• Title/Summary/Keyword: Deposit Ratio

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Fabrication of SmBCO Coated Conductors using IBAD-MgO Template (IBAD-MgO 템플릿을 이용한 SmBCO 박막선재의 제조)

  • Ha, Hong-Soo;Kim, Ho-Sup;Yang, Ju-Saeng;Jung, Yae-Hyun;Kim, Ho-Kyum;Yoo, Kwon-Kuk;Ko, Rock-Kil;Song, Kyu-Jeong;Ha, Dong-Woo;Oh, Sang-Soo;Yeom, Do-Jun;Park, Chan;Yoo, Sang-Im;Moon, Seong-Hyun;Joo, Jin-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.30-31
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    • 2006
  • We have fabricated SmBCO coated conductor on IBAD-MgO substrates using unique co-evaporation method. The batch type co-deposition system was specially designed and named as EDDC(evaporation using drum m dual chamber) that is possible to deposit superconducting layer with different composition ratio at low temperature of $700^{\circ}C$. In this study, we have investigated the influence of SmBCO phase composition and texture of IBAD-MgO template on the critical current density. We have changed the deposition rates of Sm, Ba and Cu during co-evaporation to examine the optimal composition ratio shown better critical current density. The composition ratio and surface morphology of SmBCO coated conductors were analyzed by the EDX and SEM, respectively. A higher critical current density was measured at superconducting phase composition ratio of Ba deficiency, Sm or Cu rich compared to the Sm1Ba2Cu3Ox stoichiometry.

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Evaluation of Stress Distribution Ratio According to Clay Ground Condition and Stone Column Characteristics (점토지반 조건 및 쇄석말뚝 특성에 따른 응력분담비 산정)

  • Kim, Dong-Eun;Park, Hyun-Il;Lee, Seung-Rae;You, Sang-Ho
    • Journal of the Korean Geotechnical Society
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    • v.24 no.11
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    • pp.35-41
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    • 2008
  • Stone columns, one of the soft ground improvement techniques, are being used for not only accelerating consolidation but also increasing bearing capacity of soft grounds. In this study, in order to observe the stress distribution characteristics which are one of the important factors to estimate the settlement reduction of the soft ground, lab-scale experiments were performed in stone column reinforced clay ground. The stress distribution ratio of stone column decreased with the lapse of time after surcharge loading but increased as the stiffness of clay deposit increases. It shows that the modified Baumann and Bauer's solution, which is able to easily predict the stress distribution ratio of stone column reinforced soft ground, exhibits reasonable agreement with the measured data.

A Study of Hydrodynamic Dispersions in the Unsaturated and the Saturated Zone of a Multi-soil Layer Deposit Using a Continuous Injection Tracer Test (복합토양층의 불포화대와 포화대에서 연속주입 추적자시험을 이용한 수리분산특성 연구)

  • Chung, Sang-Yong;Kang, Dong-Hwan;Lee, Min-Hee;Son, Joo-Hyong
    • Journal of Soil and Groundwater Environment
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    • v.11 no.4
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    • pp.48-56
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    • 2006
  • Using a continuous injection tracer test at a multi-soil layer deposit, the difference of hydrodynamic dispersions in unsaturated and saturated zones were analyzed through breakthrough curves of Rhodamine WT, linear regression of concentration versus time, concentration variation rates versus time, and concentration ratio according to the distance from injection well. As a result of continuous injection tracer test, the difference of the maximum concentrations of Rhodamine WT in unsaturated and saturated zones were 13-15 times after 160 hours, and the increased rate of concentration versus time in unsaturated zone was about 10 times higher than in saturated zone. The fluctuation of Rhodamine WT breakthrough curve and concentration variation rate with time in saturated zone were larger than in unsaturated zone. Rhodamine WT concentration ratio with the distance from the injection well in saturation zone was linearly decreased faster than in unsaturated zone, and the elapsed time necessary for the concentration ratio less than 2 was longer in saturation zone. The differences resulted from the lower concentration and slower hydrodynamic dispersion of Rhodamine WT at the saturation zone of the multi-soil layer deposit, in which groundwater flow significantly flow and aquifer materials have high hydraulic heterogeneity. Effective porosity, longitudinal and transverse dispersivities were estimated $10.19{\sim}10.50%,\;0.80{\sim}1.98m$ and $0.02{\sim}0.04m$, respectively. The field longitudinal dispersivity is over 12 times larger than the laboratory longitudinal dispersivity by the scale-dependent effect.

