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Diffusion Length Measurement of the Triplet Exciton in PHOLEDs by using Double Quantum Well Structure

  • Park, Won-Hyeok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.225-225
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    • 2016
  • PHOLED devices which have the structure of ITO/HAT-CN(5nm)/NPB(50nm)/EML(47nm)/TPBi(10nm)/Alq3(20nm)/LiF(0.8nm)/Al(100nm) are fabricated to investigate the diffusion length of the triplet exciton by using double-quantum-well(DQE) EML structure. To fabricate DQW structures, Ir(ppy)3(2% wt) and Ir(btp)2(8% wt) are used as green and red emission zones, respectively. In DQW structured EML, as shown in Fig. 1, 1nm thick layers of green and red emission zones are located middle of the EML, and the distance between these wells(x) is changed from 0nm to 10nm. As shown in Fig. 2, the emission spectra from DQW PHOLED devices are changed with different x. The intensity of the green emission(520nm) is decreased when x is decreased, and it goes to near zero when x=0nm. This behavior can be identified as the diffusion of the triplet excitons from Ir(ppy)3 to Ir(btp)2 by the Dexter energy transfer(DET). From the external quantum efficiency(EQE) of the red emission, as shown in Fig. 3, the diffusion length of the triplet excitons can be determined by the equation of DET rate, R=A Exp(-2RDA/L), where RDA is donor-acceptor distance and L is the sum of the van der Wals radii. As a result, the measured data of the red EQEs with different x are identified to theoretical result from the equation of DET rate(Fig. 4). From this results, we could confirm that the diffusion length of the triplet excitons can be determined by using DQW structure and this method is very useful to investigate the behavior of the excitons in PHOLEDs.

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Landscape Structure in the Greenbelt Zone around the Seoul, the Metropolis of Korea

  • Lee, Chang-Seok;Hong, Sun-Kee;Moon, Jeong-Suk;You, Young-Han
    • The Korean Journal of Ecology
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    • v.24 no.6
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    • pp.385-394
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    • 2001
  • An attempt to clarify the landscape structure of urban areas was carried out in the greenbelt around Seoul, Korea's metropolis. By means of aerial photographs and a field survey, a vegetation map including land-use pattern was made. Landscape structure was described by analyzing this vegetation map and the results of phytosociological survey. Landscape element types identified were (1) secondary forest, (2) plantation, (3) cultivated field, (4) urbanized area, (5) graveyard, and (6) bare rock. Vegetation units, resulting from the phytosociological analysis, included Quercus mongolica, Q. variabilis, Q. acutissima, Pinus densiflora, Q. aliena, and Alnus japonica communities. Plantations were composed of Robinia pseudoacacia, Populus tomentiglandulosa, P. rigida, Larix leptolepis, P. koraiensis, and Castanea crenata stands. Patches near to human settlements in the lower zones of the mountains were fragmented and small but they became larger towards the higher mountain zones. On the other hand, the number of patches was fewer and their size was larger in Mt. Cheonggye more distant from the principal residential area, larger in size, and higher in elevation compared with the other 2 mountains, Mt. Daemo and Mt. Acha. Floristic composition of Mongolian oak(Q. mongolica) stand distributing in the upper part of each mountain, in which artificial interference is rare, showed a difference among those study areas different in parent rock and disturbance regime. But that of black locust(R. pseudoacacia) stand located in lowland of mountainous area, in which artificial interference is frequent was similar to each other. As the results of analyses on the frequency distribution of diameter classes of major species, dominant landscape elements, Mongolian oak forest showed different responses depending on artificial interference as continuous maintenance and retrogressive succession in the sites far from and near to the residential areas, respectively. On the other hand, black locust stands showed a probability to be restore to the native oak forest through progressive succession.

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Development of Asynchronous Blocking Algorithm through Asynchronous Case Study of Steam Turbine Generator (스팀터빈 발전기 비동기 투입 사례연구를 통한 비동기 방지 알고리즘 개발)

  • Lee, Jong-Hweon
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.61 no.10
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    • pp.1542-1547
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    • 2012
  • Asynchronous phenomenon occurs on the synchronous generators under power system when a generator's amplitude of electromagnetic force, phase angle, frequency and waveform etc become different from those of other synchronous generators which can follow instantly varying speed of turbine. Because the amplitude of electromagnetic force, phase frequency and waveform differ from those of other generators with which are to be put into parallel operation due to the change of excitation condition for load sharing and the sharing load change, if reactive current in the internal circuit circulates among generators, the efficiency varies and the stator winding of generators are overheated by resistance loss. When calculation method of protection settings and logic for protection of generator asynchronization will be recommended, a distance relay scheme is commonly used for backup protection. This scheme, called a step distance protection, is comprised of 3 steps for graded zones having different operating time. As for the conventional step distance protection scheme, zone 2 can exceed the ordinary coverage excessively in case of a transformer protection relay especially. In this case, there can be overlapped protection area from a backup protection relay and, therefore, malfunctions can occur when any fault occurs in the overlapped protection area. Distance relays and overcurrent relays are used for backup protection generally, and both relays have normally this problem, the maloperation, caused by a fault in the overlapped protection area. Corresponding to an IEEE standard, this problem can be solved with the modification of the operating time. On the other hand, in Korea, zones are modified to cope with this problem in some specific conditions. These two methods may not be obvious to handle this problem correctly because these methods, modifying the common rules, can cause another coordination problem. To overcome asynchronizing protection, this paper describes an improved backup protection coordination scheme using a new logic that will be suggested.

