• 제목/요약/키워드: Der-f

검색결과 234건 처리시간 0.022초

The Crystal Structure of Cinmetacin ($C_{21}H_{19}NO_4$), A Non-steroidal Antiinflammatory Agent

  • Kim, Yang-Bae;Park, Il-Yeong;Park, Yang-Hwan
    • Archives of Pharmacal Research
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    • 제12권1호
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    • pp.52-57
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    • 1989
  • The structure of cinmetacin was determined by single crystal X-ray diffraction analysis. The compound was recrystallized from a mixture of acetone and water in orthorhombic, space group $P2_12_12_1$, with Z=4, a=35.681(8), b=9.482(2), c:5.071(1) ${\AA}$, $D_x=1.352 g/cm^3$, and $D_m=1.35g/cm^3$. The structure was solved by direct method and refined by least-squares procedure to the final R value of 0.036 for 1441 observed reflections ($F{\geq}3{\sigma}(F)$). The carboxyl group of the molecule is nearly perpendicular to the indole ring. The dihedral angle between indole ring and phenyl group is $64.5^{\circ}$. The molecules are linked together via O(1)-H ----O(3) hydrogen bonds, and arranged along 2-fold screw axis in the crystal. The intermolecular contacts are the normal van der Waals' forces.

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한독 워드넷 구축을 위한 기본 방법론 고찰 (Eine methodische Betrachtung fur die Erstellung des koreanisch-deutschen WordNets)

  • 남유선
    • 한국독어학회지:독어학
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    • 제9집
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    • pp.217-236
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    • 2004
  • Das Ziel dieser Arbeit ist es, als eine methodische Grundlage zur Erstellung des koreanisch-deutschen WordNets das Grundwissen $\"{u}ber$ das WordNet und einige bisherige Untersuchungen des WordNets darzulegen. Ais erster Schritt wurde einige grundlegende Punkte $f\"{u}r$ das WordNet im Rahmen des WordNets fur Englisch in Betracht gebracht. Dabei ging es um lexikalische Hierarchie, und um semantische Relationen zwischen den Synsets(Zusammensetzen der synonymen $W\"{o}rter$) wie Synonymy, Antonymy, Hyponymy, Mronymy, Troponomy und Entailment. $Anschlie{\ss}end$ wurden EuroNet und GermaNet in kurzer Form vorgestellt, die auf dem Princeton WordNet basierten. EuroNet ist eine multilinguale Datenbasis mit WordNets $f\"{u}r$ einige europaische Sprachen (hollandisch, italienisch, spanisch, deutsch, franzasisch, tschechisch und estnisch). Dieses auf das Deutsch bezogenen WordNet kann wichtige Hinweise $f\"{u}r$ die Erstellung des koreanisch-deutschen WordNets geben. In Korea wurden auch verschiedene Untersuchungen uber das WordNet $f\"{u}r$ Koreanisch unternommen. Darunter kann insbesondere KORTERM WordNet $f\"f{u}r$ Koreanisch als ein umfassendes System $erw\"{a}hnt$ werden, in dem Nomen, Verben, Adjektive und Adverbien miteinander interagieren. KORTERM WordNet fur Koreanisch ist eine multilinguale Datenbasis mit WordNets $f\"{u}r$ einige asiatische Sprachen (koreanisch, japanisch und chinesisch) und versucht noch die weiteren Sprachen in diese multilinguale Datenbasis hineinzubringen. Nach diesem WordNet wird das koreanisch-deutsche WordNet erstellt.

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Effect of Genotype and Dietary Protein Level on Growth Performance and Carcass Characteristics of Fattening Pigs in Central Vietnam

