• Journal of Korea Foundry Society
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• v.2 no.3
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• pp.2-15
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• 1982

In this study, the influenced of graphite shape on the boriding of cast iron and boride structure was investigated. Gray cast iron, ferritic and pearlitic ductile cast iron were borided at 750,850,900 and $950^{\circ}C$ for 1,3 and 5 hours by powder pack method with the mixture of $B_4C_9\;Na_2B_4O_7$, $KBF_4$ and Shc. The boride layer was consisted of FeB(little), $Fe_2B$ (main) and graphite. Some possibility of the existence of unknown Fe-B-C compound in the boride layer was suggested. And precipitates in the diffusion zone was $Fe_3(B,C)$. The concentration of Si and precipitation of $Fe_3(B,C)$ in the ${\alpha}$ layer raised the hardness of this Zone. The depth and hardness of boride layer increased with the increase of treating temperature and tim. But high temperature (over $950^{\circ}C)$ caused pore at graphite position and long treating time (5hrs) sometimes caused formation of graphite layer beneath the boride layer. So, for the practical application of borided cast iron, treating in short time and at low temperature was recommended. And for ductile cast iron, ferritizing or pearlitizing heat treatment was seemmed to be possible at the same time with boriding. The graphite in the boride layer was deeply concerned with the qualitx and characteristics of the boride layer. And it greatly influenced on the shape of the boride phase, structure of the boride layer. Generally speaking, the existance of graphite restrained the growth of the boride phase. But the boundary between the gsaphite and the matrix acted as the shortcut of boron diffusion. So, for gray cast iron, the graphite layed length-wise led the formation of boride layer.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.11 no.1
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• pp.21-31
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• 1985

The effect of dispersed phase on the stability of emulsion system with polyoxyethylene dodecyl ethers and their variation of ethylene oxide moles was studied by such methods as interfacial tension measurement, centrifugation and droplet size variation with time. The experiments showed that, in interfacial tension measurement, long chain alkanols into dispersed phaes are more effectively adsorbed onto interface, while long chain alkanes nearly not, and in centrifugation, dispersed phase with alkanols is less separated than that with alkanes. On the other hand, alkanes help more stabilyzing emulsion than alkanols in droplet size variation. And the addition of NaCl or Urea, and variation of E.O. moles have very slight effects on the stability with alkanes than with alkanols. Moreover, the longer carbon chain length is, dispersed phase is more effective on emulsion stability. Supposed from these facts is that more stable emulsion can be made with alkanes which retard molecular diffusion by water solubility decrease rather than alkanols which raise resistance to coalescence by rigid interfacial mixed monolayers formation. In conclusion, the stabilities of these emulsions are proved to be more influenced by molecular diffusion than coalescence.

• Journal of the Korean Vacuum Society
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• v.7 no.2
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• pp.77-81
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• 1998

The eptiaxial growth of Ge on the clean and surfactant (Sn) adsorbed surface of Ge(111) was studied by the intensity oscillation of a RHEED specular spot. In the case of epitaxial growth without the adsorbed surfactant, the RHEED intensity oscillation was stable and periodic up to 24 ML at the substrate temperature of $200^{\circ}C$. Therefore the optimum temperature for the epitaxial growth of Ge on clean Ge(111) seems to be $200^{\circ}C$. However, in the case of epitaxial growth with the adsorbed surfactant, the irregular oscillations are observed in the early stage of the growth. The RHEED intensity osicillation was very stable and periodic up to 38 ML, and the d2$\times$2 structure was not charged with continued adsorption of Ge at the substrate temperature of 2002$\times$2. These results may be explained by the fact that the diffusion length of Ge atoms is increased by decreasing the activation energy of the Ge surface diffusion, resulted by segregation of Sn toward the growing surface.

