• Journal of Embryo Transfer
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• v.14 no.3
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• pp.219-224
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• 1999

The effect of several potential antioxidants were examined as a means of increasing the in vitro development of in vitro matured and in vitro fertilized oocytes into morulae and blastocysts. Korean native cattle embryos after in vitro fertilization were cultrued for 7 days at 38.5$^{\circ}C$ in CR1aa containing varing concentration of the antioxidants in a gas phases consisting of 5% CO2, 95% humidified air. The results obtained were summarized as follows; The proportion of embryos developed to morulae and blastocysts in CR1aa containing 2.5uM $\alpha$-tocopherol(11.0% and 6.0%) was significantly higher than those of 0, 5.0, and 7.5uM $\alpha$-tocopherol (P<0.05). concentration of 50uM L-ascorbic acid (7.5% blastocysts) did affect the proportion of embryos developing into blastocystes(P>0.05). Addition of 200uM cysteamine was significantly higher than those of 0, 100 and 300uM (P<0.05). When the fertilized oocytes were cultured at 0. 200, 400 and 600uM of selenium for 168 hrs, the morulae rates were 12.2, 5.2, 16.0 and 16.1% respectively, and addition of 200uM selenium was significantly higher than those of 0, 400, 600uM (P<0.05). These results suggested that the addition of $\alpha$-tocopherol, L-ascorbic acid, cysteamine and selenicum can enhanced development to the morulae and blastocysts of in vitro derived fertilized oocytes.

• Asian Journal of Atmospheric Environment
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• v.4 no.2
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• pp.72-79
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• 2010

In this study, the ionic composition of volcanogenically derived particles and their temporal and spatial distributions have been investigated to evaluate the impact of the volcanic eruption on the local ecosystem and residents. To this end, an intensive field study was conducted to measure the size-segregated particulate matters at the east part of Sakurajima in Japan. Fractionated sampling of particles into > $PM_{10}$, $PM_{10-2.5}$, and $PM_{2.5}$ was made by a multi nozzle cascade impactor (MCI). The concentration of various ions present in the size-resolved particles was determined by Ion chromatography. The time dependent 3-dimensional Volcanic Ash Forecast Transport And Dispersion (VAFTAD) model developed by the NOAA Air Resources Laboratory (ARL) indicated that the sampling site of this work was affected by the volcanic aerosol particles plume. The temporal distributions of sulfate and $PM_{2.5}$ during the field campaign were significantly variable with important contributions to particle mass concentration. The chlorine loss, suspected to be caused by acidic components of volcanic gases, occurred predominantly in fine particles smaller than $10\;{\mu}m$.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2003.11a
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• pp.61-64
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• 2003

This study was conducted to investigate the chemical characteristics of $PM^{10}$ at Anmyeon-do during the periods from January 1998 to December 2001. The $PM^{10}$ samples ($PM^{10}$) were collected by High Volume Air sampler (HVAS). The measured items were mass concentration of $PM^{10}$ with the major ions ($Cl^{-}$, ${SO_{4}}^{2-}$, ${NO_3}^{-}$, ${Mg}^{2+}$, ${Ca}^{2+}$, ${K}^{+}$etc.) and metallic elements (AI, Fe, Mn, Cr, Zn, Pb etc.). The chemical analysis of major ion components were made by Ion Chromatography (DX-500) and that of metallic elements were made by Inductively Coupled Plasma Spectrometer (ICP-AES, ICP-Mass). The average mass concentration of $PM^{10}$ increased substantially during the heavy dust periods (Asian Dust cases). For water-soluble ions, concentrations of ${Ca}^{2+}$, ${SO_{4}}^{2-}$ and ${NO_3}^{-}$ were remarkably enhanced. Concentrations and mass fraction of crustal elements such as Na, Mg, Ca, Fe, Mn were highly elevated, but those of pollution-derived heavy metals were appreciably decreased. The factor analysis was conducted in order to make the large and diverse data set as manageable levels and to qualitatively examine the relationship between the variables.