  • Pham, Khanh Tu;Hoang, Nghia Duyet;Le Duc, Ngoan;Hendriks, W.H.;Van Der Peet-Schwering, C.M.C.;Verstegen, M.W.A.
    • Asian-Australasian Journal of Animal Sciences
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    • 제23권8호
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    • pp.1034-1042
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    • 2010
  • This study aimed to determine the optimum dietary crude protein level in a typical diet for fattening pigs fed ad libitum under normal climate conditions in Central Vietnam. One hundred and ninety two gilts of Mong Cai local breed (MC), $F_1$ Large White${\times}$Mong Cai and $F_2$ crossbreds of (Landrace${\times}$Mong Cai)${\times}$Large White were used. At the start of the experiment, Mong Cai pigs weighed 12 kg at 11 weeks of age, $F_1$ pigs 12.1 kg at 8 weeks of age and $F_2$ pigs 12.2 kg at 8 weeks of age. Four diets differing in crude protein (CP) content (10.1, 13.1, 16.1 and 18.9% in DM) were formulated from rice bran, corn meal, cassava meal and fish meal. Calculated digestible energy content of the diets ranged from 13.5 to 13.8 MJ per kg DM. Pigs were housed individually in pens of $2.5\;m^2$ each and had ad libitum access to feed in a trough as well as water in bowls. The final weights after a growing period of 150 days were 66, 86 and 96 kg for MC, $F_1$ and $F_2$, respectively. Feed intake of MC pigs was highest at 13.1% CP while $F_1$ and $F_2$ had the highest feed intake at 16.1% CP. The results showed that for MC the maximum gain was obtained at levels between 13 to 16% CP. For the $F_1$ the maximum gain was at dietary protein levels of 16-17%. For $F_2$ the max gain was obtained at CP levels of 16 to 18%. Feed conversion was highest in MC pigs (~4.0) followed by $F_1$ (~3.3) and $F_2$ (~3.1), and within genotypes was lowest at the optimum CP level (p<0.05). Back fat thickness in MC (33.1 mm), $F_1$ (23.0 mm) and $F_2$ (20.5 mm) pigs was different and within genotypes was the lowest at intermediate CP levels. In conclusion, increasing the dietary crude protein contents in practical diets for pigs in Vietnam can increase production on small holder farms. Optimal performance for MC, $F_1$ and $F_2$ pigs is achieved at different dietary crude protein contents.

트리풀르오로메칠트리페닐-1,2,4-트리오키소란의 결정 및 분자구조 (The Crystal and Molecular Structure of Trifluoromethyltriphenyl-1,2,4-Trioxolane)

  • 안중태;서일환
    • 한국결정학회지
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    • 제5권1호
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    • pp.14-19
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    • 1994
  • 트리풀르오로메칠트리페닐 1,2,4-트리오키소란(C21H15F3O3)은 삼사정계인 공간군 P1으로 a=10.477(1), b=11.056(1), c=9.917(3)A, a=104.7(1), B=122.7(1), r=63.9(1)°, Z=2, V=867.9(3) A3, Dc=1.43 g/cm3, λ(Mo BCn)=0.71069 A, μ=0.0116 cm-1, F(000)=384, 그리고 I ) 1.0 o(I) 인 1713 개의 관측 된 회절점에 대한 R 값은 0.067 였다. 직접법에 의하여 구조를 풀었으며 전행열-최소자숭법에 의하여 정밀화하였고 C-H결합길이는 0.96 A 에 고정하였다. 106.6°의 두 사이각을 갖는 페닐고리(2)와 고리(3)는 트리오키소란분자평면의 위쪽에 있으나 CF3기와 페닐고리(1)은 아래쪽으로 있다. 트리오키소란 꼬리는 봉투모양의 구조를 갖고 있으며 그의 두 탄소 원자(C(2)와 C(3))는 탄소원자의 내각에 거의 비슷한 각으로 치환기들과 연결되어 있다. 분자들은 van der Waals 힘에 의하여 결합되었고 가장 가까운 거리는 0(2) 와 F(2)(-x, 1+y,1-z) 사이의 3.256 A 이다.

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Warm Dust and Gas of Massive YSOs Revealed by Herschel PACS Spectroscopy

  • 권우진
    • 천문학회보
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    • 제40권2호
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    • pp.41.3-41.3
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    • 2015
  • As part of the Herschel key program "Water in Star-forming Regions with Herschel (WISH)", PACS imaging spectroscopy data have been taken toward ten massive young stellar objects (YSOs): four high mass protostellar objects (HMPOs), two hot molecular cores (HMCs), and four ultracompact HII regions (UCHIIs). The spectra cover a broad range of wavelengths (55 to 210 micron) presenting various atomic and molecular lines as well as excellent dust thermal continua. By fitting the continua utilizing a modified black-body formula we estimate mass-weighted temperature and column density distributions of warm dust and find that UCHII regions are warmer and HMCs are more deeply embedded than the other types. We also estimate rotational temperature and column density distributions of warm CO gas using the rotational diagram analysis. In addition, based on the comparison of high J CO line fluxes to the RATRAN estimates of central heating envelope models, we find that majority of warm CO is originated from bipolar outflow shocks.

