• 자원환경지질
• /
• 제4권3호
• /
• pp.113-119
• /
• 1971

The Daeheung Dolomite Mine, which is about 6km south of Danyang, Chungcheongbugdo, is coincided with almost central portion of the Danyang quardrangle scaled in 1 : 50,000. The purpose of this report is to prepare a information for the economic evaluation on the mine. Geology of the region is composed of worm-eaten limestone, crystalline limestone, crystalline dolomite rock, sandstone and shale from bottom, those are applicable to socalled Dumugol and Maggol formation of Ordovician, and batholithic biotite granite is intruded the west-side of the ditto sedimentary rocks. The dolomite bed, emplaced in bottom of the upper limestone formation, so-called Maggol formation, is about 270m in thickness, and dips $30^{\circ}{\sim}50^{\circ}$ northwest. The facies of the dolomite rock contained many brucite crystals is not only coarse-grained crystalline, but also micro crystalline in contact metasomatic parts. 25 samples were taken from the two series, A and B, in the nearly crossed direction to the strike of the dolomite bed as shown in the geological map. They were chemically analysed on the components of MgO, CaO, and $SiO_2$ as shown in Table 2. The estimate ore reserves total some 107,200,000 metric tons above the 320m level with the following average contents: MgO 21.80%, CaO 29.27% and $SiO_2$ 0.64%. It is caused by brucite minerals that MaO content in the dolomite rock is higher than pure dolomite (21.7%). The dolomite ore is possible in use for magnesian fertilizer, magnesian cement and refractory material, especially the microcrystalline dolomite ore is useful for a refractory material in furnaces of iron industries.

• 한국세라믹학회지
• /
• 제48권3호
• /
• pp.236-240
• /
• 2011

In order to deposit a homogeneous and uniform ${\beta}$-SiC films by chemical vapor deposition, we demonstrated the phase stability of ${\beta}$-SiC over graphite and silicon via computational thermodynamic calculation considering pressure, temperature and gas composition as variables. The ${\beta}$-SiC predominant region over other solid phases like carbon and silicon was changed gradually and consistently with temperature and pressure. Practically these maps provide necessary conditions for homogeneous ${\beta}$-SiC deposition of single phase. With the thermodynamic analyses, the CVD apparatus for uniform coating was modeled and simulated with computational fluid dynamics to obtain temperature and flow distribution in the CVD chamber. It gave an inspiration for the uniform temperature distribution and low local flow velocity over the deposition chamber. These calculation and model simulation could provide milestones for improving the thickness uniformity and phase homogeneity.

• 한국진공학회지
• /
• 제6권2호
• /
• pp.114-121
• /
• 1997

투명전도성 산화주석 박막이 펄스레이저증착에 의하여 파이렉스유리 기판상에 제조 되었다. 진공, $O_2$, 및 $Sn(CH_3)_4$분위기에서 Nd-YAG레이저 빛살이 다결정 $SnO_2$ 타겟을 융제 하여 실온에서 기판상에 박막을 증착시키고, 증착된 막을 230, 420, 및 $610^{\circ}C$에서 각각 2시 간 동안 공기중에서 열처리하였다. 박막의 특성이 UV-VIS-NIR 분광법과 X-선 회절법에 의하여 조사되고, 전기적 성질이 촉심식법으로 구해진 막의 두께와 함께 사점탐침법에 의하 여 측정되었다. $Sn(CH_3)_4$이 존재할 때 $SnO_2$상들이 실온에서조차 성장되는 것이 관찰되었다. 이는 레이저 융제 동안 발생된 마이크로플라즈마가 전구물질분자의 분해에 중요한 역할을 함을 시사한다.

• 한국표면공학회지
• /
• 제43권2호
• /
• pp.105-110
• /
• 2010

Electroless nickel plating on porous carbon substrate for the application of MCFC electrodes was investigated. Acidic and alkaline bath were used for the electroless nickel plating. The pore sizes of carbon substrates were 16-20 ${\mu}m$ and over 20 ${\mu}m$. The carbon surface was changed from hydrophobic to hydrophilic after immersing the substrate in an ammonia solution for 40 min at $60^{\circ}C$. The contact angle of water was decreased from $85^{\circ}C$ to less than $20^{\circ}$ after ammonia pretreatment. The deposition rate in the alkaline bath was higher than that in the acidic bath. The deposition rate was increased with increasing pH in both acidic and alkaline bath. The content of phosphorous in nickel deposit was decreased with increasing pH in both acidic and alkaline bath. The contents of phosphorous is low in alkaline bath. The minimum concentration of $PdCl_2$ for the electroless nickel plating was 10 ppm in alkaline bath and 5 ppm in acidic bath. The thickness of nickel was not affected by the concentration of $PdCl_2$.

