• Title/Summary/Keyword: Diffraction and scattering

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Geometrical and Electronic Structure of Epitaxial Graphene on SiC(0001) : A Scanning Tunneling Microscopy Study

  • Ha, Jeong-Hoon;Yang, Hee-Jun;Baek, Hong-Woo;Chae, Jung-Seok;Hwang, Beom-Yong;Kuk, Y.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.368-368
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    • 2010
  • Monolayers of graphite can be grown by fine controlled surface graphitization on the surfaces of various metallic and semiconducting materials. Epitaxial graphene grown on polished silicon carbide crystal surfaces has drawn much attention due to well known vacuum annealing procedures from surface analysis methods, especially scanning tunneling microscopy(STM) and scanning tunneling spectroscopy(STS). In this study, we have grown single layer and few layer graphene on silicon terminated 6H-SiC(0001) crystals. The growth of graphene layers were observed by low energy electron diffraction(LEED) patterns. Scanning tunneling microscopy and spectroscopy measurements were performed to illustrate the electronic structure which may display some clue on the influence of the underlying structure. Spatially resolved STS results acquired at the edges of epitaxial graphene show in detail the electron density of states, which is compared to theoretical calculations. STM measurements were also done on graphene films grown by chemical vapor deposition(CVD) and transferred onto a SiC(0001) crystal. These observations may provide a hint for the understanding of carrier scattering at the edges.

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Preparation and characterization of rutile phase TiO2 nanoparticles and their cytocompatibility with oral cancer cells

  • Vu, Phuong Dong;Nguyen, Thi Kieu Trang;Yoo, Hoon
    • International Journal of Oral Biology
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    • v.44 no.3
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    • pp.108-114
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    • 2019
  • In the present study, rutile phase titanium dioxide nanoparticles ($R-TiO_2$ NPs) were prepared by hydrolysis of titanium tetrachloride in an aqueous solution followed by calcination at $900^{\circ}C$. The composition of $R-TiO_2$ NPs was determined by the analysis of X-ray diffraction data, and the characteristic features of $R-TiO_2$ NPs such as the surface functional group, particle size, shape, surface topography, and morphological behavior were analyzed by Fourier-transform infrared spectroscopy, scanning electron microscopy and energy dispersive X-ray spectroscopy, transmission electron microscopy, dynamic light scattering, and zeta potential measurements. The average size of the prepared $R-TiO_2$ NPs was 76 nm, the surface area was $19m^2/g$, zeta potential was -20.8 mV, and average hydrodynamic diameter in dimethyl sulfoxide (DMSO)-$H_2O$ solution was 550 nm. The 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MTT) assay and morphological observations revealed that $R-TiO_2$ NPs were cytocompatible with oral cancer cells, with no inhibition of cell growth and proliferation. This suggests the efficacy of $R-TiO_2$ NPs for the aesthetic white pigmentation of teeth.

Canna edulis Leaf Extract-Mediated Preparation of Stabilized Silver Nanoparticles: Characterization, Antimicrobial Activity, and Toxicity Studies

  • Otari, S.V.;Pawar, S.H.;Patel, Sanjay K.S.;Singh, Raushan K.;Kim, Sang-Yong;Lee, Jai Hyo;Zhang, Liaoyuan;Lee, Jung-Kul
    • Journal of Microbiology and Biotechnology
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    • v.27 no.4
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    • pp.731-738
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    • 2017
  • A novel approach to synthesize silver nanoparticles (AgNPs) using leaf extract of Canna edulis Ker-Gawl. (CELE) under ambient conditions is reported here. The as-prepared AgNPs were analyzed by UV-visible spectroscopy, transmission emission microscopy, X-ray diffraction, Fourier transform-infrared spectroscopy, energy-dispersive analysis of X-ray spectroscopy, zeta potential, and dynamic light scattering. The AgNPs showed excellent antimicrobial activity against various pathogens, including bacteria and various fungi. The biocompatibility of the AgNPs was analyzed in the L929 cell line using NRU and MTT assays. Acridine orange/ethidium bromide staining was used to determine whether the AgNPs had necrotic or apoptotic effects on L929 cells. The concentration of AgNPs required for 50% inhibition of growth of mammalian cells is far more than that required for inhibition of pathogenic microorganisms. Thus, CELE is a candidate for the eco-friendly, clean, cost-effective, and nontoxic synthesis of AgNPs.

