• Title/Summary/Keyword: Deposition transfer

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Improvement of PDMS graphene transfer method through surface modification of target substrate (폴리디메틸실록산(PDMS)을 이용한 그래핀 전사법 개선을 위한 계면처리 연구)

  • Han, Jae-Hyung;Choi, Mu-Han
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.2
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    • pp.232-239
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    • 2015
  • In this paper, we study the dry transfer technology utilizing PDMS (Polydimethylsiloxane) stamp of a large single-layer graphene grown on Cu-foil as catalytic metal by using Chemical Vapor Deposition (CVD). By changing the surface property of the target substrate through $UV/O_3$ treatment, we can transfer the graphene on the target substrate while minimizing mechanical damages of graphene layer. Multi-layer (1~4 layers) graphene was stacked on $SiO_2/Si$ wafer successfully by repeating thetransfer method/process and then optical transmittance and sheet resistance of graphene layers have been measured as a quality assessment.

Fabrication and Properties of Organic Semiconductor CuPccp LB Thin Film (유기 반도체 CuPccp LB초박막의 제작 및 특성)

  • Jho, Mean Jea;Xouyang, Saiyang;Lee, Jin Su;Ahn, Da Hyun;Jung, Chi Sup
    • Journal of Sensor Science and Technology
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    • v.28 no.1
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    • pp.23-29
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    • 2019
  • A copper tetracumylphenoxy phthalocyanine (CuPccp) thin film was formed on an organic insulator film by Langmuir-Blodgett (LB) deposition for gas sensor fabrication. To increase the reproducibility of film transfer, stearyl alcohol was used as a transfer promoter. The structural properties of the CuPccp layers were optically monitored through attenuated total reflection and polarization-modulated ellipsometry techniques. The average thickness of a single layer of the CuPccp LB film was measured to be 2.5 nm. Despite the role of the transfer promoter, the stability of the layer transfer was not sufficient to ensure homogeneity of the LB film. This was probably due to the presence of aggregates in the molecular structure of the CuPccp LB film. Nevertheless, copper phthalocyanine polymorphism can be greatly suppressed by the LB arrangement, which appears to contribute to the improvement of electrical conductivity. The p-type semiconductor characteristics were confirmed by Hall measurements from the CuPccp LB films.

Fireside Corrosion Characteristics in Coal-Fired Boiler Tube (석탄연소중 발생되는 보일러 튜브의 화염측 부식특성)

  • Kim, Tae-Hyung;Seo, Sang-Il;Park, Ho-Young;Kim, Young-Ju
    • 한국연소학회:학술대회논문집
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    • 2006.10a
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    • pp.276-281
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    • 2006
  • Although fireside corrosion of heat transfer surfaces in coal fired steam generators has been a problem to some extent for a number of tears, with the advent of low NOx firing systems these surfaces can be exposed to conditions that will exacerbate wastage rates. Numerous reports of waterwall wastage in coal fired boilers have appeared in the literature. It is believed that wastage results both from gaseous phase attack of metal surfaces and from deposition of ash and unburned fuel. Gaseous phase attack is known to occur in the presence of reducing sulfur species such as $H_2S$ and in the presence of fuel chlorine. The highest wastage rates are thought to be due to deposition of unoxidized material and the presence of fuel chlorine. Localized wall and near wall conditions that may exacerbate wastage include reducing conditions, high temperatures, high heat fluxes, and a high fraction of unoxidized material deposited. So, this study is directed at developing an advanced corrosion model in coal-fired utility boilers.

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Use of Lycopene, an Antioxidant Carotinoid, in Laying Hens for Egg Yolk Pigmentation

  • Kang, D.-K.;Kim, S.-I.;Cho, C.-H.;Yim, Y.-H.;Kim, H.-S.
    • Asian-Australasian Journal of Animal Sciences
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    • v.16 no.12
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    • pp.1799-1803
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    • 2003
  • The possibility of lycopene affecting egg yolk pigmentation was studied with lycopene diets containing 0, 4, 8, and $12{\mu}g/g$ meal, respectively. The addition of lycopene above $4{\mu}g/g$ meal significantly improved yolk color after four days of supplementation. The transfer of lycopene into egg yolk was confirmed by thin layer chromatography, and high-performance liquid chromatography-mass spectrometry (HPLC-MS). The deposition rate of lycopene into egg yolk was approximately 2%, which was quantitatively determined using a HPLC with a UV detector. The result indicates that lycopene is a good candidate for egg yolk pigmentation and for making functional eggs.

Deposition Characteristics and Stability of Itaconate LB Films (이타코네이트계 LB막의 안정성 및 누적특성)

  • 신훈규;최용성;김은구;김경철;권영수;이범종;장정수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1994.11a
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    • pp.198-201
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    • 1994
  • Stability improvement of fragile LB films was attempted by polyion complexation of monolayers at the air-water interface and crosslinking of the resulting LB films. The spreading polymers were synthesized by radical copolymerization of monoalkyl itaconate with oligoethyleneglycol methyl vinylether, and poly(allylamine) was employed as the subphase polymer. Formation and characteristic of the monolayers were comfirmed by surface pressure-area($\pi$-A) isotherms. The two different polymers formed polyion-complexed monolayer through the formation of carboxylate/ammonium salt at the air-water interface. Y-type deposition occurred on solid substrates, and the transfer ratio was over 0.7. Pores (diameter, 0.1$\mu\textrm{m}$) of a membrane filter could be covered by polyion-complexed 6 layers. Interactions of the polymers with metal ions were investigated of the air-water interface and in the LB films. The structure change and macroscope morphology of the LB films were confirmed by FT-lR and SEM, respective1y.

