• Title/Summary/Keyword: Diffusion Angle

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Properties of Glass-Ceramics in the System CaO-TiO2-SiO2 with the Additives of Al2O3, ZrO2 and B2O3 for Use in the Solid Oxide Fuel Cells.

  • Lee, Jun-Suk;Park, Min-Jin;Shin, Hyun-Ick;Lee, Jae-Chun
    • The Korean Journal of Ceramics
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    • v.5 no.4
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    • pp.336-340
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    • 1999
  • Glasses in the system $CaO-TiO_2-SiO_2-Al_2O_3-ZrO_2-B_2O_3$ were investigated to find the glass seal compositions suitable for use in the planar solid oxide fuel cell (SOFC). Glass-ceramics prepared from the glasses by one-stage heat treatment at $1,000^{\circ}C$ showed various thermal expansion coefficients (i,e., $8.6\times10^{-6^{\circ}}C^{-1}$ to $42.7\times10^{-6^{\circ}}C^{-1}$ in the range 25-$1,000^{\circ}C$) due to the viscoelastic response of glass phase. The average values of contact angles between the zirconia substrate and the glass particles heated at 1,000-$1,200^{\circ}C$ were in the range of $131^{\circ}\pm4^{\circ}$~$137^{\circ}\pm9^{\circ}$, indicating that the glass-ceramic was in partial non-wetting condition with the zirconia substrate. With increasing heat treatment time of glass samples from 0.5 to 24 h at $1,100^{\circ}C$, the DC electrical conductivity of the resultant glass-ceramics decreased from at $800^{\circ}C$. Isothermal hold of the glass sample at $1100^{\circ}C$ for 48h resulted in diffusion of Ca, Si, and Al ions from glass phase into the zirconia substrate through the glass/zirconia bonding interface. Glass phase and diffusion of the moving ion such as $Ca^{2+}$ in glass phase is responsible for the electrical conduction in the glass-ceramics.

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A study on the spray characteristics of a coaxial nozzle by LDV measurement (LDV계측에 의한 동축노즐의 분무특성 연구)

  • 윤석주;노병준
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.14 no.6
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    • pp.1613-1620
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    • 1990
  • For the purpose of the study on the spray characteristics of a coaxial nozzle, the measurement of the velocity and size of droplets, concentration, and the statistical correlation coefficient between the fluctuation of the velocity and that of the corresponding drop diameter have been carried out. Various method of simultaneous measurement of velocity and drop size have been developed from LDV techniques. The technique used here belongs to the method that supposed by Yule, Holve and Self. It has the advantages of making use of a standard LDV apparatus to which minor modifications have been brought, photomultiplier is equipped with a slit instead of a pinhole and observed the measuring volume at an angle of 90.deg.. The voltage supplied by the photomultiplier has undergone an appropriate analog and digital processing. The experimental results give a good idea of the two phase flow organization and can be helpful to find a drop diffusion model when suitable data are imput.

Improving the Color Gamut of a Liquid-crystal Display by Using a Bandpass Filter

  • Sun, Yan;Zhang, Chi;Yang, Yanling;Ma, Hongmei;Sun, Yubao
    • Current Optics and Photonics
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    • v.3 no.6
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    • pp.590-596
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    • 2019
  • To improve the color gamut of a liquid-crystal display (LCD), we propose a bandpass filter that is added to the backlight unit to optimize the backlight spectrum. The bandpass filter can only transmit red, green and blue light in the visible range, while reflecting the unwanted light. We study the optical properties of the bandpass filter using the transfer-matrix method, and the effect of the bandpass filter on the color gamuts of LCDs is also investigated. When a bandpass filter based on a 5-layer configuration comprising low and high refractive indices ((HL)2H) is used in phosphor-converted white-light-emitting diode (pc-WLED), K2SiF6:Mn4+ (KSF-LED), and quantum-dot (QD) backlights, the color gamuts of the LCDs improve from 72% to 95.3% of NTSC, from 92% to 106.7% of NTSC, and from 104.3% to 112.2% of NTSC respectively. When the incident angle of light increases to 30°, the color gamuts of LCDs with pc-WLED and KSF-LED backlights decrease by 2.9% and 1% respectively. For the QD backlight, the color gamut almost does not change. When the (HL)2H structure is coated on the diffusion film, the color gamut can be improved to 92.6% of NTSC (pc-WLED), 105.6% of NTSC (KSF-LED), and 111.9% of NTSC (QD). The diffusion film has no obvious effect on the color gamut. The results have an important potential application in wide-color-gamut LCDs.

