• 제목/요약/키워드: Deposition index

검색결과 290건 처리시간 0.035초

유기금속화학증착법으로 유리기판 위에 성장된 산화아연 하이브리드 구조의 광학적 전기적 특성 (Optical and Electrical Properties of ZnO Hybrid Structure Grown on Glass Substrate by Metal Organic Chemical Vapor Deposition)

  • 김대식;강병훈;이창민;변동진
    • 한국재료학회지
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    • 제24권10호
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    • pp.543-549
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    • 2014
  • A zinc oxide (ZnO) hybrid structure was successfully fabricated on a glass substrate by metal organic chemical vapor deposition (MOCVD). In-situ growth of a multi-dimensional ZnO hybrid structure was achieved by adjusting the growth temperature to determine the morphologies of either film or nanorods without any catalysts such as Au, Cu, Co, or Sn. The ZnO hybrid structure was composed of one-dimensional (1D) nanorods grown continuously on the two-dimensional (2D) ZnO film. The ZnO film of 2D mode was grown at a relatively low temperature, whereas the ZnO nanorods of 1D mode were grown at a higher temperature. The change of the morphologies of these materials led to improvements of the electrical and optical properties. The ZnO hybrid structure was characterized using various analytical tools. Scanning electron microscopy (SEM) was used to determine the surface morphology of the nanorods, which had grown well on the thin film. The structural characteristics of the polycrystalline ZnO hybrid grown on amorphous glass substrate were investigated by X-ray diffraction (XRD). Hall-effect measurement and a four-point probe were used to characterize the electrical properties. The hybrid structure was shown to be very effective at improving the electrical and the optical properties, decreasing the sheet resistance and the reflectance, and increasing the transmittance via refractive index (RI) engineering. The ZnO hybrid structure grown by MOCVD is very promising for opto-electronic devices as Photoconductive UV Detectors, anti-reflection coatings (ARC), and transparent conductive oxides (TCO).

졸-겔법을 이용한 광증폭기의 Er 이온 캡슐화 및 광학적 특성 (Encapsulation and optical properties of Er3+ ions for planar optical amplifiers via sol-gel process)

  • Kim, Joo-Hyeun;Seok, Sang-Il;Ahn, Bok-Yeop
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2003년도 추계학술발표강연 및 논문개요집
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    • pp.135-135
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    • 2003
  • The fast evolution in the fold of optical communication systems demands powerful optical information treatment. These functions can be performed by integrated optical systems. A key component of such systems is erbium doped waveguide amplifier(EDWA). The intra 4f radiative transition of Er at 1.5 $\mu\textrm{m}$ is particularly interesting because this wavelength is standard in optical telecommunications. The fabrication of waveguide amplifier for integrated optics using sol-gel process has received an increasing attention. Potential advantage of lower cost by less capital equipment and easy processing makes this process an attractive alternatives to conventional technologies like flame hydrolysis deposition, ion exchange and chemical vapor deposition, etc. In addition, sol-gel process has been found to be extremely suitable for the control of composition and refractive index related directly with optical properties. The main drawback of such an amplifier with respect to the EDWA is the need for a much higher Er3+ concentration to compensate for the smaller interaction length. However, the high doping of Er might be resulted in the non-radiative relaxation by clustering of Er ions End co-operative upconversion. In order to solve this problem, we investigate the possibility of avoiding short Er-Er distances by encapsulation of Er3+ ions in hosts such as organic-inorganic hybrid materials. For inorganic-organic hybrid sols, methacryloxypropyltrimethoxysilane (MPTS), zirconyl chloride octahydrate and erbium(III) chloride hexahydrate were used as starting materials, followed by conventional sol-gel process. It was observed by TEM that nano sols having core/shell toplology were formed, depending on the mole ratio of Zr/Er. The surface roughness for the coatings on Si substrate was investigated by AFM as a function of Zr/Er ratio. The local environment and vibrational Properties of Er3+ ions were studied using Near-IR, FT-IR, and UV/Vis spectroscopy. Nano hybrid coatings derived from polymer and Er doped encapsulation Eave the good luminescence at 1.55$\mu\textrm{m}$.