• Journal of Korean Society for Atmospheric Environment
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• v.18 no.6
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• pp.437-452
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• 2002

The Metropolitan Tracer Experiment (METREX) was performed over the Washington, D.C. area using two inert, non-deposition perfluorocarbon gases for over 1 year period (November 1983∼December 1984). Two perfluorocarbon gas tracers (PDCH, PMCH) were released simultaneously at intervals of every 36 hours for 6 hours, regardless of the meteorological conditions in metropolitan area. Samples were collected continuously for 8 hours at a central downtown and two adjacent suburban locations. Monthly air samples were collected at 93 sites across the whole region (at urban, suburban, and rural locations). The purpose of this study is to simulate INPUFF and ISCST model using METREX data, and to compare calculated and observed concentrations. In the case of INPUFF simulation, two meteorological input data were used. One is result data from wind field model which was calculated by diagnostic wind model (DWM), the other is meteorological data observed at single station. Here, three kinds of model calculation were performed during April and July 1984; they include (1) INPUFF model using DWM data (2) INPUFF model using single meteorological data (3) ISCST model. The monthly average concentration data were used for statistic analysis and to draw their horizontal distribution patterns. Eight-hour-averaged concentration was used to describe movement of puff during the episode period. The results showed that the concentrations calculated by puff model (INPUFF) were better than plume model (ISCST). In the case of puff model (INPUFF), a model run using wind field data produced better results than that derived by single meteorological data.

• Journal of Korean Society for Atmospheric Environment
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• v.16 no.6
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• pp.585-594
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• 2000

Through an application of Micrometerorological methods, we conducted measurements of Hg fluxes from Nan-Ji-Do which is well known as one of the major local areal sources in Seoul metropolitan area during Match/April of 2000. In the course of our study, we determined the concentration gradients of total gaseous Hg(between 20 and 2000 cm heights) and combined these data with Micrometerorological components to derive is fluxes. It turned out that emission from and dry deposition to soil surfaces occurred at the ratio of 72:27 from a total of 271 hourly measurements. The validity of measured concentration gradients( or resulting fluxes) was evaluated in terms of percent gradient. Accordingly, about more than 95% of gradient data derived were statistically significant. The mean fluxes of Hg across soil-air interface, when computed using the concentrations gradients and relevant parameters, were found at 253(during emission) and -846ng/$m^2$/h(during dry deposition) The occurrences of abnormalously high exchange rates appear to be the combined effects of enormously high gradient values and high transfer coefficients. While the emissions of Hg occurred constantly during the whole study periods, the occurrences of dry deposition events were observed most intensively during very limited time periods(3/29 and 4/3). The results of our study cleary indicated that the studied area is a strong local areal source, while exhibiting great potential as a major sink simultaneously.

• Bulletin of the Korean Chemical Society
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• v.35 no.12
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• pp.3475-3481
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• 2014

This paper describes how primary contaminants in ambient air affect the performance of the cathode in fuel cell electric vehicle applications. The effect of four atmospheric pollutants ($SO_2$, $NH_3$, $NO_2$, and CO) on cathode performance was investigated by air impurity injection and recovery test under load. Electrochemical analysis via polarization and electrochemical impedance spectroscopy was performed for various concentrations of contaminants during the impurity test in order to determine the origins of performance decay. The variation in cell voltage derived empirically in this study and data reported in the literature were normalized and juxtaposed to elucidate the relationship between impurity concentration and performance. Mechanisms of cathode degradation by air impurities were discussed in light of the findings.

• Journal of Environmental Science International
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• v.3 no.3
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• pp.263-271
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• 1994

A detachment of biofilm was investigated in an inverse fluidized bed biofilm reactor(IFRBR). The biofilm thickness, 5 and the bioparticle density, Pm were decreased by the increase of Reynolds number, Re and the decrease of biomass concentration, h. The correlations were expressed as $\delta$=6l.6+16.33$b_c$-0.004Re and Ppd=0.3+0.027$b_c$- 2.93x$l0^{-5}$ no by multiple linear regression analysis method. Specific substrate removal rate, q was derived by F/M ratio and biofilm thickness as q=0.44.+0.82F/M-5.Ix10$-4^{$\delta$}$. Specific biofilm detachment rate, bds was influenced by FIM ratio and Reynolds number as $b_{ds}$=-0.26+0.26F/M+ 2.17$\times$$10^{-4}$Re. Specific biofilm deachment rate in an IFBBR was higher than that in a FBRR(fluidized bed biofilm reactor) because of the friction between air bubble and the bioparticles.

