• Journal of Welding and Joining
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• 제19권1호
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• pp.95-103
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• 2001

The properties of the detonation sprayed cermet coating are investigated through the mechanical, corrosion and erosion test. The test results are also compared with the properties of the substrate materials, STS 329J1, dual phase stainless steel and the plasma sprayed cermet coatings. The two kinds of carbide cermet power, WC+NiCr, Cr$_3$C$_2$+NiCr were used in this experiment. The experimental results showed that the anti-corrosive and anti-erosive properties of the detonation sprayed cermet coatings are superior to the plasma sprayed cermet coatings. The WC+NiCr cermet coating appears to be more effective than Cr$_3$C$_2$+NiCr cermet coating in abrasive erosion environment, whereas the Cr$_3$C$_2$+NiCr cermet coatings are more effective in cavitation erosion environment.

• 한국화재소방학회논문지
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• 제22권3호
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• pp.228-233
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• 2008

폭굉한계는 가연성물질의 화재 및 폭발 위험성을 결정하기 위해 사용되는 중요한 연소 특성치 가운데 하나이다. 본 연구에서는 가연성혼합물의 구성하는 각 순수성분의 연소열과 기상 조성을 이용하여 폭발한계를 예측하였다. 제시된 방법론에 의한 계산값은 적은 오차범위에서 문헌값과 일치하였다. 따라서 본 연구에서 제시한 방법론이 다른 가연성물질의 폭굉한계 예측에 폭넓게 적용되기를 기대한다.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2006년도 제32회 KOSCO SYMPOSIUM 논문집
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• pp.205-212
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• 2006

Three-dimensional numerical study was carried out for the investigation of the detonation wave structures propagating in tubes. Fluid dynamics equations and conservation equation of reaction progress variable were analyzed by a MUSCL-type TVD scheme and four stage Runge-Kutta time integration. Chemical reaction was modeled by using a simplified one-step irreversible kinetics model. The variable gas properties between unburned and burned states were considered by using variable specific heat ratio formulation. The unsteady computational results in three-dimension show the detailed mechanisms of rectangular and diagonal mode of detonation wave instabilities resulting same cell length but different cell width in smoked-foil record. The results for the small reaction constant shows the spinning mode of three-dimensional detonation wave dynamics, which was rarely observed in the previous numerical simulation of the detonation waves.

• 한국전산유체공학회:학술대회논문집
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• 한국전산유체공학회 1998년도 춘계 학술대회논문집
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• pp.1-14
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• 1998

Underwater explosion properties for TNT, an ideal explosive, and DXD-04, a nonideal explosive, were numerically modeled with a one-dimensional Lagrangian hydrodynamic code. The equation of state parameters for detonation products for TNT and DXD-04 were obtained from the BKW code, assuming complete reaction. Burn of TNT was modeled by using the Chapman-Jouguet(CJ) volume burn technique, a programmed-burn technique, assuming instantaneous detonation reaction. Burn of DXD-04 was modeled by using the same technique and by using the reaction rate calibrated from two-dimensional steady-state detonation experiments. The calculations for TNT reproduced the experimental peak pressure of the shock wave propagating through water with an error of $3.0\%$ and the experimental oscillation period of the bubble formed of detonation products with an error of $2.3\%$. For DXD-04, the CJ volume burn technique could not reproduce the experimental observations. When the reaction rate calibrated from two-dimensional steady-state detonation experimental data, the calculated peak pressure was slightly higher by $7.3\%$ than the experimental data, but the calculated shock profile was in good agreement. The bubble period was reproduced with an error of $1.8\%$. These results demonstrated that underwater explosion properties for an ideal explosive can be predicted by using a programmed burn technique, and that, however, those for a nonideal explosive can be predicted only when a well-calibrated reaction rate is used.

• Bulletin of the Korean Chemical Society
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• 제33권6호
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• pp.1913-1918
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• 2012

The nitramine explosives with $-NH_2$ and -F groups were optimized to obtain their molecular geometries and electronic structures at DFT-B3LYP/6-31+G(d) level. The theoretical molecular density (${\rho}$), heat of formation (HOF), detonation velocity ($D$) and detonation pressure ($P$), estimated using Kamlet-Jacobs equations, showed that the detonation properties of these compounds were excellent. Based on the frequencies scaled by 0.96 and the principle of statistic thermodynamics, the thermodynamic properties were evaluated, which were respectively related with the temperature. The simulation results reveal that 1,3,5,7-tetranitro-1,3,5,7-tetrazocan-2-amine (molecule B1) performs similarly to the famous explosive HMX, and 2-fluoro-1,3,5-trinitro-1,3,5-triazinane (molecule C1) and 2-fluoro-1,3,5,7-tetranitro-1,3,5,7-tetrazocane (molecule D1) outperform HMX. According to the quantitative standard of energetics and stability as an HEDC (high energy density compound), molecules C1 and D1 essentially satisfy this requirement. These results provide basic information for molecular design of novel high energetic density compounds.