Reset-first Resistance Switching Mechanism of HfO2 Films Based on Redox Reaction with Oxygen Drift-Diffusion

  • Kim, Jong-Gi;Lee, Sung-Hoon;Lee, Kyu-Min;Na, Hee-Do;Kim, Young-Jae;Ko, Dae-Hong;Sohn, Hyun-Chul
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.286-287
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    • 2012
  • Reset-first resistive switching mechanism based on reduction reaction in HfO2-x with oxygen drift-diffusion was studied. we first report that the indirect evidence of local filamentary conductive path formation in bulk HfO2 film with local TiOx region at Ti top electrode formed during forming process and presence of anion-migration at interface between electrode and HfO2 during resistive switching through high resolution transmission electron microscopy (HRTEM), electron disperse x-ray (EDX), and electron energy loss spectroscopy (EELS) mapping. Based on forming process mechanism, we expected that redox reaction from Ti/HfO2 to TiOx/HfO2-x was responsible for an increase of initial current with increasing the post-annealing process. First-reset resistive switching in above $350^{\circ}C$ annealed Ti/HfO2 film was exhibited and the redox phenomenon from Ti/HfO2 to TiOx/HfO2-x was observed with high angle annular dark field (HAADF) - scanning transmission electron microscopy (STEM), EDX and x-ray photoelectron spectroscopy. Therefore, we demonstrated that the migration of oxygen ions at interface region under external electrical bias contributed to bipolar resistive switching behavior.

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Variations of Magnetic Properties and Composition with Deposition Ratio in GdFe Thin film (GdFe 박막의 증착속도에 따른 조성 및 자기특성의 변화)

  • Choe, Yeong-Geun;Park, Chang-Man;Baek, Ju-Yeol;Lee, Gi-Am;Hwang, Do-Geun
    • Journal of the Korean Magnetics Society
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    • v.2 no.3
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    • pp.257-262
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    • 1992
  • We have studied the variations of composition and magnetic properties with deposition rate in GdFe thin films by means of DC magnetron sputtering with the enhanced complex target method. Gd atomic percent was decreased with the increase of deposite rate. It appeared the transition phenomena at 1.0 ${\AA}/s the deposition rate. Also, the deposition rate increased with input power and the sputtering efficience was proportional to the number of Gd chip. An increase of the coercivity with input power can be interpreted by the large size of Fe crystal grains. We have introduced by the diffusion guard sputtering and it was effective for reproducibility of the sample. We have measured ${\theta}_k$ with Kerr angle gauge, and could observe that the ${\theta}_k$ was little varied with input power.

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MAS-NMR Studies in Mixed Alkali Silicate Glasses with low Fe2O3 Content (미소량의 Fe2O3를 첨가시킨 혼합 알칼리 Silicate 유리들의 MAS-NMR 연구)

  • Kang, Myoung-Jin;Shim, Moon-Sik
    • Journal of Korean Ophthalmic Optics Society
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    • v.1 no.1
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    • pp.1-14
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    • 1996
  • The mixed alkali silicate glasses doped 0.1 mol% $Fe_2O_3$ are fabricated for studying the effect of transition metal oxides, which is related to the $Li^-$ ion movement in Magic-Angle-Spinning NMR. We have investigated the spin-lattice relaxation times in the room temperature and measured the $^7Li$ MAS-NMR spectrum with temperature. When the $Fe_2O_3$ oxides are added in alkali silicate glasses, the width of spectrum is changed a little but the line shape is hardly varied. For this reason, we can think that the mixed alkali effects are shown sufficiently in the spin-spin relaxation processes. However, it is not mixed alkali effects in this case. The activation energy of $Li^-$ ions are diminished in mixed alkali glasses. From the analysis of $Li^-$ diffusion environment, spin-lattice relaxation time and the nuclear magnetization, it is confirmed that the alkali mixed effects are not shown in $^7Li$ spin-lattice relaxation processes.

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Near-field Optical Lithography for High-aspect-ratio Patterning by Using Electric Field Enhanced Postexposure Baking (전기장이 적용된 노광후굽기 공정에 의한 고종횡비 근접장 광 리소그래피)

  • Kim, Seok;Jang, Jin-Hee;Kim, Yong-Woo;Jung, Ho-Won;Hahn, Jae-Won
    • Korean Journal of Optics and Photonics
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    • v.21 no.6
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    • pp.241-246
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    • 2010
  • In this paper, we propose an electric field enhanced postexposure baking (EFE-PEB) method to obtain deep and high aspect ratio pattern profile in near-field recording. To describe the photoacid distribution under an external electric field during the PEB, we derived the governing equations based on Fick's second law of diffusion. From the results of the numerical calculations, it is found that the vertical movement of photoacid increases while the lateral movement is stationary as electric field varies from 0 to $8.0{\times}10^6\;V/m$. Also, it is proven that the profile of near-field recording is improved by using the EFE-PEB method with increased depth, higher aspect ratio and larger sidewall angle.