Evolution of Crystal Structure by Post-extension in Nylon 56 Fibers (연신에 따른 나일론 56 섬유의 결정 구조 및 수소결합 변화)

  • Jo, Kuk Hyun;Cho, Jung Hyeong;Kim, Hyo Jung;Lee, Hyun Hwi
    • Textile Coloration and Finishing
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    • v.28 no.1
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    • pp.33-39
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    • 2016
  • The crystal structure of nylon 56 fibers post extended by drawing process was investigated by synchrotron x-ray scattering measurement. In as-cast fiber, distinct (004) and (020) diffraction peaks were observed and they were related to initial metastable alignment of nylon molecules. With increase in the drawing ratio, (110) peak intensity was increased in vertical direction with decreasing (020) peak. At the same time, (004)' peak evolved position tilted to 29 degrees from the (004) peak. This evolution is directly related to stable crystalline phase of nylon 56 originated from additional formation of hydrogen bondings between N-H and C=O by post drawing process. We also compared density variation, stress-strain curves of the fiber as a function of drawing ratio and strain. The variations of density and tanacity also supported the increase of stable structure of nylon 56.

Effects of Wave Dissipation with Circular Cylinders (원형파일군에 의한 파랑제어 특성)

  • Lee, Seong-Dae;Kim, Seong-Deuk
    • Journal of Ocean Engineering and Technology
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    • v.22 no.4
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    • pp.27-33
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    • 2008
  • One of the central problems in astudy of the coastal surface wave environment is predicting the transformation of waves as they propagate toward the shore. The transformation is mainly due to the existence of obstacles, such as breakwaters and vertical cylinders. In general, the types of wave transformation can be classified as follows: wave diffraction, reflection, transmission, scattering, radiation, et al. This research dealtwith wave transmission and dissipation problems for two dimensional irregular waves and vertical circular cylinders. Using the unsteady mild slope equation, a numerical model was developed to calculate the reflection and transmission of regular waves from a multiple-row circular breakwater and vertical cylinders. In addition, hydraulic model experiments were conducted with different values for the properties between tire piles and the opening ratio (distances) between the rows of the breakwater. It was found that the transmission coefficients decreased with a decrease in the opening ratio and an increase in the rows of vertical cylinders. A comparison between the results of hydraulic and numerical experiments showed reasonable agreement.

A Study on the Type of Light in Fashion Design (패션디자인에 활용된 빛의 유형 분석)

  • Jung, Hyun;Geum, Key-Sook
    • Journal of the Korean Society of Costume
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    • v.58 no.2
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    • pp.120-133
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    • 2008
  • The purpose of this study is to analysis types of light and to find the characteristics of light in contemporary fashion design. In a scientific context, light is electromagnetic radiation of a wavelength that has the characteristics of straightness, reflection, refraction, scattering and diffraction. But in philosophical speculations, light has been used as a metaphor of 'being', 'to-be' or 'enlightenment.' And through the ages, people have tried to represent and apply the light into plastic art like painting and architecture. The types of light in fashion design was categorized as those; reflective light from the surface of clothing which is the result of interaction between illumination and material, representative light as the pattern of light or light effect such as sun or its rays and optical or psychedelic patterns, luminescent light from light emitting material like phosphorescence or LED which combines into fashion design, projective light from a medium to reveal virtual patterns on the surface or a fashion design itself using holography. These lights in fashion design can be considered as reflection of emphasis of sexuality, longing for fantasy and mystique, visualization of interaction and communication and groping for the play.

Recovery of Copper Powder form MoO3 Leaching Solution Using Cementation Reaction System (MoO3 침출공정 폐액으로부터 치환반응 시스템을 이용한 구리 분말 회수에 대한 연구)

  • Kim, Geon-Hong;Hong, Hyun-Seon;Jung, Hang-Chul
    • Journal of Powder Materials
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    • v.19 no.6
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    • pp.405-411
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    • 2012
  • Recovery of copper powder from copper chloride solution used in $MoO_3$ leaching process was carried out using a cementation method. Cementation is a simple and economical process, necessitating less energy compared with other recovery methods. Cementation utilizes significant difference in standard reduction potential between copper and iron under standard condition. In the present research, Cementation process variables of temperature, time, and added amount of iron scraps were optimized by using design of experiment method and individual effects on yield and efficiency of copper powder recovery were investigated using bench-scale cementation reaction system. Copper powders thus obtained from cementation process were further characterized using various analytical tools such as XRF, SEM-EDS and laser diffraction and scattering methods. Cementation process necessitated further purification of recovered copper powders and centrifugal separation method was employed, which successfully yielded copper powders of more than 99.65% purity and average $1{\mu}m$ in size.