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PM-10 내 중금속의 장기간 평균농도 및 위해도 평가 (An Assessment of the Long-Term Concentration of Heavy Metals and Associated Risk in Ambient PM-10)

  • 이혜문;김동술;이진홍
    • 한국대기환경학회지
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    • 제12권5호
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    • pp.555-566
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    • 1996
  • In order to assess the long-term airborne concentrations of 6 metals such as Cr, Cd, Pb, Zn, K, and Na and the associated health resk, a great number of PM-10 samples were collected and analyzed in Kyung Hee University-Suwon Campus for three years from 1991 to 1993. The 3-year average concentration of Pb in respirable particulate matters was 142.6 ng/m$^{3}$ while that of Zn was 1,210.5ng/m$^{3}$. The corresponding hazard index from Pb Zn for the ingalation route was estimated to be 9.5.times.10$^{-2}$ and 3.5.times.10$^{-2}$ , respectively. Therefore, it can be said that there was no adverse chronic health effects by airborne Pb and Zn. However, the 2-year average concentration of Cr(6) was estimated to be 1.3ng/m$^{3}$ shile the 3-year average concentration of Cd was 3.1ng/m$^{3}$. The total cancer risk by these two metals for the inhalation route was estimated to be about 7.2.times.10$^{-6}$ . This order-of-magnitude risk estimate suggests that the ingalation risk in the study area from all carcinogenic metals including As and Ni (subsulfide) might exceed the acceptable risk criteria of 10$^{-5}$ -10$^{-6}$ by U.S.EPA.For a better risk assessment in the future, alveolar deposition of PM-10 in the study area were also discussed and an assessment was done.

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Effect of Dietary Conjugated Linoleic Acid (CLA) on Abdominal Fat Deposition in Yellow-feather Broiler Chickens and Its Possible Mechanism

  • Zhou, J.
    • Asian-Australasian Journal of Animal Sciences
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    • 제21권12호
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    • pp.1760-1765
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    • 2008
  • A total of 60 one-day-old Yellow-feather broiler chickens were allotted into treatment and control groups. The treatment group was fed with the diet supplemented with 3% conjugated linoleic acid (CLA) for 48 d, while control group was fed with the diet supplemented with 3% rapeseed oil. Chickens were slaughtered in each group at the age of 49 d, and the blood and the abdominal adipose tissue were sampled. Serum cLeptin and serum cAdiponectin were measured by ELISA. The total RNA was extracted from adipose tissue to measure the abundance of the chicken growth hormone receptor (cGHR), insulin-like growth factor 1 (cIGF-1), insulin-like growth factor I receptor (cIGF-IR), peroxisome proliferator-activated receptor gamma ($cPPAR{\gamma}$), cAdiponectin and cAdipoIR mRNA by RT-PCR using ${\beta}$-actin as an internal standard. Results showed that the CLA decreased the abdominal fat index by 20.93% (p<0.05). The level of serum cLeptin but not serum cAdiponectin was significantly increased by CLA treatment (p<0.05). CLA down-regulated the relative abundance of cGH-R mRNA and $cPPAR{\gamma}$ mRNA in abdominal adipose tissue by 24.74% (p<0.05) and 66.52% (p<0.01) respectively. However, no differences were found between CLA treatment group and control group (p>0.05) in the relative abundance of cIGF-1, cIGF-IR, cAdiponectin, and cAdipoIR mRNA in abdominal adipose tissue. The data suggested that CLA inhibited abdominal fat deposition in broiler chicken may be determined by decreasing the GHR available for GH, and by inhibiting the differentiation of preadipocytes via down-regulation of $PPAR{\gamma}$, but independent of IGF and (or) GH-IGF pathway or adiponectin action.