Mutagenicity Assessment of Drinking Water in Combination with Flavored Black Tea Bags: a Cross Sectional Study in Tehran

  • Alebouyeh, Farzaneh;Bidgoli, Sepideh Arbabi;Ziarati, Parisa;Heshmati, Masoomeh;Qomi, Mahnaz
    • Asian Pacific Journal of Cancer Prevention
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    • v.16 no.17
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    • pp.7479-7484
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    • 2015
  • Diseases related to water impurities may present as major public health burdens. The present study aimed to assess the mutagenicity of drinking water from different zones of Tehran, and evaluate possible health risks through making tea with tea bags, by Ames mutagenicity test using TA 100, TA 98 and YG1029 strains. For this purpose, 450 water samples were collected over the period of July to December 2014 from 5 different zones of Tehran. Except for one sample, no mutagenic potential was detected during these two seasons and the MI scores were almost normal (${\leq}1-1.6$) in TA 100, TA 98 and YG1029 strains. Although no mutagenic effects were considered in TA 98 and TA 100 in the test samples of our three evaluated tea bag brands, one sample from a local company showed mutagenic effects in the YG1029 strain (MI=1.7-1.9 and 2) after prolonged (10-15 min.) steeping. Despite the mild mutagenic effect discovered for one of the brand, this cross sectional study showed relative safety of water samples and black tea bags in Tehran. According to the sensitivity of YG1029 to the mutagenic potential of water and black tea, even without metabolic activation by s9 fraction, this metabolizer strain could be considered as sensitive and applicable to food samples for quantitative analysis of mutagens.

Development of Multiscale Modeling Methods Coupling Molecular Dynamics and Stochastic Rotation Dynamics (분자동역학과 확률회전동역학을 결합한 멀티스케일 모델링 기법 개발)

  • Cha, Kwangho;Jung, Youngkyun
    • KIISE Transactions on Computing Practices
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    • v.20 no.10
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    • pp.534-542
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    • 2014
  • Multiscale modeling is a new simulation approach which can manage different spatial and temporal scales of system. In this study, as part of multiscale modeling research, we propose the way of combining two different simulation methods, molecular dynamics(MD) and stochastic rotation dynamics(SRD). Our conceptual implementations are based on LAMMPS, one of the well-known molecular dynamics programs. Our prototype of multiscale modeling follows the form of the third party implementation of LAMMPS. It added MD to SRD in order to simulate the boundary area of the simulation box. Because it is important to guarantee the seamless simulation, we also designed the overlap zones and communication zones. The preliminary experimental results showed that our proposed scheme is properly worked out and the execution time is also reduced.

Effect of Pressure Gradients on the Hairpin Structures in Turbulent Boundary Layers (난류 경계층의 Hairpin와 구조에 대한 압력구배의 영향)

  • Kim, Gyeong-Cheon;Yun, Hong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.25 no.8
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    • pp.1103-1112
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    • 2001
  • The effect of pressure gradients on the hairpin structures in three different turbulent boundary layers (ZPG : Re(sub)$\theta$=910, FPG : Re(sub)$\theta$=575, APG : Re(sub)$\theta$=1290) has been examined with instantaneous velocity fields obtained in streamwise-wall-normal planes using PIV (particle image velocimetry) method. In the outer layer hairpin vortices occur in streamwise-aligned packets that propagate with small velocity dispersion. The signature pattern of the hairpin consists of a spanwise vortex core located above a region of strong second quadrant fluctuation (u<0 and v>0 : Q2 event) is clearly observed. The formation of packets explains the occurrence of multiple VITA events in turbulent burst. Noticeable differences are found in the average inclination angles of hairpin vortex packets which are 45$^{\circ}$, 35.7$^{\circ}$, and 51.9$^{\circ}$in the case of ZPG, FPG and APG, respectively. It is found that the large, time-varying, irregularly shaped zones with nearly constant streamwise momentum exist throughout the boundary layer. Within the interior of the envelope the spatial coherence between the velocity fields induced by the individual vortices leads to strongly retarded streamwise momentum, explaining the zones of uniform momentum. The formation of the uniform momentum zone is remarkably different with respect to the pressure gradients especially in the logarithmic layer.

Friction Stir Welding of 7075-T651 Aluminum Plates and Its Fatigue Crack Growth Property (7075-T651 알루미늄 판재의 마찰교반용접과 피로균열전파 특성)

  • Kim, Chi-Ok;Sohn, Hye-Jeong;Kim, Seon-Jin
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.35 no.10
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    • pp.1347-1353
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    • 2011
  • Friction stir welding (FSW) method has extensively been used in manufacturing methods because of the several advantages over conventional welding methods, such as better mechanical properties, reduced occurrence of joining defects, high material saving, and low production time, etc. The aim of this paper is to review the optimal FSW conditions using the previous experimental results and is to investigate the fatigue crack growth rate in three different zones, WM, HAZ and BM for FSWed Al7075-T651 aluminum plates. As far as our experiments are concerned, the optimal conditions are obtained as rotation speed, 800rpm and travelling speed, 0.5mm/sec. The fatigue crack growth rate showed strong dependency on three different zones WM, HAZ and BM, and crack driving force.