• Advances in materials Research
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• v.4 no.2
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• pp.63-76
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• 2015

The energy crisis involving depletion of fossil fuel resource is not the sole driving force for developing renewable energy technologies. Another driving force is the ever increasing concerns on the air quality of our planet, associated with the continuous and dramatic increase of the concentration of greenhouse gas (mainly carbon dioxide) emissions. The internal combustion engine is a major source of distributed $CO_2$ emissions caused by combustion of gasoline derived largely from fossil fuel. Another major source of $CO_2$ is the combustion of fossil fuels to produce electricity. New technologies for generating electricity from sources that do not emit $CO_2$, such as water, solar, wind, and nuclear, together with the advent of plug-in hybrid electric vehicles (PHEV) and even all-electric vehicles (EVs), offer the potential of alleviating our present problem. Therefore, the relevant technologies in $LiFePO_4$ as cathode material for Li-ion batteries suitable to the friendly environment are reviewed aim to provide the vital information about the growing field for energies to minimize the potential environmental risks.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.24 no.4
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• pp.436-445
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• 2014

Objectives: Time-activity studies have become an integral part of comprehensive exposure assessment and personal exposure modeling. The aims of this study were to estimate exposure levels to nitrogen dioxide($NO_2$) and volatile organic compounds(VOCs), and to compare estimated exposures by using time-activity patterns and indoor air concentrations. Methods: The major microenvironments for office workers were selected using the Time-Use Survey conducted by the National Statistical Office in Korea in 2009. A total of 9,194 and 6,130 workers were recruited for weekdays and weekends, respectively, from the Time-Use Survey. It appears that workers were spending about 50% of their time in the house and about 30% of their time in other indoor areas during the weekdays. In addition, we analyzed the time-activity patterns of 20 office workers and indoor air concentrations in Daegu using a questionnaire and time-activity diary. Estimated exposures were compared with measured concentrations using the time-weighted average analysis of air pollutants. Conclusions: According to the time-activity pattern for the office workers, time spent in the residence indoors during the summer and winter have been shown as $11.12{\pm}2.20$ hours and $12.48{\pm}1.77$ hours, respectively, which indicates higher hours in the winter. Time spent in the office in the summer has been shown to be 1.5 hours higher than in the winter. The target pollutants demonstrate a positive correlation ($R^2=0.076{\sim}0.553$)in the personal exposure results derived from direct measurement and estimated personal exposure concentrations by applying the time activity pattern, as well as measured concentration of the partial environment to the TWA model. However, these correlations were not statistically significant. This may be explained by the difference being caused by other indoor environments, such as a bar, cafe, or diner.

• Korean Journal of Remote Sensing
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• v.36 no.5_4
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• pp.1267-1276
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• 2020

To quantitatively predict the impacts of large-scale volcanic eruptions of Mt. Baekdu on air quality and damage around the Korean Peninsula, a three-dimensional chemistry-transport modeling system (Weather Research & Forecasting - Sparse Matrix Operation Kernel Emission - Comunity Multi-scale Air Quality) was adopted. A worst-case meteorology scenario was selected to estimate the direct impact on Korea. This study applied the typical worst-case scenarios that are likely to cause significant damage to Korea among worst-case volcanic eruptions of Mt. Baekdu in the past decade (2005~2014) and assumed a massive VEI 4 volcanic eruption on May 16, 2012, to analyze the concentration of PM_2.5 caused by the volcanic eruption. The effects of air quality in each region-cities, counties, boroughs-were estimated, and vulnerable areas were derived by conducting an exposure assessment reflecting vulnerable groups. Moreover, the effects of cities, counties, and boroughs were analyzed with a high-resolution scale (9 km × 9 km) to derive vulnerable areas within the regions. As a result of analyzing the typical worst-case volcanic eruptions of Mt. Baekdu, a discrepancy was shown in areas between high PM_2.5 concentration, high population density, and where vulnerable groups are concentrated. From the result, PM_2.5 peak concentration was about 24,547 ㎍/㎥, which is estimated to be a more serious situation than the eruption of Mt. St. Helensin 1980, which is known for 540 million tons of volcanic ash. Paju, Gimpo, Goyang, Ganghwa, Sancheong, Hadong showed to have a high PM_2.5 concentration. Paju appeared to be the most vulnerable area from the exposure assessment. While areas estimated with a high concentration of air pollutants are important, it is also necessary to develop plans and measures considering densely populated areas or areas with high concentrations of susceptible population or vulnerable groups. Also, establishing measures for each vulnerable area by selecting high concentration areas within cities, counties, and boroughs rather than establishing uniform measures for all regions is needed. This study will provide the foundation for developing the standards for disaster declaration and preemptive response systems for volcanic eruptions.