• 대한기계학회논문집
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• 제19권8호
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• pp.1989-1998
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• 1995

Characteristics of the flame propagation for normal and abnormal combustion in hydrogen premixture in a cylindrical constant-volume combustion chamber are studied numerically. A detailed hydrogen oxidation kinetic mechanism, mixture transport properties and a model describing spark ignition process are used. The calculated pressure-time history of the stable deflagration wave propagation agrees well with the experiment. The ignition of the premixture in the unburned gas, initiated by the hot spot, causes a transition from deflagration to detonation under some initial temperature and pressure. Under the initial conditions with high temperature and pressure, excessive ignition energy initiates a strong blast wave and a detonation wave that follows. The chemical reaction in the detonation wave is much more vigorous than that in the deflagration wave and the peak pressure in the detonation wave is much higher than the equilibrium value.

• 한국산학기술학회논문지
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• 제12권10호
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• pp.4689-4695
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• 2011

나노다이아몬드는 넓은 적용성 측면을 고려한다면 상대적으로 신물질이라 할 수 있다. 본 연구에서는 XRD, EDS, HRTEM, FTIR, Raman 분광기, 열분석 장치와 BET 측정 장치와 같은 다양한 장비를 통해 단결정 폭발 나노다이아몬드와 다결정 합성 나노다이아몬드의 물리화학적 특성들을 고찰하였다. 단결정 폭발 나노다이아몬드는 4nm ~ 6nm 크기의 구형이나 타원 모양이지만, 다결정 합성 다이아몬드는 80nm ~ 120nm 크기의 각이 진 입체도형 모양이다. 단결정과 다결정 나노다이아몬드의 표면은 수산기, 카보닐기, 카복실기 등과 같은 다양한 관능기를 가지고 있다. 질소분위기 하에서 단결정 폭발 나노다이아몬드의 상전이 온도는 대략 $650^{\circ}C$이었다.

• Structural Engineering and Mechanics
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• 제56권4호
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• pp.535-548
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• 2015

A series of experimental results on thin mild steel plates clamped at the boundary subjected to gas detonation shock loading are presented. Detonation occurred by mixing Acetylene (C2H2)-Oxygen (O2) in various volume ratio and different initial pressure. The applied impulse is varied to give deformation in the range from 6 mm to 35 mm. Analytical modeling using energy method was also performed. Dependent material properties, as well as strain rate sensitivity, are included in the theoretical modeling. Prediction values for midpoint deflections are compared with experimental data. The analytical predictions have good agreement with experimental values. Moreover, it has been shown that the obtained model has much less error compared with those previously proposed in the literature.

• Bulletin of the Korean Chemical Society
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• 제35권4호
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• pp.1043-1049
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• 2014

Density functional theory (DFT) calculations at the B3LYP/6-31G(d,p) theoretical level were performed for two novel explosives (compounds B and C) based on the guanidine-fused bicyclic skeleton $C_4N_6H_8$ (A). The heats of formation (HOFs) were calculated via isodesmic reaction. The detonation properties were evaluated by using the Kamlet-Jacobs equations. The bond dissociation energies (BDEs) for the thermolysis initiation bond were also analyzed to investigate the thermal stability. The results show that the compounds have high positive HOF values (B, 1064.68 $kJ{\cdot}mol^{-1}$; C, 724.02 $kJ{\cdot}mol^{-1}$), high detonation properties (${\rho}$, D and P values of 2.04 $g{\cdot}cm^{-3}$ and 2.21 $g{\cdot}cm^{-3}$, 9.98 $km{\cdot}s^{-1}$ and 10.99 $km{\cdot}s^{-1}$, 46.44 GPa and 59.91 Gpa, respectively) and meet the basic stability requirement. Additionally, feasible synthetic routes of the these high energy density compounds (HEDCs) were also proposed via retrosynthetic analysis.

• 한국터널지하공간학회 논문집
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• 제5권4호
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• pp.337-348
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• 2003

밀장전한 암반 발파공에서 화약 폭발시 발생하는 고압의 폭굉압력 전파메카니즘을 충격파 이론을 적용하여 규명하고 전달된 발파압력 산정식을 유도하였다. 유도된 발파압력 산정식은 폭굉파속도, 단열지수, 화약밀도, Hugoniot 상수, 암반밀도의 함수였다. 에멀젼 화약과 서울 화강암의 특성시험을 시행하여 각 특성치의 확률분포를 정의하고 발파압력 산정식에 적용하여 발파압력의 확률분포를 산출하였다. 화약 특성치와 암반 특성치의 확률분포는 정규분포를 나타냈으며 따라서 발파압력의 확률분포도 정규분포로 추정되었다. 발파압력에 대한 매개변수분석을 시행한 결과 폭굉파속도가 발파압력에 가장 크게 영향을 미쳤다. 또한 이런 특성치의 불확실성이 발파압력의 불확실성에 미치는 영향을 분석하였다. 분석결과 암반특성치의 불확실성이 화약특성치보다 더 크게 영향을 미쳤다. 비록 매개변수분석에서 폭굉파속도가 발파압력에 가장 크게 영향을 미치는 요소이지만 암반특성치의 불확실성이 폭굉파속도의 불확실성보다 더 크기 때문에 발파압력은 후자보다 전자에 의해서 더 크게 영향을 받는다.