An Experimental Study for the Falling Test and Upwelling Effect of the Artificial Upwelling Structures in Flow Field (흐름장에서 인공용승구조물의 블록투하 및 용승효과에 관한 실험적 연구)

  • Jeon, Yong-Ho;Lee, Gyung-Sun;Kang, Yoon-Koo;Ryu, Cheong-Ro
    • Journal of Ocean Engineering and Technology
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    • v.21 no.4
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    • pp.21-27
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    • 2007
  • The multiplication equipment of marine products with artificial upwelling structures could be useful in the fishing grounds near coastal areas. Artificial upwelling structures could move the inorganic nutrients from the bottom to the surface. Artificial upwelling structures have been used to improve the productivity of fishing grounds. Until now, research on artificial upwelling structures has been related to the distribution of the upwelling region, upwelling structures, and the marine environment. However, little work on the optimum design of the rubber-mound artificial upwelling structures has been done to increase the efficiency of drawing up the inorganic nutrients. This study investigated the optimum cross-section of rubber-mound artificial upwelling structures by means of hydraulic experiments. The hydraulic experiments include the falling test of rubber. Based on the results of the falling test, the relationship between the length of the rubber mound and water velocity, and the relationship between the shape of the rubber and the stratification parameter were established. In addition, the effect of the void ratio of various artificial structures on the stratification parameter was studied. From the experiment, it was found that upwelling could be enhanced when the ratio of structure height to water depth was 0.3 and stratification parameter was 3.0. The upwelling was not improved when the void ratio exceeded 0.43. The optimum size of rubber mounds was determined when the incident velocity was influenced by the mean horizontal length rather than size of block.

A Study on the Laser Melting Deposition of Mixed Metal Powders to Prevent Interfacial Cracks (레이저 용융 금속 적층 시 결함 방지를 위한 혼합 분말 적층에 관한 연구)

  • Shim, D.S.;Lee, W.J.;Lee, S.B.;Choi, Y.S.;Lee, K.Y.;Park, S.H.
    • Transactions of Materials Processing
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    • v.27 no.1
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    • pp.5-11
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    • 2018
  • Direct energy deposition (DED) technique uses a laser heat source to deposit a metal layer on a substrate. Many researchers have used the DED technique to study the hardfacing of molds and dies. The aim of this study is to obtain high surface hardness and a sound bonding between the AISI M4 deposits and a substrate utilizing a mixed powder that contains M4 and AISI P21 powders. To prevent interfacial cracks between the M4 deposits and the substrate, the mixed powder is pre-deposited onto a JIS S45C substrate, before the deposition of M4 powders. Interfacial defects occurring between the deposits and substrate and changes in the microhardness of the intermediate layer were examined. Observations of the cross-sections of deposited specimens revealed that the interfacial cracks appeared in samples with one and two mixed layers regardless of the mixture ratio. However, the crack was removed by increasing the mixture ratio and the number of intermediate layers. Meanwhile, the microhardness in the mixed layer was found to decrease with increasing ratio of P21 powder in the mixture and that in the upper region of the deposited layers was approximately 800 HV, which was attributed to various alloying elements in the M4 powder.

Effects of Current Density and Organic Additives on via Copper Electroplating for 3D Packaging (3D패키지용 Via 구리충전 시 전류밀도와 유기첨가제의 영향)