• 한국표면공학회지
• /
• 제36권4호
• /
• pp.296-300
• /
• 2003

Extended cylindrical magnetron sputtering system with rotating 600-mm long and 90-mm diameter graphite cathode and pulsed power supply voltage generator were developed and fabricated. Time-dependent Langmuir probe characteristics as well as carbon films thickness were measured. It was shown that ratio of ions flux to carbon atoms flux for pulsed magnetron discharge mode was equal to $\Phi_{i}$ $\Phi$sub C/ = 0.2. It did not depend on the discharge current in the range of $I_{d}$ / = 10∼60 A since both the plasma density and the film deposition rate were found approximately proportional to the discharge current. In spite of this fact carbon film structure was found to be strongly dependent on the discharge current. Grain size increased from 100 nm at $I_{d}$ = 10∼20 A to 500 nm at $I_{d}$ = 40∼60 A. To deposit fine-grained hard nanocrystalline or amorphous carbon coating current regime with $I_{d}$ = 20 A was chosen. Pulsed negative bias voltage ($\tau$= 40 ${\mu}\textrm{s}$, $U_{b}$ = 0∼10 ㎸) synchronized with magnetron discharge pulses was applied to a substrate and voltage of $U_{b}$ = 3.4 ㎸ was shown to be optimum for a hard carbon film deposition. Lower voltages were not sufficient for amorphization of a growing graphite film, while higher voltages led to excessive ion bombardment and effects of recrystalization and graphitization.

• 한국표면공학회지
• /
• 제47권6호
• /
• pp.303-310
• /
• 2014

In this study, the average in-situ stress in metallic thin film was measured during deposition of the Cu thin films on the Si(111) wafer and then the phenomenon of stress shift by the interruption of deposition was measured using Cu thin films. We have observed the stress shift in accordance with changing amount of atom's movement between the surface and grain boundary through altering the grain size of the Cu thin film with variety of parameters. The grain size is known to be affected on the deposition rate, film thickness and deposition temperature. As a experimental results, the these parameters was not adequate to explain stress shift because these parameters affect directly on the amount of atom's movement between the surface and grain boundary as well as the grain size. Thus, we have observed the stress shift toward tensile side in accordance with the grain size changing through the interlayer deposition. From an experiment with inserting interlayer before deposit Cu, in thin film which has big grain size with high roughness, amount of stress movement is higher along direction of tensile stress after deposition that means, after deposition process, driving force of atoms moving in grain boundary and on the surface of the film is relatively higher than before.

• Nuclear Engineering and Technology
• /
• 제53권5호
• /
• pp.1676-1685
• /
• 2021

We develop a new high-fidelity multiphysics model to simulate boron chemistry in the porous Chalk River Unidentified Deposit (CRUD) deposits. Heat transfer, capillary flow, solute transport, and chemical reactions are fully coupled. The evaporation of coolant in the deposits is included in governing equations modified by the volume-averaged assumption of wick boiling. The axial offset anomaly (AOA) of the Seabrook nuclear power plant is simulated. The new model reasonably predicts the distributions of temperature, pressure, velocity, volumetric boiling heat density, and chemical concentrations. In the thicker CRUD regions, 60% of the total heat is removed by evaporative heat transfer, causing boron species accumulation. The new model successfully shows the quantitative effect of coolant evaporation on the local distributions of boron. The total amount of boron in the CRUD layer increases by a factor of 1.21 when an evaporation-driven increase of soluble and precipitated boron concentrations is reflected. In addition, the concentrations of B(OH)₃ and LiBO₂ are estimated according to various conditions such as different CRUD thickness and porosity. At the end of the cycle in the AOA case, the total mass of boron incorporated in CRUD deposits of a reference single fuel rod is estimated to be about 0.5 mg.

• 터널과지하공간
• /
• 제33권3호
• /
• pp.126-140
• /
• 2023

본 연구에서는 석회석 광산에서 발생한 지반침하지에 대해 라이다 기반 정밀 형상 모델을 활용하여 침하 원인을 분석하였다. 드론 및 지상 기반 라이다 시스템을 활용하여 침하지 지표 및 갱도에 대한 정밀 형상 모델 구축을 수행하고 현장 지질조사 및 암반 분류 결과를 활용하였다, 정밀 형상 모델을 통해 침하지 주변부 크라운필러 두께 및 단층 분포, 침하지 및 침하 적치물 부피 계산, 침하 지표 경사 분석을 수행하였다. 이와 같은 분석을 통해 석회석 광산에서 발생한 지반침하 원인을 규명하였다.