• Nuclear Engineering and Technology
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• v.54 no.7
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• pp.2367-2375
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• 2022

In this work, we propose a new mechanistic model for the treatment of helium behaviour at the grain boundaries in oxide nuclear fuel. The model provides a rate-theory description of helium inter-granular behaviour, considering diffusion towards grain edges, trapping in lenticular bubbles, and thermal resolution. It is paired with a rate-theory description of helium intra-granular behaviour that includes diffusion towards grain boundaries, trapping in spherical bubbles, and thermal re-solution. The proposed model has been implemented in the meso-scale software designed for coupling with fuel performance codes SCIANTIX. It is validated against thermal desorption experiments performed on doped UO₂ samples annealed at different temperatures. The overall agreement of the new model with the experimental data is improved, both in terms of integral helium release and of the helium release rate. By considering the contribution of helium at the grain boundaries in the new model, it is possible to represent the kinetics of helium release rate at high temperature. Given the uncertainties involved in the initial conditions for the inter-granular part of the model and the uncertainties associated to some model parameters for which limited lower-length scale information is available, such as the helium diffusivity at the grain boundaries, the results are complemented by a dedicated uncertainty analysis. This assessment demonstrates that the initial conditions, chosen in a reasonable range, have limited impact on the results, and confirms that it is possible to achieve satisfying results using sound values for the uncertain physical parameters.

• Journal of Electrochemical Science and Technology
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• v.13 no.4
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• pp.438-452
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• 2022

For cuboid and ellipsoid crystallites of LiFePO₄ powders, by X-ray diffraction (XRD) and microscopic (TEM) studies, it is possible to determine the anisotropic parameters of the crystallite size distribution functions. These parameters were used to describe the cathode rate capability within the model of averaging the diffusion coefficient D over the length of the crystallite columns along the [010] direction. A LiFePO₄ powder was chosen for testing the developed model, consisting of big cuboid and small ellipsoid crystallites (close to them). When analyzing the parts of big and small rate capabilities, the fitting values D = 2.1 and 0.3 nm²/s were obtained for cuboids and ellipsoids, respectively. When analyzing the results of cyclic voltammetry using the Randles-Sevcik equation and the total area of projections of electrode crystallites on their (010) plane, slightly different values were obtained, D = 0.9 ± 0.15 and 0.5 ± 0.15 nm²/s, respectively. We believe that these inconsistencies can be considered quite acceptable, since both methods of determining D have obvious sources of error. However, the developed method has a clearly lower systematic error due to the ability to actually take into account the shape and statistics of crystallites, and it is also useful for improving the accuracy of the Randles-Sevcik equation. It has also been demonstrated that the shape engineering of crystallites, among other tasks, can increase the cathode capacity by 15% by increasing their size correlation coefficients.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.28 no.1B
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• pp.137-147
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• 2008

Soil Vapor Extraction (SVE) has been extensively used to remove volatile organic compounds (VOCs) from the vadoze zone. In order to investigate the removal mechanism during SVE operation, laboratory modeling experiments were carried out and tailing effect could be observed in later stage of the experiment. Tailing effect means that removal rate of contaminants gets significantly to decrease in later stage of SVE operation. Also, mathematical model simulating the tailing effect was used, which considers rate-limited diffusion in a water film during mass transfer among gas, liquid, and solid phases. Measurement data obtained through the experiment was used as input data of the numerical analyses. Sensitivity analysis was performed to examine the effect of each parameter on required time to reach final target concentration. Finally, it was found that the concentration in the soil phase decreased significantly with a liquid and gas diffusion coefficient larger, actual path length shorter, and water saturation smaller.