Field Strength Prediction Program Using Terrain and Land Usage Data for Cheju (제주의 지형 및 토지이용 데이터를 이용한 전계강도 예측 프로그램)

  • 홍성욱;김흥수
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.9 no.6
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    • pp.824-832
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    • 1998
  • The significant additional path loss is caused by scattering, diffraction, and attenuation of propagation. Most of the wave propagation models for rural areas mainly have considered the influence of topography but ignored the effects due to land usage. The goal of this paper is development of the field strength prediction program for Cheju which is used the contour map and the effects due to land usage. In oder to classify the propagation path and divide the environment of land, data of the terrain and the land-cover are formed into a pixel. Two-ray model is transformed into equivalent model by the predicted reflection coefficient and the slope of terrain. For non line of sight, the additional loss is determined by quantitative analysis. The result show good accord and the wave propagation model program can be applied to predicted the service region in rural area of Cheju.

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Epitaxy of Si and Si1-xGex(001) by ultrahigh vacuum ion-beam sputter deposition

  • Lee, N. E.;Greene, J. E.
    • Journal of Korean Vacuum Science & Technology
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    • v.2 no.2
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    • pp.107-117
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    • 1998
  • Epitaxial undoped and Sb-doped si films have been grown on Si(001) substrates at temperatures T between 80 and 750$^{\circ}C$ using energetic Si in ultra-high-vacuum Kr+-ion-beam sputter deposition(IBSD). Critical epitaxial thicknesses te, The average thickness of epitaxial layers, in undoped films were found to range from 8nm at Ts=80$^{\circ}C$ to > 1.2 ${\mu}$m at Ts=300$^{\circ}C$ while Sb incorporation probabilities $\sigma$sb varied from unity at Ts 550$^{\circ}C$ to 0.1 at 750$^{\circ}C$. These te and $\sigma$Sb values are approximately one and one-to-three orders of magnitude, respectively, higher than reported results achieved with molecular-beam epitaxy. Plan-view and cross-sectional transmission electron microscopy, high-resolution x-ray diffraction, channeling and axial angular-yield profiles by Rutherford back scattering spectroscopy for epitaxial Si1-x Gex(001) alloy films (0.15$\leq$x$\leq$0.30) demonstrated that the films are of extremely high crystalline quality. critical layer thicknesses hc the film thickness where strain relaxation starts, I these alloys wre found to increase rapidly with decreasing growth temperature. For Si0.70 Ge0.30, hc ranged from 35nm at Ts=550$^{\circ}C$ to 650nm at 350$^{\circ}C$ compared to an equilibrium value of 8nm.

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Bi-Te Core/Shell Nanowires Synthesis Based on On-Film Formation of Nanowires Method for Thermoelectric Applications (압축응력에 의한 박막 위 나노선 성장법을 이용한 Bi-Te 코어/쉘 열전 나노선 합성)

  • Kang, Joohoon;Ham, Jinhee;Roh, Jong Wook;Noh, Jin-Seo;Lee, Wooyoung
    • Korean Journal of Metals and Materials
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    • v.48 no.5
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    • pp.445-448
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    • 2010
  • For an enhanced thermoelectric performance, one-dimensional heterostructure nanowires were created that consisted of aBi core and Te shell. The structure was fabricated by depositing Te in-situ onto a Bi nanowire grown by our unique OFF-ON (on-film formation of nanowires) method. After examining a cross-sectional TEM image, it was found that diffusive interface was formed between Bi and Te. Selected area electron diffraction revealed that the crystallinity of the Te shell was some what lower compared to the highly single-crystalline Bi core. The Bi-Te core/shell nanowires can be a smart structure that suppresses phonon transport by several scattering mechanisms, making the OFF-ON method the simplest way to realize that structure.