Toward Charge Neutralization of CVD Graphene

  • Kim, Soo Min;Kim, Ki Kang
    • Applied Science and Convergence Technology
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    • v.24 no.6
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    • pp.268-272
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    • 2015
  • We report the systematic study to reduce extrinsic doping in graphene grown by chemical vapor deposition (CVD). To investigate the effect of crystallinity of graphene on the extent of the extrinsic doping, graphene samples with different levels of crystal quality: poly-crystalline and single-crystalline graphene (PCG and SCG), are employed. The graphene suspended in air is almost undoped regardless of its crystallinity, whereas graphene placed on an $SiO_2/Si$ substrate is spontaneously p-doped. The extent of p-doping from the $SiO_2$ substrate in SCG is slightly lower than that in PCG, implying that the defects in graphene play roles in charge transfer. However, after annealing treatment, both PCG and SCG are heavily p-doped due to increased interaction with the underlying substrate. Extrinsic doping dramatically decreases after annealing treatment when PCG and SCG are placed on the top of hexagonal boron nitride (h-BN) substrate, confirming that h-BN is the ideal substrate for reducing extrinsic doping in CVD graphene.

A Study on Electrical Characteristics for Horizontal Direction of Stearic Acid LB Films (Stearic Acid LB막의 수평방향에 대한 전기적 특성 연구)

  • 김도균;최용성;장정수;권영수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.11a
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    • pp.393-396
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    • 1996
  • The electrical characteristics of stearic acid LB films far the horizontal direction were investigated to develop the gab sensor using LB films. $\pi$ -A isotherm was measured to transfer stearic acid on slide glass substrate and surface pressure for optimal deposition was 25[dyne/cm]. The deposition status of stearic acid LB films was verified by the measurement of capacitance which was increased with the number of layers. The thickness of electrode was estimated about 1000 by the I-V characteristics far the horizontal direction. The Conductivity of stearic acid LB films for horizontal direction was 10$^{-8}$ [S/cm] that mean like semiconductor.

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Establishment of calculation methodology and thermal analysis for the development of a water calorimeter

  • Kang, M.Y.;Kim, Junhyuck;Choi, H.D.
    • Nuclear Engineering and Technology
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    • v.52 no.11
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    • pp.2620-2629
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    • 2020
  • As an early stage in the development of a water calorimeter, this study established a computer simulation methodology for analyzing the thermal behavior of a water calorimeter based on radiation transport and energy deposition. As a result, this study developed a method wherein the energy deposition distribution, which is obtained by applying Monte Carlo methods in water calorimeters, is directly used as a heat source for the thermal analysis model. Based on the proposed method, heat transfer in a water vessel and the effect of thermistor self-heating were analyzed. Through an analysis of the water velocities with and without a water vessel, it was found that a water vessel can serve as a convection barrier. Furthermore, it was confirmed that when considering thermistor self-heating, the water temperature change at the thermistor location is 0.219 mK higher compared to that when the thermistor was not considered. Therefore, thermistor self-heating must be considered to analyze the thermal behavior of a water calorimeter more accurately.

Study on Cake Resistance and Microfiltraion Performance of Rotating Membrane Filters (회전막 정밀여과기에서 케이크 저항과 여과성능에 대한 연구)

  • 박원철;최창균;김재진;박진용
    • Proceedings of the Membrane Society of Korea Conference
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    • 1998.04a
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    • pp.105-109
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    • 1998
  • 1. Introduction : In microfiltration the transport, deposition and removal of particles control cake formation on a filter. In this connection a new model on cake formation, based on the wall shear stress, was tested here in comparison with experiments of fine particle slurry under Taylor-vortex flow. The model expresses the deposition process for particles as two first-order steps in series of mass transfer and adhesion, and their removal process as a linear relation to the wall shear stress. This embraces characteristics of both dead-end and crossflow filtration. The correlation resulting from fitting to experimental data represented the experimental data reasonably well. This study will be helpful in analyzing fouling in heat exchangers.

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Sensitivity Analysis of Input Parameters for a Dynamic Food-Chain Model DYNACON (동적섭식경로모델 DYNACON에 대한 입력변수의 민감도분석)

  • Hwang, Won-Tae;Lee, Geun-Chang;Han, Moon-Hee;Cho, Gyu-Seong
    • Journal of Radiation Protection and Research
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    • v.25 no.1
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    • pp.11-19
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    • 2000
  • The sensitivity analysis of input parameters for a dynamic food chain model DYNACON was conducted as a function of deposition date for the long-lived radionuclides $(^{137}Cs,\;^{90}Sr)$. Also, the influence of input parameters for the short and long-terms contamination of selected foodstuffs (cereals, leafy vegetables, milk) was investigated. The input parameters were sampled using the LHS technique, and their sensitivity indices represented as PRCC. The sensitivity index was strongly dependent on contamination period as well as deposition date. In case of deposition during the growing stages of plants, the input parameters associated with contamination by foliar absorption were relatively important in long-term contamination as well as short-term contamination. They were also important in short-term contamination in case of deposition during the non-growing stages. In long-term contamination, the influence of input parameters associated with foliar absorption decreased, while the influence of input parameters associated with root uptake increased. These phenomena were more remarkable in case of the deposition of non-growing stages than growing stages, and in case of $^{90}Sr$ deposition than $^{137}Cs$ deposition. In case of deposition during growing stages of pasture, the input parameters associated with the characteristics of cattle such as feed-milk transfer factor and daily intake rate of cattle were relatively important in contamination of milk.

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