• 한국토양비료학회지
• /
• 제42권5호
• /
• pp.364-370
• /
• 2009

벼 재배시 하해혼성층 논토양의 전북통과 지산통 작토층과 경반층의 특성을 2년간(2005~2006)조사 분석한 결과를 요약하면 다음과 같다. 하해혼성층적층 대표토양인 전북통과 곡간충적층 대표토양인 지산통을 10개소에서 조사한 결과 작토심은 전북통 12.6 cm, 지산통 12.7 cm 이었고 플라우 경운깊이는 120필지에서 조사한 결과 10.5 cm 이었으며 전북통에서 경도와 작토심과는 부의 상관을, 경도와 경반층 두께와는 정의 상관을 나타냈다. 경반층 경도는 전북통 $14.7kg\;cm^{-2}(25.3mm)$, 지산통 $8.7kg\;cm^{-2}(22.1mm)$ 이었고, 두께는 전북통 22.3 cm, 지산통 17.8 cm 이었으며 경반층 출현깊이는 전북통 15 cm, 지산통 20 cm에 있었다. 경반층 지온은 작토층과의 차이를 보면 전북통에서는 봄 $-2.0^{\circ}C$, 여름 $-2.5^{\circ}C$, 가을 $-1.0^{\circ}C$를 지산통은 봄 $-2.1^{\circ}C$, 여름 $-1.8^{\circ}C$, 가을 $-0.7^{\circ}C$를 나타냈고 전북통에서 산화환원전위차 변화는 작토층은 유수형성기부터 환원상태를 경반층은 출수후기까지 산화상태를 나타냈다. 토양물리성은 두 토양통 공히 경반층에서 용적밀도, 고상율이 높고 공극율, 기상율이 낮았다. 또한 토양화학성은 경반층에서 총질소가 낮았고, 유기물 및 유효 인산함량이 적은 반면에 pH가 높고, 유효규산, 치환성칼슘 및 마그네슘 함량이 많았다. 양이온치환용량은 전북통에서 작토층 및 경반층 비슷한 경향이었으나 지산통은 경반층에서 다소 낮은 경향을 나타냈다. 무기태질소 함량은 토양통 공히 작토층에서 많았고, 가용성 미량성분 함량은 경반층에서 많았으며 지산통에서 많은 경향을 나타냈다. 감수심은 전북통에서 심경구, 지산통 경운구는 로타리구보다 빠르고, 계절별 감수심 변화는 6월 하순까지는 감수심이 빨랐으나 7~8월에는 1~3 mm로 늦었으며 9월부터는 빠른 경향을 나타냈다. 벼 뿌리분포는 로타리 25 cm, 심경 30 cm, 경운 20 cm까지 신장하였고, 출수기 뿌리 건물중은 심경>로타리>경운 순으로 무거웠다.

• 한국지반환경공학회 논문집
• /
• 제4권4호
• /
• pp.61-71
• /
• 2003

실트질 점토로 이루어진 연약지반의 호안 제방축조는 성토 제방하중에 의한 연약지반내 강제치환 공법으로 이루어지고 있으며, 축조 제방하부 강제치환 깊이는 호안 제방의 안정성에 큰 영향을 미치고 있다. 기존의 제방하부 강제치환 깊이 산정방법은 하부 연약점토지반의 비배수 전단강도 증분율을 고려한 제방하부 연약지반의 지지력과 성토제방 하중에 의해 산정하고 있다. 그러나 지반 층후 특성에 따라 중간층 형태의 점토질 실트층 또는 모래층이 있는 경우가 있으며, 이러한 점토질 실트층 또는 모래층은 제방하부 연약지반의 지지력에 영향을 미치게 되어 강제치환 깊이에 영향을 미치게 된다. 본 논문에서는 중간 모래층이 있는 연약지반내 제방 축조시 강제치환 깊이를 Perloff et al.(1967) 영향계수를 고려한 성토제방 하중과 층두께 가중평균 지지력(Bowles, 1988)에 의해 산정하였으며, 수치해석(FLAC)적 방법에 의한 산정결과와 비교 분석하였다. 해석결과 제방하부 접지폭이 $0.2B_o$(중간 모래층), $0.5B_o$(단일층)인 경우 산정된 강제치환 깊이는 수치해석과 매우 근접하는 것을 알 수 있었으며, 제방 하부 접지폭의 영향보다 비배수 전단강도 및 중간 모래층 두께, 중간 모래층 위치의 영향이 큰 것을 알 수 있었다. 또한 중간 모래층 두께가 작을수록 강제치환 깊이는 증가하며, 중간 모래층 위치가 증가 할수록 강제치환 깊이는 증가하고, 비배수 전단강도가 감소할수록 강제치환 깊이가 증가하는 것을 알 수 있었다.