A Study on Heat and Smoke Exhaust Characteristics from the Subway Fire for Different Ventilation Modes (지하철 화재시 제연모드에 따른 열 및 연기 배출 특성 연구)

  • Chang, Hee-Chul;Yoon, Kyung-Beom;Park, Won-Hee;Kim, Tae-Kuk
    • Journal of the Korean Society of Hazard Mitigation
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    • v.8 no.3
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    • pp.37-42
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    • 2008
  • This study is focused on the numerical predictions for different smoke-control ventilation modes for the subway fire. Smoke-control ventilation mode in the domestic platform is that exhausting for the smoke detected zones while supplying air or stopping any ventilation for other zones in the platform. Three cases of smoke control ventilation modes are considered. First and second case are present running smoke control mode in Korea. The third is that smoke-control ventilation fans equipped in the platform are operated in first 4 minute(platform evacuation time, NFPA130) since then the fans equipped in the platform are stopped and the fans equipped in the tunnels are operated. Distributions of heat, carbon monoxide and visible range are compared at a height of 1.7m(passenger breath/sight height) above the platform. The numerical results show that air supply fan operation in the platform causes the smoke disturbance and a rapid spread of the smoke. The switch-operation with fans in both the platform and tunnel are better than operation with only platform fans in smoke rejection efficiency.

UK Urban Regeneration Policy for Comprtitiveness: A Government Perspective

  • Thorpe, Keith
    • Land and Housing Review
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    • v.8 no.2
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    • pp.33-53
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    • 2017
  • The UK Government's approach to how to deliver regeneration in its towns and cities has changed considerably in recent years. Traditionally, urban regeneration policy focused on reversing physical, economic and social decline in an area where market forces would not do this without intervention. Since 2010 urban regeneration has become a vital part of the Government's approach to increasing local growth and competitiveness and building a strong and balanced economy. The current emphasis is on a place-based approach to regeneration that builds on the particular strengths of different places to drive growth and addresses the factors that hold them back. This paper outlines the key features of current UK urban regeneration policy and how interventions to support regeneration and growth are being pursued at different spatial scales to ensure all parts of the country benefit. They include pan regional initiatives like the Northern Powerhouse and Midlands Way, to groups of local authorities operating at a sub regional level (combined authorities/city regions), Local Enterprise Partnerships, and a variety of smaller scale programmes delivering regeneration in areas of economic and social decline. The paper explains some of the policy instruments and funding programmes available to support regeneration, and provides case studies of some major urban regeneration projects that illustrate the new approach including housing and infrastructure improvements like the planned High Speed Rail 2 line. These are supporting regeneration through the creation of strategic partnerships involving government, places and investors. The paper concludes with some lessons from past and future regeneration schemes to improve their effectiveness and impact on places and enhance local growth potential.

Comparative assessment of antibacterial activity of different glass ionomer cements on cariogenic bacteria

  • Naik, Rahul Gaybarao;Dodamani, Arun Suresh;Khairnar, Mahesh Ravindra;Jadhav, Harish Chaitram;Deshmukh, Manjiri Abhay
    • Restorative Dentistry and Endodontics
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    • v.41 no.4
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    • pp.278-282
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    • 2016
  • Objectives: Glass ionomer cements (GICs), which are biocompatible and adhesive to the tooth surface, are widely used nowadays for tooth restoration. They inhibit the demineralization and promote the remineralization of the tooth structure adjacent to the restoration, as well as interfere with bacterial growth. Hence, the present study was conducted to assess and compare the antimicrobial activity of three commercially available GICs against two cariogenic bacteria. Materials and Methods: An agar plate diffusion test was used for evaluating the antimicrobial effect of three different GICs (Fuji IX, Ketac Molar, and d-tech) on Streptococcus mutans (S. mutans) and Lactobacillus acidophilus (L. acidophilus). Thirty plates were prepared and divided into two groups. The first group was inoculated with S. mutans, and the second group was inoculated with L. acidophilus. These plates were then incubated at $37^{\circ}C$ for 24 hours. Zones of bacterial growth inhibition that formed around each well were recorded in millimeters (mm). Results: The zones of inhibition for Fuji IX, Ketac Molar, and d-tech on S. mutans were found to be $10.84{\pm}0.22mm$, $10.23{\pm}0.15mm$, and $15.65{\pm}0.31mm$, respectively, whereas those for L. acidophilus were found to be $10.43{\pm}0.12mm$, $10.16{\pm}0.11mm$, and $15.57{\pm}0.13mm$, respectively. Conclusions: D-tech cement performed better in terms of the zone of bacterial inhibition against the two test bacteria, than the other two tested glass ionomers.