전극함몰형 실리콘 태양전지의 제작시 스프레이 방법에 의한 타이타늄 옥사이드층의 적용에 관한 연구 (Titanium dioxide by spray deposition for buried contact silicon solar cells fabrication)

  • A.U. Ebong;S.H. Lee
    • 한국결정성장학회지
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    • 제6권2호
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    • pp.263-274
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    • 1996
  • 타이타늄 옥사이드층을 태양전지의 표면 보호막으로 사용시, 그 적합성에 대해 조사하였다. 스프레이법으로 형성된 타이타늄 옥사이드의 박막층은 태양전지 제조 과정중 사용되는 화학약품에 잘 견디며, 이 층을 사용함으로서 고온산화공정을 줄일 수 있다.

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반도체 레이저 단면의 실시간 무반사 및 고반사 코팅 (Real-time controlled deposition of anti-reflection and high-reflection coatings for semiconductor laser)

  • 김효상;박흥진;황보창권;김부균;김형문;주흥로
    • 한국광학회지
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    • 제8권5호
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    • pp.395-402
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    • 1997
  • $\1.55mu\textrm{m}$ InGaAsP MQW FP 반도체 레이저 단면의 무반사 코팅 두께를 앞면에 무반사 코팅하는 동안 뒷면의 출력을 실시간으로 측정하여 결정하였다. 굴절률 1.85인 $SiO_x$ 박막의 최적 두께는 188 nm이고, 무반사 코팅 전, 후의 문턱전류비로 계산한 단면의 반사율은 약 2 $\times$ $10^{-4}$이었다. 무반사 코팅 후 주입전류 60 mA일 때 출력이 87%, 기울기 효율이 3.4배, 문턱전류가 2.64배 증가하였다. 또한 실시간으로 $Si/SiO_2$ 박막의 고반사 코팅을 뒷면에 한 후 코팅 전보다 출력이 약 160% 향상되었고, 기울기 효율이 3.8배 증가하였으며, 문턱전류는 1.07배로 코팅 전과 거의 비슷하여, 무반사 및 고반사 코팅 후 반도체 레이저의 출력특성이 크게 향상되었다.

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이온빔 보조 증착법에 의해 제작된 $TiO_2$ 박막의 광학적 특성 (Optical Properties of $TiO_2$ Thin Films Prepared by Ion-beam Assisted Deposition)

  • 조현주;이홍순;황보창권;이민희;박대윤
    • 한국광학회지
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    • 제5권1호
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    • pp.9-17
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    • 1994
  • Ar 이온빔 보조 증착법(IBAD)으로 제작한 $TiO_2$ 박막의 광학적 특성을 연구하였다. 포락선 방법으로 측정한 단층 IBAD TiO2 박막의 굴절률은 이온빔을 사용하지 않은 보통 $TiO_2$ 박막보다 증가하여 bulk의 값에 보다 가까웠으며, 진공과 공기 중에서 투과 파장 영역의 이동을 측정하여 조사한 단층 IBAD 박막의 조밀도는 보통 박막보다 현격히 증가하였다. 이온빔 보조 증착법으로 $(TiO_2/SiO_2)$ 다층 박막 간섭필터를 제작하였고, 진공과 공기 중에서 각각 간섭 필터의 최고 투과 파장의 이동을 측정하였다. IBAD 간섭 필터의 파장 이동량은 보통 간섭필터에 비해 무시할 수 있을 정도로 작아 IBAD 박막의 조밀도가 증가하고 광학적으로 안정된 것을 알 수 있었다. 또한 IBAD $TiO_2$ 박막과 보통 $TiO_2$ 박막 모두 원소 조성비는 정상이었으며 결정 구조는 비정질이었다.