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The Crystal Structure of a $\beta$-Allyl Type Phenylpropanoid 2-(4-allyl-2, 6-dimethoxyphenoxy)-1-(4-hydroxy-3-methoxyphenyl) propan-1-ol, from the Seeds of Myristica fragrans

  • Kim, Yang-Bae;Park, Il-Yeong;Kim, Jeong-Ae;Shin, Kuk-Hyun
    • Archives of Pharmacal Research
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    • 제14권2호
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    • pp.137-142
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    • 1991
  • The structure of a $\beta$-allyl type phenylpropanoid was determined by single crystal X-ray diffraction analysis. The compound was recrystallized from a mixture of n-hexane and benzene in monoclinic crystal system with a = 24.782 (2), b = 10.537 (1), c = 7.871 (1) ${\AA}, \beta=95.74$ (1)$^\circ, $D_x$=1.216, $D_m$=1.22g/$cm^3$, space group $P2_1/a$, and Z=4. The structure was solved by direct method and refined by least-squares procedure to the final R value of 0.054 for 2824 observed reflections {$F{\geq}3\sigma(F)$}. The molecular geometry shows a most stable trans-form with respect to the bulky phenyls, and this conformation is settled by an intramolecular hydrogen bond. In the crystal, the molecules are arranged along with the screw axis, and stabilized by the $O{\cdot}H{\cdots}O$ type intermolecular hydrogen bonds. The other intermolecular contacts appear to be the normal van der Waals' interactions. The compound is a dimeric phenylpropanoid, and belongs to the neolignan analogues.

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Constituents of Paulownia tomentosa Stem(III): The Crystal Structure of Methyl 5-Hydroxy-dinaphtho[1,2-2',3]furan-7,12-dione-6-carboxylate

  • Park, Il-Yeong;Kim, Bak-Kwang;Kim, Yang-Bae
    • Archives of Pharmacal Research
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    • 제15권1호
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    • pp.52-57
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    • 1992
  • The molecular structure of a natural compound was determined by single crystal X-ray diffraction analysis. The compound was isolated by methanol extraction and repeated chromatography from the stem of Paulownia tomentosa. Yellow prismatic crystals of the compound, which were recrystallized from tetrahydrofuran, are triclinic, with a = 7.310 (6), b = 10.753(6), c = 11.586(5) ${\AA}.\;\alpha= 93.30(6),\;\beta=105.62(10),\;\gamma=109.49(7)^\circ,\;D_x=1.514,\;D_m=1.51 g/cm^3$, space group P1 and Z = 2. The structure was solved by direct method, and refined by least-squares procedure to the final R-value of 0.032 for 1271 independent reflections $(F\le3\sigma{(F))}$. The compound is one of new furanquinone analogue. The molecule has a nearly planar conformation with an intramolecular hydrogen bond. In the crystal, the planar molecules are arranged as a prallel sheet-like pattern, and these stackings are stabilized by the O-H...O type intermolecular hydrogen bonds. The other intermolecular contacts appear to be the normal van der Waals interactions.

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의복 스타일 이미지 선호와 자기이미지와의 관계 연구 (A Study on Image Preferences of Clothing Styles and Self-Image)