  • Choi, Eun-Hey;Lee, Youn-Seoung;Rha, Sa-Kyun
    • Korean Journal of Materials Research
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    • v.22 no.7
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    • pp.374-378
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    • 2012
  • In an effort to overcome the problems which arise when fabricating high-aspect-ratio TSV(through silicon via), we performed experiments involving the void-free Cu filling of a TSV(10~20 ${\mu}m$ in diameter with an aspect ratio of 5~7) by controlling the plating DC current density and the additive SPS concentration. Initially, the copper deposit growth mode in and around the trench and the TSV was estimated by the change in the plating DC current density. According to the variation of the plating current density, the deposition rate during Cu electroplating differed at the top and the bottom of the trench. Specifically, at a current density 2.5 mA/$cm^2$, the deposition rate in the corner of the trench was lower than that at the top and on the bottom sides. From this result, we confirmed that a plating current density 2.5 mA/$cm^2$ is very useful for void-free Cu filling of a TSV. In order to reduce the plating time, we attempted TSV Cu filling by controlling the accelerator SPS concentration at a plating current density of 2.5 mA/$cm^2$. A TSV with a diameter 10 ${\mu}m$ and an aspect ratio of 7 was filled completely with Cu plating material in 90 min at a current density 2.5 mA/$cm^2$ with an addition of SPS at 50 mg/L. Finally, we found that TSV can be filled rapidly with plated Cu without voids by controlling the SPS concentration at the optimized plating current density.

Influence of Na/Al Ratio and Curing Temperature of Geopolymers on Efflorescence Reduction (Na/Al 비와 양생온도가 지오폴리머의 백화억제에 미치는 영향)

  • Kim, Byoungkwan;Heo, Ye-Eun;Chon, Chul-Min;Lee, Sujeong
    • Resources Recycling
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    • v.27 no.6
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    • pp.59-67
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    • 2018
  • Efflorescence is a white deposit of powders in the surface of cement concrete which can also occur in geopolymers. Efflorescence occurs when sodium ions in alkali activator react with atmospheric carbon dioxide to form sodium carbonate components. In this study, we investigated whether the secondary efflorescence can be reduced by controlling the Na/Al mole ratio or by changing the curing temperature and heat curing time in fly ash-based geopolymers. The 28 days compressive strength in geopolymers having Na/Al ratio of 1.0 was higher than geopolymers having Na/Al ratio of 0.8. The strength increased with the increasing curing temperature and longer heat curing time. On the other hand, efflorescence was lower when the curing temperature was high and the heat curing time was longer in the geopolymers having Na/Al ratio of 1.0. The geopolymers having Na/Al ratio of 0.8 showed accelerated efflorescence occurrence than the geopolymers having Na/Al ratio of 1.0. In order to reduce the occurrence of the secondary efflorescence of fly ash-based geopolymers, it will be advantageous to maintain the Na/Al ratio at 1.0, increase the curing temperature, and lengthen the heating curing time.

Growth characteristics of titanium boride($\textrn{TiB}_{x}$) thin films deposited by dual-electron-beam evaporation (2원전자빔 증착법에 의한 티타늄붕화물($\textrn{TiB}_{x}$) 박막의 성장특성)

  • 이영기;이민상;임철민;김동건;진영철
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.11 no.1
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    • pp.20-26
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    • 2001
  • Titanium boride ($\textrn{TiB}_{x}$) films were deposited on (100) silicon substrates at the substrate temperature of $500^{\circ}C$ by means of the co-evaporation of titanium and boron evaporants during deposition. The co-evaporation method makes it possible to deposit the non-stoichiometric films with different boron-to-titanium ratio($0{\le}B/Ti \le 2.5$). The resistivity increases linearly as the boron-to-titanium ratio in the as-deposited films is increased. The surface roughness of $\textrn{TiB}_{x}$ films is changed as a function of the boron-to-titanium ratio. The XRD spectrum for pure titanium film shows a highly (002) preferred orientation. For B/Ti=0.59 ratio only a single TiB phase that shows a (111) preferred orientation is observed. However, the $\textrn{TiB}_{x}$ phase with the hexagonal structure of the $AlB_2$(C32) type appears as the boron concentration increase, and only a single $\textrn{TiB}_{x}$ phase is observed for $B/Ti \ge 2.0$ ratio. The $\textrn{TiB}_{x}$/Si samples reveal a tensile stress (3~$20{\times}^9$dyn/$\textrm{cm}^2$) in the overall composition of the films, although the magnitude of the residual stresses is depended on the nominal B/Ti ratio.