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Experimental Demonstration of Enhanced Transmission Due to Impedance-matching Si3N4 Layer in Perforated Gold Film

  • Park, Myung-Soo;Yoon, Su-Jin;Hwang, Je-Hwan;Kang, Sang-Woo;Kim, Deok-kee;Ku, Zahyun;Urbas, Augustine;Lee, Sang Jun
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.359-359
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    • 2014
  • In this study, surface plasmon resonance structures for the selective and the enhanced transmission of infrared light were designed. In order to relieve the large discontinuity of refractive index between air and metal hole array, $Si_3N_4$ was used as the impedance matching layer. Experimental parameter were calculated and determined in advance by the rigorous coupled wave analysis (RCWA) simulation, and then the experiment was carried out. A 2-dimensional metal hole array structures were patterned on the size of $1{\times}1cm^2$ GaAs substrate using photolithography process, and 5 nm thick Ti, 50 nm thick Au were deposited by E-beam evaporator, respectively. Subsequently, $Si_3N_4$ films with various thicknesses (150, 350, 550, and 750 nm) were deposited by plasma enhanced chemical vapor deposition (PECVD). For the comparison, transmittance of specimens with and without $Si_3N_4$ was measured using Fourier transform infrared spectroscopy (FTIR) in the range of $2.5-15{\mu}m$. Furthermore, the surface and the cross-sectional images were collected from the specimens by scanning electron microscopy (SEM). From the results, it was demonstrated that the transmittance was enhanced up to 80% by the deposition of 750 nm $Si_3N_4$ at $6.23{\mu}m$. It has advantage of enhanced transmission despite the simple fabrication process.

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국내산 주요 침엽수 3종의 수간 내 마이크로피브릴 경사각의 변이 (Variation of Microfibril Angle Within Stems of Three Commercial Softwoods Grown in Korea)

  • 은동진;김남훈
    • Journal of the Korean Wood Science and Technology
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    • 제36권4호
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    • pp.77-83
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    • 2008
  • 국내에서 생장한 주요 침엽수 3종(소나무, 잣나무, 리기다소나무)의 수간 내 마이크로피브릴 경사각(microfibril angle, MFA)의 축방향 및 방사방향 변이를 요오드 침적법에 의해 조사하였다. 각 수종의 MFA의 평균값은 소나무 $16.4^{\circ}$, 잣나무 $14.4^{\circ}$, 리기다소나무 $26.2^{\circ}$로 리기다소나무가 가장 크게 나타났다. 공시 수종의 MFA는 약 15~20 연륜까지 감소하다가 그 후 거의 안정된 경향을 보여 주었고 만재부의 MFA는 조재부의 MFA보다 다소 작은 경향이 있었다. 공시재료의 수고에 따른 MFA의 차이는 기부 부분에서 다소 크게 나타났으며 수고가 증가함에 따라 MFA는 감소하는 경향이 있었으나 리기다소나무 조재부는 예외였다. 따라서 MFA는 국내산 주요 침엽수재의 미성숙재와 성숙재를 구분하는 지표의 하나로 이용이 가능할 것으로 생각되었다.

Rf Magnetron Sputtering 방법에 의하여 제조된 $(BaSr)TiO_3$ 박막의 구조적, 광학적 특성 고찰 (The Characterization of Structural and Optical Properties for rf Magnetron Sputtered $(BaSr)TiO_3$ Thin Film)

  • 김태송;오명환;김종희
    • 분석과학
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    • 제6권2호
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    • pp.239-246
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    • 1993
  • ITO coated glass, bare glass, 그리고 (100)Si 기판 위에 증착된 $(BaSr)TiO_3$ 박막의 구조는 기판의 종류에 관계없이 변하지 않았으나 결정성은 다결정 ITO층과 (100)Si 기판에 있어서 증대되었다. ITO coated glass 기판 위에 증착된 $(BaSr)TiO_3$ 박막의 조성은 거의 화학양론적으로 일치하였으며 ((Ba+Sr)/Ti=1.08~1.09) 증착 중 상당히 치밀하고 균질하였다. 그러나 증착온도가 증가함에 따라 성장한 박막과 ITO층 사이에, 그리고 ITO층과 base glass 사이에 확산이 보다 심화되었다. ITO coated glass 기판 위에 증착된 $(BaSr)TiO_3$ 박막은 상당히 투명하였으며(투과율 약 80%) 굴절률($n_f$)은 기판온도의 증가에 따라 2.138~2.286이었다.

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