  • 김현주
    • 복식
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    • 제33권
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    • pp.41-54
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    • 1997
  • The objectives of this study were to find out the relationships between clothing style pre-ferences and self-image and to examine the differences in clothing style preferences ac-cording to marital status educational level and social stratification of women. The drawings of clothing style were designed referring to the catalogues for spring/summer of 1996 and printed by computer 6 styles of suit corresponding to clothing image were selected. Style A is a brown suit decorated with scarf style B a grey suit with stripes C a yellow suit with printed pattern D a grey and beige suit E a chanel suit decorated with corsage and F a blue suit with pleated skirt. The self-image was separated to the actual self-image and the ideal self-image. Samples were 226 women(ages 18 to 37) in Seoul Korea. The results of the study were the followings. 1. Clothing images of 6 styles were estimated; Style A was plain conservative formal and gentle image ; B masculine solid actual dark and plain image; C feminine romantic bright and splendid image; D actual ordinary un-fashionable and plain image; E feminine ten-der romantic and non-active image ; F indi-vidual fshionable open casual sprightly and active image. 2. There were significant relationships be-tween clothing style preferences and realistic self-image. The women who considered them-selves as masculine preferred style B mascu-line and plain image. The women feminine and conservative preferred style E feminine and tender image. The women not to follow the fshion preferred style D ordinary and plain image. The women informal and open pre-ferred the style F casual and active image. 3. There were significant relationships be-tween clothing style preferences and ideal self-image. The women who wanted to be-tween clothing style preferences and ideal self-image. The women who wanted to be con-sidered themselves as feminine and conserva-tive preferred style E feminine and tender im-age. The women who wanted gentle and con-servative preferred style D ordinary and plain image. The women who wanted sprightly pre-ferred the style F casual and active image. 4. There were significant differences in clothing style preferences according to marital status educational level and social stratifi-cation. The women with more eduacation pre-ferred the splendid and the plain image at the same time. The upper class preferred feminine image and lower class casual and active image.

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Fluoxymesterone, $C_{20}H_{29}FO_3$의 결정구조 (The Crystal Structure of Fluoxymesterone, $C_{20}H_{29}FO_3$)

  • 김의성;박권일;조성일
    • 한국결정학회지
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    • 제4권1호
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    • pp.6-10
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    • 1993
  • 11 β ,17 β -dihydroxy-9a-fluoro-l7a-methyl androst-4-en-3-one (Fluoxymesterone), CgoH29 FO,, orthorhombic, P2,2,2,, a=13.468(5) A, b= 19.554 (2)A, c=6.578(9)A, a=b=r=90˚, A (CuKa)=1.5406 A , Dm=1.289cm-3, Dc=1.299cm-3 and Z=4 at T=298k. The structure was solved by direct method using seminvariants of ggg Parity group and refined by the full-matrix least-square method, resulting model with reliability factor R=0.069 for 1098 unique reflection over 3σ . Ring A is an 1β-2a-half chair, 5 ring has a highly symmetrical chair conformation, C ring is in a distorted chair conformation and D ring is a 13aenveLope conformation. In the crystal structure, the molecules are packed with a hydrogen bond of 011-H23‥‥03(0.5+x, 1.5-y, 1.0-z) [1.94(9) A of H‥‥0.2.786(9)A of 0‥‥0 and 165(8) ˚ of

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Z-3-파라-톨릴치오-4-니트로-3-헥센의 결정 및 분자구조 (The Crystal and Molecular Structure of Z-3-P-Tolylthio-4-Nitro-3-Hexene)

  • 안중태
    • 대한화학회지
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    • 제34권2호
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    • pp.130-135
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    • 1990
  • Z-3-파라-톨리치오-4-니트로-3-헥센의 결정은 단사정계에 속하며 a = 13.756 (3), b = 9.310(4), c = 21.305(3) $\AA$, $\beta = 95.0_{\circ}$이며 단위세포안에 8개의 분자가 있으며 2.0$\sigma$(I) 보다 큰 강도를 가진 2935개의 회절반점에 대하여 계단식 대각 최서자승법에 의하여 정밀화된 최종 R값은 0.085이다. 직접법에 의하여 구조를 풀었으며 C-H결합길이와 메칠기는 길이를 고정시켜 이상적인 기하학적구조에 맞도록 하여 계산을 정밀화하였다. 두 분자 A와 B는 끝의 두 에칠기를 제외하고는 거의 유사한 구조를 갖고 있다. 니트로기를 포함한 에틸렌 모양의 골격은 메칠벤젠기에 거의 수직으로 되어 있으며 두 에틸기는 시스-형 구조를 가지고 있으나 끝부분의 메칠기는 A분자에서는 그의 골격에 대해 서로 반대방향으로 향하고 있고 B분자는 같은 방향으로 향하고 있다. 결정내 분자들은 비결합성 van der Waals힘으로 쌓여져 있다.

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