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Mesozoic Granitoids and Associated Gold-Silver Mineralization in Korea (한국 중생대 화강암류와 이에 수반된 금-은광화작용)

  • 최선규;박상준;최상훈;신홍자
    • Economic and Environmental Geology
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    • v.34 no.1
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    • pp.25-38
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    • 2001
  • Contrasts in the style of the gold-silver mineralization in geologic and tectonic settings in Korea, together with radiometric age data, reflect the genetically different nature of hydrothermal activities, coinciding with the emplacement age and depth of Mesozoic magmatic activities. It represents a clear distinction between the plutonic settings of the Jurassic Daebo orogeny and the subvolcanic environments of the Cretaceous Bulgugsa igneous activities. During the Daebo igneous activities (about 200-130 Ma) coincident with orogenic time, gold mineralization took place between 197 and 127 Ma. The Jurassic deposits commonly show several characteristics: prominent association with pegmatites, low Ag/Au ratios in the ore-concentrating parts, massive vein morphology and a distinctively simple mineralogy including Fe-rich sphalerite, galena, chalcopyrite, Au-rich eIectrum. pyrrhotite and/or pyrite. During the Bulgugsa igneous activities (120-60 Ma), the precious-metal deposits are generally characterized by such features as complex vein morphology, medium to high AgiAu ratios in the ore concentrates, and abundance of ore minerals including base-metal sulfides, Ag sulfides, native silver, Ag sulfosalts and Ag tellurides. Vein morphology, mineralogical, fluid inclusion and stable isotope results indicate the diverse genetic natures of hydrothermal systems. The Jurassic Au-dominant deposits were formed at the relatively high temperature (about 300 to 450$^{\circ}$C) and deep-crustal level (>3.0 kb) from the hydrothermal fluids containing more amounts of magmatic waters (3180; 5-10 %0). It can be explained by the dominant ore-depositing mechanisms as CO2 boiling and sulfidation, suggestive of hypo/mesothermal environments. In contrast, mineralization of the Cretaceous Au-Ag type (108-71 Ma) and Agdominant type (98-71 Ma) occurred at relatively low temperature (about 200 to 350$^{\circ}$C) and shallow-crustal level «1.0 kb) from the ore-fonning fluids containing more amounts of less-evolved meteoric waters (15180; -10-5%0). These characteristics of the Cretaceous precious-metal deposits can be attributed to the complexities in the ore-precipitating mechanisms (mixing, boiling, cooling), suggestive of epilmesothermal environments. Therefore, the differences of the emplacement depth between the Daebo and the Bulgugsa igneous activities directly influence the unique temporal and spatial association of the deposit type.

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Preliminary Study of Oxidized Au skarn Model in the Geodo Mine Area to Mineral Exploration (광물자원탐사를 위한 거도광산지역의 산화형 스카른 금광상모델 예비연구)

  • Kim, Eui-Jun;Park, Maeng-Eon;Sung, Kyul-Youl
    • Economic and Environmental Geology
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    • v.42 no.4
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    • pp.289-300
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    • 2009
  • The Geodo mine area, had been developed for Fe and Cu ores since 1963 and abandoned in recent decades, is located in the central part of the Taebaeksan mineralized district. This area comprises of the Jangsan, Myobong, Pungchon, Hwajeol, Dongjeom, and Dumugol Formations in ascending stratigraphic order. These Formations were intruded by the Cretaceous Eopyeong granitoids that appears to produce the Geodo skarn. Their compositions are relatively oxidized quartz monzodiorite to granodiorite (magnetite series, $Fe_2O_3/FeO=0.3{\sim}1.1$). Mineralizations related skarn deposit occur in the Myobong, Pungchon, and Hwajeol Formations. The proximal skarn is zoned from andraditic garnet ($Ad_{44-95}Gr_{1-53}$) predominant adjacent to the Eopyeong granitoids to diopsidic pyroxene ($Hd_{10-100}Di_{0-89}$) predominant away from the one. The differential proportion of garnet and pyroxene is generated by water/rock ratio and their source, such as magmatic and meteoric water. This is useful tool for assessment the overall oxidation state of the entire skarn system. Gold occurs in proximal red to brownish garnet skarn, and genetically associated with Bi- and Te-bearing minerals. Skarn deposit developed in the Geodo mine area is considered as oxidized Au skarn category, based on chemical composition of the Eopyeong granitoids, zonation of skarn, and gold occurrences. Garnet-rich skarn zone will be the main target for exploration of gold in the study area. However, it is needed to the detailed survey on vertical zonation of this area as well as lateral zonation. The result of this survey would provide an important basis for the exploration of the skarn Au deposit in the Geodo mine area.