  • Recent developments on spectral diffusion algorithms, i.e., algorithms which exploit the projection of the solution on the eigenfunctions of the Laplacian operator, demonstrated their effective applicability in fast transient conditions. Nevertheless, the numerical error introduced by these algorithms, together with the uncertainties associated with model parameters, may impact the reliability of the predictions on short-lived volatile fission product release from nuclear fuel. In this work, we provide an upper bound on the numerical error introduced by the presented spectral diffusion algorithm, in both constant and time-varying conditions, depending on the number of modes and on the time discretization. The definition of this upper bound allows introducing a methodology to a priori bound the numerical error on short-lived volatile fission product retention.

Dissolution of Chlorpheniramine Mallate (CMP) from Sustained-Release Tablets Containing CPM in the Coated Film Layer (핵정(核鐘)에 코팅된 필름층 중에 함유되어 있는 말레인산클로르페니라민의 방출특성)

  • Yu, Jei-Man;Shim, Chang-Koo;Lee, Min-Hwa;Kim, Shin-Keun
    • Journal of Pharmaceutical Investigation
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    • v.20 no.2
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    • pp.89-95
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    • 1990
  • Ethylcellulose-PEG 4000 film coated on core tablets was investigated as a potential drug delivery system for the controlled release of chlorpheniramine maleate (CPM). The kinetic analysis of the release data indicated that CPM release followed a diffusion-controlled model, where the quantity released per unit area is proportional to the square root of time. The effect of the film composition, CPM concentration, plasticizer concentration and CPM solubility on the release characteristics were examined. The release rate constant increased as CPM concentration increased. It also increased as the PEG 4000 content in the film increased above 10%(w/w), however, it decreased as the PEG 4000 content increased in the concentration range below 10%(w/w). The release rate constant was not affected by the coated weight on the core tablet. The film-coated tablets which contain CPM only in the coated film layer seemed to be a potential oral drug delivery system for the controlled release of CPM.

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FEYNMAN INTEGRALS, DIFFUSION PROCESSES AND QUANTUM SYMPLECTIC TWO-FORMS

  • Zambrini, Jean-Claude
    • Journal of the Korean Mathematical Society
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    • v.38 no.2
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    • pp.385-408
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    • 2001
  • This is an introduction to a stochastic version of E. Cartan′s symplectic mechanics. A class of time-symmetric("Bernstein") diffusion processes is used to deform stochastically the exterior derivative of the Poincare-Cartan one-form on the extended phase space. The resulting symplectic tow-form is shown to contain the (a.e.) dynamical laws of the diffusions. This can be regarded as a geometrization of Feynman′s path integral approach to quantum theory; when Planck′s constant reduce to zero, we recover Cartan′s mechanics. The underlying strategy is the one of "Euclidean Quantum Mechanics".

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GLOBAL ASYMPTOTIC STABILITY OF POSITIVE STEADY STATES OF AN n-DIMENSIONAL RATIO-DEPENDENT PREDATOR-PREY SYSTEM WITH DIFFUSION

  • Zhou, Jun
    • Bulletin of the Korean Mathematical Society
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    • v.50 no.6
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    • pp.1847-1854
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    • 2013
  • The main concern of this paper is to study the dynamics of an n-dimensional ratio-dependent predator-prey system with diffusion. We study the dissipativeness, persistence of the system and it is shown that the unique positive constant steady state is globally asymptotically stable under some assumptions.

The measurement of p-n junction depth by SEM

  • Hur, Chang-Wu;Lee, Kyu-Chung
    • Journal of information and communication convergence engineering
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    • v.5 no.4
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    • pp.324-327
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    • 2007
  • In this paper, the p-n junction depth with nondestructive method by using scanning electron microscopy (SEM) is determined and conformed. By measuring the critical short circuit current on the p-n junction which induced by electron beam and calculating generation range, the diffusion depth can be obtained. It can be seen that values destructively measured by constant angle lapping and nondestructively by this study almost concur. As this result, it is purposed that diffusion depth of p-n junction can be easily measured by nondestruction. This nondestructive method can be recommended highly to the industrial analysis.

The Temperature Dependence of the Diffusion Bonding Between Tungsten Carbides for Micro WC-PCD Tool Fabrication (초소형 초경 PCD Tool 제작을 위한 초경합금간 확산접합의 온도 의존성 연구)

  • Jeong, B.W.;Park, J.W.
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.22 no.5
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    • pp.812-817
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    • 2013
  • This study demonstrates the diffusion bonding process between a tungsten carbide shank (K30) and tungsten carbide (DX5) for micro WC-PCD tool fabrication. A type of nickel alloy was used as the filler met alto improve the bond ability between K30 and DX5. The bonding pressure, time, and surrounding conditions were kept constant. In particular, the normal pressure was controlled precisely under buckling analysis. Diffusion bonding was performed at various operation temperatures (1170-1770 K) by using a specially designed jig. The microstructure on the localized bonded surface was analyzed using scanning electron microscopy and optical microscopy. In the case of diffusion bonding of WCat 1370-1770K, the filler metal melted completely and diffused between the two base metals, and they were bonded more tightly on both sides than at temperatures below 1370 K. Our results demonstrated the importance of sensitive temperature dependence of diffusion bonding.

Treatment of Melamine by GAC Adsorption According to Adsorbent Size: Kinetics and Dispersion-Diffusion (흡착제 크기에 따른 GAC의 멜라민 흡착 처리 : 반응속도와 분산-확산)

  • Lee, Jai-Yeop;Lee, Sangjung;Han, Ihnsup
    • Journal of Soil and Groundwater Environment
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    • v.18 no.3
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    • pp.65-72
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    • 2013
  • Adsorption of melamine was examined using columns packed with granular activated carbon (GAC). Raw GAC was sieved with 20, 40, 60 and 80 mesh to determine the influence of adsorbent particle size on reaction and diffusion. The mass ratio of the adsorption capacity of GAC for melamine ranged from 9.19 to 11.06%, and adsorption rates increased with decreasing particle size within this range. Rate constants between 3.295 ~ 4.799 $min^{-1}$ were obtained using a pseudofirst-order equation that was used to determine adsorption kinetics. A surface diffusion model was adapted to take into account the unsteady-state equation of a spherical adsorbent by converting the surface concentration from a constant to a variable governed by a dispersion equation. The calculated values were fit with the experimental results by using the diffusion coefficients as regression parameters. The modified equation exhibited a more precise agreement with respect to the sum of the absolute error (SAE).

Development of the intermittency turbulence model for a plane jet flow (자유 평면 제트유동 해석을 위한 간혈도 난류모델의 개발)

  • 조지룡;정명균
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.11 no.3
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    • pp.528-536
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    • 1987
  • In a turbulent free shear flow, the large scale motion is characterized by the intermittent flow which arises from the interaction between the turbulent fluid and the irrotational fluid of the environment through the mean velocity gradient. This large scale motion causes a bulk convection whose effect is similar to the spatial diffusion process. In this paper, the total diffusion process is proposed to be approximated by weighted sum of the bulk convection due to the large scale motion and the usual gradient diffusion due to small scale motion. The diffusion term in conventional .kappa.-.epsilon. model requires on more equation of the intermittency transport equation. A production term of this equation means mass entrainment from the irrotational fluid to the turbulent one. In order to test the validity of the proposed model, a plane jet is predicted by this method. Numerical results of this model is found to yield better agreement with experiment than the standard .kappa.-.epsilon. model and Byggstoyl & Kollmann's model(1986). Present hybrid diffusion model requires further tests for the check of universality of model and for the model constant fix.