• Journal of the Korean GEO-environmental Society
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• v.10 no.1
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• pp.5-14
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• 2009

This study is to analyze numerically the spatial behaviors of the solute transport in a spatially correlated variable-aperture fracture under the effective normal stress conditions. Numerical results show that the solute transport in a fracture is strongly affected by the spatial correlation length of apertures and applied effective normal stress. According to increasing spatial correlation length, the mean residence time of solute is decreased and the tortuosity and Peclet number (is a dimensionless number relating the rate of advection of a flow to its rate of diffusion) is also decreased. These results mean that the geometry of the aperture distribution is favorable to the solute transport as the spatial correlation length is increased. However, according to the applied effective normal stress is increased, the mean residence time and tortuosity have a tendency to increase but the Peclet number is decreased. The main reason that the Peclet number is decreased, is that the solute is displaced by one or two channels with relatively higher local flow rate due to the increment of contact areas by increasing effective normal stress. Moreover, based on numerical results of the solute transport in this study, the exponential-type correlation formulae between the mean residence time and the effective normal stress are proposed.

• Journal of Navigation and Port Research
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• v.33 no.3
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• pp.167-174
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• 2009

Recently, design technology of has been required such as catamaran yacht with high-speed according to expand a marine leisure industry. The domestic technical development for design and production of yacht is not actively than Canada, USA, Japan etc. However, with further development of yacht design & technology, it is need to develop a key technology related to increase the value of catamaran yacht. In the present paper, new guideline is suggest for catamaran yacht as like kinds of marine leisure ship in order for fundamental structure design and structural analysis for twin-hulled ship yacht and techniques for structural analysis as sea leisure ship in this research. The class of society has not been proposed formally about regulation and methodology for estimation of strength of small hight-speed craft with satisfying two conditions as noted; length less than 50meters, ratio of length to breadth less than 12. In the present study, we were adopted DNV (Yachts, Design Principles, Design Loads, Hull Structural Design) Rule and KR (FRP rule application guide) for scantling of structural members. Furthermore, ABS rule is used for structural calculation about application of loading conditions for catamaran yacht. This study can be available feedback role to manufacture of 38ft diffusion style for catamaran yacht. It is expected that this study will be a good reference in order to design of catamaran yacht with high-speed.

• Nuclear Engineering and Technology
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• v.25 no.4
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• pp.539-547
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• 1993

A stochastic approach using continuous time Markov process is presented to model the one-dimensional nuclide transport in fractured rock media as a further extension for previous works［1-3］. Nuclide transport of decay chain of arbitrary length in the single planar fractured rock media in the vicinity of the radioactive waste repository is modeled using a continuous time Markov process. While most of analytical solutions for nuclide transport of decay chain deal with the limited length of decay chain, do not consider the case of having rock matrix diffusion, and have very complicated solution form, the present model offers rather a simplified solution in the form of expectance and its variance resulted from a stochastic modeling. As another deterministic way, even numerical models of decay chain transport, in most cases, show very complicated procedure to get the solution and large discrepancy for the exact solution as opposed to the stochastic model developed in this study. To demonstrate the use of the present model and to verify the model by comparing with the deterministic model, a specific illustration was made for the transport of a chain of three member in single fractured rock medium with constant groundwater flow rate in the fracture, which ignores the rock matrix diffusion and shows good capability to model the fractured media around the repository.

• Korean Chemical Engineering Research
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• v.50 no.6
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• pp.969-979
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• 2012

In this study, the effects of cosurfactant on phase equilibrium and dynamic behavior were studied in systems containing nonylphenol ethoxylate (NP) surfactant solutions and nonpolar hydrocarbon oils. All the cosurfactants used during this study such as n-pentanol, n-octanol and n-decanol acted as a hydrophobic additive and the hydrophobic effect was found to increase with both increases in chain length and amount of addition of a cosurfactant. Dynamic behavior studies under hydrophilic conditions showed that the solubilization of hydrocarbon oil by NP micellar solution is controlled by an interface-controlled mechanism rather than a diffusion-controlled mechanism. Both spontaneous emulsification of water into oil phase and expansion of oil drop were observed under lipophilic conditions because of diffusion of surfactant and water into oil phase. Under conditions of a three phase region including a middle-phase microemulsion, both rapid solubilization and emulsification of oil into aqueous solutions were found mainly due to the existence of ultralow interfacial tension.