Sensitivity Analysis of RMA2 Model Parameter Variation with Hydraulic Characteristics of Stream Junction Area (하도 합류부의 수리학적 특성을 고려한 RMA2 모형 매개변수의 민감도 분석)

  • Ahn, Seung-Seop;Yim, Dong-Hee;Seo, Myung-Joon;Lee, Hyo-Jung
    • Journal of Environmental Science International
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    • v.17 no.7
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    • pp.783-793
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    • 2008
  • The purpose of this study is to analyze the sensitivity of the RMA2 model parameters reflecting the flow characteristics of stream junction and thus understand the hydraulic characteristics of the channel confluence flow. This study dealt with the input parameters of the RMA-2 model, a two-dimensional numerical analysis model widely used for researches both at home and abroad. The parameters of the RMA-2 model are roughness coefficient, turbulent diffusion coefficient, Coriolis forces latitude, Density, and mesh size. This study those parameters estimated from actual heavy rainfall, and varied the parameter size by (-)30%${\sim}$+30% to review the characteristics of the flow characteristics of the channel section. Weobserved that when the ratio of the channel width was relatively small, the smaller the approaching angle was, the farther from the junctions became the generating place of the maximum flow velocity, however, when the ratio of the channel width was relatively large, the larger the approaching angle was, the farther the generating place of the maximum flow velocity from the junctions became. In particular, the distance between junctions and the place where the maximum flow velocity generated showed an absolute correlationover 90% of the relative channel width, but an inverse relationwas found when the distance to the place where the flow velocity generated was shortened as relative the channel width between the main channel and tributary increased.

A Study on Nozzle Performance Influence with Aft-deck Geometry (Aft-deck 형상에 의한 노즐 성능 영향성 연구)

  • Lee, Changwook;Park, Youngseok;Jin, Juneyub;Kim, Jaewon;Choi, Seong Man
    • Journal of the Korean Society of Propulsion Engineers
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    • v.25 no.2
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    • pp.42-54
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    • 2021
  • The Aft-deck is being applied to the latest unmanned aircraft for the purpose of shielding the gas turbine exhaust plume or spreading jets to increase the mixing rate with the ambient air, thereby reducing the temperature of exhaust gases. In this study, we would like to find out how the performance of the nozzle is affected by the design variables of the Aft-deck. The design variables of aft-deck are selected as length, expansion angle and upper deck shape. The correlation between thrust and plume shielding rate with the length variable is presented. And the correlation between the thrust and the jet diffusion range is presented according to the expansion angle. In addition, the thrust increase effect is confirmed by the removal of the upper deck and the characteristics of transverse velocity vector determined mixing performance with external flow.

Preparation of diffusion dialysis membrane for acid recovery via a phase-inversion method

  • Khan, Muhammad Imran;Wu, Liang;Hossain, Md. Masem;Pan, Jiefeng;Ran, Jin;Mondal, Abhishek N.;Xu, Tongwen
    • Membrane and Water Treatment
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    • v.6 no.5
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    • pp.365-378
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    • 2015
  • Herein, the preparation of anion exchange membrane (AEM) from brominated poly(2,6-dimethyl 1,6-phenylene oxide) BPPO and dimethylaniline (DMA) by phase-inversion process is reported. Anion exchange membranes (AEMs) are prepared by varying the DMA contents. Prepared AEMs show high thermal stability, water uptake (WR) around 202% to 226%, dimensional change ratios of 1.5% to 2.6% and ion exchange capacities (IECs) of 0.34 mmol/g to 0.82 mmol/g with contact angle of $59.18^{\circ}$ to $65.15^{\circ}$. These membranes are porous in nature as confirmed by SEM observation. The porous property of membranes are important as it could reduce the resistance of transportation of ions across the membranes. They have been used in diffusion dialysis (DD) process for recovery of hydrochloric acid (HCl) from the mixture of HCl and ferrous chloride ($FeCl_2$). Presence of $-N+(CH_3)_2C_6H_5Br^-$ as a functional group in membrane matrix facilitates its applications in DD process. The dialysis coefficients of hydrochloric acid ($U_H$) of the membranes are in range of 0.0016 m/h to 0.14 m/h and the separation factors (S) are in range of 2.09 to 7.32 in the $HCl/FeCl_2$ system at room temperature. The porous membrane structure and presence of amine functional group are responsible for the mechanism of diffusion dialysis (DD).